Neutron activation analysis (NAA) is a highly sensitive and accurate method of assaying bulk materials for trace levels of many elements. This article provides a detailed account on several types of NAA, namely, nondestructive and radiochemical thermal neutron activation, delayed neutron counting, epithermal and 14-MeV fast neutron activation, and prompt gamma activation analysis. It also includes application examples, explaining where and how each method is used and the types of elements on which they are effective.

This article provides a detailed account of the concepts and applications of neutron activation analysis (NAA), covering the basic principles and neutron reactions of NAA as well as calibration methods used for NAA. The discussion also covers the factors pertinent to analytical sensitivity achievable with NAA, common neutron sources, sample-handling technique, and automated systems of NAA. The categories of NAA covered are instrumental neutron activation analysis, epithermal neutron activation analysis, radiochemical neutron activation analysis, 14 MeV fast neutron activation analysis, delayed neutron activation analysis, and prompt gamma activation analysis.

This article provides a brief introduction to neutron diffraction as well as its state-of-the-art capabilities. The discussion covers the general principles of the neutron, neutron-scattering theory, generation of neutrons, types of incident radiation, and purposes of single-crystal neutron diffraction, powder diffraction, and pair distribution function analysis. The relationship between detector space and reciprocal space are presented. Various factors involved in sample preparation, calibration, and techniques used for analyzing diffraction data are described. The article also presents application examples and possible future developments in neutron diffraction.

Neutrons are a principal tool for the study of lattice vibrational spectra in materials. This article provides a detailed account of fission and spallation methods of neutron production that are capable of producing sufficient intensity to be useful in neutron scattering research. It describes the instrumentation required for, and advancements made in, neutron powder diffraction. The article further explains the texture and residual stress (macrostresses and microstresses) problems that are analyzed using the neutron powder diffraction method. It also outlines the single-crystal neutron diffraction technique, and provides examples of the applications of neutron diffraction.

This article briefly discusses popular techniques for metals characterization. It begins with a description of the most common techniques for determining chemical composition of metals, namely X-ray fluorescence, optical emission spectroscopy, inductively coupled plasma optical emission spectroscopy, high-temperature combustion, and inert gas fusion. This is followed by a section on techniques for determining the atomic structure of crystals, namely X-ray diffraction, neutron diffraction, and electron diffraction. Types of electron microscopies most commonly used for microstructural analysis of metals, such as scanning electron microscopy, electron probe microanalysis, and transmission electron microscopy, are then reviewed. The article contains tables listing analytical methods used for characterization of metals and alloys and surface analysis techniques. It ends by discussing the objective of metallography.

Radionuclide methods for wear measurement are used to measure wear continuously throughout a tribological experiment at a resolution of nanometers or micrograms per hour. This article presents an overview of radionuclide methods for wear measurement. It discusses complementary wear measurement methods to introduce the advantages of using radioactive isotopes (RI) for wear or corrosion measurements in comparison to other methods. The article provides information on radiation safety regulations and approaches to minimize external radiation exposure. It describes neutron activation, thin layer or surface layer activation, and ultrathin layer or recoil activation that are used to create radioactive isotopes in the samples to be tested. The article reviews the two common types of wear measurement setup configurations: the direct method and the indirect method. It concludes with a discussion on the practical application of wear measurement using radioactive isotopes.

This article introduces various analytical techniques commonly used in the characterization of organic solids and liquids and discusses the challenges in performing the analysis, with examples. Some general advice in approaching a material analysis is also provided.

This article is a compilation of terms and definitions related to materials characterization.

This article is a compilation of definitions of terms related to materials characterization techniques.

The characterization, testing, and nondestructive evaluation of ceramics and glasses are vital to manufacturing control, property improvement, failure prevention, and quality assurance. This article provides a broad overview of characterization methods and their relationship to property control, both in the production and use of ceramics and glasses. Important aspects covered include the means for characterizing ceramics and glasses, the corresponding rationale behind them, and relationship of chemistry, phases, and microconstituents to engineering properties. The article also describes the effects that the structure of raw ceramic materials and green products and processing parameters have on the ultimate structure and properties of the processed piece. The effects that trace chemistry and processing parameters have on glass properties are discussed. The article describes mechanical tests and failure analysis techniques used for ceramics.

