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Brian S. Hayes, Luther M. Gammon
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Florian Feil, Matt McGreer
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ultraviolet light absorbers
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Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001731
EISBN: 978-1-62708-178-8
... Structure Ultraviolet/visible absorption spectroscopy is almost exclusively the spectroscopy of molecules dissolved in solvents (most atoms in the gas phase also absorb in this spectral region; however, this is the province of atomic absorption spectroscopy, as described in the article “Atomic...
Abstract
Ultraviolet/visible (UV/VIS) absorption spectroscopy is a powerful yet cost-effective tool that is widely used to identify organic compounds and to measure the concentration of principal and trace constituents in liquid, gas, and solid test samples. This article emphasizes the quantitative analysis of elements in metals and metal-bearing ores. The instrumentation required for such applications consists of a light source, a filter or wavelength selector, and some type of visual or automated sensing mechanism. The article examines common sensing options and provides helpful information on how to set up and run a variety of UV/VIS absorption tests.
Book Chapter
Photochemical Aging and Weathering of Polymers—The Basics
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006920
EISBN: 978-1-62708-395-9
..., some precautions can be taken to at least reduce the number of unnecessary chromophores. This includes, for example, processing at lower temperatures and the use of inert gases such as nitrogen or argon to avoid thermal degradation during processing. Ultraviolet Absorbers: Pigments Pigments...
Abstract
This article describes the processes involved in photochemical aging and weathering of polymeric materials. It explains how solar radiation, especially in the UV range, combines with atmospheric oxygen, driving photooxidation and the development of unstable photoproducts that cause various types of damage when they decompose, including the scission of carbon bonds and polymer chains. The article illustrates some of the degradation reactions that occur in different polymers and presents an overview of the strategies used to prevent such reactions or otherwise mitigate their effects.
Book Chapter
Analysis of Surface Degradation of Composites
Available to PurchaseSeries: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0009084
EISBN: 978-1-62708-177-1
... Abstract Polymer composite materials are subject to degradation if not appropriately protected from the environment. This article describes the effects of heat and atomic oxygen and ultraviolet-light on composite material surfaces, with illustrations. atomic oxygen composite material...
Abstract
Polymer composite materials are subject to degradation if not appropriately protected from the environment. This article describes the effects of heat and atomic oxygen and ultraviolet-light on composite material surfaces, with illustrations.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003844
EISBN: 978-1-62708-183-2
... coatings coating degradation permeation molecular composition PAINTS AND PROTECTIVE COATINGS are by far the most common means of protecting materials from deterioration. Besides protection, coatings add color, beautify, provide light reflectivity, camouflage, reflect heat, absorb heat, and provide...
Abstract
Paints and protective coatings are the most common means of protecting materials from deterioration. This article focuses on coating degradation that results from the environmental interaction with the coatings. The major environmental influences of the degradation include energy (solar radiation, heat and temperature variation, and nuclear radiation), permeation (moisture, solvent retention, chemical, and oxygen), stress (drying and curing, vibration, and impact and abrasion), and biological influences (microbiological and macrobiological).
Book Chapter
Weathering Testing of Polymeric Materials
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006871
EISBN: 978-1-62708-395-9
... to Laboratory Light Sources—Part 3: Fluorescent UV Lamps ,” International Organization for Standardization , 2016 28. ASTM G154 , “ Standard Practice for Operating Fluorescent Ultraviolet (UV) Lamp Apparatus for Exposure of Nonmetallic Materials ,” ASTM International , 2016 29. Francis...
Abstract
This article presents a general overview of outdoor weather aging factors, their effects on the performance of polymeric materials, and the accelerated test methods that can be used to investigate those effects. These test methods are used to characterize material performance when subjected to specific, often controlled, and well-defined factors. The article also presents an overview of weathering instrument types that simulate outdoor stress factors.
Series: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005672
EISBN: 978-1-62708-198-6
...., ultraviolet or visible light initiation). This article provides an overview of curing techniques, adhesive chemistries, surface preparation, adhesive selection, and medical applications for adhesives. Curing Techniques <xref rid="a0005672-ref2" ref-type="bibr">(Ref 2...
