This article discusses the various tests applied to a thermal barrier coating system and to the zirconia layer to establish thermomechanical, environmental stability, and thermal design properties such as coefficient of thermal expansion, specific heat, and thermal transport properties. Thermal fatigue testing and the test for evaluating oxidation resistance of the bond coat is also discussed.

This article describes the two commonly used standardized tests for determining the mechanical properties of thermal spray coatings: hardness testing and tensile adhesion testing. It discusses the destructive and non-destructive methods of residual-stress measurement. Electrochemical testing methodologies include two distinctly different methods: direct and alternating current impedance techniques for assessing the corrosion resistance of coating attributes. The article also reviews the testing methods for determining thermomechanical and environmental stability of thermal barrier coatings. It discusses the wear testing methodologies that are standardized by ASTM, including the pin-on-disk, block-on-ring, dry sand/rubber wheel, erosion, metallographic apparatus abrasion, fretting wear, cavitation, reciprocating ball-on-flat, impact, and rolling contact fatigue test. The article concludes with a discussion on the methods of testing abradability and erosion resistance in abradable coatings.

This article presents tools, techniques, and procedures that engineers and material scientists can use to investigate plastic part failures. It also provides a brief survey of polymer systems and the key properties that need to be measured during failure analysis. It describes the characterization of plastics by infrared and nuclear magnetic resonance spectroscopy, differential scanning calorimetry, differential thermal analysis, thermogravimetric analysis, thermomechanical analysis, and dynamic mechanical analysis. The article also discusses the use of X-ray diffraction for analyzing crystal phases and structures in solid materials.

Homogenization, in a broad sense, refers to the processes designed to achieve uniform distribution of solutes or phases in a given matrix. This article addresses the root cause for inhomogeneities in cast components. It is nearly a standard industrial practice to homogenize alloys before thermomechanical processing. The article lists the objectives of homogenization and benefits of homogenization treatments. The benefits include increased resistance to pitting corrosion, increased resistance to stress-corrosion cracking, improved ductility, and uniform precipitate distribution during subsequent aging. The article provides a schematic illustration of an energy-dispersive X-ray spectroscope (EDS) scattered data of solute distributions across a dendrite due to microsegregation of chromium and molybdenum. It concludes with information on the computational modeling for simulation of microsegregation of chromium and molybdenum.

Thermomechanical analysis (TMA) is a thermal analysis technique in which the length of a specimen is precisely measured versus temperature and time as the specimen is subjected to controlled heating and cooling. This article discusses the various factors and processes involved in TMA. The discussion covers the general principles, equipment used, specimen preparation process, calibration conditions, data analysis steps, and examples of the applications and interpretation of TMA.

The response of titanium and titanium alloys to heat treatment depends on the composition of the metal, the effects of the alloying elements on the alpha-beta crystal transformation, and the thermomechanical processing utilized during processing of the alloy. This article provides a detailed discussion on the effects of heat treatment on the mechanical properties for three general classes of titanium alloys, namely, alpha and near-alpha titanium alloys, alpha-beta alloys, and beta alloys.

Copper steels are precipitation-strengthened steels that are designed to have a unique combination of physical and mechanical properties. This article provides an overview of copper precipitate-strengthened steels and their applications, and discusses appropriate ASTM International standards. It describes the common phases and alloying elements present in copper precipitate-strengthened steels, and reviews the influences of alloying elements on processing, phase diagrams, microstructures, and mechanical properties. The article also discusses the thermomechanical process, solutionizing heat treatment, and isothermal aging in detail. It concludes with a review of the interrelationships between heat treatments, microstructures, and mechanical properties.

Solid-state transformations occurring in a weld are highly nonequilibrium in nature and differ distinctly from those experienced during casting, thermomechanical processing, and heat treatment. This article focuses on welding metallurgy of fusion welding of steels and highlights the fundamental principles that form the basis of many of the developments in steels and consumables for welding. Examples in the article are largely drawn from the well-known and relatively well-studied case of ferritic steel weldments to illustrate the special physical metallurgical considerations brought about by the weld thermal cycles and by the welding environment. The article provides information on welds in other alloy systems such as stainless steels and aluminum-base, nickel-base, and titanium-base alloys.

Thermomechanical are used to gain insight into the causes of problems that arise during a given thermomechanical process. This article provides examples to demonstrate how significant the parameters were selected for specific tests. It examines the types of problems that can occur during a thermomechanical process. The article provides information on the thermophysical properties, which include specific heat, coefficient of thermal expansion, thermal conductivity/diffusivity, and density. It concludes with examples that illustrate how the various considerations in testing are successfully used to solve practical thermomechanical processing problems.

This article reviews general trends in the cyclic response for representative commercial alloys to establish the spectrum of cyclic properties attainable through microstructural alteration. Individual alloy classes are examined in detail to assess the understanding of relationships between microstructure and fatigue resistance. These alloys classes include ferritic-pearlitic alloys, martensitic alloys, maraging steels, and metastable austenitic alloys. The article also discusses the role of internal defects and selective surface processing in influencing fatigue performance.

