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in Guidance for the Use of Protective Coatings in Municipal Potable Water Systems
> Protective Organic Coatings
Published: 30 September 2015
Fig. 9 Typical on-ground steel water storage tank coated externally with a zinc/epoxy/urethane coating system
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Image
Published: 01 January 2003
Fig. 24 Molecular structure of hexamethylene diisocyanate, an aliphatic isocyanate used in urethane coatings. Source: Ref 5
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Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003692
EISBN: 978-1-62708-182-5
... deposited by evaporation of water, a class of coatings called water-borne coatings. The coatings that chemically cross link by copolymerization, including epoxies, unsaturated polyesters, urethanes, high-temperature curing silicones, and phenolic linings, are also described. hardening autooxidative...
Abstract
This article discusses the coating systems categorized by the generic type of binder or resin and grouped according to the curing or hardening mechanism inherent within that generic type. It focuses on the properties, advantages, and limitations of various autooxidative cross-linked resins, thermoplastic resins, and cross-linked thermosetting resins. The autooxidative cross-linked resins include alkyd resins and epoxy esters. The article examines the two types of coatings based on thermoplastic resins: those deposited by evaporation of a solvent, commonly called lacquers, and those deposited by evaporation of water, a class of coatings called water-borne coatings. The coatings that chemically cross link by copolymerization, including epoxies, unsaturated polyesters, urethanes, high-temperature curing silicones, and phenolic linings, are also described.
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Published: 01 January 2003
Fig. 22 Molecular structures of toluene diisocyanate, an aromatic isocyanate used in urethane coatings. (a) 2,4 isomer. (b) 2,6 isomer. Source: Ref 5
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Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006011
EISBN: 978-1-62708-172-6
... esters are a special class of secondary amines designed to have reduced reactivity with polyisocyanates that are suitable for coatings applications. Polyaspartics are covered in a separate article, “Polyaspartic Coatings,” in this Volume. Fig. 1 Reactions of isocyanates to form urethane and urea...
Abstract
Polyurethane is any polymer consisting of a chain of repeating organic units joined by urethane linkages. Polyurethane polymers are formed through step-growth polymerization by making a monomer containing at least two isocyanate functional groups to react with another monomer containing at least two hydroxyl (alcohol) groups. This article provides a detailed account of the protective coatings used in the building, infrastructure, and architectural markets. It focuses on the various types of polyurethane coatings used in these applications: moisture-cure and two-pack aromatic coatings as primers and topcoats, moisture-cure aromatic elastomeric high-build coatings, moisture-cure aliphatic topcoats, two-pack aliphatic polyurethane coatings as topcoats, and one- and two-pack polyurethane dispersion coatings as sealers and topcoats. It also includes a section on the health effects of isocyanates.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001325
EISBN: 978-1-62708-170-2
...-solids has been the method most often selected for meeting the VOC requirements for topcoats. Development in this area has been concentrated primarily on aliphatic urethanes. Coatings formulated with these materials have the desirable properties of weatherability, durability, and flexibility. Low...
Abstract
This article discusses coating products available for use in the aerospace industry that are compliant with regulations requiring reductions in emissions from organic solvents. The coating products addressed include primers, topcoats, and chemical milling maskants. It describes their characteristics and limitations compared to conventional noncompliant materials. The article addresses the methods and products commonly used achieve regulatory compliance: waterborne coatings, exempt-solvent-based coatings, high-solids coatings, powder coating, and electro-deposition.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006051
EISBN: 978-1-62708-172-6
.... The isocyanate can be combined with other generic materials to enhance chemical, moisture, low-temperature, and abrasion resistance. Aromatic urethanes are typically used as primers, adhesion promoters, and intermediate coats. Polyureas Fast- to very-fast-curing, highly elastic thick-film coatings with good...
Abstract
A coating can be defined as a substance spread over a surface to provide protection or to serve decorative purposes. This article discusses two industrial coating components, namely, nonvolatile components such as the resin or binder, pigments, and any additives that may be incorporated into the formulation; and volatile components such as solvents, or water in emulsions and their composition. It provides general information on volatile organic compounds. The article describes the film-forming mechanisms of various coating types, namely, lacquers, chemically converting coatings, latex coatings, alkyds and other resins, which cure by oxidation, moisture-curing polyurethanes and inorganic zinc primers, and powder coatings. The article concludes with a discussion on the functions of the primer, intermediate coat, and topcoat in coating systems.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001278
EISBN: 978-1-62708-170-2
... with urethane linkages, lower-solids coatings are possible that do not require the use of rheology control agents for good application properties. Soft side chains other than polycaprolactone can be incorporated into the acrylic polymer. Ryntz has shown a number of ways to incorporate a polyester...
