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Book Chapter
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003818
EISBN: 978-1-62708-183-2
... behavior on soft solders, pewter, bearing alloys, tin-copper alloys, and tin-silver alloys. It reviews the influence of corrosion on immersion tin coating, tin-cadmium alloy coatings, tin-cobalt coatings, tin-copper coatings, tin-lead coatings, tin-nickel coatings, and tin-zinc coatings. The general...
Abstract
This article describes the allotropic modification and atmospheric corrosion of pure tin. Corrosion of pure tin due to oxidation reaction, and reaction with the other gases, water, acids, bases, and other liquid media, is discussed. The article provides information on corrosion behavior on soft solders, pewter, bearing alloys, tin-copper alloys, and tin-silver alloys. It reviews the influence of corrosion on immersion tin coating, tin-cadmium alloy coatings, tin-cobalt coatings, tin-copper coatings, tin-lead coatings, tin-nickel coatings, and tin-zinc coatings. The general properties and corrosion resistance of tinplate are summarized. The article also describes the methods of corrosion testing of coatings; these include an analysis of coating thickness measurements, porosity and rust resistance testing, solderability test, and specific special tests.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003778
EISBN: 978-1-62708-177-1
..., a supporting layer is deposited on the surface by electroplating or electroless plating before mounting. The coating should be harder than the specimen; copper and nickel coatings are most often used. Grinding and Polishing Distortion of the surface layers of tin and tin alloys may cause...
Abstract
This article describes the specimen preparation steps for tin and tin alloys, and for harder base metals which are coated with these materials with illustrations. The steps discussed include sectioning, mounting, grinding, polishing, and etching. The article provides information on etchants for tin and tin alloys in tabular form. It presents the procedure recommended for electron microscopy to determine the nature of the intermetallic compound formed by the reaction between tin or tin-lead coatings on various substrates. The article concludes with an illustration of the microstructures of tin-copper, tin-lead, tin-lead-cadmium, tin-antimony, tin-antimony-copper, tin-antimony-copper-lead, tin-silver, tin-indium, tin-zinc, and tin-zinc-copper systems.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001257
EISBN: 978-1-62708-170-2
... environment. Several zinc alloy processes are currently in commercial use. The choice of a particular process depends on the end-product requirements and conditions of use. Available alloys are zinc-iron, zinc-cobalt, zinc-nickel, and tin-zinc. As in unalloyed zinc plating, chromate conversion coating...
Abstract
This article provides information on the compositions of alkaline and acid baths and process parameters for zinc-iron, zinc-cobalt, zinc-nickel, and tin-zinc plating.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001460
EISBN: 978-1-62708-173-3
... or those that will experience elevated temperatures (as in testing requirements) should be covered by a solderable layer of electroplated nickel (1.5 to 3.8 μm, or 60 to 150 μin.), followed by one of the above protective finishes. This coating structure will prevent the excessive formation of copper-tin...
Abstract
Soldering represents the primary method of attaching electronic components, such as resistors, capacitors, or packaged integrated circuits, to either printed wiring board whose defects is minimized by consideration of proper PWB design, device packages, and board assembly. This article discusses the categories that are most important to successful electronic soldering, namely, solders and fluxes selection, nature of base materials and finishes, solder joint design, and solderability testing.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001256
EISBN: 978-1-62708-170-2
... for tin-lead. Bismuth as an alloying agent prevents the whiskering and tin pest that can occur in tin coatings. Tin-Nickel Tin-nickel is used for corrosion-resistant coatings, especially in seawater environments. It has an attractive chromelike appearance and high lubricity when plated over bright...
Abstract
Electrodeposition of tin alloys is used to protect steel against corrosion or wear, to impart resistance to etching, and to facilitate soldering. This article focuses on the compositions, operating conditions, advantages, and limitations of methane sulfonic acid plating solutions and fluoborate plating solutions for tin-lead. It briefly describes the solution compositions and operating conditions of tin-bismuth, tin-nickel, and tin-zinc.
