External corrosion direct assessment (ECDA) is a structured process intended for use by pipeline operators to assess and manage the impact of external corrosion on the integrity of underground pipelines. This article focuses on four steps of ECDA, namely, preassessment, indirect examinations, direct examination, and post assessment. The ECDA tool selection matrix used to determine the tool choices is also presented.

This article describes the coating materials, surface-preparation requirements, and application techniques used to protect underground pipelines. It provides a valuable insight into the types of polymer-based coatings that are both cost-effective and widely accepted in the pipeline industry.

This article describes the mechanisms of differential corrosion cells corrosion, microbiologically influenced corrosion, and stray direct current corrosion. It discusses the most common causes and contributing factors for corrosion and stress-corrosion cracking, as well as prevention, mitigation, detection, and repair processes.

This article explores the use of the electrochemical and nonelectrochemical techniques for measuring the corrosion behavior of buried metals and the types of probes used. The electrical resistance technique is the main nonelectrochemical technique used for measuring corrosion rate. Electrochemical techniques discussed include linear polarization resistance, electrochemical noise, harmonic distortion analysis, electrochemical impedance spectroscopy, and hydrogen permeation. The principles of operation for the corrosion measuring techniques are described along with examples of their use in soils.

This article describes the various environments affecting corrosion performance, corrosion protection, and corrosion control. These include freshwater environments, marine environments, and underground environments. The article provides information on corrosion in military environments and specialized environments, representing less-well-known environments with more limited applications.

A close-interval survey (CIS) is a series of structure-to-electrolyte direct current potential measurements performed at regular intervals for assessing the level of cathodic protection (CP) on pipelines and other buried or submerged metallic structures. This article describes the equipment required to perform the CIS. It provides a discussion on the activities that should be performed during the preparation and execution of the CIS. The dynamic stray current identification and compensation by CIS is discussed briefly. The article also explains various factors involved in the validation of CIS data. It concludes with information on CIS data interpretation.

This article analyzes the estimates of the cost of corrosion, made in various countries at various times. The data are extrapolated to a 2004 base and then projected to the global economy. The chronological order of the countries are the United States of America, the United Kingdom, Australia, Japan, Canada, Germany, Poland, South Africa, Czechoslovakia, Belgium, Netherlands, Sweden, Finland, the Union of Soviet Socialist Republics, Kuwait, India, and the Basque Region.

Stray current can be defined as a current in structures that are underground or immersed in an electrolyte that most often accelerate corrosion on a structure where a positive current leaves the structure to enter the earth or an electrolyte. This article provides a description of the principles of stray current and a discussion on the major types of stray current and their properties and prediction methods. It discusses the consequences of stray current and describes the interference tests used for mapping the path of the stray currents. The article also highlights the methods of mitigating the source of stray current.

This article presents the fundamentals of stray-current corrosion caused by electric rail transit systems. It describes the various corrosion-control design elements for the electric rail system. These design elements include substation spacing and grounding, track and track slab design, and construction acceptance criteria. The impacts of the electric rail construction in underground utilities are discussed. Direct physical interferences, maintenance access encroachments, stray-current effects, and utility relocation design considerations, are discussed. The article also reviews construction issues such as funding, sequencing, and working clearances. It concludes with information on the post-construction monitoring and maintenance for stray-current corrosion control.

Steel storage tanks are the primary means for storing large volumes of liquids and gaseous products. The stored fluid could be water, but it could also be volatile, corrosive, and flammable fluid requiring special precautions for storage as well. Corrosion is generally worst where the tank is in contact with the soil. This article describes the soil characteristics and addresses cathodic protection (CP) criteria for submerged metallic piping systems. It provides information on the data required for designing a CP system, alone or in conjunction with a protective coating system. These data are collected from predesign site assessments, tank electrical characteristics, and soil-resistivity measurements. The article addresses NACE Standard RP0169, which gives requirements and desired characteristics for coating in conjunction with CP. It also explains the methods of protecting aboveground storage tanks and underground storage tanks.

