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Book Chapter
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003818
EISBN: 978-1-62708-183-2
... behavior on soft solders, pewter, bearing alloys, tin-copper alloys, and tin-silver alloys. It reviews the influence of corrosion on immersion tin coating, tin-cadmium alloy coatings, tin-cobalt coatings, tin-copper coatings, tin-lead coatings, tin-nickel coatings, and tin-zinc coatings. The general...
Abstract
This article describes the allotropic modification and atmospheric corrosion of pure tin. Corrosion of pure tin due to oxidation reaction, and reaction with the other gases, water, acids, bases, and other liquid media, is discussed. The article provides information on corrosion behavior on soft solders, pewter, bearing alloys, tin-copper alloys, and tin-silver alloys. It reviews the influence of corrosion on immersion tin coating, tin-cadmium alloy coatings, tin-cobalt coatings, tin-copper coatings, tin-lead coatings, tin-nickel coatings, and tin-zinc coatings. The general properties and corrosion resistance of tinplate are summarized. The article also describes the methods of corrosion testing of coatings; these include an analysis of coating thickness measurements, porosity and rust resistance testing, solderability test, and specific special tests.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003778
EISBN: 978-1-62708-177-1
... preparation tin tin alloy coatings tin alloys tin-antimony alloys tin-antimony-copper alloys tin-antimony-copper-lead alloys tin-copper alloys tin-indium alloys tin-lead alloys tin-lead-cadmium alloys tin-silver alloys tin-zinc alloys tin-zinc-copper alloys TIN AND TIN ALLOYS are extremely...
Abstract
This article describes the specimen preparation steps for tin and tin alloys, and for harder base metals which are coated with these materials with illustrations. The steps discussed include sectioning, mounting, grinding, polishing, and etching. The article provides information on etchants for tin and tin alloys in tabular form. It presents the procedure recommended for electron microscopy to determine the nature of the intermetallic compound formed by the reaction between tin or tin-lead coatings on various substrates. The article concludes with an illustration of the microstructures of tin-copper, tin-lead, tin-lead-cadmium, tin-antimony, tin-antimony-copper, tin-antimony-copper-lead, tin-silver, tin-indium, tin-zinc, and tin-zinc-copper systems.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001460
EISBN: 978-1-62708-173-3
... with eutectic tin-lead solder (step soldering). Tin-Silver Alloys The eutectic composition, 96.5Sn-3.5Ag, is generally used, although alloy compositions are available with silver contents of up to 5%. These alloys are used at the high-temperature attachment stage of step soldering processes with eutectic...
Abstract
Soldering represents the primary method of attaching electronic components, such as resistors, capacitors, or packaged integrated circuits, to either printed wiring board whose defects is minimized by consideration of proper PWB design, device packages, and board assembly. This article discusses the categories that are most important to successful electronic soldering, namely, solders and fluxes selection, nature of base materials and finishes, solder joint design, and solderability testing.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001459
EISBN: 978-1-62708-173-3
... A (alloys with tin content greater than 35 wt%), maximum of 0.12 wt%; Class B, 0.2 to 0.5 wt%; and Class C (tin content, 20 to 40 wt%), maximum of 6 wt% ( Ref 5 ). ASTM B 32 specification for tin-lead, tin-lead-antimony, tin-lead-silver, and lead-silver solders Table 2 ASTM B 32 specification for tin...
Abstract
Soldering technology has been used in applications ranging from the packaging of integrated circuit chips to the fabrication of industrial heat exchangers and consequently in structural or electronic applications. This article provides information on various soldering parameters, including types of solder alloy in terms of selection process; selection of substrate base material; flux selection based on adequate wettability by the solder; solder joint assembly; combined substrate, solder, and flux properties; and manufacturing procedures. Each of these parameters is explored using examples of both structural and electronic applications. The article concludes with a discussion on the environmental, safety, and health issues to be considered during soldering.
Book Chapter
Series: ASM Handbook
Volume: 22A
Publisher: ASM International
Published: 01 December 2009
DOI: 10.31399/asm.hb.v22a.a0005444
EISBN: 978-1-62708-196-2
... alloys; tin and tin alloys; titanium and titanium alloys; zinc and zinc alloys; and pure metals. thermal conductivity aluminum aluminum alloys copper copper alloys iron iron alloys lead lead alloys magnesium magnesium alloys nickel nickel alloys tin tin alloys titanium titanium...