Image
Published: 01 December 2004
Fig. 11 Scanning electron micrograph of tin-plated nickel specimen that was stored 11 years at room temperature. The tin coating has been removed using the same solution as Figure 9 revealing the nickel-tin intermetallic compound formed by solid-state diffusion. 1000×
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Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001271
EISBN: 978-1-62708-170-2
... in continuous steel strip plating lines is electrodeposited with one of five metallic coatings: zinc, tin, chromium, and alloys of zinc with either nickel or iron. Several other metallic coatings, such as copper, nickel, brass (Cu-Zn), and terne (Pb-Sn), are also applied by continuous steel strip plating...
Abstract
This article explains the applications of continuous electroplated steel. For each category of application, the type of coating needed and the key attributes of the coating are discussed. The bulk of the article describes electrodeposition technology, including plating line components and process classification.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003687
EISBN: 978-1-62708-182-5
... of Coatings The principal metals that are widely plated are cadmium, zinc and its alloys, chromium, copper, gold, nickel, tin, and silver. Other metals that are plated by in-house shops and some job platers are cobalt, indium, iron, lead, palladium, platinum, rhenium, and rhodium. Plateable alloys add...
Abstract
This article discusses the various factors that affect the corrosion performance of electroplated coatings. It describes the effects of environment and the deposition process on substrate coatings. The article provides a discussion on the electrochemical techniques capable of predicting the corrosion performance of a plated part. It reviews the designs of coating systems for optimal protection of the substrate. The article also discusses controlled weathering tests and accelerated tests used to predict and determine the relative durability of the coating.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003218
EISBN: 978-1-62708-199-3
... the properties of typical CVD coating materials for wear and corrosion resistance. Coatings for the cutting tool industry utilize CVD processes, particularly TiC coatings for cemented tungsten carbide tools and TiN and carbonitride coatings for high-speed tool steels and cemented carbide tools. Nearly all...
Abstract
Chemical vapor deposition (CVD) involves the formation of a coating by the reaction of the coating substance with the substrate. Serving as an introduction to CVD, the article provides information on metals, ceramics, and diamond films formed by the CVD process. It further discusses the characteristics of different pack cementation processes, including aluminizing, siliconizing, chromizing, boronizing, and multicomponent coating.
Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006491
EISBN: 978-1-62708-207-5
... coatings can be applied. Electrodeposits of chromium, nickel, cadmium, copper, tin, zinc, gold, or silver are used for various decorative and functional applications. A few application examples are listed in Table 3 , and additional background is given on some early examples that have been used ( Ref 2...
Abstract
Aluminum components are often plated with other metals to mitigate the effects of corrosion and wear, improve application performance, and extend service life. This article discusses some of the more common aluminum plating processes, including electroplating, immersion plating, and electroless plating, and describes various plating materials and the types of applications in which they are used. It provides critical processing details such as temperatures, ratios, ranges, times, and rates. The article explains how to prepare aluminum components for electroplating, discussing surface roughening, anodizing, and immersion procedures along with expected results.
Series: ASM Handbook
Volume: 14B
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v14b.a0005164
EISBN: 978-1-62708-186-3
..., ASM Handbook , 1990. Common steel coatings include zinc, aluminum, tin, lead, nickel, and various alloys of these metals, as well as a range of organic coatings. Coatings such as porcelain enamels and electroplated copper or chromium are also commonly found on sheet steel parts...
Abstract
This article provides an overview of some common sheet steel coatings available. It discusses the formability differences between coated and bare steel and provides some general guidelines on the forming of coated steels. Coated steels are classified according to the nature of the substrate, the type of coating, and the method used for its application. The article describes various coating types for steels such as zinc-coated steels, aluminum-coated steels, tin-coated steels, terne-coated steels, and organic-coated steels.