Abstract
This article describes elastomeric coatings that are suitable for painting flexible plastic substrates. It focuses on coatings systems that find utility in automotive exterior applications, where the requirements of appearance and durability are most severe. The article discusses acrylic polyols, condensation polymers, vapor curing systems, water-based coatings, and coatings for thermoplastic olefins.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006037
EISBN: 978-1-62708-172-6
... are usually only the top broadcast layer, with one or two coats of sealer. Epoxy, urethane, urea, and acrylate chemistries are all commonly used with this system design. Fig. 26 Broadcast system (colored quartz type). Courtesy of Stonhard Fig. 27 Broadcast system (flake type). Courtesy...
Abstract
Polymeric floor coatings refer to flooring materials composed of multicomponent thermoset resins formulated with various fillers and pigments that are installed in situ, usually over concrete substrates. Polymeric flooring systems, specified for all industrial and commercial environments, use a variety of polymer chemistries and are constructed in a variety of methods and designs. This article provides a description of the service conditions for the polymeric flooring systems. It provides information on polymeric flooring systems, including thin-film coatings, self-leveling systems, membrane systems, broadcast systems, troweled systems, and terrazzo. The article also focuses on properties, applications, testing, and factors and requirements to be considered during the installation of polymeric floor coatings. It concludes with a discussion about coating failures, including bonding, cracking, chemical attack, and moisture that affect the polymeric floor coatings on concrete.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004104
EISBN: 978-1-62708-184-9
... are available ( Ref 8 , 9 ). Generic coating types include alkyds, coal tar epoxies, zinc-rich coatings, polyester resins, polyurethanes, and urethanes. All coatings must meet local, state, and federal air quality regulations. The manufacturer's recommendations for surface preparation should be strictly...
Abstract
This article provides information on predesign surveys and the various testing procedures associated with wastewater treatment plants. These include soil testing, atmospheric testing, and hydrogen sulfide testing. The primary parameters that influence the production of sulfides within the piping system that transports the wastewater to the treatment facility are discussed. The article describes the corrosion performance of various materials in the soil, fluid, and atmospheric exposures. These include concrete, steel, ductile iron, aluminum, copper, brass, stainless steel, and coatings used for wastewater facilities.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005242
EISBN: 978-1-62708-187-0
... with binders based on acid-cured resins of furan or resoles (phenolic), alkaline phenolic (phenolic ester), acrylic epoxies, and phenolic urethane, which is probably the most significant in North America Thermally cured organic binders such as alkyd oil (also known as alkyd urethane or oil sand...
Abstract
This article reviews the basic types of mold aggregates and bonding methods for expendable molds and coremaking. It provides an overview of mold media and the basic types of sands and their properties. The most significant clays used in green sand operations, such as bentonites, are discussed. The article describes the methods of sand bonding with inorganic compounds. It provides a description of resin-bonded sand systems: no-bake binder systems, heat-cured binder systems, and cold box binder systems. The article concludes with a discussion on the media used for expendable molds, namely, ceramic shells and rammed graphite, for casting reactive metals such as titanium or zirconium.
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Published: 01 June 2012
Fig. 2 Scanning electron micrograph of primary human osteoblasts on the surface of a calcium-phosphate-coated poly (carbonate urethane) substrate. Courtesy of D.H. Barnes
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Image
in Guidance for the Use of Protective Coatings in Municipal Potable Water Systems
> Protective Organic Coatings
Published: 30 September 2015
Fig. 19 Lower-film-stress acrylic coating system being applied over an aged epoxy-urethane system on a hydropillar (type of water storage tank)
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Image
Published: 01 June 2012
Fig. 1 Scanning electron micrograph of a calcium phosphate coating on the surface of a poly (carbonate urethane) substrate, formed by immersion in a concentrated simulated body-fluid-like solution. Courtesy of D.H. Barnes
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Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003048
EISBN: 978-1-62708-200-6
... in this class are chemically curing elastomers. The families include urethanes, the best of the acrylics, polyether-modified silicones, polysulfides, and silicones. In building construction, these sealants are usually intended for use in exterior high-movement applications. Some of the silicones are also used...
