This article describes typical foundry practices used to commercially produce zirconium castings. The foundry practices are divided into two sections, namely, melting and casting. The article discusses various melting processes, such as vacuum arc skull melting, induction skull melting, and vacuum induction melting. Various casting processes, such as rammed graphite casting, static and centrifugal casting, and investment casting are reviewed. The article also provides information on the mechanical and chemical properties of zirconium castings.

Skull melting refers to the use of furnaces with water-cooled crucibles that freeze a solid “skull” of material on the crucible wall. This article describes the basic components, operating pressure, advantages, and applications of vacuum arc and induction skull melting furnaces.

Plasma melting is a material-processing technique in which the heat of thermal plasma is used to melt a material. This article discusses two typical design principles of plasma torches in the transferred mode: the tungsten tip design and the hollow copper electrode design. It describes the sources of atmospheric contamination in plasma melting furnaces and their control measures. The equipment used in plasma melting furnaces are also discussed. The article provides a detailed discussion on various plasma melting processes, such as plasma consolidation, plasma arc remelting, plasma cold hearth melting, and plasma casting.

The melting process often includes refining and treating the metal. The choice of which type of melting to use depends on a number of factors: type of alloy being melted, the local cost of electric power, and local environmental regulations. This article discusses the principles, furnace types, charging practices of metal melting methods, namely induction melting, cupola melting, arc melting, crucible melting, reaction melting, and vacuum melting, and the refractories and charging practice of reverberatory furnaces. Molten metal treatment of steels and aluminum also is discussed in the article.

This article discusses the general characteristics, primary and secondary fabrication methods, product forms, and corrosion resistance of zirconium and hafnium. It describes the physical metallurgy of zirconium and its alloys, providing details on allotropic transformation and anisotropy that profoundly influences the engineering properties of zirconium and its alloys. Tables listing the values for chemical composition and tensile properties for nuclear and nonnuclear grades of zirconium are also provided.

Electron beam melting includes melting, refining, and conversion processes for metals and alloys. This article describes the electron beam melting process, as well as the principles, equipment, and process considerations of drip melting and cold hearth melting process.

This article discusses the fundamentals of thermal vaporization and condensation and provides information on the various vaporization sources and methods of vacuum deposition. It offers an overview of reactive evaporation and its deposition techniques. The article also explains the advantages, limitations, and applications of vacuum deposition processes. Finally, it provides information on the gas evaporation process, its processing chamber, and related systems.

This article reviews the pattern materials used in investment casting, which can be loosely grouped into waxes and plastics. The patternmaking process, pattern tooling, and pattern and cluster assembly are described. The article also describes the manufacture of ceramic shell molds and cores, detailing the binders and other materials used, as well as the formulation and control of slurries. Methods for pattern removal, mold firing, melting, casting, postcasting treatment, and inspection are explained. After presenting design recommendations for investment castings, the article concludes with information on applications and special versions of the investment casting process.

The combination of high strength-to-weight ratio, excellent mechanical properties, and corrosion resistance makes titanium the best material choice for many critical applications. This article commences with a description of the historical perspective of titanium casting technology. It discusses the various types of molding methods, namely, rammed graphite molding, and lost-wax investment molding. The article provides information on the casting design, melting, and pouring practices, and describes the microstructure, hot isostatic pressing, heat treatment, and mechanical properties of Ti-6AI-4V alloy. It also talks about the chemical milling and weld repair, and describes the product applications of titanium alloy castings. Tensile properties, standard industry specifications, and chemical compositions of various titanium alloy castings are tabulated.

This article reviews the bulk deformation processes for various aluminide and silicide intermetallic alloys with emphasis on the gamma titanium aluminide alloys. It summarizes the understanding of microstructure evolution and fracture behavior during thermomechanical processing of the gamma aluminides with particular reference to production scaleable techniques, including vacuum arc and cold-hearth melting, isothermal forging, conventional hot forging, and extrusion. The selection and design of manufacturing methods, in the context of processing-cost trade-offs for gamma titanium aluminide alloys, are also discussed.

