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Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006087
EISBN: 978-1-62708-175-7
...Abstract Abstract This article provides a discussion on the process descriptions, processing conditions, and processing variables of the most common chemical methods for metal powder production. These methods include oxide reduction, precipitation from solution, and thermal decomposition...
Abstract
This article provides a discussion on the process descriptions, processing conditions, and processing variables of the most common chemical methods for metal powder production. These methods include oxide reduction, precipitation from solution, and thermal decomposition. Methods such as precipitation from salt solution and gas, chemical embrittlement, hydride decomposition, and thermite reactions are also discussed. The article also discusses the methods used to produce powders electrolytically and the types of metal powders produced. The physical and chemical characteristics of these powders are also reviewed.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003185
EISBN: 978-1-62708-199-3
..., electrochemical, atomizing, oxide reduction, and thermal decomposition processes. It also covers the consolidation of powders by pressing and sintering, as well as by high density methods. Further emphasis is provided on the distinguishing features of powders, their manufacturing processes, compacting processes...
Abstract
This article focuses on the significant fundamental powder characteristics, which include particle size, particle size distribution, particle shape, and powder purity, followed by an overview of general and individual powder production processes such as mechanical, chemical, electrochemical, atomizing, oxide reduction, and thermal decomposition processes. It also covers the consolidation of powders by pressing and sintering, as well as by high density methods. Further emphasis is provided on the distinguishing features of powders, their manufacturing processes, compacting processes, and consolidated part properties. In addition, a glossary of powder metallurgy terms is included.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003112
EISBN: 978-1-62708-199-3
... Hoeganaes process, Pyron process, atomization of liquid metal, thermal decomposition and the electrodeposition process for carbonyl and electrolytic iron powders. It describes the types of compaction and sintering, explaining their effects of processing with designations. Further, the article deals...
Abstract
Iron powders are the most widely used powder metallurgy (P/M) material for structural parts. This article reviews low to medium density iron and low-alloy steel parts produced by the pressing and sintering technology. It explains different powder production methods, including Hoeganaes process, Pyron process, atomization of liquid metal, thermal decomposition and the electrodeposition process for carbonyl and electrolytic iron powders. It describes the types of compaction and sintering, explaining their effects of processing with designations. Further, the article deals with the mechanical and physical properties of ferrous P/M materials, which may depend on certain factors, namely microstructure, porosity, density, infiltration, re-pressing, chemical composition, and heat treatment.
Book Chapter
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006673
EISBN: 978-1-62708-213-6
... of temperature or time in a controlled atmosphere. The weight of the evaluated material can decrease due to volatilization or decomposition or increase because of gas absorption or chemical reaction. Thermogravimetric analysis can provide valuable information regarding the composition and thermal stability...
Abstract
Thermogravimetric analysis (TGA) is a thermal analysis technique that measures the amount and rate of change in the weight of a material as a function of temperature or time in a controlled atmosphere. This article provides a detailed account of the concepts of TGA, covering the various criteria to be considered for specimen preparation and calibration of TGAs. The use of thermogravimetric analysis data in the assessment of failure analysis of plastics and the combined usage of TGA with other techniques to understand the changes in the sample are also covered. The article provides examples of applications and provides information on the interpretation of TGA.
Series: ASM Handbook
Volume: 4D
Publisher: ASM International
Published: 01 October 2014
DOI: 10.31399/asm.hb.v04d.a0005959
EISBN: 978-1-62708-168-9
... by a discussion on physical metallurgy, including crystallographic identity, thermal stability and decomposition, nitrogen and carbon solubility in expanded austenite, and diffusion kinetics of interstitials. It provides a description of low-temperature nitriding and nitrocarburizing processes for primarily...
Abstract
Low-temperature surface hardening is mostly applied to austenitic stainless steels when a combination of excellent corrosion performance and wear performance is required. This article provides a brief history of low-temperature surface hardening of stainless steel, followed by a discussion on physical metallurgy, including crystallographic identity, thermal stability and decomposition, nitrogen and carbon solubility in expanded austenite, and diffusion kinetics of interstitials. It provides a description of low-temperature nitriding and nitrocarburizing processes for primarily austenitic and, to a lesser extent, other types of stainless steels along with practical examples and industrial applications of these steels.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003006
EISBN: 978-1-62708-200-6
... in polymers. Bond strength has a dramatic influence upon important properties, such as thermal decomposition. As can be seen from Table 6 , it is dependent on both the elements and type of bonds involved. Bond energies for common bonds in polymers Table 6 Bond energies for common bonds in polymers...
