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urethanes
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Image
Published: 30 September 2015
Fig. 17 Urethane chemistry. Polyol + isocyanate reaction to create urethanes. Urethane groups form hard segments, while polyol midblocks form soft segments to give elastomeric (rubberlike) properties. Courtesy of Loyd Burcham, Stonhard
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Published: 30 September 2015
Fig. 18 Polymeric isocyanates used in field-applied urethanes. Courtesy of Loyd Burcham, Stonhard
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Published: 01 December 2008
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Published: 01 December 2008
Fig. 14 Effect of increasing oil urethane system (part B) (catalyst) on work time and strip time
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Published: 30 September 2015
Fig. 19 Moisture-cured urea (isocyanate + water reaction). Moisture-cured urethane (isocyanate prepolymer contains urethane groups; reaction with water makes urethane/urea hybrid. Note: These reactions generate CO 2 . Courtesy of Loyd Burcham, Stonhard
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in Coatings for Commercial Structures and Building Deficiencies that Affect Performance
> Protective Organic Coatings
Published: 30 September 2015
Fig. 14 Barrier wall (core-fill insulation such as spray urethane foam). CMU, concrete masonry unit
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Published: 01 January 2003
Fig. 21 Reaction of an isocyanate and a polyol to form a urethane. R and R′ are different aromatic or aliphatic groups. Source: Ref 4
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Published: 01 January 2003
Fig. 25 Curing reaction of a single-package moisture-cured urethane. (a) The isocyanate reacts with water to form unstable carbamic acid, which decomposes into an amine plus carbon dioxide gas. (b) The amine then reacts with isocyanate to form a urea derivative. R indicates an aromatic
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Published: 01 January 2003
Fig. 26 Difference between polyurethane and polyurea resins. (a) Urethane link in polyurethane. (b) Substituted urea link in polyurea
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in Physical, Chemical, and Thermal Analysis of Thermoplastic Resins
> Characterization and Failure Analysis of Plastics
Published: 15 May 2022
Fig. 18 Dynamic mechanical properties of a cylindrical urethane foam sample; 6.60 mm (0.26 in.) diameter, 6.28 rad/s frequency
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Published: 12 September 2022
Fig. 30 Stiffness softening of poly(urea-urethane) nanohybrid elastomer (PUU-POSS) scaffolds under compression. (a) Optical images of surface and cross section of the scaffolds with infill densities 80–30% made by 3D, thermally induced phase separation. (b) Scanning electron microscope images
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Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006011
EISBN: 978-1-62708-172-6
... Abstract Polyurethane is any polymer consisting of a chain of repeating organic units joined by urethane linkages. Polyurethane polymers are formed through step-growth polymerization by making a monomer containing at least two isocyanate functional groups to react with another monomer...
Abstract
Polyurethane is any polymer consisting of a chain of repeating organic units joined by urethane linkages. Polyurethane polymers are formed through step-growth polymerization by making a monomer containing at least two isocyanate functional groups to react with another monomer containing at least two hydroxyl (alcohol) groups. This article provides a detailed account of the protective coatings used in the building, infrastructure, and architectural markets. It focuses on the various types of polyurethane coatings used in these applications: moisture-cure and two-pack aromatic coatings as primers and topcoats, moisture-cure aromatic elastomeric high-build coatings, moisture-cure aliphatic topcoats, two-pack aliphatic polyurethane coatings as topcoats, and one- and two-pack polyurethane dispersion coatings as sealers and topcoats. It also includes a section on the health effects of isocyanates.
Book Chapter
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005354
EISBN: 978-1-62708-187-0
... binders, namely, furan no-bake resins, phenolic no-bake resins, and urethanes. The article provides an overview of gas-cured organic binders. It also illustrates the three commercial systems for sand reclamation: wet reclamation systems, dry reclamation systems, and thermal reclamation. inorganic...