This article provides information on predesign surveys and the various testing procedures associated with wastewater treatment plants. These include soil testing, atmospheric testing, and hydrogen sulfide testing. The primary parameters that influence the production of sulfides within the piping system that transports the wastewater to the treatment facility are discussed. The article describes the corrosion performance of various materials in the soil, fluid, and atmospheric exposures. These include concrete, steel, ductile iron, aluminum, copper, brass, stainless steel, and coatings used for wastewater facilities.

This article describes the test methods for evaluating the durability of a metal in soil. It provides useful information on soil characteristics such as soil electrical resistivity, pH value, and soil texture. Specimen design, preparation, burial, and retrieval techniques are discussed. The type of information sought during soil-induced corrosion evaluation controls the design configuration and the nature of the corrosion measurements. Consideration of these factors during the planning stage helps the corrosion engineer to obtain the maximum amount of information with the minimum number of problems.

This article discusses the failure analysis of several steel transmission pipeline failures, describes the causes and characteristics of specific pipeline failure modes, and introduces pipeline failure prevention and integrity management practices and methodologies. In addition, it covers the use of transmission pipeline in North America, discusses the procedures in pipeline failure analysis investigation, and provides a brief background on the most commonly observed pipeline flaws and degradation mechanisms. A case study related to hydrogen cracking and a hard spot is also presented.

Coating of cast irons is done to improve appearance and resistance to degradation due to corrosion, erosion, and wear. This article describes inorganic coating methods commonly applied to cast irons. The coating methods include plating, hot dip coating, conversion coating, diffusion coating, cladding, porcelain enameling, and thermal spray. Organic coatings have a wide variety of properties, but their primary use is for corrosion resistance combined with a pleasing colored appearance. The article discusses the various types of organic coatings applied to cast irons. Practically any degree of smoothness or roughness and requirement for color and gloss can be filled by organic coatings. The article describes abrasive blast cleaning, abrasive waterjet cleaning and finishing, vibratory finishing, barrel finishing, and shot peening for processing iron castings.

The major benefit of the implementation of the corrosion-control technologies at Army installations is the extension of the service life of buildings and other structures. This article reviews the exposure of military facilities and equipment to a wide variety of environmental conditions, including soils, waters, or atmospheres of varying corrosivity. It presents the case studies illustrating typical examples of the types of corrosion problems found on military installations. The article describes the various corrosion-control technologies used in military facilities. These include protective coatings and linings, cathodic protection, advanced materials selection and design, water treatment, equipment inspection and monitoring, and below-grade moisture mitigation.

A variety of electrochemical techniques are used to detect and monitor material deterioration in service or in the field. This article describes the static or direct current measurements in a number of applications, including buried pipelines and storage tanks. It reviews the electrochemical impedance spectroscopy and electrochemical noise measurements in a laboratory, especially for the inspection of coatings.

This article describes the features, benefits and limitations of petrolatum and microcrystalline wax. It provides a detailed discussion on the steps to be followed before applying the various forms of the wax-based coatings. The wax-based coating forms include petrolatum and microcrystalline tapes, marine petrolatum-based pile systems; cold-applied petrolatum-based paste coating systems; hot-applied microcrystalline wax flood coating systems; wax-based dips, brushons, and sprays; and wax-impregnated fabrics and wax-coated papers. The article also discusses the applications and limitations of these wax-based coatings. It concludes by highlighting the steps involved in the installation of wax-based casing fillers.

This article explains how an engineer might go about assessing the risk of microbiologically influenced corrosion (MIC) in an industrial situation. It describes the systems that are susceptible to the effects of MIC by sulfate-reducing bacteria (SRB). The article discusses the effects of microorganisms other than SRB on metals. SRB-related problems, which are the most common MIC issue, are also explored. The article describes the test procedures used to enumerate microbiological populations. It concludes with a discussion on risk assessment based on operating conditions.

Cathodic protection is an electrochemical means of corrosion control in which the oxidation reaction in a galvanic cell is concentrated at the anode, which suppresses corrosion of the cathode in the same cell. This article provides a detailed discussion on the fundamentals and types of cathodic protection as well as their power sources and design considerations. The criteria for the cathodic protection and types of materials used in sacrificial anodes and impressed-current anodes are also discussed. The article provides examples selected for familiarizing the design engineer with the steps for selecting a specific corrosion control method.