This article focuses on ceramics, glasses, glass-ceramics, and their derivatives, that is, inorganic-organic hybrids, in the forms of solid or porous bodies, oxide layers/coatings, and particles with sizes ranging from nanometers to micrometers, or even millimetres. These include inert crystalline ceramics, porous ceramics, calcium phosphate ceramics, and bioactive glasses. The article discusses the compositions of ceramics and carbon-base implant materials, and examines their differences in processing and structure. It describes the chemical and microstructural basis for their differences in physical properties, and relates properties and hard-tissue response to particular clinical applications. The article provides information on glass or glass-ceramic particles for cancer treatments.

Ceramic-matrix composites (CMCs) are being developed for a number of high-temperature and high-performance applications in industrial, aerospace, and energy conservation sectors. This article focuses on processing, fabrication, testing, and characterization methods of CMCs, namely, discontinuously reinforced composites and continuous-fiber-reinforced composites. Processing methods include cold pressing, sintering, hot pressing, reaction bonding, melt infiltration, directed metal oxidation, sol-gel and polymer pyrolysis, self-propagating high-temperature synthesis and joining. A table summarizes the properties of various ceramic reinforcements and industrial applications of these composites.

The selection of engineered materials is an integrated process that requires an understanding of the interaction between materials properties, manufacturing characteristics, design considerations, and the total life cycle of the product. This article classifies various engineered materials, including ferrous alloys, nonferrous alloys, ceramics, cermets and cemented carbides, engineering plastics, polymer-matrix composites, metal-matrix composites, ceramic-matrix and carbon-carbon composites, and reviews their general property characteristics and applications. It describes the synergy between the elements of the materials selection process and presents a general comparison of material properties. Finally, the article provides a short note on computer aided materials selection systems, which help in proper archiving of materials selection decisions for future reference.

This article addresses the types, properties, forms, and applications of fibers that are available for use in fiber-reinforced polymeric matrix composites, including glass, graphite, carbon, aramid, boron, silicon carbide, ceramic, continuous oxide and discontinuous oxide fibers. It describes the functions, types, and chemical composition of fiber sizing agents. The article discusses the styles, properties, applications, and weaving methods of unidirectional, two-directional and multidirectionally reinforced fabrics. The article also reviews the use of prepreg resins in aerospace and lower performance applications.

This article explains how ceramic powders are made. It begins by briefly describing the raw materials used in structural clay products, whitewares, refractories, and advanced ceramics. It then examines various additives that promote uniformity at different stages of the process. After a description of the comminution process (wet and dry milling methods), it discusses batching and mixing operations and granulation methods. The article also deals with the effect of process variables and the steps involved in chemical synthesis, including preparation from solution and gas-phase reactions, filtration and washing, and powder recovery techniques. It concludes with a discussion on characterization, centering on size distribution analysis, specific surface area, density, porosity chemical composition, phase, and surface composition.

This article describes the chemical composition, physical properties, thermal properties, mechanical properties, electrical properties, optical properties, magnetic properties, and chemical properties of glasses, glass-matrix composites, and glass-ceramics.

The biocompatibility of a material relates to its immunological response, toxicity profile, and ability to integrate with surrounding tissue without undesirable local or systemic effects on a patient. This article underscores the transformation of the medical device design ecosystem engaged as an integral part of the device ecosystem. It discusses the various applications of biomaterials, including orthopedic, cardiovascular, ophthalmic, and dental applications. The article describes the four major categories of biomaterials, such as metals, polymers, glass and ceramics, and composites. A discussion on natural materials, nanomaterials, and stem cells is also provided. The article concludes with information on examples of biomaterials applications, including endovascular devices, knee implants, and neurostimulation.

This article reviews the friction and wear of various dental materials that have been studied by fundamental wear measurements, simulated service wear measurements, and clinical measurements. The materials include dental amalgam, composite restorative materials, pit and fissure sealants, dental cements, porcelain and plastic denture teeth, dental feldspathic porcelain and ceramics, endodontic instruments, periodontal Instruments, and orthodontic wires. The article describes the correlations of properties, such as hardness, fracture toughness, and wear. It discusses wear mechanism such as sliding adhesive wear, two-body abrasion, three-body abrasion, erosion, and fatigue.

Painting is a generic term for the application of a thin organic coating to the surface of a material for decorative, protective, or functional purposes. This article provides a detailed account of the types and selection factors of paints and the various application methods, including conventional air atomized, airless, and electrostatic spray; roller coating; dip coating; flow coating; curtain coating; tumble coating; electrocoating; and powder coating. Surface preparation methods and prepaint treatments for coating systems are also discussed. The article includes information on quality control procedures, causes of paint film defects, cost calculation, and safety and environmental precautions. The composition and characteristics of organic coatings, coating system selection factors, the types of paints for structural steel, and the applications of paint on structural steel are also reviewed.

This article outlines some of the selection criteria for choosing an implant material for biomedical devices in orthopedic, dental, soft-tissue, and cardiovascular applications. It details the development of implants based on materials, such as metallic implants, ceramic implants, and polymeric implants. The article discusses the specific problems associated with implant manufacturing processes and the consequent compromises in properties of functionally graded implants. It describes the manufacturing of the functionally-graded hip implant by using the LENS process. It reviews the four different types of tissue responses to the biomaterial. The article discusses the testing of implant failure, such as in vitro and in vivo assessment of tissue compatibility.

