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Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003778
EISBN: 978-1-62708-177-1
... on etchants for tin and tin alloys in tabular form. It presents the procedure recommended for electron microscopy to determine the nature of the intermetallic compound formed by the reaction between tin or tin-lead coatings on various substrates. The article concludes with an illustration...
Abstract
This article describes the specimen preparation steps for tin and tin alloys, and for harder base metals which are coated with these materials with illustrations. The steps discussed include sectioning, mounting, grinding, polishing, and etching. The article provides information on etchants for tin and tin alloys in tabular form. It presents the procedure recommended for electron microscopy to determine the nature of the intermetallic compound formed by the reaction between tin or tin-lead coatings on various substrates. The article concludes with an illustration of the microstructures of tin-copper, tin-lead, tin-lead-cadmium, tin-antimony, tin-antimony-copper, tin-antimony-copper-lead, tin-silver, tin-indium, tin-zinc, and tin-zinc-copper systems.
Book Chapter
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003818
EISBN: 978-1-62708-183-2
... behavior on soft solders, pewter, bearing alloys, tin-copper alloys, and tin-silver alloys. It reviews the influence of corrosion on immersion tin coating, tin-cadmium alloy coatings, tin-cobalt coatings, tin-copper coatings, tin-lead coatings, tin-nickel coatings, and tin-zinc coatings. The general...
Abstract
This article describes the allotropic modification and atmospheric corrosion of pure tin. Corrosion of pure tin due to oxidation reaction, and reaction with the other gases, water, acids, bases, and other liquid media, is discussed. The article provides information on corrosion behavior on soft solders, pewter, bearing alloys, tin-copper alloys, and tin-silver alloys. It reviews the influence of corrosion on immersion tin coating, tin-cadmium alloy coatings, tin-cobalt coatings, tin-copper coatings, tin-lead coatings, tin-nickel coatings, and tin-zinc coatings. The general properties and corrosion resistance of tinplate are summarized. The article also describes the methods of corrosion testing of coatings; these include an analysis of coating thickness measurements, porosity and rust resistance testing, solderability test, and specific special tests.
Image
Published: 01 January 1993
Fig. 4 Copper-tin intermetallic layer (Cu 6 Sn 5 + Cu 3 Sn) growth kinetics. (a) For electroplated tin coating. (b) For electroplated 60Sn-40Pb coating. (c) For hot-dipped 63Sn-37Pb coating. (d) For tin-lead coatings at room temperature. Source: International Tin Research Institute and Sandia
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Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001460
EISBN: 978-1-62708-173-3
..., when compared with tin-lead alloys. Tin plate is sometimes used as a protective finish on device leads and terminations, although a solder dip coating is the preferred finish. Tin-base tin-lead solders represent the most widely used solders for electronic assembly: eutectic 63Sn-37Pb, near-eutectic...
Abstract
Soldering represents the primary method of attaching electronic components, such as resistors, capacitors, or packaged integrated circuits, to either printed wiring board whose defects is minimized by consideration of proper PWB design, device packages, and board assembly. This article discusses the categories that are most important to successful electronic soldering, namely, solders and fluxes selection, nature of base materials and finishes, solder joint design, and solderability testing.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001256
EISBN: 978-1-62708-170-2
... powder on the surface, also called tin disease ). These properties make it a valuable coating for integrated-circuit leads, surface-mount (small outline transistor) components, and circuit board connections. Tin-Bismuth Tin-bismuth processes have been developed in recent years as a substitute...
Abstract
Electrodeposition of tin alloys is used to protect steel against corrosion or wear, to impart resistance to etching, and to facilitate soldering. This article focuses on the compositions, operating conditions, advantages, and limitations of methane sulfonic acid plating solutions and fluoborate plating solutions for tin-lead. It briefly describes the solution compositions and operating conditions of tin-bismuth, tin-nickel, and tin-zinc.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003145
EISBN: 978-1-62708-199-3
... is determined largely by the amounts of impurities that can be tolerated in each end product. High-purity brands of tin may contain small amounts of lead, antimony, copper, arsenic, iron, bismuth, nickel, cobalt, and silver. Total impurities in commercially pure tin rarely exceed 0.25%. Tin in Coatings...
