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Image
Published: 01 December 1998
Fig. 3 Multilayer CVD coating (TiC/Ti(C,N)/TiN) on a cobalt-enriched 86WC-8(Ti,Ta,Nb)-6Co substrate. Note increased cobalt content (white constituent) at the substrate surface.
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Book Chapter
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003818
EISBN: 978-1-62708-183-2
... behavior on soft solders, pewter, bearing alloys, tin-copper alloys, and tin-silver alloys. It reviews the influence of corrosion on immersion tin coating, tin-cadmium alloy coatings, tin-cobalt coatings, tin-copper coatings, tin-lead coatings, tin-nickel coatings, and tin-zinc coatings. The general...
Abstract
This article describes the allotropic modification and atmospheric corrosion of pure tin. Corrosion of pure tin due to oxidation reaction, and reaction with the other gases, water, acids, bases, and other liquid media, is discussed. The article provides information on corrosion behavior on soft solders, pewter, bearing alloys, tin-copper alloys, and tin-silver alloys. It reviews the influence of corrosion on immersion tin coating, tin-cadmium alloy coatings, tin-cobalt coatings, tin-copper coatings, tin-lead coatings, tin-nickel coatings, and tin-zinc coatings. The general properties and corrosion resistance of tinplate are summarized. The article also describes the methods of corrosion testing of coatings; these include an analysis of coating thickness measurements, porosity and rust resistance testing, solderability test, and specific special tests.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001257
EISBN: 978-1-62708-170-2
... environment. Several zinc alloy processes are currently in commercial use. The choice of a particular process depends on the end-product requirements and conditions of use. Available alloys are zinc-iron, zinc-cobalt, zinc-nickel, and tin-zinc. As in unalloyed zinc plating, chromate conversion coating...
Abstract
This article provides information on the compositions of alkaline and acid baths and process parameters for zinc-iron, zinc-cobalt, zinc-nickel, and tin-zinc plating.
Image
Published: 01 January 1994
Fig. 4 Multilayer chemical vapor deposition coatings on cobalt-enriched substrates. (a) 86WC-8(Ti,Ta,Nb)C-6Co alloy with cobalt-enriched periphery and a TiC/TiCN/TiN coating. (b) Second-generation cobalt-enriched cemented carbide tool with TiC/Al 2 O 3 /TiN coating
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Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003797
EISBN: 978-1-62708-177-1
... ( Ref 10 ). Fig. 30 86WC-8(Ta,Ti,Nb)C-6Co alloy, 91.6 HRA, coated with chemical-vapor-deposited multilayers of TiC, TiCN, and TiN. Note the gradient microstructure of the substrate (first-generation cobalt-enriched alloy), with the insert periphery (below the coating layers) showing higher levels...
Abstract
This article contains tables that list standard reduction potentials for electrochemical reactions. The first table lists reactions alphabetically by element of interest. The second table is ranked by potential value. Potential is measured versus the Standard Hydrogen Electrode which has a value of 0.0000 V. Reactions with more than one voltage indicate that results have not been reconciled. Parenthetical materials not needed to balance reactions are catalysts.
Image
Published: 01 January 1990
Fig. 23 Microstructure of a cobalt-enriched coating. 86WC-8(Ti,Ta,Nb) C-6Co tool with a TiC/TiCN/TiN coating. (a) Cobalt-enriched periphery (beneath the coating). (b) Bulk microstructure. Both etched with Murakami's reagent for 2 min. 1500×
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Image
Published: 01 January 1989
Fig. 23 Microstructure of a cobalt-enriched coated tool. 86WC-8(Ti,Ta,Nb)C-6Co tool with a TiC/TiCN/TiN coating. (a) Cobalt-enriched periphery (beneath the coating). (b) Bulk microstructure. Both etched with Murakami's reagent for 2 min. 1500×
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Image
Published: 01 January 1994
Fig. 7 Combination of a chemical vapor deposition TiN-TiCN coating and a physical vapor deposition TiN coating on a cobalt-enriched cemented carbide insert
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Image
Published: 01 January 1990
Fig. 24 Microstructure of a second-generation cobalt-enriched coated tool. 85WC-9(Ti,Ta,Nb) C-6Co tool with a TiC/Al 2 O 3 /TiN coating. (a) Cobalt-enriched periphery (beneath the coating). (b) Bulk microstructure. Both etched with Murakami's reagent for 2 min. 1500×
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Image
Published: 01 January 1989
Fig. 24 Microstructure of a second-generation cobalt-enriched coated tool. 85WC-9(Ti,Ta,Nb)C-6Co tool with a TiC/Al 2 O 3 /TiN coating. (a) Cobalt-enriched periphery (beneath the coating). (b) Bulk microstructure. Both etched with Murakami's reagent for 2 min. 1500×
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Image
Published: 01 December 2004
Fig. 33 83.5WC-10.5(Ta,Ti,Nb)C-6Co alloy, 92 HRA. This cobalt-enriched alloy is coated with chemical-vapor-deposited TiN/TiCN and physical-vapor-deposited TiN (gold coating on top) layers. Murakami's reagent, 1 min. 1500×.
