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Book Chapter
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003818
EISBN: 978-1-62708-183-2
... behavior on soft solders, pewter, bearing alloys, tin-copper alloys, and tin-silver alloys. It reviews the influence of corrosion on immersion tin coating, tin-cadmium alloy coatings, tin-cobalt coatings, tin-copper coatings, tin-lead coatings, tin-nickel coatings, and tin-zinc coatings. The general...
Abstract
This article describes the allotropic modification and atmospheric corrosion of pure tin. Corrosion of pure tin due to oxidation reaction, and reaction with the other gases, water, acids, bases, and other liquid media, is discussed. The article provides information on corrosion behavior on soft solders, pewter, bearing alloys, tin-copper alloys, and tin-silver alloys. It reviews the influence of corrosion on immersion tin coating, tin-cadmium alloy coatings, tin-cobalt coatings, tin-copper coatings, tin-lead coatings, tin-nickel coatings, and tin-zinc coatings. The general properties and corrosion resistance of tinplate are summarized. The article also describes the methods of corrosion testing of coatings; these include an analysis of coating thickness measurements, porosity and rust resistance testing, solderability test, and specific special tests.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001257
EISBN: 978-1-62708-170-2
... Zinc-nickel (8% Ni) 1000 Tin-zinc (70% Sn) 1000 (a) Coating thickness, 8 μm; iridescent yellow chromate post-treatment Selected References Selected References • Blunden S. , Sn-Zn Alloy Electroplates Outperform Cadmium Deposits , Advanced Materials & Processes...
Abstract
This article provides information on the compositions of alkaline and acid baths and process parameters for zinc-iron, zinc-cobalt, zinc-nickel, and tin-zinc plating.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003687
EISBN: 978-1-62708-182-5
... of Coatings The principal metals that are widely plated are cadmium, zinc and its alloys, chromium, copper, gold, nickel, tin, and silver. Other metals that are plated by in-house shops and some job platers are cobalt, indium, iron, lead, palladium, platinum, rhenium, and rhodium. Plateable alloys add...
Abstract
This article discusses the various factors that affect the corrosion performance of electroplated coatings. It describes the effects of environment and the deposition process on substrate coatings. The article provides a discussion on the electrochemical techniques capable of predicting the corrosion performance of a plated part. It reviews the designs of coating systems for optimal protection of the substrate. The article also discusses controlled weathering tests and accelerated tests used to predict and determine the relative durability of the coating.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003778
EISBN: 978-1-62708-177-1
... preparation tin tin alloy coatings tin alloys tin-antimony alloys tin-antimony-copper alloys tin-antimony-copper-lead alloys tin-copper alloys tin-indium alloys tin-lead alloys tin-lead-cadmium alloys tin-silver alloys tin-zinc alloys tin-zinc-copper alloys TIN AND TIN ALLOYS are extremely...
Abstract
This article describes the specimen preparation steps for tin and tin alloys, and for harder base metals which are coated with these materials with illustrations. The steps discussed include sectioning, mounting, grinding, polishing, and etching. The article provides information on etchants for tin and tin alloys in tabular form. It presents the procedure recommended for electron microscopy to determine the nature of the intermetallic compound formed by the reaction between tin or tin-lead coatings on various substrates. The article concludes with an illustration of the microstructures of tin-copper, tin-lead, tin-lead-cadmium, tin-antimony, tin-antimony-copper, tin-antimony-copper-lead, tin-silver, tin-indium, tin-zinc, and tin-zinc-copper systems.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003211
EISBN: 978-1-62708-199-3
... to the soldering operation can facilitate soldering. Coatings of tin, copper, silver, cadmium, iron, nickel, and the alloys of tin-lead, tin-zinc, tin-copper, and tin-nickel are used for this purpose. The precoating of metals that have tenacious oxide films (for example, aluminum, aluminum bronzes, stainless...
