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Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006117
EISBN: 978-1-62708-175-7
... Abstract Sintering is a thermal treatment process in which a powder or a porous material, already formed into the required shape, is converted into a useful article with the requisite microstructure. Sintering can be classified as solid-state, viscous, liquid-phase, and pressure-assisted...
Abstract
Sintering is a thermal treatment process in which a powder or a porous material, already formed into the required shape, is converted into a useful article with the requisite microstructure. Sintering can be classified as solid-state, viscous, liquid-phase, and pressure-assisted (or pressure) sintering. This article provides information on the mechanisms and theoretical analysis of sintering and focuses on the types, mechanisms, process and microstructural variables, computer simulation, stages, and fundamentals of densification and grain growth of solid-state sintering and liquid-phase sintering. It describes the models for viscous sintering and the methods used in pressure-assisted sintering, namely, uniaxial hot pressing, hot isostatic pressing, sinter forging, and spark plasma sintering.
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Published: 30 September 2015
Fig. 30 The conceptual outline of supersolidus liquid-phase sintering densification for three particles: (a) initial particle packing, (b) formation of initial liquid with insufficient wetting of grain boundaries for densification, (c) viscous flow densification of semisolid particles, and (d
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Series: ASM Handbook
Volume: 24
Publisher: ASM International
Published: 15 June 2020
DOI: 10.31399/asm.hb.v24.a0006580
EISBN: 978-1-62708-290-7
... without fully melting. This sintering process is a viscous flow mechanism. Surface energy/tension is minimized, driven by thermal energy, and the surfaces of each road go through a process called necking. Ultimately, when the sintering process is complete, an entropy-driven intermixing of molecular...
Abstract
Material extrusion systems are the most common types of additive manufacturing systems, also known as three-dimensional (3D) printers. This article focuses on the general 3D printing processes as can be demonstrated and manipulated in desktop printers. The discussion includes details of the components involved in material extrusion as well as the melt extrusion solidification (during cooling) process, the underlying mechanism of road bonding, and the factors affecting good part quality. The discussion also covers support material, postprocessing, and road-quality considerations and the addition of infill in melt extrusion to the hollow spaces inside an object to give it structural strength. Information is also provided on different materials and associated material properties that affect the rate the printer is able to advance and retract material, thereby affecting the quality and rate at which a part is printed. The final section provides information on the mechanism of viscous extrusion 3D printing.
Series: ASM Handbook
Volume: 24
Publisher: ASM International
Published: 15 June 2020
DOI: 10.31399/asm.hb.v24.a0006543
EISBN: 978-1-62708-290-7
..., destroying weak interfaces between prior particle boundaries. Residual porosity is reduced by extended exposure to elevated temperature. Additionally, viscous sintering allows flow and bonding of the polymer melt. Thermal issues are less extensive for areal PBF of polymers compared with point-source PBF...
Abstract
Powder bed fusion (PBF) of polymers is a collection of additive manufacturing processes that melt and fuse polymer in a powder bed. This article provides a complete suite of materials and processes involved in PBF of polymers. The discussion includes details of thermal and manufacturing issues, and safety, postprocessing, and finishing considerations, as well as of principal defects in PBF polymer parts and the mechanical properties of the parts produced by PBF. The article provides case studies on the applications of polymer PBF.
Series: ASM Handbook
Volume: 24
Publisher: ASM International
Published: 15 June 2020
DOI: 10.31399/asm.hb.v24.a0006550
EISBN: 978-1-62708-290-7
... a separate debinding heat treatment step. Finally, the part is sintered to obtain final density. These steps are shown in Fig. 1 . Fig. 1 Generic flowpath for material jetting of ceramics The distinguishing attribute of material jetting, which simplifies handling, is that the part material...
Abstract
This article discusses the advantages, limitations, and applications of material jetting of ceramics, focusing on two primary methods of droplet formation: continuous stream and drop on demand (thermal and piezoelectric) ink jetting processes.