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Image
Published: 01 December 2004
Fig. 30 86WC-8(Ta,Ti,Nb)C-6Co alloy, 91.6 HRA, coated with chemical-vapor-deposited multilayers of TiC, TiCN, and TiN. Note the gradient microstructure of the substrate (first-generation cobalt-enriched alloy), with the insert periphery (below the coating layers) showing higher levels
More
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001320
EISBN: 978-1-62708-170-2
... breakthrough in resolving the conflict between fracture toughness and deformation resistance occurred in the late 1970s, when a TiC/TiCN/TiN-coated tool was developed with a peripheral cobalt-enriched zone, 10 to 30 μm thick ( Fig. 4a ), that provided superior edge strength while maintaining the deformation...
Abstract
The classes of tool materials for machining operations are high-speed tool steels, carbides, cermets, ceramics, polycrystalline cubic boron nitrides, and polycrystalline diamonds. This article discusses the expanding role of surface engineering in increasing the manufacturing productivity of carbide, cermet, and ceramic cutting tool materials used in machining operations. The useful life of cutting tools may be limited by a variety of wear processes, such as crater wear, flank wear or abrasive wear, builtup edge, depth-of-cut notching, and thermal cracks. The article provides information on the applicable methods for surface engineering of cutting tools, namely, chemical vapor deposited (CVD) coatings, physical vapor deposited coatings, plasma-assisted CVD coatings, diamond coatings, and ion implantation.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003219
EISBN: 978-1-62708-199-3
... for tools, dies, etc. Effect much deeper than original implantation depth. Precise area treatment, excellent process control Ion plating, ARE RT-0.7 T m of coating. Best at elevated temperatures Moderate to good Ion plating: Al, other metals (few alloys) ARE: TiN and other compounds Electronic...
Abstract
Physical vapor deposition (PVD) coatings are harder than any metal and are used in applications that cannot tolerate even microscopic wear losses. This article describes the three most common PVD processes: thermal evaporation, sputtering, and ion plating. It also discusses ion implantation in the context of research and development applications.
Book: Machining
Series: ASM Handbook
Volume: 16
Publisher: ASM International
Published: 01 January 1989
DOI: 10.31399/asm.hb.v16.a0002124
EISBN: 978-1-62708-188-7
..., tailored substrates, and the application of thin, hard coatings to cemented carbides by chemical vapor deposition and physical vapor deposition will also be discussed. This article is limited to tungsten carbide cobalt-base materials. Information on titanium carbide nickel-base materials is given...
Abstract
This article discusses the manufacturing steps and compositions of cemented carbides, as well as their microstructure, classifications, applications, and physical and mechanical properties. It provides information on new tool geometries, tailored substrates, and the application of thin and hard coatings to cemented carbides by chemical vapor deposition and physical vapor deposition. The article also discusses tool wear mechanisms and the methods available for holding the carbide tool.
Book: Machining
Series: ASM Handbook
Volume: 16
Publisher: ASM International
Published: 01 January 1989
DOI: 10.31399/asm.hb.v16.a0002121
EISBN: 978-1-62708-188-7
... Cutting tool Coating Workpiece material Workpieces machined before resharpening Type High-speed tool steel, AISI type Uncoated Coated End mill M7 TiN 1022 steel, 35 HRC 325 1,200 End mill M7 TiN 6061-T6 aluminum alloy 166 1,500 End mill M3 TiN 7075T aluminum alloy 9 53...
Abstract
This article discusses the classifications of high-speed tool steels and describes alloying elements and their effects on the properties of high-speed tool steels. It analyzes the heat treatment of high-speed tool steels, namely, preheating, austenitizing, quenching, and tempering. Surface treatments for the high-speed tool steels are reviewed. The article emphasizes the properties and applications of high-speed tool steels and provides information on the factors in selecting high-speed tool steels.