Abstract
Soldering involves heating a joint to a suitable temperature and using a filler metal (solder) that melts below 450 deg C (840 deg F). Beginning with an overview of the specification and standards and applications, this article discusses the principal levels and effects of the most common impurity elements in tin-lead solders. It describes the various processes involved in the successful soldering of joints, including shaping the parts to fit closely together; cleaning and preparing the surfaces to be joined; applying a flux; assembling the parts; and applying the heat and solder.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003781
EISBN: 978-1-62708-177-1
... Abstract This article discusses the specimen preparation techniques for zinc and its alloys and zinc-coated specimens, namely, sectioning, mounting, grinding and polishing, and etching. It describes the characteristics of lead, cadmium, iron, copper, titanium, aluminum, magnesium, and tin...
Abstract
This article discusses the specimen preparation techniques for zinc and its alloys and zinc-coated specimens, namely, sectioning, mounting, grinding and polishing, and etching. It describes the characteristics of lead, cadmium, iron, copper, titanium, aluminum, magnesium, and tin, which are present in the microstructure of zinc alloys. The article also provides information on microexamination that helps to determine the dendrite arm spacing, as well as the grain size, grain boundaries, and grain counts.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001322
EISBN: 978-1-62708-170-2
....” Cadmium Coating Specifications Cadmium coatings are applied in accordance with both consensus specifications (e.g., Society of Automotive Engineers) and federal and military specifications. Table 3 lists representative cadmium and cadmium alloy coating specifications. Unless directly specified...
Abstract
Environmental and worker health regulations have increased the costs associated with cadmium coating application and cadmium-beating waste disposal, thus creating economic incentives for industrial users to seek cadmium plating replacements. This article presents a cadmium replacement identification matrix that includes information on the specifications, corrosion control performance, environment-assisted cracking, coating lubricity, environmental and worker health regulations, and cost and performance factors for various replacement processes.
Book Chapter
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001261
EISBN: 978-1-62708-170-2
... Palladium Platinum Rhenium Rhodium Silver (hard) Silver (noncyanide) Silver (soft) Plating solutions for alloys Babbitt Navy Grade 2 Babbitt SAE 11 Brass Cadmium-tin Cobalt-tungsten Nickel-cobalt Nickel-tungsten Tin-indium Tin-lead-nickel Special-purpose...
Abstract
Selective plating, also known as brush plating, differs from traditional tank or bath plating in that the workpiece is not immersed in a plating solution (electrolyte). Instead, the electrolyte is brought to the part and applied by a handheld anode or stylus, which incorporates an absorbent wrapping for applying the solution to the workpiece (cathode). This article focuses on the selective plating systems that include a power pack, plating tools, anode covers, specially formulated plating solutions, and any auxiliary equipment required for the particular application. It provides a detailed account of the applications of selective plating, with examples. The article describes the advantages, limitations, key process elements, and health and safety considerations of selective plating. It also includes the most important industrial, government, and military specifications.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003635
EISBN: 978-1-62708-182-5
... tested near the melting point of these inclusions. The severity of embrittlement increases from lead to cadmium to bismuth. Copper Mercury embrittles copper ( Ref 41 ), and the severity of embrittlement increases when copper is alloyed with aluminum and zinc. Antimony, cadmium, lead, tin ( Ref 51...
Abstract
Liquid metal induced embrittlement (LMIE) is the reduction of the fracture resistance of a solid material during exposure to a liquid metal. This article discusses the mechanisms and occurrence condition of LMIE and describes the effects of metallurgical factors, such as grain size, temperature and strain rate, stress, inert carriers, and fatigue, on LMIE. It provides a detailed discussion on LMIE in ferrous and nonferrous metals and their alloys. In addition, the article highlights the ways of preventing embrittlement in metals and alloys.
Book Chapter
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0006541
EISBN: 978-1-62708-183-2
...+paint or resin seal C Cadmium, beryllium Chromate conversion coating+paint or resin seal D Aluminum, Al-Mg, Al-Zn Anodic coating+paint or resin seal E Aluminum-copper Anodic coating+paint or resin seal F Steel, carbon and low alloy Metallic coating, sacrificial (Zn) or nonsacrificial...
Abstract
This guide rates the compatibility of dissimilar structural materials joined together for service in seawater, marine atmosphere, or industrial atmosphere. It contains a table that indicates the material code and most generally effective surface treatment typically used to reduce corrosion of bare metals.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003554
EISBN: 978-1-62708-180-1
... Titanium Hg, Cd, Ag, Au It should be pointed out that alloys of these embrittler metals can also be embrittling. In fact, for service failures, the embrittling metal is probably not pure but is impure or an alloy. For example, tin- and lead-base bearing alloys and solders also cause metal-induced...
