This article discusses the materials and properties of polymer-matrix composites to characterize each generic material according to its composition and method of manufacture. It contains a table that lists the key physical, mechanical, thermal, and electrical properties, and in-service conditions of concern for resin-matrix composites. Axes definitions, symbols, and special property calculations for composite material property tests are reviewed. The article provides an overview of the performance capabilities of selected polymer-matrix composite materials such as thermoplastic-matrix composites and thermoset-matrix composites. The thermoplastic-matrix composites include thermoplastic polyester resins and fiber resin composites; thermoplastic polyamide resins and fiber-resin composites; and thermoplastic polysulfone resins and fiber-resin composites.

The design and analysis of aerospace and industrial composite components and assemblies requires a detailed knowledge of materials properties, which, in turn, depend on the manufacturing, machining, and assembly methods used. This article, through several tables and graphs, provides the mechanical properties, physical properties, and service characteristics of representative composite fiber-resin combinations, including thermoplastic matrix composites such as thermoplastic polyester resins, thermoplastic polyamide resins, and thermoplastic polysulfone resins, and thermoset matrix composites such as thermoset polyester resins, thermoset phenolic resins, thermoset epoxy resins, thermoset polyimide resins, and thermoset bismaleimide resins.

This article discusses the properties and applications of two types of polyimide resins: condensation polyimides and addition-type polyimides. It describes the chemistry of condensation-type polyimides during synthesis, processing of polyamide acid precursor solution to polyimide, and preparation of polyimide films from thermoplastic polyamic acid precursors. The article reviews the chemistry of several addition-type polyimides, including phenylethynyl-containing imide oligomers, nadic end-capped polyimides, and LARC RP46. It explains the preparation processes of nadic end-capped amic acid oligomer resin solutions, including the preparation of resin powder and resin disks, adhesive film, adhesive bond specimens, and films.

This article discusses the coating systems categorized by the generic type of binder or resin and grouped according to the curing or hardening mechanism inherent within that generic type. It focuses on the properties, advantages, and limitations of various autooxidative cross-linked resins, thermoplastic resins, and cross-linked thermosetting resins. The autooxidative cross-linked resins include alkyd resins and epoxy esters. The article examines the two types of coatings based on thermoplastic resins: those deposited by evaporation of a solvent, commonly called lacquers, and those deposited by evaporation of water, a class of coatings called water-borne coatings. The coatings that chemically cross link by copolymerization, including epoxies, unsaturated polyesters, urethanes, high-temperature curing silicones, and phenolic linings, are also described.

This article discusses the thermal properties of engineering plastics and elastomers with respect to chemical composition, chain configuration, and base polymer conformation as determined by thermal analysis. It describes the processing of base polymers with or without additives and their response to chemical, physical, and mechanical stresses whether as an unfilled, shaped article or as a component of a composite structure. It summarizes the basic thermal properties of thermoplastics and thermosets, including thermal conductivity, temperature resistance, thermal expansion, specific heat, and glass transition temperature. It also provides information on polyimide and bismaleimide resin systems. Representative examples of different types of engineering thermoplastics are discussed primarily in terms of structure and thermal properties.

This introductory article describes the various aspects of chemical structure that are important to an understanding of polymer properties and thus their eventual effect on the end-use performance of engineering plastics. The polymers covered include hydrocarbon polymers, carbon-chain polymers, heterochain polymers, and polymers containing aromatic rings. The article also includes some general information on the classification and naming of polymers and plastics. The most important properties of polymers, namely, thermal, mechanical, chemical, electrical, and optical properties, and the most significant influences of structure on those properties are then discussed. A variety of engineering thermoplastics, including some that are regarded as high-performance thermoplastics, are covered in this article. In addition, a few examples of commodity thermoplastics and biodegradable thermoplastics are presented for comparison. Finally, the properties and applications of six common thermosets are briefly considered.

There are many reasons why plastic materials should not be considered for an application. It is the responsibility of the design/materials engineer to recognize when the expected demands are outside of what the plastic can provide during the expected life-time of the product. This article reviews the numerous considerations that are equally important to help ensure that part failure does not occur. It provides a quick review of thermoplastic and thermoset plastics. The article focuses primarily on thermoset materials that at room temperature are below their glass transition temperature. It describes the motivation for material selection and the goal of the material selection process. The use of material datasheets for material selection as well as the processes involved in plastic material selection and post material selection is also covered.

Advanced thermoplastics are stiff, moldable plastics that compete with traditional engineering thermoplastics and thermosets owing to their good tensile, compressive, impact, and shear strength, electrical properties, and corrosion resistance. This article discusses commercial forms, family characteristics, properties and applications of the following advanced thermoplastics: homopolymer and copolymer acetals, fluoropolymers, ionomers, polyamides, polyamide-imides, polyarylates, polyketones, polyaryl sulfones, polybutylene terephthalates, polycarbonates, polyether-imides, polyether sulfones, polyethylene terephthalates, thermoplastic polyimides, liquid crystal polymers, polyphenylene ether blends, polyphenylene sulfides, and polysulfones.