Very high density materials are used for such applications as counterweights and radiation shields. This article focuses on the metallurgy, processing, properties, fabrication, design considerations, health and safety considerations, and applications of the most commonly used very high density materials: depleted uranium and tungsten and their alloys.

The initial cast superalloy developments in the United States centered on cobalt-base materials. Nickel-base and nickel-iron-base superalloys owe their high-temperature strength potential to their gamma prime content. For polycrystalline superalloy components, high-temperature strength is affected by the condition of the grain boundaries and, in particular, the grain-boundary carbide morphology and distribution. Vacuum induction melting offers more control over alloy composition and homogeneity than all other vacuum melting processes. The primary purification reaction occurring in the process is the removal of melt contained oxygen by means of a reaction with carbon to form carbon monoxide. A number of casting processes can provide near-net shape superalloy cast parts, but essentially all components are produced by investment casting. The solidification of investment cast superalloy components is precisely controlled so that the microstructure, which ultimately determines mechanical properties, remains consistent. Heat treating cast superalloys involves homogenization and solution heat treatments or aging heat treatments.

Zirconium, hafnium, and titanium are produced from ore that generally is found in a heavy beach sand containing zircon, rutile, and ilmenite. This article discusses the processing methods of these metals, namely, liquid-liquid separation process, distillation separation process, refining, and melting. It also discusses the primary and secondary fabrication of zirconium and hafnium and its alloys. The article talks about the metallurgy of zirconium and its alloys with emphasis on allotropic transformation, cold work and recrystallization, anisotropy and preferred orientation, and the role of oxygen. It concludes by providing useful information on the applications of reactor and industrial grades of zirconium alloys.

The combination of high strength-to-weight ratio, excellent mechanical properties, and corrosion resistance makes titanium the best material choice for many critical applications. This article begins with a description of the historical perspective of titanium casting technology. It discusses the types of molding methods, such as rammed graphite molding and lost-wax investment molding. The article provides information on the casting design, melting, postcasting, and pouring practices. It describes the microstructure and mechanical properties of Ti-6AI-4V alloy. The article examines the product applications of titanium alloy castings. The tensile properties, standard industry specifications, and chemical compositions of various titanium alloy castings are tabulated.

This article is a compilation of definitions for terms related to welding fundamentals and all welding processes. The processes include arc and resistance welding, friction stir welding, laser beam welding, explosive welding, and ultrasonic welding.

This article describes the physical principles of brazing with illustrations and details elements of the brazing process. The elements of brazing process include filler-metal flow, base-metal characteristics, filler-metal characteristics, surface preparation, joint design and clearance, temperature and time, rate and source of heating, and protection by an atmosphere or flux. The article explains the different types of brazing processes: manual torch brazing, furnace brazing, induction brazing, dip brazing, resistance brazing, infrared (quartz) brazing, exothermic brazing, electron-beam and laser brazing, microwave brazing, and braze welding.

This article focuses on the construction, operation of electric arc furnaces (EAF), and their auxiliary equipment in the steel foundry industry. It provides information on the power supply of EAF and discusses the components of the EAF, including the roof, furnace shell, spout and tap hole, water-cooling system, preheat and furnace scrap burners, and ladles. The article describes the acid and basic steelmaking practices. It discusses the raw materials used, oxidation process, methods of heat reduction, and deoxidation process in the practices. The article provides a discussion on the arc melting of iron and EAF steelmaking.

Aluminum alloys are primarily used for nonferrous castings because of their light weight and corrosion resistance. This article discusses at length the melting and metal treatment, structure control, sand casting, permanent mold casting, and die casting of aluminum alloys. It also covers the types and melting and casting practices of copper alloys, zinc alloys, magnesium alloys, titanium alloys, and superalloys, and provides a brief account on the casting technique of metal-matrix composites.