Abstract
Metal-induced embrittlement is a phenomenon in which the ductility or fracture stress of a solid metal is reduced by surface contact with another metal in either liquid or solid form. This article summarizes the characteristics of solid metal induced embrittlement (SMIE) and liquid metal induced embrittlement (LMIE). It describes the unique features that assist in arriving at a clear conclusion whether SMIE or LMIE is the most probable cause of the problem. The article briefly reviews some commercial alloy systems where LMIE or SMIE has been documented. It also provides some examples of cracking due to these phenomena, either in manufacturing or in service.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003215
EISBN: 978-1-62708-199-3
... for coating aluminum and other amphoteric metals; its alkaline corrosion resistance provides a wider measure of corrosion protection for these metals than that provided by cadmium, tin, or zinc. Equipment and Plating Baths Equipment Indium can be plated without special apparatus. Any shop...
Abstract
Copper can be electrodeposited from numerous electrolytes. Cyanide and pyrophosphate alkalines, along with sulfate and fluoborate acid baths, are the primary electrolytes used in copper plating. This article provides information on the chemical composition, plating baths, and operating conditions of electrodeposition processes for chromium plating, nickel plating, iron plating, cadmium plating, zinc plating, indium plating, lead plating, tin plating, silver plating, gold plating, brass plating, bronze plating, tin-lead plating, zinc-iron plating, and zinc-nickel plating. The article also discusses selective plating, electroforming, and other processes and where they are typically used.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001247
EISBN: 978-1-62708-170-2
... °C (500 °F), damage occurs that adversely affects mechanical properties. Diffused Coatings The aviation industry has developed an application for cadmium for low-alloy steel jet engine parts. The substrate is first plated with 10 μm (400 μin.) of nickel and then 5 μm (200 μin.) of cadmium...
Abstract
Electrodeposits of cadmium are used to protect steel and cast iron against corrosion. This article provides an overview of the surface preparation of, and brighteners used in, cyanide baths. It focuses on the anode system, current density, deposition rates, and bath temperature of cadmium plating with attention to the materials of construction and equipment used. The article provides a description of the selection of plating method with examples, applications, and several postplating processes of cadmium plating.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006786
EISBN: 978-1-62708-295-2
... of these embrittler metals can also be embrittling. In fact, for service failures, the embrittling metal is probably not pure but is impure or an alloy. For example, tin- and lead-base bearing alloys and solders also cause metal-induced embrittlement. Furthermore, some alloy additions to embrittling metals have been...
Abstract
Metal-induced embrittlement is a phenomenon in which the ductility or the fracture stress of a solid metal is reduced by surface contact with another metal in either the liquid or solid form. This article summarizes some of the characteristics of liquid-metal- and solid-metal-induced embrittlement. This phenomenon shares many of these characteristics with other modes of environmentally induced cracking, such as hydrogen embrittlement and stress-corrosion cracking. The discussion covers the occurrence, failure analysis, and service failures of the embrittlement. The article also briefly reviews some commercial alloy systems in which liquid-metal-induced embrittlement or solid-metal-induced embrittlement has been documented and describes some examples of cracking due to these phenomena, either in manufacturing or in service.
Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006491
EISBN: 978-1-62708-207-5
...% sodium chloride solution Metal Potential, mV (a) Magnesium –850 Zinc –350 Cadmium –20 to 0 Aluminum (pure) 0 Aluminum-magnesium alloys +100 Aluminum-copper alloys +150 Iron, low-carbon steel +50 to 150 Tin +300 Brass +500 Nickel +500 Copper +550...
Abstract
Aluminum components are often plated with other metals to mitigate the effects of corrosion and wear, improve application performance, and extend service life. This article discusses some of the more common aluminum plating processes, including electroplating, immersion plating, and electroless plating, and describes various plating materials and the types of applications in which they are used. It provides critical processing details such as temperatures, ratios, ranges, times, and rates. The article explains how to prepare aluminum components for electroplating, discussing surface roughening, anodizing, and immersion procedures along with expected results.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001077
EISBN: 978-1-62708-162-7
...% provided that the lead, cadmium, and tin do not exceed 0.003, 0.003, and 0.002% respectively. Nominal compositions of zinc-aluminum foundry and die casting alloys directly poured to produce castings and in ingot form for remelting to produce castings Table 4 Nominal compositions of zinc-aluminum...