Adhesive bonding is a proven technology in the manufacture of automotive assemblies, helping carmakers achieve weight reduction goals without compromising body stiffness, crash performance, and noise-vibration-handling characteristics. This article discusses the advantages and limitations of adhesive-bonded aluminum joints and the procedures used to produce them. It addresses surface preparation, the addition of interfacial coatings and primers, and the application of thermoplastic and thermosetting resins. The article examines the nature and role of the various layers that constitute the joint and explains how each contributes to performance. It also discusses adhesive selection factors, joint design, and testing procedures.

This article is a compilation of abbreviations of terms, techniques, standards, compounds, and properties of materials that are relevant to the characterization and failure analysis of plastics.

This article describes the most significant tests to characterize the properties of constituent materials. It discusses the chemical, physical, and mechanical tests for determining the properties of reinforcement fibers and fabrics. The article provides information on some of the basic materials used for thermoset and thermoplastic resin matrices. It reviews the identification of the individual characteristics of thermoset and thermoplastic resin along with the test methods normally used for their determination. The article contains a table that lists properties and tests for uncured and cured thermoset-matrix resins and prepregs.

This article discusses the types, properties, and uses of continuous-fiber-reinforced composites, including glass, carbon, aramid, boron, continuous silicon carbide, and aluminum oxide fiber composites. While polyester and vinyl ester resins are the most used matrix materials for commercial applications, epoxy resins, bismaleimide resins, polyimide resins, and thermoplastic resins are used for aerospace applications. The article addresses design considerations as well as product forms and fabrication processes.

This article illustrates the polymer matrices used for composite materials. It describes the use of prepeg materials in manufacturing high-performance composites. The article discusses the various infusion processes for the development of fiber-reinforced composites, namely, resin transfer molding, vacuum-assisted resin transfer molding, and resin film infusion. It explains the composite- and matrix-toughening methods for fiber-reinforced composites, such as dispersed-phase toughening and interlayer toughening. The article concludes with information on optical microscopy, which provides an insight into the micro- and macrostructure of fiber-reinforced composites.

Thermal analysis provides a powerful tool for researchers and engineers in determining both unknown and reproducible behavioral properties of polymer molecules. This article covers the thermal analysis and thermal properties of engineering plastics with respect to chemical composition, chain configuration, conformation of the base polymers, processing of the base polymers with or without additives; and the response to chemical, physical, and mechanical stresses of base polymers as unfilled, shaped articles or as components of composite structures. It also describes thermal analysis techniques, including differential scanning calorimetry, thermogravimetric analysis, thermomechanical analysis, and rheological analysis. This article also summarizes the basic thermal properties used in the application of engineering plastics, such as thermal conductivity, temperature resistance, thermal expansion, specific heat, and the determination of glass transition temperatures. It concludes with a discussion of the thermal and related properties of nine thermostat resin systems divided into three groups by low, medium, and high service temperature capabilities.

This article discusses the three basic elements of an epoxy resin formulation that must be understood when selecting a thermoset system. These include base resins, epoxy resin curatives, and modifiers. The article provides examples of epoxy resin formulations that illustrate how raw materials are combined to tailor a formulation to a specific application. It concludes with a discussion on general guidelines for the safe handling of epoxy resins and their associated products.

Powder bed fusion (PBF) of polymers is a collection of additive manufacturing processes that melt and fuse polymer in a powder bed. This article provides a complete suite of materials and processes involved in PBF of polymers. The discussion includes details of thermal and manufacturing issues, and safety, postprocessing, and finishing considerations, as well as of principal defects in PBF polymer parts and the mechanical properties of the parts produced by PBF. The article provides case studies on the applications of polymer PBF.

This article provides information on the thermoplastic resins used as matrix materials for continuous fiber reinforced composites. It focuses on the materials that are suitable for fabrication of structural laminates and used for aerospace applications. The article provides a discussion on the background, categories, characteristics, product forms, properties, cost benefits, and processing techniques of thermoplastic resins. Strategies that have been advanced to deal with impregnation difficulties are also discussed.

This article provides a detailed discussion on the principal classes and curatives of epoxy resins used in the coatings industry. The principal classes are bisphenol A epoxy, bisphenol F epoxy, epoxy phenol novolac, cycloaliphatic epoxies, epoxy acrylate, brominated bisphenol-A-based epoxy, phosphorus-containing epoxy, fluorinated epoxies, epoxy esters, epoxy phosphate esters, and waterborne epoxy. The principal curatives are amines, amine adducts, cyanoethylated amines, ketimines, polyoxyalkylene amines, cycloaliphatic amines, aromatic amines, polyamides, amido amines, and dicyandiamides. Other curatives include polyester co-polymers, phenolic co-polymers, melamine and urea formaldehyde co-polymer resins, phosphate flame retardants, ultraviolet and electron beam curing of epoxy resins, Mannich bases, Mannich-based adducts, and anhydrides. The article concludes by discussing the concerns regarding the use of epoxy coatings.