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thin-superconducting films
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Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001113
EISBN: 978-1-62708-162-7
... Abstract This article focuses on different thin-film deposition techniques used to make superconducting films and discusses the properties and advantages of high-critical-temperature and low-critical-temperature materials in a number of applications, including signal processing and analog...
Abstract
This article focuses on different thin-film deposition techniques used to make superconducting films and discusses the properties and advantages of high-critical-temperature and low-critical-temperature materials in a number of applications, including signal processing and analog electronic devices. The article gives a brief introduction on superconducting materials, substrates and buffer layers and discusses the major deposition techniques such as, electron-beam co-evaporation, sputtering from either a composite target or multiple sources and laser ablation. The article also describes the in-situ film growth techniques for producing atomic oxygen by radio frequency excitation or microwave discharge or with ozone.
Book Chapter
High-Temperature Superconductors for Wires and Tapes
Available to PurchaseSeries: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001114
EISBN: 978-1-62708-162-7
... for microcracking. These processing problems, however, are balanced to some degree by the ability to produce a high percentage of single-phase material if the processing is properly followed. A fairly high 92 K superconducting transition and production of satisfactory critical current density in idealized thin-film...
Abstract
The discovery of the high-critical-temperature oxide superconductors has accelerated the interest for superconducting applications due to its higher-temperature operation at liquid nitrogen or above and thus reduces the refrigeration and liquid helium requirement. It also permits usage of the high-critical-temperature oxides in magnets or power applications in high-current-carrying wire or tape with acceptable mechanical capability. This article discusses the powder techniques mainly based on the production of an oxide powder precursor, which is then subjected to various processing, including powder-in-tube processing, vapor deposition processing, and melt processing. It further discusses the microstructural, anisotropy and weak link influences on these processes.
Book Chapter
Superconducting Materials
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003155
EISBN: 978-1-62708-199-3
...) Measured with field parallel to the c axis. (c) Measured with field parallel to the a-b plane. (d) Epitaxial thin film, current in the a-b plane Superconductor Categories Superconductivity is observed in several hundred materials. These include more than half of the metallic...
Abstract
Superconductors are materials that exhibit a complete disappearance of electrical resistivity on lowering the temperature below the critical temperature. A superconducting material must exhibit perfect diamagnetism, that is, the complete exclusion of an applied magnetic field from the bulk of the superconductor. Superconducting materials that have received the most attention are niobium-titanium superconductors (the most widely used superconductor), A15 compounds (in which class the important ordered intermetallic Nb3Sn lies), ternary molybdenum chalcogenides (Chevrel phases), and high-temperature ceramic superconductors. This article provides an overview of basic principles of superconductors and the different classes of superconducting materials and their general characteristics.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001294
EISBN: 978-1-62708-170-2
... of thin-film superconductors at the time that bulk superconductors were being developed. Even though PLD was far from the advanced level of other film growth techniques, it was demonstrated that high-quality superconducting films could be reproducibly deposited by PLD. As a result, the technique became...
Abstract
This article presents a general description of pulsed-laser deposition. It describes the components of pulsed-laser deposition equipment. The article also discusses the effects of angular distribution of materials. Finally, the article reviews the characteristics of high-temperature superconductors and ferroelectric materials.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001108
EISBN: 978-1-62708-162-7
... 3 Sn lies) “Ternary Molybdenum Chalcogenides (Chevrel Phases)” “Thin-Film Materials” “High-Temperature Superconductors for Wires and Tapes” Even with this broad view, however, only a brief flavor of the breadth of the superconducting state and its applications can be given here...
Abstract
This article reviews the history of superconductivity from its discovery in the early 1900s to the renewed interest in the mid-1980s spurred by the development of high-temperature superconducting devices. It identifies some of the materials in which superconductivity has been observed, including metals and alloys, compounds, and oxides, and discusses their properties as well as potential applications. The article also explains how various superconducting materials are produced and provides a foundation for understanding the basic operating principles.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001095
EISBN: 978-1-62708-162-7
... of the earliest reflection electron diffraction studies of thin films in a high-vacuum chamber. In addition, they developed in situ methods for measuring the electrical resistivity of films. Using these methods, they found that the amorphous films became superconducting at temperatures higher than those...