Abstract
This article describes the zinc and zinc alloys for decorative and functional applications. It focuses on the types of zinc coatings, namely, hot dip galvanizing, electrogalvanizing, metallizing, and mechanical galvanizing. The article covers the uses of zinc alloy castings, including pressure die castings, and gravity castings. It details the wrought products of zinc and zinc alloys, including flat-rolled products, wire-drawn products, extruded products, and forged products. The article also describes various properties of zinc alloys, including mechanical, thermal, electrical, chemical, and magnetic properties. The listing for each alloy includes chemical compositions, relevant specifications, mass characteristics, and fabrication characteristics.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001256
EISBN: 978-1-62708-170-2
... for tin-lead. Bismuth as an alloying agent prevents the whiskering and tin pest that can occur in tin coatings. Tin-Nickel Tin-nickel is used for corrosion-resistant coatings, especially in seawater environments. It has an attractive chromelike appearance and high lubricity when plated over bright...
Abstract
Electrodeposition of tin alloys is used to protect steel against corrosion or wear, to impart resistance to etching, and to facilitate soldering. This article focuses on the compositions, operating conditions, advantages, and limitations of methane sulfonic acid plating solutions and fluoborate plating solutions for tin-lead. It briefly describes the solution compositions and operating conditions of tin-bismuth, tin-nickel, and tin-zinc.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001076
EISBN: 978-1-62708-162-7
... and Consumption Hot Dip Coatings Solders Impurities in Solders Aluminum Antimony Arsenic Bismuth Cadmium Applications of Unalloyed Tin Impact Strength Specific Damping Capacity Powder Applications Chemical Properties and Corrosion Behavior Tin in Chemicals...
Abstract
Tin is produced from both primary and secondary sources. This article discusses the chemical compositions, production, properties, microstructure and applications of tin and tin alloys. The major tin alloys discussed here are tin-antimony-copper alloy (pewter), bearing alloy, solder alloy and other alloys containing traces of tin. Data on tin consumption in the United States is presented graphically.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001459
EISBN: 978-1-62708-173-3
... characteristics of solders are expressed as the solidus and the liquidus temperatures for the alloy. Solders composed of one metallic element, such as tin or indium, have a single melting temperature. Alloys with a eutectic composition have liquidus and solidus temperatures, but they are coincident...
Abstract
Soldering technology has been used in applications ranging from the packaging of integrated circuit chips to the fabrication of industrial heat exchangers and consequently in structural or electronic applications. This article provides information on various soldering parameters, including types of solder alloy in terms of selection process; selection of substrate base material; flux selection based on adequate wettability by the solder; solder joint assembly; combined substrate, solder, and flux properties; and manufacturing procedures. Each of these parameters is explored using examples of both structural and electronic applications. The article concludes with a discussion on the environmental, safety, and health issues to be considered during soldering.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003145
EISBN: 978-1-62708-199-3
... of organic compounds. A number of alloy coatings can be electroplated from mixed stannate-cyanide baths, including coatings of tin-zinc and tin-cadmium alloys and a wide range of tin-copper alloys (bronzes). The bronzes range in tin content from 7 to 98%. Red bronze deposits contain up to 20% Sn; high...
Abstract
Tin is a soft, brilliant white, low-melting metal that is most widely known and characterized in the form of coating. This article discusses the primary and secondary production of tin and explains the uses of tin in coating, namely tinplating, electroplating, and hot dip coatings. It presents a short note on pure (unalloyed) tin and uses of tin in chemicals. The article also covers the compositions and uses of tin alloys which include solders, pewter, bearing alloys, alloys for organ pipes, and fusible alloys. It goes on to discuss the other alloys containing tin including battery grid alloys, type metals, copper alloys, dental alloys, cast irons, titanium alloys, and zirconium alloys. Finally, it presents a short note on the applications of tin powder and corrosion resistance of tin.
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