Abstract
This article contains a table that lists the thermal conductivity of selected metals and alloys near room temperature. These include aluminum and aluminum alloys; copper and copper alloys; iron and iron alloys; lead and lead alloys; magnesium and magnesium alloys; nickel and nickel alloys; tin and tin alloys; titanium and titanium alloys; zinc and zinc alloys; and pure metals.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003211
EISBN: 978-1-62708-199-3
... Table 1 ASTM B 32 specification for tin-lead, Sn-Pb-Sb, Sn-Pb-Ag, and lead-silver solders Alloy grade Composition (a) , % Melting range (b) Solidus Liquidus Sn Pb Sb Ag Cu Cd Al Bi As Fe Zn °C °F °C °F Sn70 69.5–71.5 bal 0.50 0.015 0.08 0.001 0.005 0.25 0.03...
Abstract
Soldering involves heating a joint to a suitable temperature and using a filler metal (solder) that melts below 450 deg C (840 deg F). Beginning with an overview of the specification and standards and applications, this article discusses the principal levels and effects of the most common impurity elements in tin-lead solders. It describes the various processes involved in the successful soldering of joints, including shaping the parts to fit closely together; cleaning and preparing the surfaces to be joined; applying a flux; assembling the parts; and applying the heat and solder.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006207
EISBN: 978-1-62708-163-4
... pair. Additional binary systems that include tin are provided in the following locations in this Volume: “Ag-Sn (Silver - Tin)” in the article “Ag (Silver) Binary Alloy Phase Diagrams.” “Al-Sn (Aluminum - Tin)” in the article “Al (Aluminum) Binary Alloy Phase Diagrams.” “As-Sn...
Abstract
This article is a compilation of binary alloy phase diagrams for which tin (Sn) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004175
EISBN: 978-1-62708-184-9
... alloys, tin and tin-lead alloys, nickel, gold, palladium, and palladium-silver are employed in lead frame materials, pad metallurgies, lead finishes, etc. At the second level assembly where the packages are assembled onto the printed wiring board, the materials include copper, immersion tin, immersion...
Abstract
This article provides information on various forms of corrosion that occur in electronic packaging. Portable consumer electronic hardware which is subjected to humidity exposures is prone to condensed moisture and liquid damage. The article discusses two other corrosion-related phenomena that are found only in electronics, namely, electrochemical migration (ECM) and conductive anodic filament formation (CAF). It describes the corrosion that takes place in metals such as copper, tin, and tin-lead alloys, which are commonly used in electronic packaging. The article also discusses the corrosion of the components used in electronic assemblies.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004173
EISBN: 978-1-62708-184-9
...,” Parts Advisory NA-044, NASA Goddard Space Flight Center , Oct 1998 8. “Round Robin Testing and Analysis of Lead Free Solder Pastes with Alloys of Tin, Silver and Copper—Final Report,” SPVC2005-CD, IPC Solder Products Value Council, IPC Association Connecting Electronic Industries...
Abstract
This article focuses on the various types of corrosion-related failure mechanisms and their effects on passive electrical components. The types include halide-induced corrosion, organic-acid-induced corrosion, electrochemical metal migration, silver tarnish, fretting, and metal whiskers. The passive electrical components include resistors, capacitors, wound components, sensors, transducers, relays, switches, connectors, printed circuit boards, and hardware.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003145
EISBN: 978-1-62708-199-3
...-temperature service Tin-silver eutectic alloy ASTM B32, grade Sn96 96 Sn, 0.12 Sb, 3.4–3.8 Ag, 0.005 Al, 0.01 As, 0.15 Bi, 0.005 Cd, 0.08 Cu, 0.02 Fe, 0.10 Pb, 0.005 Zn Popular choice with properties similar to those of ASTM B 32, Grade Sn 95 Soft solder (70-30 solder) ASTM B 32, grade Sn70 70 Sn...
Abstract
Tin is a soft, brilliant white, low-melting metal that is most widely known and characterized in the form of coating. This article discusses the primary and secondary production of tin and explains the uses of tin in coating, namely tinplating, electroplating, and hot dip coatings. It presents a short note on pure (unalloyed) tin and uses of tin in chemicals. The article also covers the compositions and uses of tin alloys which include solders, pewter, bearing alloys, alloys for organ pipes, and fusible alloys. It goes on to discuss the other alloys containing tin including battery grid alloys, type metals, copper alloys, dental alloys, cast irons, titanium alloys, and zirconium alloys. Finally, it presents a short note on the applications of tin powder and corrosion resistance of tin.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006138
EISBN: 978-1-62708-175-7
... as brass. Copper-nickel-zinc alloys are known as nickel silver (a color reference). The common metal named bronze is a copper-tin alloy. Metallurgical bronzes represent a wide family of materials used in the manufacture of very diverse items. These items range from structural components to wear surfaces...
