This article discusses the various tests applied to a thermal barrier coating system and to the zirconia layer to establish thermomechanical, environmental stability, and thermal design properties such as coefficient of thermal expansion, specific heat, and thermal transport properties. Thermal fatigue testing and the test for evaluating oxidation resistance of the bond coat is also discussed.

This article provides information on the salt baths used for a variety of heat treatments, including heating, quenching, interrupted quenching (austempering and martempering), case hardening, and tempering. It describes two general types of salt bath systems for steel hardening: the first type uses atmosphere austenitizing followed by salt quench and the second type employs austenitizing salt baths with rapid transfer to the quench salt. The article provides a detailed account on the construction, advantages and disadvantages, and limitations of isothermal quenching furnaces, submerged-electrode furnaces, immersed-electrode furnaces, and externally heated furnaces. It discusses the important applications of various furnace designs, including the austempering of ductile iron, the hardening of tool steels, and the isothermal annealing of high-alloy steels.

Thermal analysis provides a powerful tool for researchers and engineers in determining both unknown and reproducible behavioral properties of polymer molecules. This article covers the thermal analysis and thermal properties of engineering plastics with respect to chemical composition, chain configuration, conformation of the base polymers, processing of the base polymers with or without additives; and the response to chemical, physical, and mechanical stresses of base polymers as unfilled, shaped articles or as components of composite structures. It also describes thermal analysis techniques, including differential scanning calorimetry, thermogravimetric analysis, thermomechanical analysis, and rheological analysis. This article also summarizes the basic thermal properties used in the application of engineering plastics, such as thermal conductivity, temperature resistance, thermal expansion, specific heat, and the determination of glass transition temperatures. It concludes with a discussion of the thermal and related properties of nine thermostat resin systems divided into three groups by low, medium, and high service temperature capabilities.

This article provides information on the various stages of quenching, sources of distortion, and factors that affect the creation of thermal gradients. It reviews the various determinations of heat-transfer coefficients by the thermal conductivity and diffusivity method, analytical and empirical methods, application of cooling curves, computational fluid dynamics, and the inverse conduction calculation and measurement of parts. Suitable examples are also provided.

This article describes the specific features and mechanisms of oxidation in thermal spray coatings. It discusses the two forms of hot corrosion in sulfur-containing combustion, namely high-temperature hot corrosion and low-temperature hot corrosion. The article reviews the behavior of corrosion-resistant coatings in boilers. The effects of high-temperature corrosion in waste incinerators are detailed. The article also examines the effects of erosion-corrosion in fluidized bed combustion boilers.

This article introduces thermal spray coatings and describes the various types of coating processes and coating devices, including the flame spray, electric-arc spray, plasma spray, transferred plasma arc, high-velocity oxyfuel, and detonation gun. It provides information on the surface preparation methods and finishing treatments of coated parts. The article also explains the tests to evaluate the coating quality and the effects of coating structures and mechanical properties on coated parts. It concludes with a discussion on the uses of thermal spray coatings.

This article provides a general technical description of thermal spray coatings used for corrosion protection in atmospheric and aqueous environments. It further discusses two basic coating approaches of corrosion protection, namely, the sacrificial coating of thermal spray aluminum (TSA) and thermal spray zinc (TSZ), and the barrier-type coating of corrosion-resistant materials. The emphasis is on sacrificial coatings. The article describes the steps involved in the application of TSA and TSZ: surface preparation, coating deposition, and postspray treatment. It discusses their field exposure tests and application history. The article also contains helpful information on the dense barrier coatings by high-velocity spraying processes along with their corrosion performance.

Additives for plastics and elastomers are used to increase the ease of processing and to improve the properties of the final product. Additives improve processing characteristics by increasing lubricity and by stabilizing the polymer. Additives that improve properties include those that decrease static charge development and microbial activity and those that improve flame retardation characteristics, color, light stability, impact resistance, density and mechanical properties. This article focuses on the additives for polymers and elastomers that are used for improving processing--blowing agents, mold-release agents, lubricants, plasticizers, and heat stabilizers--and for improving properties antimicrobials, antioxidants, antistatic agents, colorants, fillers and fiber reinforcements, flame retardants, impact modifiers, light stabilizers, plasticizers, and heat stabilizers. Furthermore, it discusses the method for addition of these additives and the problems faced during compounding.

This article introduces the different types, distinctions, and grades of commercially pure titanium and titanium alloys. It describes three types of alloying elements: alpha stabilizers, beta stabilizers, and neutral additions. The article discusses the basic categories of titanium alloys, namely, alpha and near-alpha titanium alloys, beta and near-beta titanium alloys, and alpha-beta titanium alloys. It also describes the general microstructural features of titanium alloys.

One impressive example of plane front solidification (PFS) is the industrial production of large silicon single crystals, used mainly as substrates for integrated circuits. This article explores the PFS of a single phase, without taking convection into account. It discusses the solute build-up at the solid-liquid interface forming transients and steady state, the morphological stability/instability and perturbation theory, and rapid solidification effects, including solute trapping and oscillatory instabilities. The article presents a microstructural selection map that gives an overview of interface stability as a function of composition for a given alloy.

This article describes testing and characterization methods of ceramics for chemical analysis, phase analysis, microstructural analysis, macroscopic property characterization, strength and proof testing, thermophysical property testing, and nondestructive evaluation techniques. Chemical analysis is carried out by X-ray fluorescence spectrometry, atomic absorption spectrophotometry, and plasma-emission spectrophotometry. Phase analysis is done by X-ray diffraction, spectroscopic methods, thermal analysis, and quantitative analysis. Techniques used for microstructural analysis include reflected light microscopy using polarized light, scanning electron microscopy, transmission electron microscopy, energy dispersive analysis of X-rays, and wavelength dispersive analysis of X-rays. Macroscopic property characterization involves measurement of porosity, density, and surface area. The article describes testing methods such as room and high-temperature strength test methods, proof testing, fracture toughness measurement, and hardness and wear testing. It also explains methods for determining thermal expansion, thermal conductivity, heat capacity, and emissivity of ceramics and glass and measurement of these properties as a function of temperature.