Series: ASM Handbook
Volume: 22B
Publisher: ASM International
Published: 01 November 2010
DOI: 10.31399/asm.hb.v22b.a0005502
EISBN: 978-1-62708-197-9
... such as surface diffusion, grain-boundary diffusion, volume diffusion, viscous flow (for amorphous materials), plastic flow (for crystalline materials), evaporation condensation, and rearrangement. For industrial application, the phenomenological models are used for sintering simulations with the following key...
Abstract
This article presents the governing equations and methodologies to model the press and sinter powder metallurgy, including continuum, micromechanical, multiparticle, and molecular dynamics approaches. It describes the constitutive relation for compaction and sintering. The article discusses the experimental determination of material properties and simulation verification for compaction and sintering. It reviews the use of modeling and simulation of press and sinter powder metallurgy, including gravitational distorting in sintering, compaction optimization, sintering optimization, and coupled press and sinter optimization.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006033
EISBN: 978-1-62708-175-7
... et al. ( Ref 17 , 19 ), Riedel et al. ( Ref 13 , 26 , 27 ), Bouvard and Meister ( 28 ), Cocks ( 29 ), Kwon et al. ( Ref 30 , 31 ), and Bordia and Scherer ( Ref 32 , Ref 33 , Ref 34 ) based on a sintering mechanism such as surface diffusion, grain-boundary diffusion, volume diffusion, viscous...
Abstract
This article discusses continuum modeling, which is the most relevant approach in modeling grain growth, densification, and deformation during sintering. Continuum plasticity models are frequently used to describe the mechanical response of metal powders during compaction. The article illustrates the typical procedure for computer simulation for press and sinter process. It describes the procedure to obtain the material properties based on the generalized Shima-Oyane model. The article presents a wide variety of tests, accounting for data on the grain growth, densification, and distortion where these data help in the development of a constitutive model for sintering simulation. Finally, the article provides information on the simulation approaches used to optimize die compaction and sintering.
Series: ASM Handbook
Volume: 22B
Publisher: ASM International
Published: 01 November 2010
DOI: 10.31399/asm.hb.v22b.a0005503
EISBN: 978-1-62708-197-9
...) and polymer binders. The particles are small to aid in sintering densification and often have near-spherical shapes to improve flow and packing. The thermoplastic binders are mixtures of waxes, polymers, oils, lubricants, and surfactants. When molten, the binder imparts viscous flow characteristics...
Abstract
This article focuses on the axisymmetric 2.5-dimensional approach used in metal powder injection molding (PIM) simulations. It describes three stages of PIM simulations: filling, packing, and cooling. The article discusses the process features of numerical simulation of PIM, such as filling and packing analysis, cooling analysis, and coupled analysis between filling, packing, and cooling stages. It explains the experimental material properties and verification for filling, packing, and cooling stages in the PIM simulations. The article presents simulation results from some of the 2.5-dimensional examples to demonstrate the usefulness of the computer-aided engineering analysis and optimization capability of the PIM process.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006106
EISBN: 978-1-62708-175-7
... of the multitude of variables that influence sintering. The major factors that influence sintering response can be classified in terms of transport mechanisms, reaction types, and sintering parameters. These factors include viscous flow, surface diffusion, lattice or volume diffusion, grain-boundary diffusion...
Abstract
Bronze and brass alloys are two key classes of materials in copper-base powder metallurgy applications. They are often compacted using mechanical or hydraulic pressing machines. This article provides an overview of the powder pressing process, providing information on the powder properties of bronze and brass and the roles of lubricant and compaction dies in the pressing process. It discusses the structural defects that originate during the compaction process. The article also describes the major factors that influence the sintering response in bronze, prealloyed bronze, brass, and nickel-silver.
Series: ASM Handbook
Volume: 24
Publisher: ASM International
Published: 15 June 2020
DOI: 10.31399/asm.hb.v24.a0006562
EISBN: 978-1-62708-290-7
... parts, followed by sintering to obtain the final dense part. Processes Two feedstock forms used in material extrusion-based ceramic additive manufacturing (MECAM) are paste and filament. The paste-form feedstock is extruded by mechanisms capable of dispensing a viscous fluid, such as the positive...