Book Chapter
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001261
EISBN: 978-1-62708-170-2
... 0.030 Silver, noncyanide 0.750 Silver, pure 0.004 Babbitt 0.006 Brass 0.017 Bronze 0.017 Cobalt-nickel 0.019 Cobalt-tungsten 0.015 Nickel-cobalt 0.020 Nickel-tungsten 0.020 Tin-cadmium 0.007 Tin-indium 0.008 Tin-lead (90/10) 0.006 Tin-lead (60–40...
Abstract
Selective plating, also known as brush plating, differs from traditional tank or bath plating in that the workpiece is not immersed in a plating solution (electrolyte). Instead, the electrolyte is brought to the part and applied by a handheld anode or stylus, which incorporates an absorbent wrapping for applying the solution to the workpiece (cathode). This article focuses on the selective plating systems that include a power pack, plating tools, anode covers, specially formulated plating solutions, and any auxiliary equipment required for the particular application. It provides a detailed account of the applications of selective plating, with examples. The article describes the advantages, limitations, key process elements, and health and safety considerations of selective plating. It also includes the most important industrial, government, and military specifications.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001104
EISBN: 978-1-62708-162-7
... size is increased ( Fig. 11b ). Abrasion resistance is also lower for complex carbides than for straight WC grades having the same cobalt content. Coated Carbide Tools One of the challenges in the design of cemented carbide tools is the optimization of toughness associated with straight WC-Co...
Abstract
Cemented carbides belong to a class of hard, wear-resistant, refractory materials in which the hard carbide particles are bound together, or cemented, by a soft and ductile metal binder. The performance of cemented carbide as a cutting tool lies between that of tool steel and cermets. Almost 50% of the total production of cemented carbides is used for nonmetal cutting applications. Their properties also make them appropriate materials for structural components, including plungers, boring bars, powder compacting dies and punches, high-pressure dies and punches, and pulverizing hammers. This article discusses the manufacture, microstructure, composition, classifications, and physical and mechanical properties of cemented carbides, as well as their machining and nonmachining applications. It examines the relationship between the workpiece material, cutting tool and operational parameters, and provides suggestions to simplify the choice of cutting tool for a given machining application. It also examines new tool geometries, tailored substrates, and the application of thin, hard coatings to cemented carbides by chemical vapor deposition and physical vapor deposition. It discusses the tool wear mechanisms and the methods available for holding the carbide tool. The article is limited to tungsten carbide cobalt-base materials.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003218
EISBN: 978-1-62708-199-3
... the properties of typical CVD coating materials for wear and corrosion resistance. Coatings for the cutting tool industry utilize CVD processes, particularly TiC coatings for cemented tungsten carbide tools and TiN and carbonitride coatings for high-speed tool steels and cemented carbide tools. Nearly all...
Abstract
Chemical vapor deposition (CVD) involves the formation of a coating by the reaction of the coating substance with the substrate. Serving as an introduction to CVD, the article provides information on metals, ceramics, and diamond films formed by the CVD process. It further discusses the characteristics of different pack cementation processes, including aluminizing, siliconizing, chromizing, boronizing, and multicomponent coating.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003152
EISBN: 978-1-62708-199-3
... the diffusion wear resistance of the coating layers. An example of a multiple-layer coating applied to a cobalt-enriched complex grade substrate is shown in Fig. 3 . Fig. 3 Multilayer CVD coating (TiC/Ti(C,N)/TiN) on a cobalt-enriched 86WC-8(Ti,Ta,Nb)-6Co substrate. Note increased cobalt content (white...
Abstract
Cemented carbides belong to a class of hard, wear-resistant, refractory materials in which the hard carbide particles are bound together, or cemented, by a ductile metal binder. Cermet refers to a composite of a ceramic material with a metallic binder. This article discusses the manufacture, composition, classifications, and physical and mechanical properties of cemented carbides. It describes the application of hard coatings to cemented carbides by physical or chemical vapor deposition (PVD or CVD). Tungsten carbide-cobalt alloys, submicron tungsten carbide-cobalt alloys, and alloys containing tungsten carbide, titanium carbide, and cobalt are used for machining applications. The article also provides an overview of cermets used in machining applications.
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