Abstract
Metallic glasses can be prepared by solidification of liquid alloys at cooling rates sufficient to suppress the nucleation and growth of competing crystalline phases. This article presents a historical survey of the study of metallic glasses and other amorphous metals and alloys. This includes a discussion of synthesis and processing methods, structure and morphology, and a description of the electronic, magnetic, thermodynamic, chemical, and mechanical properties of metallic glasses. In addition, the article describes the development of metallic glasses as materials for technical applications.
Book Chapter
Electrical/Electronic Applications for Advanced Ceramics
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003062
EISBN: 978-1-62708-200-6
... with an expansion coefficient relatively close to that of silicon and, in consequence, is being rapidly developed for substrate use. Thin-film insulators (including SiO 2 and other oxides, glasses, and Si 3 N 4 ) have been developed as interlayer dielectric and as thin-film passivation for integrated circuit...
Abstract
Ceramic materials serve important insulative, capacitive, conductive, resistive, sensor, electrooptic, and magnetic functions in a wide variety of electrical and electronic circuitry. This article focuses on various applications of advanced ceramics in both electric power and electronics industry, namely, dielectric, piezoelectric, ferroelectric, sensing, magnetic and superconducting devices.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001111
EISBN: 978-1-62708-162-7
... with composition of Nb 3 Sn. The ratio is determined from tunneling data. Source: Ref 4 . (b) Plot of superconducting transition temperature of optimum Nb-Sn films versus composition. The 5, 50, and 95% completion points are indicated on each transition. The films are 0.5 μm (20 μin.) thick and were deposited...
Abstract
This article reviews the phase diagrams, alloy with third element additions, layer growth, critical current density, and matrix materials of A15 superconductors. It describes the production methods of tape conductors (chloride deposition, and surface diffusion) and multifilamentary wires (rod process, modified jelly roll process, niobium tube process, in-situ process, powder metallurgy process, and jelly roll method). The article focuses on reaction heat treatment, which is required at the end of wire processing to convert the ductile components to the desired, but brittle, superconductor. Finally, it discusses the applications of A15 superconductors in commercial magnets, power generation, power transmission, high-energy physics, and fusion.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001109
EISBN: 978-1-62708-162-7
...) Measured with field parallel to the a - b plane. (d) Epitaxial thin film, current in the a - b plane Fig. 1 Periodic table of the elements showing the large number of elements known to have superconducting transitions The primary physical property of the superconducting state...
Abstract
Superconductivity has been found in a wide range of materials, including pure metals, alloys, compounds, oxides, and organic materials. Providing information on the basic principles, this article discusses the theoretical background, types of superconductors, and critical parameters of superconductivity. It discusses the magnetic properties of selected superconductors and types of stabilization, including cryogenic stability, adiabatic stability, and dynamic stability. The article also focuses on alternating current losses in superconductors, including hysteresis loss, penetration loss, eddy current loss, and radio frequency loss. Furthermore, the article describes the flux pinning phenomenon and Josephson effects.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001110
EISBN: 978-1-62708-162-7
...-strand transposed Rutherford cable for the superconducting supercollider. Polyamide (Kapton) film wrap allows slippage with low friction as the coils are energized, reducing thermal transients in the conductor. Widely spaced fiberglass insulation promotes better cryogenic cooling. Courtesy of the SSC...
Abstract
Niobium-titanium alloys (NbTi) became the superconductors of choice in the early 1960s, providing a viable alternative to the A-15 compounds and less ductile alloys of niobium-zirconium. This can be attributed to the relative ease of fabrication, better electrical properties, and greater compatibility with copper stabilizing materials. This article discusses the ramifications of design requirements, selection criteria and processing methods of superconducting fibers and matrix materials. It provides information on the various steps involved in the fabrication of superconducting composites, including assembly, welding, isostatic compaction, extrusion, wire drawing, twisting, and final sizing. The article also provides a detailed account of the properties and applications of NbTi superconducting composites.
