Thermal analysis provides a powerful tool for researchers and engineers in determining both unknown and reproducible behavioral properties of polymer molecules. This article covers the thermal analysis and thermal properties of engineering plastics with respect to chemical composition, chain configuration, conformation of the base polymers, processing of the base polymers with or without additives; and the response to chemical, physical, and mechanical stresses of base polymers as unfilled, shaped articles or as components of composite structures. It also describes thermal analysis techniques, including differential scanning calorimetry, thermogravimetric analysis, thermomechanical analysis, and rheological analysis. This article also summarizes the basic thermal properties used in the application of engineering plastics, such as thermal conductivity, temperature resistance, thermal expansion, specific heat, and the determination of glass transition temperatures. It concludes with a discussion of the thermal and related properties of nine thermostat resin systems divided into three groups by low, medium, and high service temperature capabilities.

Solvent cleaning is a surface preparation process that can be accomplished in room temperature baths (cold cleaning ) or by condensing vapors of a solvent on a workpiece (vapor degreasing). This article provides a detailed discussion on solvents, equipment, process limitations and applications, and safety and health hazards of cold cleaning and vapor degreasing. It also includes information on control of contamination, conservation and recovery of solvent, and disposal of solvent wastes.

Shell molding is used for making production quantities of castings that range in weight from a few ounces to approximately 180 kg (400 lb), in both ferrous and nonferrous metals. This article lists the limitations or disadvantages of shell mold casting. It describes the two methods for preparation of resin-sand mixture for shell molding, namely, mixing resin and sand according to conventional dry mixing techniques, and coating the sand with resin. Shaping of shell molds and cores from resin sand mixtures is accomplished in machines. The article discusses the major steps in producing a mold or core and describes the problems most frequently encountered in shell-mold casting. The problems include mold cracking, soft molds, low hot tensile strength of molds, peelback, and mold shift. The article concludes with information on examples that provide some relative cost comparisons between shell molding and green sand molding.

This article focuses on manufacturing-related failures of injection-molded plastic parts, although the concepts apply to all plastic manufacturing processes It provides detailed examples of failures due to improper material handling, drying, mixing of additives, and molecular packing and orientation. It also presents examples of failures stemming from material degradation improper use of metal inserts, weak weld lines, insufficient curing of thermosets, and inadequate mixing and impregnation in the case of thermoset composites.

This article focuses on the electroless gold plating technique, describing the advantages and limitations, applications, and properties of plated deposits. It also reviews process variables of the technique, including gold concentration, reducing agent, agitation, and contaminants.

This article is an informative primer on sealants and the role they play in engineered assemblies. It discusses the physical, thermal, chemical, and electrical properties of sealant materials and the various forms in which they are applied, including liquids, pastes, and extruded tapes. It also describes classifications and types, comparing and contrasting sealants made from oil-based caulks, asphalts, coal tar resins, latex acrylic sealants, polyvinyl acetate caulks, solvent acrylics, butyl sealants, polysulfides, polyurethanes, modified silicones, anaerobics, vinyl plastisols, and polypropylenes. In addition, the article provides practical design insight, addressing application requirements, seal configurations, and joint stresses. It concludes with a brief discussion on the use of sealants in aerospace, automotive, electrical, and construction applications.

This article reviews the pattern materials used in investment casting, which can be loosely grouped into waxes and plastics. The patternmaking process, pattern tooling, and pattern and cluster assembly are described. The article also describes the manufacture of ceramic shell molds and cores, detailing the binders and other materials used, as well as the formulation and control of slurries. Methods for pattern removal, mold firing, melting, casting, postcasting treatment, and inspection are explained. After presenting design recommendations for investment castings, the article concludes with information on applications and special versions of the investment casting process.

This article outlines the processes by which materials are selected to prevent or control localized corrosion, galvanic corrosion, and intergranular corrosion. It reviews the operating conditions and the design of candidate materials for material selection. The article discusses various corrosion-resistant materials, including ferrous and nonferrous metals and alloys, thermoplastics, reinforced thermosetting plastics, nonmetallic linings, glass, carbon and graphite, and catalyzed resin coatings. It examines an unusual form of intergranular corrosion known as exfoliation, which occurs in aluminum-copper alloys. The article also describes three types of erosion-corrosion: liquid erosion-corrosion, cavitation, and fretting. It concludes with information on the various factors to be considered for material selection, including minimum cost or economic design, minimum corrosion, minimum investment, and minimum maintenance.

This article focuses on the corrosion and deterioration of components on recreational and small workboats. It discusses the materials selection and corrosion control for the components. These components include hulls, fittings, fasteners, metal deck gear, winches, backing plates, lifeline supports, inboard engines, cooling systems, propulsion systems, electrical and electronic systems, plumbing systems, masts, spars, and rigging.

Hard chromium plating is produced by electrodeposition from a solution containing chromic acid and a catalytic anion in proper proportion. This article presents the major uses of hard chromium plating, and focuses on the selection factors, plating solutions, solution and process control, equipment, surface preparation, and crack patterns and other characteristics of hard chromium plating. It offers recommendations for the design and use of plating racks, describes the problems encountered in hard chromium plating, and their corrective procedures. The article provides information on the removal of chromium plate from coated metals, recovery and disposal of wastes, and stopoff media for selective plating.