Book Chapter
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001261
EISBN: 978-1-62708-170-2
... 0.030 Silver, noncyanide 0.750 Silver, pure 0.004 Babbitt 0.006 Brass 0.017 Bronze 0.017 Cobalt-nickel 0.019 Cobalt-tungsten 0.015 Nickel-cobalt 0.020 Nickel-tungsten 0.020 Tin-cadmium 0.007 Tin-indium 0.008 Tin-lead (90/10) 0.006 Tin-lead (60–40...
Abstract
Selective plating, also known as brush plating, differs from traditional tank or bath plating in that the workpiece is not immersed in a plating solution (electrolyte). Instead, the electrolyte is brought to the part and applied by a handheld anode or stylus, which incorporates an absorbent wrapping for applying the solution to the workpiece (cathode). This article focuses on the selective plating systems that include a power pack, plating tools, anode covers, specially formulated plating solutions, and any auxiliary equipment required for the particular application. It provides a detailed account of the applications of selective plating, with examples. The article describes the advantages, limitations, key process elements, and health and safety considerations of selective plating. It also includes the most important industrial, government, and military specifications.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003145
EISBN: 978-1-62708-199-3
... is determined largely by the amounts of impurities that can be tolerated in each end product. High-purity brands of tin may contain small amounts of lead, antimony, copper, arsenic, iron, bismuth, nickel, cobalt, and silver. Total impurities in commercially pure tin rarely exceed 0.25%. Tin in Coatings...
Abstract
Tin is a soft, brilliant white, low-melting metal that is most widely known and characterized in the form of coating. This article discusses the primary and secondary production of tin and explains the uses of tin in coating, namely tinplating, electroplating, and hot dip coatings. It presents a short note on pure (unalloyed) tin and uses of tin in chemicals. The article also covers the compositions and uses of tin alloys which include solders, pewter, bearing alloys, alloys for organ pipes, and fusible alloys. It goes on to discuss the other alloys containing tin including battery grid alloys, type metals, copper alloys, dental alloys, cast irons, titanium alloys, and zirconium alloys. Finally, it presents a short note on the applications of tin powder and corrosion resistance of tin.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003215
EISBN: 978-1-62708-199-3
... conditions of electrodeposition processes for chromium plating, nickel plating, iron plating, cadmium plating, zinc plating, indium plating, lead plating, tin plating, silver plating, gold plating, brass plating, bronze plating, tin-lead plating, zinc-iron plating, and zinc-nickel plating. The article also...
Abstract
Copper can be electrodeposited from numerous electrolytes. Cyanide and pyrophosphate alkalines, along with sulfate and fluoborate acid baths, are the primary electrolytes used in copper plating. This article provides information on the chemical composition, plating baths, and operating conditions of electrodeposition processes for chromium plating, nickel plating, iron plating, cadmium plating, zinc plating, indium plating, lead plating, tin plating, silver plating, gold plating, brass plating, bronze plating, tin-lead plating, zinc-iron plating, and zinc-nickel plating. The article also discusses selective plating, electroforming, and other processes and where they are typically used.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003219
EISBN: 978-1-62708-199-3
... for tools, dies, etc. Effect much deeper than original implantation depth. Precise area treatment, excellent process control Ion plating, ARE RT-0.7 T m of coating. Best at elevated temperatures Moderate to good Ion plating: Al, other metals (few alloys) ARE: TiN and other compounds Electronic...
Abstract
Physical vapor deposition (PVD) coatings are harder than any metal and are used in applications that cannot tolerate even microscopic wear losses. This article describes the three most common PVD processes: thermal evaporation, sputtering, and ion plating. It also discusses ion implantation in the context of research and development applications.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004175
EISBN: 978-1-62708-184-9
... for ECM. Furthermore, silver commonly coats the ends of the passive device to ensure that there is a good contact between the electrodes in a capacitor and the termination, which is often made of tin. Therefore, nickel is used as a barrier layer between the silver base and the tin outer layers...