Book Chapter
In-Service Techniques—Damage Detection and Monitoring
Available to PurchaseSeries: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003653
EISBN: 978-1-62708-182-5
... on a macroscale using copper cup, glass beads, and steel screens ( Ref 19 ) or on a microscale with implantable bimetallic thin-film galvanic sensors ( Ref 20 , 21 , 22 , 23 ) have been developed and tested. The latter stand- alone, microthin film coulometer, called intelligent corrosivity sensor (ICS...
Abstract
This article focuses on the methods that are being developed for detecting and monitoring corrosion: electrochemical methods, electromagnetic or sound wave methods, fiber-optic technology, fluorescence methods, and the Diffracto Sight method. It reviews the importance of data management and the Corrosion Expert System. It concludes with information on the simulation and modeling for incorporating the mechanisms of corrosion prevention into military hardware systems design and operation.
Book Chapter
General Characteristics and Applications of Ceramics and Glasses
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003049
EISBN: 978-1-62708-200-6
... uses in either thin film or bulk forms. Future applications of these superconductors may include superconducting quantum interference devices, electrical power transport, magnets, motors, and communication and computer equipment. Semiconducting Ceramics Semiconducting ceramics include materials...
Abstract
This article provides an overview of the types, properties, and applications of traditional and advanced ceramics and glasses. Principal product areas for traditional ceramics include whitewares, glazes, porcelain enamels, structural clay products, cements, and refractories. Advanced ceramics include electronic ceramics, optical ceramics, magnetic ceramics, and structural ceramics.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003744
EISBN: 978-1-62708-177-1
... Abstract This article describes the mechanisms involved in creating texture for various metal-fabrication processes, namely, solidification, deformation, recrystallization and grain growth, thin-film deposition, and imposition of external magnetic fields. It discusses two experimental...
Abstract
This article describes the mechanisms involved in creating texture for various metal-fabrication processes, namely, solidification, deformation, recrystallization and grain growth, thin-film deposition, and imposition of external magnetic fields. It discusses two experimental and analytical approaches for experimental determination of texture: one using classical diffraction and pole figure measurement techniques and the other using individual orientation measurements. The article also provides information on microtexture, grain-boundary character, and texture gradients. It concludes with information on texture evolution through modeling.
Book Chapter
Thermal Spray Coatings for Electrical and Electronic Applications
Available to PurchaseBook: Thermal Spray Technology
Series: ASM Handbook
Volume: 5A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v05a.a0005736
EISBN: 978-1-62708-171-9
... 2 Cu 2 O 7- x for superconducting thin films. Fig. 6 Rotatable sputter target produced by spraying zinc oxide coating on a metallic tube. Courtesy of GfE Fremat GmbH References References 1. Janowiecki R. , Willson M. , and Harris D.H. , Plasma Spraying Process...
Abstract
Thermal spray processes involve complete or partial melting of a feedstock material in a high-temperature flame, and propelling and depositing the material as a coating on a substrate. This article describes the properties of sprayed electronic materials, including dielectrics, conductors, and resistors, and discusses their implications and associated limitations for device applications and potential remedial measures. The article presents specific examples of electrical/electronic device applications, including electromagnetic interference/radio-frequency interference shielding, planar microwave devices, waveguide devices, sensing devices, solid oxide fuel cells, heating elements, electrodes for capacitors and other electrochemical devices.
Book Chapter
Properties Needed for Electronic and Magnetic Applications
Available to PurchaseSeries: ASM Handbook
Volume: 20
Publisher: ASM International
Published: 01 January 1997
DOI: 10.31399/asm.hb.v20.a0002475
EISBN: 978-1-62708-194-8
..., as is the case with thin films which see an increasing use in electronic applications ( Ref 6 ). Another factor influencing the numerical values is the microstructure of the material: totally amorphous, crystalline regions within an amorphous matrix, polycrystalline, or monocrystalline. Chemical composition...
Abstract
This article presents an overview of the electric and magnetic parameters and discusses the significance of these parameters for electronic applications. It describes the components of analog and digital electronic circuits. The article reviews the augmenting technologies: magnetic and special technologies such as electrooptical.