Abstract
No-bake sand molds are based on the curing of inorganic or organic binders with either gaseous catalysts or liquid catalysts. This article reviews the major aspects of no-bake sand bonding in terms of coremaking, molding methods, and sand processing. It discusses the points to be noted in handling sand-resin mixtures for no-bake molds or cones and lists some advantages of no-bake air-set cores and molds. The article describes the process procedures, advantages, and disadvantages of gas curing and air-setting hardening of sodium silicates. It examines the members of the air-setting organic binders, namely, furan no-bake resins, phenolic no-bake resins, and urethanes. The article provides an overview of gas-cured organic binders. It also illustrates the three commercial systems for sand reclamation: wet reclamation systems, dry reclamation systems, and thermal reclamation.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003692
EISBN: 978-1-62708-182-5
... deposited by evaporation of water, a class of coatings called water-borne coatings. The coatings that chemically cross link by copolymerization, including epoxies, unsaturated polyesters, urethanes, high-temperature curing silicones, and phenolic linings, are also described. hardening autooxidative...
Abstract
This article discusses the coating systems categorized by the generic type of binder or resin and grouped according to the curing or hardening mechanism inherent within that generic type. It focuses on the properties, advantages, and limitations of various autooxidative cross-linked resins, thermoplastic resins, and cross-linked thermosetting resins. The autooxidative cross-linked resins include alkyd resins and epoxy esters. The article examines the two types of coatings based on thermoplastic resins: those deposited by evaporation of a solvent, commonly called lacquers, and those deposited by evaporation of water, a class of coatings called water-borne coatings. The coatings that chemically cross link by copolymerization, including epoxies, unsaturated polyesters, urethanes, high-temperature curing silicones, and phenolic linings, are also described.
Series: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005672
EISBN: 978-1-62708-198-6
... of curable adhesives used for medical device assemblies, including acrylics, cyanoacrylates, epoxies, urethanes, and silicones. Other forms of adhesives, such as hot melts, bioadhesives, and pressure-sensitive adhesives, are also discussed. The typical characteristics and applications of biocompatible...
Abstract
This article provides an overview of curing techniques, adhesive chemistries, surface preparation, adhesive selection, and medical applications of adhesives. The curing techniques are classified into moisture, irradiation, heat, and anaerobic. The article highlights the common types of curable adhesives used for medical device assemblies, including acrylics, cyanoacrylates, epoxies, urethanes, and silicones. Other forms of adhesives, such as hot melts, bioadhesives, and pressure-sensitive adhesives, are also discussed. The typical characteristics and applications of biocompatible medical device adhesives are listed in a table. The article concludes with a section on the selection of materials for medical adhesives.
Book Chapter
Series: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005687
EISBN: 978-1-62708-198-6
... Acetal resin, Polyoxymethylene, polytrioxane POM C, POM-C, POMC Heart valves Polysulfones Polyphenylsulfone Polyphenylsulphone PPSU Fixation devices Polysulfone ASTM F702 PSU Fixation devices Vascular strippers Polyurethanes Poly(ether urethane) ASTM F624 Polyether...
Abstract
This article tabulates materials that are known to have been used in orthopaedic and/or cardiovascular medical devices. The materials are grouped as metals, ceramics and glasses, and synthetic polymers in order. These tables were compiled from the Medical Materials Database which is a product of ASM International and Granta Design available by license online and as an in-house version. The material usage was gleaned from over 24,000 U.S. Food and Drug Administration (USFDA), Center for Devices and Radiological Health, Premarket notifications (510k), and USFDA Premarket Approvals, and other device records that are a part of this database. The database includes other material categories as well. The usage of materials in predicate devices is an efficient tool in the material selection process aiming for regulatory approval.
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Published: 01 January 2003
Fig. 24 Molecular structure of hexamethylene diisocyanate, an aliphatic isocyanate used in urethane coatings. Source: Ref 5
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in Guidance for the Use of Protective Coatings in Municipal Potable Water Systems
> Protective Organic Coatings
Published: 30 September 2015
Fig. 9 Typical on-ground steel water storage tank coated externally with a zinc/epoxy/urethane coating system
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