Abstract
This article is a review of the material extrusion-based ceramic additive manufacturing (MECAM) processes. The discussion begins with details of extrusion with filament and paste, covering the most popular variants of paste extrusion-based MECAM techniques that can be differentiated based on paste type and the method of shape retention of the deposited layer: extrusion freeforming, robocasting ceramic on-demand extrusion, and freeze-form extrusion fabrication. The article then focuses on post-processing considerations and the mechanical properties of sintered ceramic parts. It concludes with information on innovation opportunities in ceramic additive manufacturing, such as incorporating UV-curing and gelation in the process and producing geometrically complex structures from shapeable green bodies.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003054
EISBN: 978-1-62708-200-6
... Abstract Sintering provides the interparticle bonding that generates the attractive forces needed to hold together the otherwise loose ceramic powder mass. It also improves hardness, strength, transparency, toughness, electrical conductivity, thermal expansion, magnetic saturation, corrosion...
Abstract
Sintering provides the interparticle bonding that generates the attractive forces needed to hold together the otherwise loose ceramic powder mass. It also improves hardness, strength, transparency, toughness, electrical conductivity, thermal expansion, magnetic saturation, corrosion resistance, and other properties. This article discusses the fundamentals of sintering and its effects on pore structures and particle density. It addresses some of the more common sintering methods, including solid-state, liquid-phase, and gas pressure sintering, and presents alternative processes such as reaction sintering and self-propagating, high-temperature synthesis. It also describes several pressure densification methods, including hot isostatic pressing, gas pressure sintering, molten particle deposition, and sol-gel processing. The article concludes with a section on grain growth that discusses the underlying mechanisms and kinetics and the relationship between grain growth and densification.
Series: ASM Handbook
Volume: 8
Publisher: ASM International
Published: 01 January 2000
DOI: 10.31399/asm.hb.v08.a0003287
EISBN: 978-1-62708-176-4
..., and viscous glide of dislocations is the rate-controlling process. The principal interaction mechanisms that impede dislocation glide include segregation of solute atoms to dislocations, the destruction of short-range atomic order by gliding dislocations, and chemical interaction of solute atoms...
Abstract
Creep deformation is normally studied by applying either a constant load or a constant true stress to a material at a sufficiently high homologous temperature so that a measurable amount of creep strain occurs in a reasonable time. This article provides the phenomenological descriptions of creep and explains the testing and mechanism of creep in crystalline solids. It also presents information on the creep response of crystalline and amorphous solids.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006111
EISBN: 978-1-62708-175-7
... response can be classified in terms of diffusion mechanisms, reaction types, and sintering parameters. These major factors include the following variables. The mechanism of diffusion includes: Viscous flow Surface diffusion Lattice or volume diffusion Grain-boundary diffusion...
Abstract
This article provides information on the most frequently used atmospheres in commercial sintering of powder metallurgy iron and steel materials. These include endothermic, exothermic, dissociated ammonia, pure hydrogen, and nitrogen-base atmospheres. The article discusses sintering of iron and iron-graphite powder, iron-copper and iron-copper graphite, and alloy steels. The effects of various sinter conditions on the amount of combined carbon formed in the steel are also discussed. The article concludes with information on high-temperature sintering and sinter hardening.
Series: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006887
EISBN: 978-1-62708-392-8
... techniques such as selective laser sintering, binder jet printing, and direct ink writing ( Ref 5 - 7 ). Biological materials with organic or inorganic constituents have been selected and used. Geometric distributions should be modulated according to individual osseous tissues ( Ref 8 ). Bioscaffold...
Abstract
Stereolithographic (STL) additive manufacturing (AM) can be used to fabricate practical components. This article discusses the processes involved in STL-AM of biological scaffolds, providing information on bioscaffold processing, cavity arrangements, and microlattice distributions. Within the last topic, the sub-topic of scaffold modulation is discussed.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006674
EISBN: 978-1-62708-213-6
... an application such as reactive sintering but should always be used with great caution, typically with the instrument inside a fume hood or glove box. Temperature Range The temperature range of TMA spans cryogenic (approximately −150 °C, or −240 °F) to 2400 °C (4350 °F), but no single instrument...