Acrylic coatings are one of the major generic classes of organic coatings and are prevalent in both architectural and industrial applications. This article provides information on the chemistry of acrylic polymers, the methods used in their manufacture, the relationship between structure and properties when they are formulated into coatings, and how they are being used in coatings. The main discussion points are the differences between solventborne and waterborne technologies and some of the challenges in formulating and applying waterborne acrylic coatings. The article describes the mechanism of film formation of acrylic latex polymers and its effect on final coating properties. It discusses the types of waterborne acrylic latex coatings based on chemical properties and based on applications such as primers, intermediate coats, topcoats, stains, and direct-to-substrate finishes. The article concludes with a description of the advances in the development of waterborne acrylic coatings for maintenance and protective applications.

Polymeric floor coatings refer to flooring materials composed of multicomponent thermoset resins formulated with various fillers and pigments that are installed in situ, usually over concrete substrates. Polymeric flooring systems, specified for all industrial and commercial environments, use a variety of polymer chemistries and are constructed in a variety of methods and designs. This article provides a description of the service conditions for the polymeric flooring systems. It provides information on polymeric flooring systems, including thin-film coatings, self-leveling systems, membrane systems, broadcast systems, troweled systems, and terrazzo. The article also focuses on properties, applications, testing, and factors and requirements to be considered during the installation of polymeric floor coatings. It concludes with a discussion about coating failures, including bonding, cracking, chemical attack, and moisture that affect the polymeric floor coatings on concrete.

Polymers offer a wide range of choices for medical applications because of their versatility in properties and processing. This article provides an overview of polymeric materials and the characteristics that make them a unique class of materials. It describes the ways to classify polymers, including the polymerization method, how the material deforms, or molecular origin or stability. The article contains tables that list common medical polymers used in medical devices. It describes the medical polymer selection criteria and regulatory aspects of materials selection failure analysis and prevention. Failure analysis and prevention processes to determine the root cause of failures that arise at different stages of the product life cycle are reviewed. The article describes the mechanisms of plastic product failure analysis. It discusses the trends in the use of medical polymers, such as high-performance polymers for implants, tissue engineering, and bioresorbable polymers.

Nanotechnology and smart-coating technologies have been reported to show great promise for improved performance in critical areas such as corrosion resistance, durability, and conductivity. This article exemplifies nanofilms and nanomaterials used in coatings applications, including carbon nanotubes, silica, metals/metal oxides, ceramics, clays, buckyballs, graphene, polymers, titanium dioxide, and waxes. These can be produced by a variety of methods, including chemical vapor deposition, plasma arcing, electrodeposition, sol-gel synthesis, and ball milling. The application of nanotechnology and the development of smart coatings have been dependent largely on the availability of analytical and imaging techniques such as Raman spectroscopy, scanning and transmission electron microscopy, atomic force microscopy, and scanning tunneling microscopy.

This article focuses on those areas of coatings technology where silicon-based technology (SBT) is the primary enabling technology and where SBT is used as an additive to provide unique properties to the coating film. It describes the chemistry and the uses of alkoxy silanes. The uses of silicates, siliconates, silicone fluids, and silicone resins in coatings are reviewed. The article discusses the various applications of SBT, namely, primers, heat-resistant coatings, industrial maintenance coatings, hygienic coatings, and abrasion-resistant coatings, and for marine biofouling control. It also provides information on the benefits of silicon-base additives.

This article describes eight stages of the atomistic film growth: vaporization of the material, transport of the material to the substrate, condensation and nucleation of the atoms, nuclei growth, interface formation, film growth, changes in structure during the deposition, and postdeposition changes. It also discusses the effects and causes of growth-related properties of films deposited by physical vapor deposition processes, including residual film stress, density, and adhesion.

This article reviews the basic types of mold aggregates and bonding methods for expendable molds and coremaking. It provides an overview of mold media and the basic types of sands and their properties. The most significant clays used in green sand operations, such as bentonites, are discussed. The article describes the methods of sand bonding with inorganic compounds. It provides a description of resin-bonded sand systems, namely, no-bake binder systems, heat-cured binder systems, and cold box binder systems. The article concludes with a discussion on the media used for expendable molds, namely, ceramic shells and rammed graphite, for casting reactive metals such as titanium or zirconium.

An alkyd is an ester-based polymer derived from the polycondensation reaction of polyhydric alcohol and polybasic acid. This article provides useful information on the chemistry, production, coating formulations, modification, commercial products, and application methods of alkyd resins. It also provides a section on drying oil, which is used in the manufacture of resins. The article describes the three categories of metals that have been used in drier compounds: primary driers (active or oxidation driers), secondary driers (through-driers), and auxiliary driers. It also provides information on the oil length of an alkyd resin and on solvents, which play a critical role in the formulation and use of the coating. The article concludes with a description of the concerns that a user, specifier, or applicator should be aware of when using alkyd coatings.