Abstract
Tin is a soft, brilliant white, low-melting metal that is most widely known and characterized in the form of coating. This article discusses the primary and secondary production of tin and explains the uses of tin in coating, namely tinplating, electroplating, and hot dip coatings. It presents a short note on pure (unalloyed) tin and uses of tin in chemicals. The article also covers the compositions and uses of tin alloys which include solders, pewter, bearing alloys, alloys for organ pipes, and fusible alloys. It goes on to discuss the other alloys containing tin including battery grid alloys, type metals, copper alloys, dental alloys, cast irons, titanium alloys, and zirconium alloys. Finally, it presents a short note on the applications of tin powder and corrosion resistance of tin.
Image
Published: 01 January 2002
Fig. 9 Morphology of cracks leading to rolling-contact fatigue failure of PVD (TiN) coatings. (a) Crack parallel to the interface leading to spalled area for hard substrate (60 HRC) TiN coating. (b) Cracks parallel to the coating-substrate interface for hard substrate (60 HRC) TiN coating. (c
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Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001076
EISBN: 978-1-62708-162-7
... powders find minor uses in sprayed coatings for food-handling equipment, metallizing of nonconductors, and bearing repairs. Tin particles can also be used in food can lacquers to decrease the dissolution of iron and any exposed lead-base solder by the food product. Additions of 2% tin powder and 3...
Abstract
Tin is produced from both primary and secondary sources. This article discusses the chemical compositions, production, properties, microstructure and applications of tin and tin alloys. The major tin alloys discussed here are tin-antimony-copper alloy (pewter), bearing alloy, solder alloy and other alloys containing traces of tin. Data on tin consumption in the United States is presented graphically.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001078
EISBN: 978-1-62708-162-7
... and silver. Residual zinc generally is removed by the vacuum dezincing process. In electrolytic practice, the drossed lead bullion is cast into anodes, which are placed in electrolytic cells. Lead dissolves from the anode and is deposited on the cathode. Precious metals, along with antimony, arsenic, tin...
Abstract
This article discusses the processing, properties, and applications of various grades of lead and lead-base alloys with the aid of several tables and illustrations. It lists the Unified Numbering System (UNS) designations for various pure lead grades and lead-base alloys grouped according to nominal chemical composition. The properties of lead that make it useful in a wide variety of applications are also discussed. The largest usage of lead is in the lead acid storage batteries (in the grid plates, posts, and connector straps). Other applications include ammunition; cable sheathing; cast products such as type metals, terneplates, and foils; and building construction materials. Lead is also used as an alloying element in steel and in copper alloys to improve machinability and other characteristics. In many applications, lead is combined with stronger materials to make structures that have the best qualities of both materials such as the plumbum series.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001250
EISBN: 978-1-62708-170-2
... to tinplate used for food packaging because the absence of oxygen inside tin-plated food containers prevents the electrochemical cell reactions that lead to corrosion.) Thick, nonporous coatings of tin provide long-term protection in almost any application. The required coating thickness is established...
Abstract
A tin deposit provides sacrificial protection to copper, nickel, and many other nonferrous metals and alloys. Tin also provides good protection to steel. Tin can be deposited from either alkaline or acid electrolytes. This article explains the compositions and operating conditions of these electrolytes.
Image
Published: 01 January 2003
Fig. 10 Effect of tin on internal resistance of lead alloys or lead grids with a tin-rich coating during overcharge conditions in a lead-acid battery. Source: Ref 10
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Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001459
EISBN: 978-1-62708-173-3
... 6.60 3.00 Sn 4.85 2.20 Cu 2.90 1.30 Sb 2.00 0.90 Pb 0.80 0.35 Prices shown are from 1992. Source: Ref 4 Tin-Lead, Tin-Lead-Antimony, Tin-Lead-Silver, and Lead-Silver Solder Tin-lead, tin-lead-antimony, tin-lead-silver, and lead-silver solder compositions, per ASTM...