Abstract
This article provides an overview of curing techniques, adhesive chemistries, surface preparation, adhesive selection, and medical applications of adhesives. The curing techniques are classified into moisture, irradiation, heat, and anaerobic. The article highlights the common types of curable adhesives used for medical device assemblies, including acrylics, cyanoacrylates, epoxies, urethanes, and silicones. Other forms of adhesives, such as hot melts, bioadhesives, and pressure-sensitive adhesives, are also discussed. The typical characteristics and applications of biocompatible medical device adhesives are listed in a table. The article concludes with a section on the selection of materials for medical adhesives.
Book Chapter
Aging and Weathering Testing of Polymers
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003028
EISBN: 978-1-62708-200-6
... their total energy can be absorbed within a few micrometers of the surface. Ultraviolet radiation absorption on the surface of a material can result in chalking, which is a surface film that breaks molecular bonds. Ultraviolet radiation also causes discoloration (yellowing and bleaching) and loss...
Abstract
This article describes weathering and environmental factors that contribute to degradation in plastics, including temperature variations, moisture, sunlight, oxidation, microbiologic attack, and other environmental elements. It presents a general overview of aging factors, their effects on plastic materials, and the accelerated test methods that can be used to estimate the reaction of a plastic component during actual use. The article focuses on the determination of service temperature as it indicates the ability of a material to retain a certain property, when exposed to elevated temperatures for an extended period of time. It concludes by describing various degradation processes, namely, thermal degradation, thermal oxidative degradation, photooxidative degradation, environmental corrosion, and chemical corrosion and discussing the ways of detecting these degradation processes.
Book Chapter
Glossary of Terms: Materials Characterization
Available to PurchaseSeries: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0005692
EISBN: 978-1-62708-178-8
... in the intensity of the beam ac noncapacitive arc. A high-voltage elec- of the response to measurement (for ex- (light, x-rays, electrons, and so on) when trical discharge used in spectrochemical ample, emission, absorbance, and con- passing through matter. In many cases analysis to vaporize the sample material...
Abstract
This article is a compilation of definitions of terms related to materials characterization techniques.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001730
EISBN: 978-1-62708-178-8
... corresponding to the difference in energies between the ground state and an excited state of the analyte element is passed through the atomizer. This light is generated by a low-pressure electrical discharge lamp containing a volatile form of the analyte element. Free analyte atoms within the atomizer absorb...
Abstract
Atomic absorption spectrometry (AAS) is generally used for measuring relatively low concentrations of approximately 70 metallic or semimetallic elements in solution samples. This article describes several features that are common to three techniques, namely, AAS, atomic emission spectrometry (AES), and atomic fluorescence spectrometry (AFS). It discusses the reasons for the extreme differences in AAS sensitivities that affect AFS and AES. The article provides information on the advantages and disadvantages of the Smith/Hieftje system and two types of background correction systems, namely, the continuum-source background correction and Zeeman background correction. It also provides a list of applications of conventional AAS equipment, which includes most of the types of samples brought to laboratories for elemental analyses.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006653
EISBN: 978-1-62708-213-6
... for absorption measurements to only a few millimeters. The measured absorbance is proportional to the number of absorbing species (i.e., gaseous atoms) within the optical viewing volume ( Ref 1 , 6 ). Therefore, the absorbance is related to both the path length of the incident light within the metal atom...
Abstract
This article focuses on some of the factors pertinent to atomic absorption spectroscopy (AAS). It begins by describing the working principle, critical components, and construction of flame atomic absorption instrumentation. This is followed by sections discussing various types of interferences in AAS, namely vaporization, ionization, matrix interferences, and background correction. Some of the methods for the analysis of microliter-sized samples and methods of standard additions to the sample solution for generating calibration standards are then reviewed. The article concludes with a section on processes involved in matrix matching.
Book Chapter
Sheet Molding Compounds
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003035
EISBN: 978-1-62708-200-6
... and mechanical properties, including catalyst, fillers, thickeners, pigments, thermoplastic polymers, flame retardants, and ultraviolet absorbers. It talks about the mixing techniques available for SMC resin pastes, including batch, batch/continuous, and continuous mixing. The article also outlines the design...
