Search Results for three-electrode measurement

Electrode potential is a key parameter in the thermodynamic and kinetic processes that drive aqueous corrosion. This article discusses the complexities associated with measuring electrode potential and explains where and how to use reference electrodes to improve measurement accuracy. It describes a three-electrode approach that compensates for measurement error stemming from nonequilibrium conditions. It also examines electrode materials and behaviors and offers insights on selection and operating conditions.

Submerged arc welding (SAW) is suited for applications involving long, continuous welds. This article describes the operating principle, application, advantages, limitations, power source, equipment, and fluxes in SAW. It reviews three different types of electrodes manufactured for SAW: solid, cored, and strip. The article highlights the factors to be considered for controlling the welding process, including fit-up of work, travel speed, and flux depth. It also evaluates the defects that occur in SAW: lack of fusion, slag entrapment, solidification cracking, and hydrogen cracking. Finally, the article provides information on the safety measures to be followed in this process.

This article provides an overview of the components of a resistance welding machine. It focuses on the single-phase control system and medium-frequency direct current system of resistance welding. The article also includes information on their feedback systems, rectification systems, and power sources.

This article explores the use of the electrochemical and nonelectrochemical techniques for measuring the corrosion behavior of buried metals and the types of probes used. The electrical resistance technique is the main nonelectrochemical technique used for measuring corrosion rate. Electrochemical techniques discussed include linear polarization resistance, electrochemical noise, harmonic distortion analysis, electrochemical impedance spectroscopy, and hydrogen permeation. The principles of operation for the corrosion measuring techniques are described along with examples of their use in soils.

This article provides a discussion on the operation of various methods and sensors that have been used or have the potential to be used for on-line, real-time monitoring of localized corrosion. These include the electrochemical noise (ECN) method, nonelectrochemical methods, the galvanically coupled differential flow cell, galvanically coupled crevice cell, coupled multielectrode sensor, and electrochemical biofilm activity sensor.

This article focuses on the testing and typical corrosion behavior of coating-substrate systems in aqueous solutions and humid aggressive atmospheres. It includes a short review of the fundamentals of corrosion, followed by a discussion of specific system behavior, electrochemical and laboratory accelerated tests, and simulated service tests. The article also contains examples of different types of corrosion damage and presents guidelines for improving corrosion resistance.

This article provides a discussion on the fundamentals of corrosion thermodynamics. The discussion focuses on electrochemical reactions, molten salt corrosion thermodynamics, and geochemical modeling.

Molten salts, in contrast to aqueous solutions in which an electrolyte (acid, base, salt) is dissolved in a molecular solvent, are essentially completely ionic. This article begins with an overview of the thermodynamics of cells and classification of electrodes for molten salts: reference electrodes and indicator electrodes. It explains that corrosion in molten salts can be caused by the solubility of the metal in the salt, particularly if the metal dissolves in its own chloride. The article describes the factors that affect the corrosion of titanium, namely, the titanium chloride content of the magnesium chloride melt, magnesium or sodium content, and oxygen content of the product. It concludes with a discussion on the oxygen activity in the titanium metal product.

This article addresses electrical testing and characterization of plastics and presents a number of techniques for evaluating the electrical properties of insulating materials, with a special focus on plastics, accompanied by a list of the electrical properties of different types of plastics. It provides the reader with sufficient information to select the appropriate electrical test(s) for a specific application. The tests covered in this article are widely used in industry to determine the electrical properties of insulating materials, particularly plastics. The article lists and defines terms used in connection with testing and specification of plastics for electrical applications.

A variety of electrochemical techniques are used to detect and monitor material deterioration in service or in the field. This article describes the static or direct current measurements in a number of applications, including buried pipelines and storage tanks. It reviews the electrochemical impedance spectroscopy and electrochemical noise measurements in a laboratory, especially for the inspection of coatings.

Resistance welding (RW) encompasses many variations on the basic theme of local Joule heating while an external pressure is applied. This article provides an overview of the most generally applied RW processes, followed by a discussion on the general design aspects of various resistance-welded joints. The various resistance-welded joints include spot welds, projection welds, seam welds, and butt welds. The article explains the relative contributions of the Joule, Peltier, and Thomson effects for typical RW scenarios. It concludes with information on the electrode “follow” behavior.

Corrosion monitoring is important in the operation of modern industrial plants and in the use and maintenance of expensive assets such as bridges and aircrafts, because the damage caused by corrosion and the rate of the deterioration can be huge and the risks devastating. This article discusses the system considerations and installation techniques of different types of direct and indirect techniques in electrochemically based on-line corrosion monitoring process. It describes the importance of probe location and on-line corrosion monitoring techniques with examples.

This article describes various methods of electrochemical analysis, namely coulometry, electrogravimetry, voltammetry, electrometric titration, and nanometer electrochemistry. The discussion covers the general uses, sample requirements, application examples, advantages, and limitations of these methods. Some of the factors pertinent to electrochemical cells are also provided. In addition, the article provides information on various potentiometric membrane electrodes used to quantify numerous ionic and nonionic species.

Three types of energy are used primarily as direct heat sources for fusion welding: electric arcs, laser beams, and electron beams. This article reviews the physical phenomena that influence the input-energy distribution of the heat source for fusion welding. It also discusses several simplified and detailed heat-source models that have been used in the modeling of arc welding, high-energy-density welding, and resistance welding.

The vacuum arc remelting (VAR) process is widely used to improve the cleanliness and refine the structure of standard air melted or vacuum induction melted (VIM) ingots. It is also used in the triplex production of superalloys. This article illustrates the VAR process and the capabilities and variables of the process. It also presents a discussion on the melt solidification, resulting structure, and ingot defects. The article concludes with a discussion on the VAR process of superalloy and titanium and titanium alloy.

The resistance welding processes commonly employed for joining aluminum are resistance spot welding, resistance seam welding, resistance roll welding, upset and flash welding for butt joining welding, and high-frequency resistance welding. This article discusses the general factors affecting resistance welding: electrical and thermal conductivities, rising temperature, plastic range, shrinkage, and surface oxide. It reviews the weldability of base materials such as Alclad alloys and aluminum metal-matrix composites. The article describes the joint design and welding procedures for resistance spot welding, as well as the joint type, equipment, and welding procedures for seam and roll spot welding. It concludes with information on flash welding, high-frequency welding, and cross-wire welding.

This article provides the basic physics of the two most widely used arc welding processes: gas tungsten arc welding and gas metal arc welding. It describes the various control parameters of these processes such as arc length control, voltage control, heat input control, and metal-transfer control.