Abstract
This article outlines the fundamentals of polymer science and emphasizes the aspects that are necessary and useful to applications of engineering plastics. The basic structure of polymers influences the properties of both polymers and the plastics made from them. An understanding of this basic structure permits the engineers to understand which polymers may be acceptable for a certain application, and which may not. There are various possible classification schemes for polymers. Typical classification categories include polymerization process, chemical elements that make up the monomer, or crystalline versus noncrystalline structure. The article describes the various aspects of chemical structure that are important to an understanding of polymer properties and, thus, affect eventual end uses. It discusses different types of names assigned to polymers. The article details the aspects of polymer structure and examines the properties of polymers and the way they are altered by structure.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006331
EISBN: 978-1-62708-179-5
... their mechanism of formation by introducing the scalar relation, known as the additive strain decomposition. The main factors influencing casting deformation are volume changes during solidification and cooling, phase transformations, alloy composition, thermal gradients, casting geometry, and mold stability...
Abstract
In cast iron, residual stresses normally arise due to hindered thermal contraction, meaning that they are associated with the presence of constraints that prevent the natural, free volumetric variation of the material upon solid-state cooling. This article explains their mechanism of formation by introducing the scalar relation, known as the additive strain decomposition. The main factors influencing casting deformation are volume changes during solidification and cooling, phase transformations, alloy composition, thermal gradients, casting geometry, and mold stability. The article reviews the dimensional stability in cast iron and discusses macroscopic and microscopic stresses in cast iron.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003218
EISBN: 978-1-62708-199-3
... necessary to produce the coating on the substrate. The numerous chemical reactions used in CVD include thermal decomposition (pyrolysis), reduction, hydrolysis, disproportionation, oxidation, carburization, and nitridation. These reactions take place singly or in combination and are controlled...
Abstract
Chemical vapor deposition (CVD) involves the formation of a coating by the reaction of the coating substance with the substrate. Serving as an introduction to CVD, the article provides information on metals, ceramics, and diamond films formed by the CVD process. It further discusses the characteristics of different pack cementation processes, including aluminizing, siliconizing, chromizing, boronizing, and multicomponent coating.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003013
EISBN: 978-1-62708-200-6
... (TPA). Thermal decomposition (also known as thermolysis or pyrolysis): The scrap or waste plastic is heated to high temperature in the absence of oxygen or in an oxygen-deficient atmosphere. No burning takes place. An example is the complete decomposition of mixed-plastic packaging waste to syngas...
Abstract
This article discusses postconsumer plastics recyclate quantities, the classification of plastics recycling into primary, secondary, tertiary, and quaternary categories, and how the life cycle of plastics is affected by recycling. The recycling processes of polyethylene terephthalate (PET), which accounts for the largest percentage of plastic recycling, high-density polyethylene (HDPE) plastics, the other large-volume plastic recyclate, as well as vinyl resins and polycarbonate resins are described. The life cycle of plastics has four phases: poly formation, part fabrication, product service, and disposal. Landfilling is still the primary method of final disposal, and incineration is another option, but recycling has become a viable alternative. The article presents a comparison between secondary and tertiary recycling.
Book Chapter
Series: ASM Handbook
Volume: 4B
Publisher: ASM International
Published: 30 September 2014
DOI: 10.31399/asm.hb.v04b.a0005983
EISBN: 978-1-62708-166-5
... are methane (CH 4 ), ethane (C 2 H 6 ), propane (C 3 H 8 ), and butane (C 4 H 10 ). These gases impart a carburizing tendency to a furnace atmosphere. The chemical activity in reacting with the surface of hot steel depends on their thermal decomposition and their tendency to form nascent carbon at the steel...