Abstract
Selection of the process steps used, powder chosen, and lubricant choice have marked effects on the quality of a sintered component. This article describes the alloy composition, mechanical and structural properties, processing routes, and advantages of the common members of the copper alloy family, namely, pure copper, brass, and bronze, which all aid in the selection of the suitable material for structural and bearing applications. It outlines the structural applications of nickel silver alloys.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006245
EISBN: 978-1-62708-163-4
... where lead is the first-named element in the ternary system. Additional ternary systems that include lead are provided in the following locations in this Volume: “Ag-Pb-Sn (Silver - Lead - Tin)” in the article “Ag (Silver) Ternary Phase Diagrams.” “Cu-Pb-Zn (Copper - Lead - Zinc...
Abstract
This article is a compilation of ternary alloy phase diagrams for which lead (Pb) is the first-named element in the ternary system. The diagrams are presented with element compositions in weight percent. The article includes 7 phase diagrams: Pb-Sb-Sn liquidus projection; Pb-Sb-Sn isothermal section at 240 °C; Pb-Sb-Sn isothermal section at 189 °C; Pb-Sb-Sn (Pb) liquidus projection; Pb-Sn-Zn liquidus projection; and Pb-Sn-Zn isothermal section at 532 °C.
Series: ASM Handbook
Volume: 4C
Publisher: ASM International
Published: 09 June 2014
DOI: 10.31399/asm.hb.v04c.a0005856
EISBN: 978-1-62708-167-2
... than lead. Traditional tin-silver solder filler metals are also now in much greater use. These have been joined by tin-copper alloys in more recent times. While tin has been rising in price over a number of years, a similar phenomenon has been happening with other precious and commodity metals...
Abstract
This article focuses on the process design set-up procedure for brazing and soldering. It provides a detailed account of the types of base metals that can be joined by these processes, and reviews the factors to be considered to enhance the joint design. Criteria for selection of the right induction heating equipment to carry out the brazing or soldering operation are also provided. The article describes the types of brazing filler metals and joint designs. It also presents the types of inspection methods, namely, mechanical and visual, used to determine the quality of the brazed joint. Important considerations for the automation of induction-heated brazing applications are also discussed. The article concludes by emphasizing the need for documenting an in-control process which is a vitally important reference for questions or problems arising in the machine settings or part quality.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003136
EISBN: 978-1-62708-199-3
... copper or may be intentionally alloyed to molten cathode copper, also imparts resistance to softening to cold-worked metal. Silver-bearing coppers and cadmium-bearing coppers are used for applications such as automotive radiators and electrical conductors that must operate at temperatures above about 200...
Abstract
Copper and copper alloys are used extensively in structural applications in which they are subject to moderately elevated temperatures. At relatively low operating temperatures, these alloys can undergo thermal softening or stress relaxation, which can lead to service failures. This article is a collection of curves and tables that present data on thermal softening and stress-relaxation in copper and copper alloys. Thermal softening occurs over extended periods at temperatures lower than those inducing recrystallization in commercial heat treatments. Stress relaxation occurs because of the transformation of elastic strain in the material to plastic, or permanent strain.
Series: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005670
EISBN: 978-1-62708-198-6
... silver powder, silver-coated silver-tin, and a small amount of silver-tin precipitated from the solution were first researched in the mid-1990s ( Ref 37 ). The direct silver alloys are included here because they form by cold welding particles together in a similar way to the gold-base direct filling...
Abstract
This article focuses on the use of noble and precious metals for biomedical applications. These include gold, platinum, palladium, ruthenium, rhodium, iridium, and osmium. The physical and mechanical properties of noble and precious metals are presented in tables. A brief discussion on the ancient history of noble and precious metal use in dentistry is provided. The article discusses the use of direct gold dental filling materials, direct silver dental filling materials, traditional amalgam alloys, high-copper amalgam alloys, and gallium alloys in biomedical applications. It also provides information on gold coatings and iridium oxide coatings for stents.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004209
EISBN: 978-1-62708-184-9
.... Contact allergic reactions to chromium from dental alloys are also reported ( Ref 20 ), but the occurrences of such reactions are rare. Mercury is contained in amalgam fillings, which contain microstructural phases composed of silver-mercury and tin-mercury. Mercury ions may be released from...