Abstract
Soldering technology has been used in applications ranging from the packaging of integrated circuit chips to the fabrication of industrial heat exchangers and consequently in structural or electronic applications. This article provides information on various soldering parameters, including types of solder alloy in terms of selection process; selection of substrate base material; flux selection based on adequate wettability by the solder; solder joint assembly; combined substrate, solder, and flux properties; and manufacturing procedures. Each of these parameters is explored using examples of both structural and electronic applications. The article concludes with a discussion on the environmental, safety, and health issues to be considered during soldering.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004172
EISBN: 978-1-62708-184-9
... Abstract In a typical semiconductor integrated circuits (SICs) component, corrosion may be observed at the chip level and at the termination area of the lead frames that are plated with a solderable metal or alloy, such as tin and tin-lead alloys that are susceptible to corrosion. This article...
Abstract
In a typical semiconductor integrated circuits (SICs) component, corrosion may be observed at the chip level and at the termination area of the lead frames that are plated with a solderable metal or alloy, such as tin and tin-lead alloys that are susceptible to corrosion. This article focuses on the key factors contributing to corrosion of electronic components, namely, chemicals (salts containing halides, sulfides, acids, and alkalis), temperature, air (polluted air), moisture, contact between dissimilar metals in a wet condition, applied potential differences, and stress. It discusses the chip corrosion and oxidation of tin and tin-lead alloys (solders) in SIC. The article also addresses the corrosion of the device terminations resulting in lead (termination) tarnishing that are caused by various factors, including galvanic corrosion, chemical residues, base metal migration and plating additives.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004129
EISBN: 978-1-62708-184-9
... is copper. Connectors may be made of phosphor bronze or beryllium-copper alloys. The coating applied to the connectors and circuits is generally gold plating, to provide solderability, conductivity, and corrosion resistance for maximum reliability. In other instances, tin plating, lead-tin plating (solder...
Abstract
This article provides a historical review of corrosion problems in military electronic equipment. It describes the importance of design for corrosion control of an electronic black box used to contain electrical equipment that provides various functions. The article illustrates corrosion control aspects, such as the position of printed circuit boards (PCBs) and proper location of connectors for insertion of the PCBs. It discusses various materials and alloys considered for connectors, PCB contacts, and circuits. The article concludes with a discussion on the effects of contaminants on the electronic black box.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004175
EISBN: 978-1-62708-184-9
... to further ingress of moisture and CO 2 and provides a permanent light green coating on copper. This patina sometimes provides an architectural appeal for buildings with copper sheet roofing and is sometimes referred to as architectural weathering ( Ref 14 ). Tin and Tin-Lead Alloys Until recently...
Abstract
This article provides information on various forms of corrosion that occur in electronic packaging. Portable consumer electronic hardware which is subjected to humidity exposures is prone to condensed moisture and liquid damage. The article discusses two other corrosion-related phenomena that are found only in electronics, namely, electrochemical migration (ECM) and conductive anodic filament formation (CAF). It describes the corrosion that takes place in metals such as copper, tin, and tin-lead alloys, which are commonly used in electronic packaging. The article also discusses the corrosion of the components used in electronic assemblies.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003563
EISBN: 978-1-62708-180-1
... of cracks leading to rolling-contact fatigue failure of PVD (TiN) coatings. (a) Crack parallel to the interface leading to spalled area for hard substrate (60 HRC) TiN coating. (b) Cracks parallel to the coating-substrate interface for hard substrate (60 HRC) TiN coating. (c) Cracks perpendicular...