Abstract
This article describes the effects of furnace atmospheric elements on steels. These elements are air, water vapor, molecular nitrogen, carbon dioxide, and carbon monoxide. The article provides useful information on six groups of commercially important prepared atmospheres classified by the American Gas Association on the basis of method of preparation or on the original constituents employed. These groups are designated and defined as follows: Class 100, exothermic base; Class 200, prepared nitrogen base; Class 300, endothermic base; Class 400, charcoal base; Class 500, exothermic-endothermic base; and Class 600, ammonia base. These are subclassified and numerically designated to indicate variations in the method by which they are prepared. The article also contains a table that lists significant furnace atmospheres and their typical applications.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006661
EISBN: 978-1-62708-213-6
..., and tribology ( Ref 33 ). A few studies where TPD was used to elucidate surface reactions that impact the tribological performances of materials are discussed here. MoS<sub>2</sub> on Molybdenum Pierce et al. ( Ref 34 ) used TPD to investigate the thermal decomposition of a molybdenum disulfide (MoS 2...
Abstract
This article focuses on the principles and applications of thermal desorption spectroscopy (TDS) use to study adsorption, desorption, and reaction of adsorbed atoms and molecules on surfaces. The discussion provides information on various components of and specimen preparation processes for a TDS experiment. The factors that must be considered when performing TPD experiments and several methods of analyzing TPD data are covered. A few studies where TPD was used to elucidate surface reactions that impact the tribological performances of materials are also discussed.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001283
EISBN: 978-1-62708-170-2
... in the same integrated equipment in a sequential fashion without breaking the vacuum (thus minimizing contamination), and the distinction between the two basic processes becomes blurred ( Ref 3 ). CVD Reactions The numerous chemical reactions used in CVD include thermal decomposition (pyrolysis...
Abstract
This article presents the principles of chemical vapor deposition (CVD) with illustrations. It discusses the types of CVD processes, namely, thermal CVD, plasma CVD, laser CVD, closed-reactor CVD, chemical vapor infiltration, and metal-organic CVD. The article reviews the CVD reactions of materials related to hard, tribological, and high-temperature coatings and to free-standing structures. It concludes by reviewing the advantages, disadvantages, and applications of CVD.
Series: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005574
EISBN: 978-1-62708-174-0
... the diffusion bonding literature. Resulting models show the importance of the size and distribution of the residual oxide particles, as well as the role of the thermal cycle. Finally, the third underlying mechanism of forge welding processes is the decomposition of the interfacial structure. Following...
Abstract
This article discusses three distinct mechanisms of bonding for solid-state (forge) welding processes, namely, contaminant displacement/interatomic bonding, dissociation of retained oxides, and decomposition of the interfacial structure. It explains the processes that can be characterized as having two stages: heating and forging. The article also includes a table that illustrates weld strengths as a function of annealing temperature for a range of materials.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003367
EISBN: 978-1-62708-195-5
... and Ising ( Ref 7 ) in early postcured Kevlar (DuPont) laminates. The amount of carbamate formed is also dependent on the catalyst used in the formulation; zinc catalysts promoted the carbamate formation more than copper or cobalt. During thermal decomposition of the carbamate into carbon dioxide and amine...
Abstract
Cyanate ester resins are a family of high-temperature thermosetting resins that bridge the gap in thermal performance between engineering epoxy and high-temperature polyimides. This article discusses the chemistry, properties and characteristics of the cyanate ester resins. It describes the processing procedures for the cyanate ester resins and provides information on properties for selected applications, such as space applications, radomes, and printed circuit boards.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006102
EISBN: 978-1-62708-175-7
.... Fig. 4 Particle images of commercial electrolytic iron powders (a) A and (b) B. Top row: SEM images; bottom row: cross section optical microscope images Carbonyl iron powder is produced by thermal decomposition of iron pentacarbonyl [Fe(CO) 5 ] which is formed at >130 atm from a reaction...
Series: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005587
EISBN: 978-1-62708-174-0
... is defined by two constants, such as Young's modulus and Poisson's ratio. Most FEM analyses of welds have used an additive decomposition of the total strain rate into elastic, thermal, plastic, and transformation plasticity strain rates: (Eq 21) ∈ ˙ Tot = ∈ ˙ Elas...