Book Chapter
Vacuum Deposition, Reactive Evaporation, and Gas Evaporation
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001287
EISBN: 978-1-62708-170-2
..., reactivities of the residual gases and depositing species, and the tolerable impurity level in the deposit. Vacuum deposition of a film was first reported by Faraday in 1857 using exploding wires. Nahrwold was the first to use thermal evaporation in a vacuum to produce a thin film, in 1887. Vacuum...
Abstract
This article discusses the fundamentals of thermal vaporization and condensation and provides information on the various vaporization sources and methods of vacuum deposition. It offers an overview of reactive evaporation and its deposition techniques. The article also explains the advantages, limitations, and applications of vacuum deposition processes. Finally, it provides information on the gas evaporation process, its processing chamber, and related systems.
Book Chapter
Semiconductor Characterization
Available to PurchaseSeries: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006670
EISBN: 978-1-62708-213-6
... of the microelectronics industry. This section also considers germanium, gallium arsenide (GaAs), and the various epitaxial thin film semiconductors that can be grown on single-crystal wafer substrates. These materials are characterized first by their single-crystal nature and lack of transverse phase domains or grain...
Abstract
This article introduces various techniques commonly used in the characterization of semiconductors, namely single-crystal, polycrystalline, amorphous, oxide, organic, and low-dimensional semiconductors and semiconductor devices. The discussion covers material classification, fabrication methods, sample preparation, bulk/elemental characterization methods, microstructural characterization methods, surface characterization methods, and electronic characterization methods.
Book: Thermal Spray Technology
Series: ASM Handbook
Volume: 5A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v05a.a0005706
EISBN: 978-1-62708-171-9
... ceramics Computer-aided design/rapid prototyping techniques such as stereolithography Diamond synthesis and deposition Thin film deposition via VPS Improved feedstock production techniques and quality control New materials (e.g., composites, nanophase materials, perovskites, and zirconates...
Abstract
Thermal spray is a generic term for a group of coating processes used to apply metallic, ceramic, cermet, and some polymeric coatings for a broad range of applications. This article provides a brief description of commercially important thermal spray processes, namely, powder-fed flame spray, wire- or rod-fed flame spray, electric arc spray, plasma arc spray, vacuum plasma spray, high-velocity oxyfuel spray, detonation gun deposition, and cold spray, and their advantages. It provides details on the microstructural characteristics of thermal spray coatings. The article also presents information on a wide variety of materials that can be thermal sprayed, such as metals, ceramics, intermetallics, composites, cermets, polymers, and functionally gradient materials. Tables are included, which list the thermal spray processes and coating properties of importance for various industrial applications.
Book Chapter
Properties and Selection of Powder Metallurgy Refractory Metals
Available to PurchaseBook: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006123
EISBN: 978-1-62708-175-7
... Anodes Mo, W X-ray targets W, Mo, Re, composite W-Mo Electrodes (mercury switches) Mo, W Thin-film substrates Mo, W Electrical contacts W, W-Ag, W-Cu Heat sinks Mo, W Integrated circuit substrates Mo-Cu composites and laminates Filaments, ion gages, photoflash Re, W-Re...
Abstract
This article focuses on the selection, properties, and applications of powder metallurgy refractory metals and their alloys, including tungsten, molybdenum, tantalum, niobium, and rhenium.
Book Chapter
Corrosion of Niobium and Niobium Alloys
Available to PurchaseBook: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003824
EISBN: 978-1-62708-183-2
... and pure niobium. Nb-50Ta and Nb-40Ta showed a constant or increasing corrosion rate as time increased. The corrosion rate of niobium will increase with hydrochloric acid concentration and diminish initially with time, due to the formation of superficial oxide films ( Ref 14 ). In niobium-tantalum alloys...
Abstract
For chemical processing, niobium resists a wide variety of corrosive environments, including mineral acids, many organic acids, liquid metals, and most salt solutions. This article focuses on the mechanisms of corrosion resistance of niobium alloys in these environments. The niobium alloys include Nb-1Zr, Nb-55Ti, Nb-50Ta, and Nb-40Ta. The article describes the use of these corrosion resistant niobium alloys, and provides information on applications of niobium in various industries.
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