This article reviews the bulk deformation processes for various aluminide and silicide intermetallic alloys with emphasis on the gamma titanium aluminide alloys. It summarizes the understanding of microstructure evolution and fracture behavior during thermomechanical processing of the gamma aluminides with particular reference to production scaleable techniques, including vacuum arc and cold-hearth melting, isothermal forging, conventional hot forging, and extrusion. The selection and design of manufacturing methods, in the context of processing-cost trade-offs for gamma titanium aluminide alloys, are also discussed.

Titanium and its alloys are used in various applications owing to its high strength, stiffness, good toughness, low density, and good corrosion resistance. This article discusses the applications of titanium and titanium alloys in gas turbine engine components, aerospace pressure vessels, optic-system support structures, prosthetic devices, and applications requiring corrosion resistance and high strength. It explains the effects of alloying elements in titanium alloys as they play an important role in controlling the microstructure and properties and describes the secondary phases and martensitic transformations formed in titanium alloy systems. Information on commercial and semicommercial grades and alloys of titanium is tabulated. The article also discusses the different grades of titanium alloys such as alpha, near-alpha alloys, alpha-beta alloys, beta alloys, and advanced titanium alloys (titanium-matrix composites and titanium aluminides).

Alloys based on ordered intermetallic compounds constitute a unique class of metallic material that form long-range ordered crystal structures below a critical temperature. Aluminides, a unique class of ordered intermetallic materials, possesses many attributes like low densities, high melting points, and good high-temperature strength that make them an attractive material for high-temperature structural application. This article discusses the properties, chemical composition, corrosion resistance, processing, fabrication, alloying effects and crystallographic data of nickel aluminides (Ni3Al and NiAl), iron aluminides (Fe3Al and FeAl) and titanium aluminides (alpha-2 alloys, orthorhombic alloys, and gamma alloys).

Titanium alloys are forged into a variety of shapes and types of forgings, with a broad range of final part forging design criteria based on the intended end-product application. This article begins with a discussion on the classes of titanium alloys, their forgeability, and factors affecting forgeability. It describes the forging techniques, equipment, and common processing elements associated with titanium alloy forging. The processing elements include the preparation of forging stock, preheating of the stock, die heating, lubrication, forging process, trimming and repair, cleaning, heat treatment, and inspection. The article presents a discussion on titanium alloy precision forgings and concludes with information on the forging of advanced titanium materials and titanium aluminides.

This article provides a detailed discussion on heat treatment of titanium alloys such as alpha alloys, alpha-beta alloys, and beta and near-beta alloys. Common processes include stress-relief, annealing, solution treating, aging, quenching, and age hardening. It provides information on the effects of alloying elements on alpha/beta transformation. The article also discusses the heat treating procedures, and the furnaces used for heat treating titanium and titanium alloys.

The combination of high strength-to-weight ratio, excellent mechanical properties, and corrosion resistance makes titanium the best material choice for many critical applications. This article begins with a description of the historical perspective of titanium casting technology. It discusses the types of molding methods, such as rammed graphite molding and lost-wax investment molding. The article provides information on the casting design, melting, postcasting, and pouring practices. It describes the microstructure and mechanical properties of Ti-6AI-4V alloy. The article examines the product applications of titanium alloy castings. The tensile properties, standard industry specifications, and chemical compositions of various titanium alloy castings are tabulated.

This article reviews cleaning and finishing operations that have proven to be effective on titanium, its alloys, and semi-fabricated titanium products. It explains how to remove scale, tarnish films, grease, and other soils and how to achieve required finishes and/or improve wear and oxidation resistance through the use of polishing, buffing, and wire brushing operations. The article also covers a wide range of surface modification and coating processes, including ion implantation, diffusion, chemical and physical vapor deposition, plating, anodizing, and chemical conversion coatings as well as sprayed and sol-gel coatings and laser and electron-beam treatments.

This article introduces the different types, distinctions, and grades of commercially pure titanium and titanium alloys. It describes three types of alloying elements: alpha stabilizers, beta stabilizers, and neutral additions. The article discusses the basic categories of titanium alloys, namely, alpha and near-alpha titanium alloys, beta and near-beta titanium alloys, and alpha-beta titanium alloys. It also describes the general microstructural features of titanium alloys.

This article discusses surface engineering of nonferrous metals including aluminum and aluminum alloys, copper and copper alloys, magnesium alloys, nickel and nickel alloys, titanium and titanium alloys, zirconium and hafnium, zinc alloys, and refractory metals and alloys. It describes various techniques to improve functional surface properties and enhance the appearance of product forms. The article discusses various cleaning and finishing techniques such as abrasive blast cleaning, polishing and buffing, barrel burnishing, chemical cleaning, pickling, etching and bright dipping, electrochemical cleaning, mechanical cleaning, and mass finishing. It also examines coating processes such as plating, anodizing, chemical conversion coating, and thermal spray, and concludes with a discussion on oxidation-resistant coatings for refractory metals.

Metalworking is one of the three major technologies used to fabricate metal products. This article tabulates the classification of metal forming processes. It discusses different types of metalworking equipment, including rolling mills, ring-rolling machines, and thread-rolling and surface-rolling machines. The article outlines the significant characteristics of pressing-type machines: load and energy characteristics, time-related characteristics, and accuracy characteristics. It summarizes different specialized processes such as advanced roll-forming methods, equal-channel angular extrusion, incremental forging, and microforming. The article describes the thermomechanical processing of nickel- and titanium-base alloys and concludes with information on the advancements in process simulation.