Abstract
Thermomechanical analysis (TMA) is a thermal analysis technique in which the length of a specimen is precisely measured versus temperature and time as the specimen is subjected to controlled heating and cooling. This article discusses the various factors and processes involved in TMA. The discussion covers the general principles, equipment used, specimen preparation process, calibration conditions, data analysis steps, and examples of the applications and interpretation of TMA.
Series: ASM Handbook
Volume: 24
Publisher: ASM International
Published: 15 June 2020
DOI: 10.31399/asm.hb.v24.a0006578
EISBN: 978-1-62708-290-7
..., curing characteristics, green-part fabrication, property identification, process design and planning, and quality control and optimization are introduced. The article also provides information on postprocessing techniques, namely debinding and sintering, as well as on the phenomenon of shrinkage...
Abstract
This article presents a detailed account of the processes involved in vat-photopolymerization-based fabrication of ceramics, namely bioceramics, structural ceramics, piezoelectric ceramics, optical ceramics, and polymer-derived ceramics. Information and methods of material preparation, curing characteristics, green-part fabrication, property identification, process design and planning, and quality control and optimization are introduced. The article also provides information on postprocessing techniques, namely debinding and sintering, as well as on the phenomenon of shrinkage and compensation.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003789
EISBN: 978-1-62708-177-1
... equipment and techniques and provides data on etchants and etching procedures. specimen grinding liquid-phase sintering macroexamination metallographic examination microstructure particle size analysis powder metallurgy alloys particle shape analysis specimen polishing specimen preparation...
Abstract
This article provides information on the microstructure of powder metal alloys and the special handling requirements of porous materials. It covers selection, sectioning, mounting, grinding, and polishing, and describes procedures, such as washing, liquid removal, and impregnation, meant to preserve pore structures and keep them open for analysis. The article compares and contrasts the microstructures of nearly 50 powder metal alloys, using them to illustrate the effect of consolidation and compaction methods as well as particle size, composition, and shape. It discusses imaging equipment and techniques and provides data on etchants and etching procedures.
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006409
EISBN: 978-1-62708-192-4
... Abstract This article provides an overview of experimental, analytical, and numerical tools for temperature evaluation of dry and lubricated systems. It describes the analytical methods and numerical techniques for frictional heating and temperature estimation, as well as viscous heating...
Abstract
This article provides an overview of experimental, analytical, and numerical tools for temperature evaluation of dry and lubricated systems. It describes the analytical methods and numerical techniques for frictional heating and temperature estimation, as well as viscous heating in full-film lubrication. The article also discusses the viscous heating temperature measurements and numerical analysis of viscous heating.
Series: ASM Handbook
Volume: 24A
Publisher: ASM International
Published: 30 June 2023
DOI: 10.31399/asm.hb.v24A.a0006987
EISBN: 978-1-62708-439-0
... in the process appeared to be similar to the theory of “viscous sintering.” Sintering was the term that seemed closest to describing how the material was bonded together to form the parts. Therefore, the process was patented ( Ref 5 , Ref 6 ), trademarked, and commercialized as “Selective Laser Sintering...
Abstract
This article provides an introduction to the additive manufacturing (AM) terminology. The article describes the input and output of the AM process. It explains AM process categories, providing comments on the international standard on AM terminology, ISO/ASTM 52900.
Book Chapter
Series: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006883
EISBN: 978-1-62708-392-8
... deposition. This article discusses the processes involved in polymer powder 3D printing using laser fusion/ sintering and fusing agents and energy, as well as the thermally fused PBF. It provides information on polymer powder parameters and modeling, the powder-handling system, powder characterization...
Abstract
According to International Organization for Standardization (ISO)/ASTM International 52900, additive manufacturing (AM) can be classified into material extrusion, material jetting, vat photo polymerization, binder jetting, sheet lamination, powder-bed fusion (PBF), and directed-energy deposition. This article discusses the processes involved in polymer powder 3D printing using laser fusion/ sintering and fusing agents and energy, as well as the thermally fused PBF. It provides information on polymer powder parameters and modeling, the powder-handling system, powder characterization, the flowability of powder feedstock, and polymer part characteristics. The article describes the types of polymers in PBF, the processes involved in powder recycling, and the prospects of PBF in AM. In addition, the biomedical application of polyether ether ketone (PEEK) is also covered.
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