Thermal analysis provides a powerful tool for researchers and engineers in determining both unknown and reproducible behavioral properties of polymer molecules. This article covers the thermal analysis and thermal properties of engineering plastics with respect to chemical composition, chain configuration, conformation of the base polymers, processing of the base polymers with or without additives; and the response to chemical, physical, and mechanical stresses of base polymers as unfilled, shaped articles or as components of composite structures. It also describes thermal analysis techniques, including differential scanning calorimetry, thermogravimetric analysis, thermomechanical analysis, and rheological analysis. This article also summarizes the basic thermal properties used in the application of engineering plastics, such as thermal conductivity, temperature resistance, thermal expansion, specific heat, and the determination of glass transition temperatures. It concludes with a discussion of the thermal and related properties of nine thermostat resin systems divided into three groups by low, medium, and high service temperature capabilities.

This article addresses some established protocols for characterizing thermoplastics and whether they are homogeneous resins, alloyed, or blended compositions or highly modified thermoplastic composites. It begins with a discussion on characterizing mechanical, rheological, and thermal properties of polymer. This is followed by a section describing molecular weight determination using viscosity measurements. Next, the article discusses the use of cone and plate and parallel plate geometries in melt rheology. It then reviews the processes involved in the analysis of thermoplastic resins by chromatography. Finally, the article covers three operations of thermoanalysis, namely differential scanning calorimetry, thermogravimetric analysis, and thermomechanical testing.

This article describes microstructures and microstructure-property relationships in steels. It emphasizes the correlation of microstructure and properties as a function of carbon content and processing in low-alloy steels. The article discusses the iron-carbon phase diagram and the phase transformations that change the structure and properties at varying levels of carbon content. Microstructures described include pearlite, bainite, proeutectoid ferrite and cementite, ferrite-pearlite, and martensite. The article depicts some of the primary processing steps that result in ferrite-pearlite microstructures. It shows the range of hardness levels which may be obtained by tempering at various temperatures as a function of the carbon content of the steel. To reduce the number of processing steps associated with producing quenched and tempered microstructures, new alloying approaches have been developed to produce high-strength microstructures directly during cooling after forging.

This article discusses the wrought product forms of titanium and titanium-base alloys, which include forgings and the typical mill products with tabulations for various specifications, and compares specifications for pure titanium, titanium alloys for mechanical, physical properties and chemical properties, including chemical composition, corrosion resistance, and chemical reactivity. The article discusses the effects of alloying elements in titanium alloys, and describes the classes of titanium alloys, namely, alpha alloys, alpha-beta alloys, and beta alloys. It also describes the typical applications of various titanium-base materials, and explains the crystal structure, effect of impurities, and microstructural constituents of titanium alloys. The article provides a brief description on the processing of wrought titanium alloys, including primary fabrication in which ingots are converted into general mill products and secondary fabrication (forging, extrusion, forming, machining, chemical milling and joining) of finished shapes from mill products and the heat treatment of titanium alloys.

This article focuses on the various technology drivers for finishing methods, namely, tolerance, consistency, surface quality, and productivity. Every finishing method may be viewed as a manufacturing system consisting of four input categories: machine tool, processing tool, work material, and operational factors. The article provides a classification of finishing as a surface generation process and addresses the characteristics of the generated surfaces and the methods used to measure them. It describes the thermomechanical interactions occurring between the processing tool and the work material in the presence of machine tool and operational factors.

The Al-Cu-Li alloy 2050 was designed to replace 2xxx alloys at low thicknesses and 7xxx alloys on the thicker end of the range. This datasheet provides information on key alloy metallurgy and processing effects on mechanical properties of this 2xxx series alloy. A figure presents a performance comparison of 2050 and 7050.

This article summarizes some issues and approaches in performing computational analyses of mechanical behavior, distortion, and hot tearing during solidification. It presents the governing equations and describes the methods used to solve them. The article reviews the finite element formulation, multidomain approaches, and arbitrary Lagrangian Eulerian method in solidification modeling. It illustrates the sand casting of braking disks and continuous casting of steel slabs.

The residual porosity in sintered refractory metal ingots is usually eliminated by different densification processes, such as thermomechanical processes. This article focuses on thermomechanical processing of tungsten, molybdenum, and tantalum. It provides an overview of liquid-phase sintering of tungsten heavy alloys and describes the infiltration of tungsten and molybdenum for attaining full density. The article concludes by providing information on hot isostatic pressing of refractory metal alloys to full density.

Titanium and its alloys have been used extensively in a wide variety of implant applications, such as artificial heart pumps, pacemaker cases, heart valve parts, and load-bearing bone or hip joint replacements or bone splints. This article discusses the properties of titanium and its alloys and presents a list of titanium-base biomaterials. Titanium components are produced in wrought, cast, and powder metallurgy (PM) form. The article describes forging, casting, and heat treating of titanium alloys for producing titanium components. Typical mechanical properties of titanium biomedical implant alloys are listed in a tabular form. The article presents an overview of the surface-modification methods for titanium and its alloys implants. It concludes with a section on biocompatibility and in vivo corrosion of titanium alloys.

This article introduces the different types, distinctions, and grades of commercially pure titanium and titanium alloys. It describes three types of alloying elements: alpha stabilizers, beta stabilizers, and neutral additions. The article discusses the basic categories of titanium alloys, namely, alpha and near-alpha titanium alloys, beta and near-beta titanium alloys, and alpha-beta titanium alloys. It also describes the general microstructural features of titanium alloys.