Abstract
Sheet molding compounds (SMCs) refers to both material and process for producing glass-fiber-reinforced polyester resin items. This article discusses the material components incorporated into the resin paste for desirable processing and molding characteristics and optimum physical and mechanical properties, including catalyst, fillers, thickeners, pigments, thermoplastic polymers, flame retardants, and ultraviolet absorbers. It talks about the mixing techniques available for SMC resin pastes, including batch, batch/continuous, and continuous mixing. The article also outlines the design features and the operations of continuous-belt and beltless machine type SMCs.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006073
EISBN: 978-1-62708-172-6
.... Recently, however, experience has shown that there is sufficient radiation and penetration of UV light as low as 280 nm to cause deterioration of paint. Ultraviolet radiations below this wavelength are not considered detrimental, because they are generally absorbed by moisture and other small molecules...
Abstract
This article discusses the environmental influences on protective coating films that can result in deterioration. These environmental factors can be classified into four groups: (1) energy: solar, heat; (2) permeation: moisture, solvent, chemical, and gas; (3) stress: drying and curing-internal stress, and vibration-external stress; and (4) biological influences such as microbiological, mildew, and marine fouling.
Book Chapter
Liquid-Penetrant Inspection
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003231
EISBN: 978-1-62708-199-3
... inspection. The developer does not produce indications but simply absorbs the penetrant already present in or at the flaw and makes it more visible. Equipment Requirements With the exception of a source of ultraviolet (black) light for use with fluorescent penetrants, there is no special...
Abstract
Liquid-penetrant inspection is a nondestructive method used to find discontinuities that are open to the surface of solid, essentially nonporous materials. This article describes the physical principles and the process of liquid-penetrant inspection. It also describes the basic penetrant systems, such as the water-washable system, the post-emulsifiable system, and the solvent-removable system. The article provides information on the liquid-penetrant materials, emulsifiers, solvent cleaners, and developers. It details the equipment requirements, selection of penetrant system, and specifications and standards for the liquid-penetrant inspection.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001778
EISBN: 978-1-62708-178-8
...-through spectrophotometric cell as a detector broadens the capabilities of ion chromatography. In this mode of detection, the spectrophotometer is set to direct a given wavelength of ultraviolet or visible light through the detecting cell. Any material flowing through the cell that absorbs this wavelength...
Abstract
Ion chromatography (IC) is an analytical technique that uses columns packed with ion exchange resins to separate ions in aqueous solutions and dynamically elute them to a detector. This article provides information on the different modes of detection, namely, eluent-suppressed conductivity detection, single-column ion chromatography with conductivity detection, ion chromatography with spectrophotometric detection, and amperometric electrochemical detection. It describes the modes of separation techniques in IC and reversed-phase IC. The article discusses the detection capabilities of IC, the procedures for preparing solid and liquid samples, as well as the applications of IC.
Book Chapter
Glossary of Terms: Materials Characterization
Available to PurchaseSeries: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006748
EISBN: 978-1-62708-213-6
... of absorbing unwanted electromagnetic tron microscopy and synchrotron radiation. radiation and transmitting the remainder. A neutral density lter attenuates relatively eyepiece. The lens system used in an optical uniformly from the ultraviolet to the infra- instrument for magni cation of the image red...
Abstract
This article is a compilation of terms and definitions related to materials characterization.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001777
EISBN: 978-1-62708-178-8
... phase. The ultraviolet/visible (UV/VIS) absorbance detector is currently the most popular detector of this type because most compounds absorb 190- to 700-nm wavelength radiation, and many other compounds that have no absorption can be chemically reacted to form an absorbing species. There are three...