Abstract
This article is a comprehensive collection of formulas and numerical solutions, addressing many heat-transfer scenarios encountered in welds. It provides detailed explanations and dimensioned drawings in order to discuss the geometry of weld models, transfer of energy and heat in welds, microstructure evaluation, thermal stress analysis, and fluid flow in the weld pool.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006031
EISBN: 978-1-62708-172-6
..., mechanical malfunction or human error may lead to thermal decomposition at elevated temperatures, with evolution of toxic hydrogen fluoride. The thermal decomposition temperature of PVDF is over 375 °C (705 °F) ( Ref 20 ), well above its normal bake temperature of ∼200 to 250 °C (390 to 480 °F...
Abstract
Polyvinylidene fluoride (PVDF)-based coatings are typically used in outdoor applications that require exceptionally high performance and excellent long-term exterior durability with little maintenance. This article provides a background of three fluoropolymers most commonly used for coatings, namely, PVDF, polyvinyl fluoride, and polytetrafluoroethylene. It focuses on general properties, polymerization, resin types, coating formulation, technology of organic coatings, coating properties, and health and related safety considerations of PVDF. The article describes the application and typical end uses of PVDF-based coatings and the opportunities for improvement in PVDF-based coatings as with all organic coatings.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003023
EISBN: 978-1-62708-200-6
...Abstract Abstract Thermal analysis provides a powerful tool for researchers and engineers in determining both unknown and reproducible behavioral properties of polymer molecules. This article covers the thermal analysis and thermal properties of engineering plastics with respect to chemical...
Abstract
Thermal analysis provides a powerful tool for researchers and engineers in determining both unknown and reproducible behavioral properties of polymer molecules. This article covers the thermal analysis and thermal properties of engineering plastics with respect to chemical composition, chain configuration, conformation of the base polymers, processing of the base polymers with or without additives; and the response to chemical, physical, and mechanical stresses of base polymers as unfilled, shaped articles or as components of composite structures. It also describes thermal analysis techniques, including differential scanning calorimetry, thermogravimetric analysis, thermomechanical analysis, and rheological analysis. This article also summarizes the basic thermal properties used in the application of engineering plastics, such as thermal conductivity, temperature resistance, thermal expansion, specific heat, and the determination of glass transition temperatures. It concludes with a discussion of the thermal and related properties of nine thermostat resin systems divided into three groups by low, medium, and high service temperature capabilities.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006849
EISBN: 978-1-62708-395-9
... temperatures, T m , of a material, as well as the onset of thermal decomposition of blowing agents or other materials. Figure 25 is a representative DSC thermogram. Typical DSC examples are given in Fig. 26 and 27 . Fig. 25 Differential scanning calorimetry thermogram Fig. 26 Melting...
Abstract
This article addresses some established protocols for characterizing thermoplastics and whether they are homogeneous resins, alloyed, or blended compositions or highly modified thermoplastic composites. It begins with a discussion on characterizing mechanical, rheological, and thermal properties of polymer. This is followed by a section describing molecular weight determination using viscosity measurements. Next, the article discusses the use of cone and plate and parallel plate geometries in melt rheology. It then reviews the processes involved in the analysis of thermoplastic resins by chromatography. Finally, the article covers three operations of thermoanalysis, namely differential scanning calorimetry, thermogravimetric analysis, and thermomechanical testing.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006300
EISBN: 978-1-62708-179-5
...Abstract Abstract This article discusses the stable and metastable three-phase fields in the binary Fe-C phase diagram. It schematically illustrates that austenite decomposition requires accounting for nucleation and growth of ferrite and then nucleation and growth of pearlite in the remaining...
Abstract
This article discusses the stable and metastable three-phase fields in the binary Fe-C phase diagram. It schematically illustrates that austenite decomposition requires accounting for nucleation and growth of ferrite and then nucleation and growth of pearlite in the remaining untransformed volume. The article describes the austenite decomposition to ferrite and pearlite in spheroidal graphite irons and lamellar graphite irons. It provides a discussion on modeling austenite decomposition to ferrite and pearlite.