Metal-matrix composites (MMCs) are a class of materials with potential for a wide variety of structural and thermal applications. This article discusses the mechanical properties of MMCs, namely aluminum-matrix composites, titanium-matrix composites, magnesium-matrix composites, copper-matrix composites, superalloy-matrix composites, and intermetallic-matrix composites. It describes the processing methods of discontinuous aluminum MMCs which include casting processes, liquid-metal infiltration, spray deposition and powder metallurgy. The article provides useful information on aluminum MMC designation system and also describes the types of continuous fiber aluminum MMCs, including aluminum/boron MMC, aluminum/silicon carbide MMC, aluminum/graphite MMC, and aluminum/alumina MMC.

Grain refinement in aluminum casting alloys tends to reduce the amount of porosity and the size of the pores and to improve mechanical properties, especially fatigue strength. This article provides information on measurement of grain size in alloys and describes the mechanisms of grain refinement in aluminum casting alloys. It reviews the use of boron and titanium as a grain refiner for aluminum casting alloys. The article discusses the best practices for grain refinement in various aluminum casting alloys. These include aluminum-silicon casting alloys, aluminum-silicon-copper casting alloys, aluminum-silicon-copper casting alloys, aluminum-zinc-magnesium casting alloys, and aluminum-magnesium casting alloys. The article also discusses benefits of grain refinement in aluminum casting alloys.

This article begins with the discussion on the background of metal-matrix composites (MMC) and moves into a broad description of the general parameters affecting the corrosion of MMC. It discusses the primary sources of MMC corrosion that include galvanic corrosion between MMC constituents, chemical degradation of interphases and reinforcements, microstructure-influenced corrosion, and processing-induced corrosion. The article elaborates on the corrosion behavior of specific aluminum, magnesium, titanium, copper, stainless steel, lead, depleted uranium, and zinc MMCs systems. It concludes with a description on the corrosion control of MMCs using protective coatings and inhibitors.

This article reviews the corrosion behavior of intermetallics for the modeling of the corrosion processes and for devising a strategy to create corrosion protective systems through alloy and coating design. It discusses the high-temperature corrosion properties of intermetallics and aqueous corrosion properties. Thermodynamic principles in the context of high-temperature corrosion and information on oxidation; sulfidation; hot corrosion of NiAl-, FeAl-, and TiAl-based intermetallics; and silicides are included. The article explores the thermodynamic consideration, ordering influencing kinetics, stress-cracking corrosion, and hydrogen embrittlement of aqueous corrosion. It also explains the practical issues dealing with the corrosion problems.

This article discusses two types of hot-tension tests, namely, the Gleeble test and conventional isothermal hot-tension test, as well as their equipment. It summarizes the data for hot ductility, strength, and hot-tension for commercial alloys. The article presents isothermal hot-tension test data, which helps to gain information on a number of material parameters and material coefficients. It details the effect of test conditions on flow behavior. The article briefly describes the detailed interpretation of data from the isothermal hot-tension test using numerical model. It also explains the cavitation mechanism and failure modes that occur during hot-tension testing.

This article focuses on the modeling and simulation of cavitation phenomena. It summarizes the experimental observations of cavitation and reviews the modeling of cavity nucleation and growth. The article discusses the modeling of the cavity growth based on mesoscale and microscale under uniaxial versus multiaxial tensile-stress conditions. Mesoscale models incorporate the influence of local microstructure and texture on cavitation. The article outlines the descriptions of cavity coalescence and shrinkage. It also describes the simulation of the tension test to predict tensile ductility and to construct failure-mechanism maps.

Plasma melting is a material-processing technique in which the heat of a thermal plasma is used to melt a material. This article discusses the two typical design principles of plasma torches in the transferred mode: the tungsten tip design and the hollow copper electrode design. It briefly describes the sources of atmospheric contamination in plasma melting furnaces and their control measures. The equipment used in plasma melting furnaces are also discussed. The article provides a detailed discussion on various plasma melting processes, such as plasma consolidation, plasma arc remelting, plasma cold hearth melting, and plasma casting.

Neural-network (NN) modeling is most suitable for simulations of correlations that are hard to describe or cannot be accurately predicted by physical models. This article describes the principles and procedures of NN modeling. It discusses the use of NN modeling in general organization of software and graphical user interfaces. The article also provides information on the ways to improve and upgrade the NN models.

This article presents the principles of chemical vapor deposition (CVD) with illustrations. It discusses the types of CVD processes, namely, thermal CVD, plasma CVD, laser CVD, closed-reactor CVD, chemical vapor infiltration, and metal-organic CVD. The article reviews the CVD reactions of materials related to hard, tribological, and high-temperature coatings and to free-standing structures. It concludes by reviewing the advantages, disadvantages, and applications of CVD.

This article reviews the general aspects of microstructure evolution during thermomechanical processing. The effect of thermomechanical processing on microstructure evolution is summarized to provide insight into the aspect of process design. The article provides information on hot working and key processes that control microstructure evolution: dynamic recovery, static recovery, recrystallization, and grain growth. Some of the key phenomenological descriptions of plastic flow and microstructure evolution are also summarized. The article concludes with a discussion on the modeling of microstructure evolution.