Abstract
This article introduces the fundamental concepts and the essential components of liquid chromatography (LC). It discusses the different modes of LC, such as liquid-solid chromatography, liquid-liquid chromatography, bonded-phase chromatograph, normal-phase chromatography, reversed-phase chromatography, ion-exchange chromatography, ion-pair chromatography, and size-exclusion chromatography. The article also includes a discussion on the qualitative and quantitative analyses and the applications of LC.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003432
EISBN: 978-1-62708-195-5
... functionality, which is useful in differentiating epoxies with similar EEWs. A thin film of resin is placed on a crystal, and IR light is passed through the crystal and film at varying frequencies. Functional groups absorb at certain defined frequencies. The test is usually qualitative, but because absorption...
Abstract
This article focuses on epoxy because this resin category has widespread use and because it is tested using quality control measures typical of most resin systems. It explains that a typical resin system will consist of one or more epoxy resins, a curing agent, and a catalyst to control the rate of reaction. The article describes the component material tests, mixed resin system tests, and prepreg tests for the resin system. These tests include high-performance liquid chromatography, infrared spectroscopy, and gel permeation chromatography. The article contains a table that lists typical resin and prepreg property tests.
Book Chapter
Magnetic-Particle Inspection
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003232
EISBN: 978-1-62708-199-3
... as the base for wet particles. For increased visibility, particles are coated with fluorescent pigment by the manufacturer. Inspection is conducted in total or partial darkness, using ultraviolet light to activate the fluorescent dyes. Inspected surfaces should be illuminated with a minimum of 1000 μW/cm...
Abstract
Magnetic-particle inspection is a nondestructive testing technique used to locate surface and subsurface discontinuities in ferromagnetic materials. Beginning with an overview of the applications, advantages, and limitations of magnetic-particle inspection, this article provides a detailed account of the portable power sources available for magnetization, and the different ways of generating magnetic fields using yokes, coils, central conductors, prod contacts, direct-contact, and induced current. In addition, the article discusses the characteristics and classification, and properties of magnetic particles and suspended liquids. Finally, the article outlines the types of discontinuities (surface and subsurface) that can be identified by magnetic-particle inspection and the importance of demagnetization after inspection.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006051
EISBN: 978-1-62708-172-6
...) Reactive diluents Butyl glycidyl ether, C12-C14 aliphatic glycidyl ether, cresyl glycidyl ether, 2-ethylhexyl glycidyl ether Polyurethane Ultraviolet absorbers Titanium dioxide, zinc oxide, cerium oxide, hindered-amine light stabilizers Waterborne polymer Surfactants Polyethoxylated octyl phenol...
Abstract
A coating can be defined as a substance spread over a surface to provide protection or to serve decorative purposes. This article discusses two industrial coating components, namely, nonvolatile components such as the resin or binder, pigments, and any additives that may be incorporated into the formulation; and volatile components such as solvents, or water in emulsions and their composition. It provides general information on volatile organic compounds. The article describes the film-forming mechanisms of various coating types, namely, lacquers, chemically converting coatings, latex coatings, alkyds and other resins, which cure by oxidation, moisture-curing polyurethanes and inorganic zinc primers, and powder coatings. The article concludes with a discussion on the functions of the primer, intermediate coat, and topcoat in coating systems.
Book Chapter
Thermal Inspection
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003239
EISBN: 978-1-62708-199-3
...-gloss appearance when viewed with oblique illumination. Thermally Quenched Phosphors Thermally quenched phosphors are organic compounds that emit visible light when excited by ultraviolet light. The brightness of a phosphor is inversely proportional with temperature over a range from room...
Abstract
Thermal inspection comprises all methods in which heat-sensing devices or substances are used to detect irregular temperatures. Inspection of workpieces can be used to detect flaws and undesirable distribution of heat during service. Though there are several methods of thermal inspection and many types of temperature-measuring devices and substances, this article focuses only on thermography, which is the mapping of isotherms, or contours of equal temperature, over a test surface, and on thermometry, which is the measurement of temperature. Thermography techniques can be classified as contact thermographic methods using cholesteric liquid crystals, thermally quenched phosphors, and heat-sensitive paints, and noncontact techniques using hand-held infrared scanners, high-resolution infrared imaging systems, and thermal wave interferometer systems. Contact thermometric inspection devices include bolometers, thermocouples, thermopiles, and meltable substances, whereas radiometers and pyrometers come under the noncontact category.
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