Abstract
This article provides information on various forms of corrosion that occur in electronic packaging. Portable consumer electronic hardware which is subjected to humidity exposures is prone to condensed moisture and liquid damage. The article discusses two other corrosion-related phenomena that are found only in electronics, namely, electrochemical migration (ECM) and conductive anodic filament formation (CAF). It describes the corrosion that takes place in metals such as copper, tin, and tin-lead alloys, which are commonly used in electronic packaging. The article also discusses the corrosion of the components used in electronic assemblies.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001320
EISBN: 978-1-62708-170-2
... of Nonsemiconductor Materials” in this Volume. Multilayer CVD Coatings During the 1970s, CVD coatings evolved from single-layer TiC coatings to multilayer hard coatings comprising various combinations of TiC, TiCN, TiN, HfN, and Al 2 O 3 ( Fig. 3 ). Multilayer coatings, through a combination of properties...
Abstract
The classes of tool materials for machining operations are high-speed tool steels, carbides, cermets, ceramics, polycrystalline cubic boron nitrides, and polycrystalline diamonds. This article discusses the expanding role of surface engineering in increasing the manufacturing productivity of carbide, cermet, and ceramic cutting tool materials used in machining operations. The useful life of cutting tools may be limited by a variety of wear processes, such as crater wear, flank wear or abrasive wear, builtup edge, depth-of-cut notching, and thermal cracks. The article provides information on the applicable methods for surface engineering of cutting tools, namely, chemical vapor deposited (CVD) coatings, physical vapor deposited coatings, plasma-assisted CVD coatings, diamond coatings, and ion implantation.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001346
EISBN: 978-1-62708-173-3
... The coating of the base metal surfaces with a more-solderable metal or alloy prior to the soldering operation can facilitate soldering. Coatings of tin, copper, silver, cadmium, iron, nickel, and the alloys of tin-lead, tin-zinc, tin-copper, and tin-nickel are used for this purpose. The advantages...
Abstract
Soldering is defined as a joining process by which two substrates are bonded together using a filler metal with a liquidus temperature. This article provides an overview of fundamentals of soldering and presents guidelines for flux selection. Types of fluxes, including rosin-base fluxes, organic fluxes, inorganic fluxes, and synthetically activated fluxes, are reviewed. The article describes the joint design and precleaning and surface preparation for soldering. It addresses some general considerations in the soldering of electronic devices. Soldering process parameters, affecting wetting and spreading phenomena, such as temperature, time, vapor pressure, metallurgical and chemical nature of the surfaces, and surface geometry, are discussed. The article also describes the applications of furnace soldering, resistance soldering, infrared soldering, and ultrasonic soldering. It contains a table that lists tests commonly used to evaluate the solderability properties of selected soldered components.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003211
EISBN: 978-1-62708-199-3
... to the soldering operation can facilitate soldering. Coatings of tin, copper, silver, cadmium, iron, nickel, and the alloys of tin-lead, tin-zinc, tin-copper, and tin-nickel are used for this purpose. The precoating of metals that have tenacious oxide films (for example, aluminum, aluminum bronzes, stainless...
Abstract
Soldering involves heating a joint to a suitable temperature and using a filler metal (solder) that melts below 450 deg C (840 deg F). Beginning with an overview of the specification and standards and applications, this article discusses the principal levels and effects of the most common impurity elements in tin-lead solders. It describes the various processes involved in the successful soldering of joints, including shaping the parts to fit closely together; cleaning and preparing the surfaces to be joined; applying a flux; assembling the parts; and applying the heat and solder.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004126
EISBN: 978-1-62708-184-9
... performance of these coatings. Table 1 lists electroplated coatings. Typical direct current (dc) electroplated coatings used on steel surfaces include cadmium, zinc, chromium, nickel, copper, tin, lead, and aluminum. Anodizing and hardcoat are two processes used on aluminum surfaces that require dc...
Abstract
This article focuses on the various coatings used on Department of Defense (DoD) systems. These include electroplated coatings; conversion coatings; supplemental oils, waxes, and lubricants; organic paint coatings; and other finishes such as vacuum deposits, mechanical plating, thermal spray coatings, and hot-dip coatings. The article also lists the test requirements and time to failure of the coatings.
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