Abstract
This article is an informative primer on sealants and the role they play in engineered assemblies. It discusses the physical, thermal, chemical, and electrical properties of sealant materials and the various forms in which they are applied, including liquids, pastes, and extruded tapes. It also describes classifications and types, comparing and contrasting sealants made from oil-based caulks, asphalts, coal tar resins, latex acrylic sealants, polyvinyl acetate caulks, solvent acrylics, butyl sealants, polysulfides, polyurethanes, modified silicones, anaerobics, vinyl plastisols, and polypropylenes. In addition, the article provides practical design insight, addressing application requirements, seal configurations, and joint stresses. It concludes with a brief discussion on the use of sealants in aerospace, automotive, electrical, and construction applications.
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in Microbiologically Influenced Corrosion Testing
> Corrosion: Fundamentals, Testing, and Protection
Published: 01 January 2003
Fig. 7 Impedance spectra for coated steel exposed to natural seawater for 1, 4, and 7 months at Port Hueneme, CA. (a) Zinc primer, epoxy polyamide midcoat, urethane topcoat. (b) Zinc primer, epoxy polyamide, midcoat, latex topcoat. (c) Epoxy polyamide primer and midcoat, latex topcoat. (d
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Book Chapter
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005354
EISBN: 978-1-62708-187-0
... binders, namely, furan no-bake resins, phenolic no-bake resins, and urethanes. The article provides an overview of gas-cured organic binders. It also illustrates the three commercial systems for sand reclamation: wet reclamation systems, dry reclamation systems, and thermal reclamation. inorganic...
Abstract
No-bake sand molds are based on the curing of inorganic or organic binders with either gaseous catalysts or liquid catalysts. This article reviews the major aspects of no-bake sand bonding in terms of coremaking, molding methods, and sand processing. It discusses the points to be noted in handling sand-resin mixtures for no-bake molds or cones and lists some advantages of no-bake air-set cores and molds. The article describes the process procedures, advantages, and disadvantages of gas curing and air-setting hardening of sodium silicates. It examines the members of the air-setting organic binders, namely, furan no-bake resins, phenolic no-bake resins, and urethanes. The article provides an overview of gas-cured organic binders. It also illustrates the three commercial systems for sand reclamation: wet reclamation systems, dry reclamation systems, and thermal reclamation.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006047
EISBN: 978-1-62708-172-6
.... Initially, polyurea technology had set itself in a different class of coating/lining systems as compared to conventional urethane coating/lining systems. This distinction was primarily due to the unique characteristics of the technology, both in processing and performance. However, over the years there has...
Abstract
Two-component polyurea elastomeric coating/lining systems are the newest technology in the protective coating/lining industry and a wide variety of applications have been developed. These include coating/lining applications over concrete, geotextile membranes, various metals for corrosion and decorative areas, and some plastics. This article discusses the formulation basics of polyurea technology and compares the technology to that of polyurethane and polyurethane/polyurea systems. It addresses performance issues and describes application processing considerations and safety practices of polyurea coating/lining systems.
Book Chapter
Series: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005687
EISBN: 978-1-62708-198-6
... Acetal resin, Polyoxymethylene, polytrioxane POM C, POM-C, POMC Heart valves Polysulfones Polyphenylsulfone Polyphenylsulphone PPSU Fixation devices Polysulfone ASTM F702 PSU Fixation devices Vascular strippers Polyurethanes Poly(ether urethane) ASTM F624 Polyether...
Abstract
This article tabulates materials that are known to have been used in orthopaedic and/or cardiovascular medical devices. The materials are grouped as metals, ceramics and glasses, and synthetic polymers in order. These tables were compiled from the Medical Materials Database which is a product of ASM International and Granta Design available by license online and as an in-house version. The material usage was gleaned from over 24,000 U.S. Food and Drug Administration (USFDA), Center for Devices and Radiological Health, Premarket notifications (510k), and USFDA Premarket Approvals, and other device records that are a part of this database. The database includes other material categories as well. The usage of materials in predicate devices is an efficient tool in the material selection process aiming for regulatory approval.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006072
EISBN: 978-1-62708-172-6
.../waterborne acrylic … √ … Thermal spray coating/sealer √ √ … Epoxy sealer/epoxy mastic/acrylic polyurethane or polyaspartic … … √ Epoxy mastic/acrylic polyurethane … … √ Epoxy mastic/waterborne acrylic … … √ Moisture-cured urethane sealer/moisture-cured urethane/moisture-cured...
Abstract
This article provides a basic overview of bridge corrosion, where it occurs on steel and concrete bridge structures, and how to prevent corrosion by using coatings. It describes types of bridge designs, with illustrations, and presents information on how corrosion occurs in different bridge zones and areas, with illustrations. The article concludes with a discussion on the common methods of coating systems applications on bridge structures and key elements in coating condition assessment.
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