The diffraction pattern of any material contains structural and chemical property information that can be extracted using radial distribution function analysis. This article provides an introduction to the technique and presents several examples highlighting various ways in which it can be used. It begins with a discussion on the principles of diffraction and scattering and the effectiveness of x-ray, neutron, and electron energy sources for different types of measurements. It provides information on data collection and reduction and explains how to create atomic distribution plots from intensity and scattering angle data. The article also presents application parameters for defining short distances and background intensity and describes a procedure for generating pair distribution functions.

This article examines a type of corrosion that occurs when solids (primarily metals) are exposed to liquid metal environments. It describes the principle mechanisms of liquid metal corrosion, including dissolution, impurity and interstitial reactions, alloying, and compound reduction. It also provides guidelines for materials selection and alloy development based on liquid metal corrosion reactions.

This article introduces the fundamental sources of residual stresses common to most manufacturing processes. It explains the effect of material removal on residual stresses and distortions in a part. The article assists the reader in making a choice between trial-and-error and computer-simulation approaches for the control of residual stresses. It provides a summary of the commonly used techniques of measuring residual stresses. The article also describes the finite element method for predicting residual stresses caused by various manufacturing processes. It concludes with a discussion on the operations involved in thermal and mechanical stress-relief methods.

Adhesive-bonded joints are extensively used in aircraft components and assemblies where structural integrity is critical. This article addresses the problem of how to inspect bonded assemblies so that all discrepancies are identified. It describes several inspection techniques and presents drawbacks and limitations of these techniques. Generic flaw types and flaw-producing mechanisms are listed in a table. The article discusses metal-to-metal defects, adherend defects, honeycomb sandwich defects, repair defects, and in-service defects. It reviews the methods applicable to the inspection of bonded structures, including visual inspection, ultrasonic inspection, X-ray radiography, and neutron radiography. The evaluation and correlation of inspection results are also discussed. The article concludes with information on the effects of ultrasonic wave interference in the ultrasonic inspection of adhesive-bonded joints.

This article describes testing and characterization methods of ceramics for chemical analysis, phase analysis, microstructural analysis, macroscopic property characterization, strength and proof testing, thermophysical property testing, and nondestructive evaluation techniques. Chemical analysis is carried out by X-ray fluorescence spectrometry, atomic absorption spectrophotometry, and plasma-emission spectrophotometry. Phase analysis is done by X-ray diffraction, spectroscopic methods, thermal analysis, and quantitative analysis. Techniques used for microstructural analysis include reflected light microscopy using polarized light, scanning electron microscopy, transmission electron microscopy, energy dispersive analysis of X-rays, and wavelength dispersive analysis of X-rays. Macroscopic property characterization involves measurement of porosity, density, and surface area. The article describes testing methods such as room and high-temperature strength test methods, proof testing, fracture toughness measurement, and hardness and wear testing. It also explains methods for determining thermal expansion, thermal conductivity, heat capacity, and emissivity of ceramics and glass and measurement of these properties as a function of temperature.

The purity of aluminum is generally characterized in one of two ways, by terminology or by the Aluminum Association designation system. This article reviews the properties of pure aluminum in purities from 99.99 percent through commercial purity, 99.00 percent. The mechanical properties of aluminum are discussed in terms of tensile properties, stress-strain relationships, and creep. The article also reviews the physical properties of aluminum, such as atomic structure and nuclear properties, atomic spectrum, crystal structure, density, thermal expansion, and thermal conductivity. It discusses the chemical properties of aluminum and presents a summary tabulation of the mechanical strength, ductility, and hardness of pure aluminum.

Several qualitative, semiquantitative, and quantitative tests are available to estimate and control metal cleanliness, particularly inclusion concentration of aluminum alloys. This article provides a description of a few of the metal cleanliness assessment techniques, such as chemical analysis, pressure filter tests, electric resistivity tests, reduced-pressure test, and ultrasonic technique. Detection methods based on the certain principles and the types of impurities in chemical analysis are discussed.