Abstract
A major cause of failure in components subjected to rolling or rolling/sliding contacts is contact fatigue. This article focuses on the rolling contact fatigue (RCF) performance and failure modes of overlay coatings such as those deposited by physical vapor deposition, chemical vapor deposition, and thermal spraying (TS). It provides a background to RCF in bearing steels in order to develop an understanding of failure modes in overlay coatings. The article describes the underpinning failure mechanisms of TiN and diamond-like carbon coatings. It presents an insight into the design considerations of coating-substrate material properties, coating thickness, and coating processes to combat RCF failure in TS coatings.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003217
EISBN: 978-1-62708-199-3
... Abstract There are various coating techniques in practice to prevent the deterioration of steels. This article focuses on dip, barrier, and chemical conversion coatings and describes hot-dip processes for coating carbon steels with zinc, aluminum, lead-tin, and other alloys. It describes...
Abstract
There are various coating techniques in practice to prevent the deterioration of steels. This article focuses on dip, barrier, and chemical conversion coatings and describes hot-dip processes for coating carbon steels with zinc, aluminum, lead-tin, and other alloys. It describes continuous electrodeposition for steel strip and babbitting and discusses phosphate and chromate conversion coatings as well. It also addresses painting, discussing types and selection, surface preparation, and application methods. In addition, the article describes rust-preventive compounds and their application. It also provides information on weld-overlay and thermal spray coating, porcelain enameling, and the preparation of enamel frits for steels. The article closes by describing methods and materials for ceramic coating.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001270
EISBN: 978-1-62708-170-2
... considered in this article include metal coatings, such as zinc coatings, and alloy coatings, such as zinc-iron, types 1 and 2 aluminum, Zn-5AI, Zn-55AI, and lead-tin coatings. aluminum coatings continuous hot dip coatings ferrous metals lead-tin alloycoatings microstructure steel sheet surface...
Abstract
This article discusses the processes involved in continuous hotdip coating of steel sheets, namely, hot and cold line processing, surface preparation, and post treatment. It outlines the properties and microstructures of metals and their alloys used in this process. The coatings considered in this article include metal coatings, such as zinc coatings, and alloy coatings, such as zinc-iron, types 1 and 2 aluminum, Zn-5AI, Zn-55AI, and lead-tin coatings.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003211
EISBN: 978-1-62708-199-3
... to the soldering operation can facilitate soldering. Coatings of tin, copper, silver, cadmium, iron, nickel, and the alloys of tin-lead, tin-zinc, tin-copper, and tin-nickel are used for this purpose. The precoating of metals that have tenacious oxide films (for example, aluminum, aluminum bronzes, stainless...
Abstract
Soldering involves heating a joint to a suitable temperature and using a filler metal (solder) that melts below 450 deg C (840 deg F). Beginning with an overview of the specification and standards and applications, this article discusses the principal levels and effects of the most common impurity elements in tin-lead solders. It describes the various processes involved in the successful soldering of joints, including shaping the parts to fit closely together; cleaning and preparing the surfaces to be joined; applying a flux; assembling the parts; and applying the heat and solder.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001346
EISBN: 978-1-62708-173-3
... The coating of the base metal surfaces with a more-solderable metal or alloy prior to the soldering operation can facilitate soldering. Coatings of tin, copper, silver, cadmium, iron, nickel, and the alloys of tin-lead, tin-zinc, tin-copper, and tin-nickel are used for this purpose. The advantages...
Abstract
Soldering is defined as a joining process by which two substrates are bonded together using a filler metal with a liquidus temperature. This article provides an overview of fundamentals of soldering and presents guidelines for flux selection. Types of fluxes, including rosin-base fluxes, organic fluxes, inorganic fluxes, and synthetically activated fluxes, are reviewed. The article describes the joint design and precleaning and surface preparation for soldering. It addresses some general considerations in the soldering of electronic devices. Soldering process parameters, affecting wetting and spreading phenomena, such as temperature, time, vapor pressure, metallurgical and chemical nature of the surfaces, and surface geometry, are discussed. The article also describes the applications of furnace soldering, resistance soldering, infrared soldering, and ultrasonic soldering. It contains a table that lists tests commonly used to evaluate the solderability properties of selected soldered components.
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