Sheet molding compounds (SMCs) refers to both material and process for producing glass-fiber-reinforced polyester resin items. This article discusses the material components incorporated into the resin paste for desirable processing and molding characteristics and optimum physical and mechanical properties, including catalyst, fillers, thickeners, pigments, thermoplastic polymers, flame retardants, and ultraviolet absorbers. It talks about the mixing techniques available for SMC resin pastes, including batch, batch/continuous, and continuous mixing. The article also outlines the design features and the operations of continuous-belt and beltless machine type SMCs.

This article discusses the most common thermal analysis methods for thermosetting resins. These include differential scanning calorimetry, thermomechanical analysis, thermogravimetric analysis, and dynamic mechanical analysis. The article also discusses the characterization of uncured thermosetting resins as well as the curing process. Then, the techniques to characterize the physical properties of cured thermosets and composites are presented. Several examples of stress-strain curves are shown for thermosets and thermoplastic polymers.

This introductory article describes the various aspects of chemical structure that are important to an understanding of polymer properties and thus their eventual effect on the end-use performance of engineering plastics. The polymers covered include hydrocarbon polymers, carbon-chain polymers, heterochain polymers, and polymers containing aromatic rings. The article also includes some general information on the classification and naming of polymers and plastics. The most important properties of polymers, namely, thermal, mechanical, chemical, electrical, and optical properties, and the most significant influences of structure on those properties are then discussed. A variety of engineering thermoplastics, including some that are regarded as high-performance thermoplastics, are covered in this article. In addition, a few examples of commodity thermoplastics and biodegradable thermoplastics are presented for comparison. Finally, the properties and applications of six common thermosets are briefly considered.

This article outlines the fundamentals of polymer science and emphasizes the aspects that are necessary and useful to applications of engineering plastics. The basic structure of polymers influences the properties of both polymers and the plastics made from them. An understanding of this basic structure permits the engineers to understand which polymers may be acceptable for a certain application, and which may not. There are various possible classification schemes for polymers. Typical classification categories include polymerization process, chemical elements that make up the monomer, or crystalline versus noncrystalline structure. The article describes the various aspects of chemical structure that are important to an understanding of polymer properties and, thus, affect eventual end uses. It discusses different types of names assigned to polymers. The article details the aspects of polymer structure and examines the properties of polymers and the way they are altered by structure.

This article illustrates the polymer matrices used for composite materials. It describes the use of prepeg materials in manufacturing high-performance composites. The article discusses the various infusion processes for the development of fiber-reinforced composites, namely, resin transfer molding, vacuum-assisted resin transfer molding, and resin film infusion. It explains the composite- and matrix-toughening methods for fiber-reinforced composites, such as dispersed-phase toughening and interlayer toughening. The article concludes with information on optical microscopy, which provides an insight into the micro- and macrostructure of fiber-reinforced composites.

This article provides information on the thermoplastic resins used as matrix materials for continuous fiber reinforced composites. It focuses on the materials that are suitable for fabrication of structural laminates and used for aerospace applications. The article provides a discussion on the background, categories, characteristics, product forms, properties, cost benefits, and processing techniques of thermoplastic resins. Strategies that have been advanced to deal with impregnation difficulties are also discussed.

Plastics or polymers are used in a variety of engineering and nonengineering applications where they are subjected to surface damage and wear. This article discusses the classification of polymer wear mechanisms based on the methodologies of defining the types of wear. The first classification is based on the two-term model that divides wear mechanisms into interfacial and bulk or cohesive. The second is based on the perceived wear mechanism. The third classification is specific to polymers and draws the distinction based on mechanical properties of polymers. In this classification, wear study is separated as elastomers, thermosets, glassy thermoplastics, and semicrystalline thermoplastics. The article describes the effects of environment and lubricant on the wear failures of polymers. It presents a case study on nylon as a tribological material. The article explains the wear failure of an antifriction bearing, a nylon driving gear, and a polyoxymethylene gear wheel.

This article presents the mechanisms of polymer wear and quantifies wear in terms of wear rate (rate of removal of the material). Interfacial and bulk wear are discussed as well as a discussion on the wear study of "elastomers," "thermosets," "glassy thermoplastics," and "semicrystalline thermoplastics." The article also discusses the effects of environment and lubricant on the wear failures of polymers. It presents a case study on considering nylon as a tribological material and failure examples, explaining wear resistance of polyurethane elastomeric coatings and failure of an acetal gear wheel.

This article addresses some established protocols for characterizing thermoplastics and whether they are homogeneous resins, alloyed, or blended compositions or highly modified thermoplastic composites. It begins with a discussion on characterizing mechanical, rheological, and thermal properties of polymer. This is followed by a section describing molecular weight determination using viscosity measurements. Next, the article discusses the use of cone and plate and parallel plate geometries in melt rheology. It then reviews the processes involved in the analysis of thermoplastic resins by chromatography. Finally, the article covers three operations of thermoanalysis, namely differential scanning calorimetry, thermogravimetric analysis, and thermomechanical testing.

Molding compounds are plastic materials in varying stages of pellets or granulation that consist of resin, filler, pigments, reinforcement, plasticizers, and other ingredients ready for use in a molding operation. This article describes the material components and physical properties of sheet molding compounds (SMC). The three types of resin paste mixing techniques, such as batch, batch/continuous, and continuous, for an SMC operation are reviewed. The article discusses the design features and functional operations of the two types of SMC machines, namely, continuous-belt and beltless machines. It explains the formulation and processing of bulk molding compounds and reviews molding methods for bulk molding compounds, including compression, transfer, and injection molding. The effects of the fiber type and length and the matrix type on thermoset bulk molding compounds are discussed. It describes the four injection molding processes of injection molding compounds such as feeding, transporting, injecting, and flowing.

The discussion on the fracture of solid materials, both metals and polymers, customarily begins with a presentation of the stress-strain behavior and of how various conditions such as temperature and strain-rate affect the mechanisms of deformation and fracture. This article describes crazing and fracture in polymeric materials, with a review of the behavior of the elastic modulus as a function of temperature or time parameters, emphasizing the importance of the viscoelastic nature of their deformation and fracture. The discussion covers the behavior of polymers under stress, provides information on ductile and brittle behaviors, and describes craze initiation in polymers and crack formation and fracture by crazing. Macroscopic permanent deformation of polymeric materials caused by shear-yielding and crazing, which eventually can result in fracture and failure, is also covered.

This article describes the most significant tests to characterize the properties of constituent materials. It discusses the chemical, physical, and mechanical tests for determining the properties of reinforcement fibers and fabrics. The article provides information on some of the basic materials used for thermoset and thermoplastic resin matrices. It reviews the identification of the individual characteristics of thermoset and thermoplastic resin along with the test methods normally used for their determination. The article contains a table that lists properties and tests for uncured and cured thermoset-matrix resins and prepregs.

This article discusses the thermal properties of engineering plastics and elastomers with respect to chemical composition, chain configuration, and base polymer conformation as determined by thermal analysis. It describes the processing of base polymers with or without additives and their response to chemical, physical, and mechanical stresses whether as an unfilled, shaped article or as a component of a composite structure. It summarizes the basic thermal properties of thermoplastics and thermosets, including thermal conductivity, temperature resistance, thermal expansion, specific heat, and glass transition temperature. It also provides information on polyimide and bismaleimide resin systems. Representative examples of different types of engineering thermoplastics are discussed primarily in terms of structure and thermal properties.