Abstract
This article describes dental alloy compositions and its properties. It discusses the safety and efficacy considerations of dental alloy devices. The article defines and compares interstitial fluid and oral fluid environments. Artificial solutions developed for the testing and evaluation of dental materials are summarized. The article examines the effects of restoration contact on electrochemical parameters and reviews the concentration cells developed by dental alloy-environment electrochemical reactions. The composition and characterization of biofilms, corrosion products, and other debris that deposit on dental material surfaces are discussed. The article evaluates the types of alloys available for dental applications, including direct filling alloys, crown and bridge alloys, partial denture alloys, porcelain fused to metal alloys, wrought wire alloys, soldering alloys, and implant alloys. The effects of composition and microstructure on the corrosion of each alloy group are also discussed. The article concludes with information on the tarnishing and corrosion behavior of these alloys.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003219
EISBN: 978-1-62708-199-3
... for tools, dies, etc. Effect much deeper than original implantation depth. Precise area treatment, excellent process control Ion plating, ARE RT-0.7 T m of coating. Best at elevated temperatures Moderate to good Ion plating: Al, other metals (few alloys) ARE: TiN and other compounds Electronic...
Abstract
Physical vapor deposition (PVD) coatings are harder than any metal and are used in applications that cannot tolerate even microscopic wear losses. This article describes the three most common PVD processes: thermal evaporation, sputtering, and ion plating. It also discusses ion implantation in the context of research and development applications.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006219
EISBN: 978-1-62708-163-4
... element in the binary pair. Additional binary systems that include ytterbium are provided in the following locations in this Volume: “Ag-Yb (Silver - Ytterbium)” in the article “Ag (Silver) Binary Alloy Phase Diagrams.” “Al-Yb (Aluminum - Ytterbium)” in the article “Al (Aluminum) Binary...
Abstract
This article is a compilation of binary alloy phase diagrams for which ytterbium (Yb) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003146
EISBN: 978-1-62708-199-3
... alloys (2.38–2.5% Ag, 4.76–5.0% In. 92.5–92.8% Pb) L51510, L51512 Lead-indium solder alloys (5.0% In, 95.0% Pb) L51511 Lead-indium alloys (19.0–70% In, 30–81% Pb) L51530, L51532, L51535, L51540, L51550, L51560, L51570 Indium-tin-lead alloy (40% In, 40% Sn, 20% Pb) L51545 Indium-silver...
Abstract
This article discusses the properties, primary and secondary production, product forms and applications of various grades of lead and lead-base alloys with the aid of several tables and illustrations. It lists the Unified Numbering System (UNS) designations for various pure lead grades and lead-base alloys grouped according to nominal chemical composition. The properties of lead that make it useful in a wide variety of applications are also discussed. The largest use of lead is in lead-acid storage batteries. Other applications include ammunition, cable sheathing, cast products such as type metals, terneplate, foils, and building construction materials. Lead is also used as an alloying element in steel and in copper alloys to improve machinability. The article concludes with information on the principles of lead corrosion, corrosion resistance of lead in water, atmospheres, underground ducts, soil and chemicals.
Book Chapter
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006412
EISBN: 978-1-62708-192-4
..., bimetal systems, and trimetal systems. The article describes the designations, nominal compositions, mechanical properties, and applications of various sliding bearing alloys: tin-base alloys, lead-base alloys, copper-base alloys, aluminum-base alloys, silver-base alloys, zinc-base alloys, additional...
Abstract
A sliding bearing (plain bearing) is a machine element designed to transmit loads or reaction forces to a shaft that rotates relative to the bearing. This article discusses the properties of bearing materials. It provides information on bearing material systems: single-metal systems, bimetal systems, and trimetal systems. The article describes the designations, nominal compositions, mechanical properties, and applications of various sliding bearing alloys: tin-base alloys, lead-base alloys, copper-base alloys, aluminum-base alloys, silver-base alloys, zinc-base alloys, additional metallic materials, nonmetallic materials. It describes casting processes, powder metallurgy processes, and electroplating processes. The article also discusses the selection criteria for bearing materials.
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