The presence of macroscopic residual stresses in heat treatable aluminum alloys can give rise to machining distortion, dimensional instability, and increased susceptibility to in-service fatigue and stress-corrosion cracking. This article details the residual-stress magnitudes and distributions introduced into aluminum alloys by thermal operations associated with heat treatment. The available technologies by which residual stresses in aluminum alloys can be relieved are also described. The article shows why thermal stress relief is not a feasible stress-reduction technology for precipitation-hardened alloys. It examines the consequences of aging treatments on the residual stress, namely, annealing, precipitation heat treatment, and cryogenic treatment. The article provides information on uphill quenching, which attempts to reverse thermal gradients encountered during quenching. It examines how quench-induced residual stresses in heat treatable aluminum alloys are reduced when sufficient load is applied to cause plastic deformation. The article also shows how plastic deformation reduces residual stress.

Polymers offer a wide range of choices for medical applications because of their versatility in properties and processing. This article provides an overview of polymeric materials and the characteristics that make them a unique class of materials. It describes the ways to classify polymers, including the polymerization method, how the material deforms, or molecular origin or stability. The article contains tables that list common medical polymers used in medical devices. It describes the medical polymer selection criteria and regulatory aspects of materials selection failure analysis and prevention. Failure analysis and prevention processes to determine the root cause of failures that arise at different stages of the product life cycle are reviewed. The article describes the mechanisms of plastic product failure analysis. It discusses the trends in the use of medical polymers, such as high-performance polymers for implants, tissue engineering, and bioresorbable polymers.

Electrical resistance alloys used to control or regulate electrical properties are called resistance alloys, and those used to generate heat are referred to as heating alloys. This article covers both alloy types, describing the construction and use of resistors as well as heating elements. It also discusses soldering and joining methods, sensitivity and stability factors, and various design coefficients. In addition, it provides a detailed account of the properties and applications of thermostat metals and discusses the design of resistance heaters and their operating ranges.

Annealing is an essential treatment in the fabrication of metal parts and semiproducts. This article discusses the processes involved in annealing, namely, recovery, recrystallization, and grain coarsening. It lists the heat treatment conditions of processed aluminum alloys. It provides information on the types of heat treatment, which include preheating, full anneal, stabilization, and stoving. The article describes the steps involved for achieving the age-hardening effect and the strongest hardening effect in aluminum. The steps to increase the strength of aluminum alloys by extremely fine, dispersed second-phase particles are: solution heat treatment, quenching, and age hardening. Finally, the article also discusses the process parameters of annealing, including the effect of strain, effect of temperature, effect of heating rate, and the effect of alloy elements, and the effect of annealing on anisotropy.

Premanent magnet refers to solid materials that have sufficiently high resistance to demagnetizing fields and sufficiently high magnetic flux output to provide useful and stable magnetic fields. Permanent magnet materials include a variety of alloys, intermetallics, and ceramics. This article discusses the composition, properties, and applications of permanent magnetic materials, such as hysteresis alloys used in motors. It primarily focuses on the stability of magnetic fields that influences reversible and irreversible losses in magnetization with time, and the choice of magnet material, component shape and magnetic circuit arrangement.

This article provides information on nickel alloying elements, and the heat treatment processes of various nickel alloys for applications requiring corrosion resistance and/or high-temperature strength. These processes are homogenization, annealing, solution annealing, solution treating, stabilization treatment, age hardening, stress relieving, and stress equalizing. Discussion of furnaces, fixtures, and atmospheres is included. Nickel alloys used for the heat treatment processes include corrosion-resistant nickel alloys, heat-resistant nickel alloys, nickel-beryllium alloys, special-purpose alloys such as nitinol shape memory alloys, low-expansion alloys, electrical-resistance alloys and soft magnetic alloys. Finally, the article focuses on heat treatment modeling for selecting the appropriate heat treatment process.

This article begins with an overview of classes and applications of gray iron. It discusses the castability of gray iron in terms of section sensitivity and fluidity. The article provides information on the dimensions of prevailing sections recommended for gray irons and reviews the properties and specifications of test bar. It discusses the properties of gray iron, such as fatigue limit, pressure tightness, impact resistance, machinability, and dimensional stability, at both room and elevated temperature. Wear behavior of gray iron castings during sliding contact under conditions of normal lubrication is also discussed. The article reviews the use of alloys and heat treatment to modify as-cast properties. It concludes with information on physical properties of gray iron castings.

Thermodynamic descriptions have become available for a large number of alloy systems and allow the calculation of the phase diagrams of multicomponent alloys. This article begins with a discussion on three laws of thermodynamics: the Law of Conservation of Energy, the Second Law of Thermodynamics, and the Third Law of Thermodynamics. It informs that for transformations that occur at a constant temperature and pressure, the relative stability of the system is determined by its Gibbs free energy. The article describes the Gibbs free energy of a single-component unary system and the Gibbs free energy of a binary solution. It schematically illustrates the structure of a binary solid solution with interatomic bonds and shows how the equilibrium state of an alloy can be obtained from the free-energy curves at a given temperature. The article concludes with information on the construction of eutectic and binary phase diagrams from Gibbs free-energy curves.