Electrical contacts are metal devices that make and break electrical circuits. This article provides information on materials selection criteria and failure modes of make-break contacts. It describes the property requirements for make-break arcing contacts, namely, electrical conductivity, mechanical properties, chemical properties, fabrication properties, and thermal properties. The article presents a brief note on brush contact materials and their interdependence factors for sliding contacts. It also describes the type of commercial contact materials for electrical contacts, namely, copper metals, silver metals, gold metals, metals of the platinum group, precious metal overlays, tungsten and molybdenum, aluminum, and composite materials. Finally, the article provides information on composite manufacturing methods, and tabulates the physical, and mechanical properties of electrical contact materials, including copper, silver, gold, platinum, palladium, and composites.

Anodizing refers to conversion coating of the surface of aluminum and its alloys to porous aluminum oxide. This article provides the reasons for performing anodizing and discusses the three principal types of anodizing processes, namely, chromic acid process, sulfuric acid process, and hard anodic process. It describes the limitations imposed by variables, such as alloy composition, surface finish, prior processing, temper or heat treatment, and the use of inserts, on the anodizing processes. The article explains the causes and means adopted for correcting several specific problems in anodizing aluminum. It also discusses the process control techniques and equipment used for anodizing. The article reviews the sealing processes for anodic coatings and the method for coloring the coatings. It concludes with a discussion on the effects of anodic coatings on the surface and mechanical properties of aluminum and its alloys.

This article reviews the fundamentals of electrochemical corrosion test methods. The features and requirements of the instrumentation needed for an electrochemical test are briefly discussed. The article provides a discussion on the various electrochemical techniques and tests available for laboratory studies of corrosion phenomena. The techniques and tests include no-applied-signal tests, small-signal polarization tests, large-signal polarization tests, scanning electrode techniques, and miscellaneous techniques.

Addition of beryllium, up to about 2 wt″, produces dramatic effects in copper, nickel, aluminum, magnesium, gold, zinc, and other base metal alloys. This article provides information on the chemical composition, microstructure, heat treatment, fabrication characteristics, production steps and physical metallurgy of beryllium-copper, beryllium-nickel, and beryllium-aluminum alloy, and tabulates their mechanical, electrical and physical properties, and temper designations. It describes the important features of this alloy group, including information on safe handling. Additionally, the article presents examples of the beneficial properties of beryllium-copper alloys and quantifies some of the major reasons for their selection for particular applications.

This article provides an overview of surface contaminants that may affect the heat treatment processes and end-product quality. It presents information on the chemicals used to clean different surface contaminants of steels. The article discusses three types of cleaning methods, namely, mechanical, chemical, and electrochemical and their effectiveness and applicability. The mechanical cleaning methods include grinding, brushing, steam or flame jet cleaning, abrasive blasting, and tumbling. Solvent cleaning, emulsion cleaning, alkaline cleaning, acid cleaning, pickling, and descaling are chemical cleaning methods. The electrochemical cleaning methods include electropolishing, electrolytic alkaline cleaning, and electrolytic pickling. The article provides information on cleanliness measurement methods such as qualitative tests and quantitative tests to ensure product quality. Health hazards that may be associated with each cleaning method and the general control measures to be used for each hazard are tabulated.

Thermomechanical analysis (TMA) is a thermal analysis technique in which the length of a specimen is precisely measured versus temperature and time as the specimen is subjected to controlled heating and cooling. This article discusses the various factors and processes involved in TMA. The discussion covers the general principles, equipment used, specimen preparation process, calibration conditions, data analysis steps, and examples of the applications and interpretation of TMA.

This article describes various methods of electrochemical analysis, namely coulometry, electrogravimetry, voltammetry, electrometric titration, and nanometer electrochemistry. The discussion covers the general uses, sample requirements, application examples, advantages, and limitations of these methods. Some of the factors pertinent to electrochemical cells are also provided. In addition, the article provides information on various potentiometric membrane electrodes used to quantify numerous ionic and nonionic species.

This article provides an overview of experimental, analytical, and numerical tools for temperature evaluation of dry and lubricated systems. It describes the analytical methods and numerical techniques for frictional heating and temperature estimation, as well as viscous heating in full-film lubrication. The article also discusses the viscous heating temperature measurements and numerical analysis of viscous heating.

Magnesium and magnesium alloys are used in a wide variety of structural and nonstructural applications. This article provides information on selection and application of magnesium and magnesium alloys, mainly, casting alloys and wrought alloys. It also provides tabulated data for the composition, properties of these alloys, including compressive strength, bearing strength, shear strength, hardness, wear resistance, and fatigue strength. The article describes the selection of product forms (castings, extrusions, forgings) for structural applications which is based on mechanical property requirements, cost, availability, and fabricability. It also discusses the types of inserts used in magnesium. The article also deals with the joining of magnesium alloys by welding, adhesive bonding, and riveting. It concludes by describing the formability and machinability of magnesium and magnesium alloys, and explains the role of magnesium in design and weight reduction.