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Published: 01 November 1995
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003013
EISBN: 978-1-62708-200-6
... Abstract This article discusses postconsumer plastics recyclate quantities, the classification of plastics recycling into primary, secondary, tertiary, and quaternary categories, and how the life cycle of plastics is affected by recycling. The recycling processes of polyethylene terephthalate...
Abstract
This article discusses postconsumer plastics recyclate quantities, the classification of plastics recycling into primary, secondary, tertiary, and quaternary categories, and how the life cycle of plastics is affected by recycling. The recycling processes of polyethylene terephthalate (PET), which accounts for the largest percentage of plastic recycling, high-density polyethylene (HDPE) plastics, the other large-volume plastic recyclate, as well as vinyl resins and polycarbonate resins are described. The life cycle of plastics has four phases: poly formation, part fabrication, product service, and disposal. Landfilling is still the primary method of final disposal, and incineration is another option, but recycling has become a viable alternative. The article presents a comparison between secondary and tertiary recycling.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003471
EISBN: 978-1-62708-195-5
... R.J. , Properties of Carbon Fibers Reclaimed from Composite Manufacturing Scrap by Tertiary Recycling , 28th International SAMPE Technical Conf. , Nov 1996 , p 139 – 150 24. Kennerley J.R. , Fenwick N.J. , Pickering S.J. , and Rudd C.D. , The Properties of Glass...
Abstract
This article begins with a discussion on the driving forces for recycling composites. It reviews the recycling process of thermoset-matrix composites and thermoplastic-matrix composites. The recycling of thermoset-matrix composites includes regrind, chemical, energy recovery, and thermal processes. Thermoplastic-matrix composites are recycled by regrinding, compounding/blending and reprocessing. The article concludes with discussion on the properties of recycled composite fibers.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003415
EISBN: 978-1-62708-195-5
..., and adhesion priming or friction welding for tertiary assembly operations with other parts and components. This type of composite component manufacture is based on either thermoplastic or thermosetting matrix materials reinforced, in the overwhelming majority of instances, by glass fibers. Emerging new...
Abstract
Compression molding is the single largest primary manufacturing process used for automotive composite applications. This article provides an overview of the compression molding process. It describes the basic design, materials, and processing equipment of three main groups of composite materials, namely, glass-fiber-mat-reinforced thermoplastics, long-fiber-reinforced thermoplastics, and sheet molding compounds. The article also presents information on the application examples and market volume of compression molding.
Series: ASM Handbook
Volume: 8
Publisher: ASM International
Published: 01 January 2000
DOI: 10.31399/asm.hb.v08.a0003289
EISBN: 978-1-62708-176-4
... because the increase of residual alloying elements from scrap recycling, higher nitrogen content, and improved alignment and temperature control in modern testers tend to raise indicated creep and rupture properties. At a test temperature of 593 °C (1100 °F) and at a stress of 207 MPa (30 ksi...
Abstract
This article discusses the methods for assessing creep-rupture properties, particularly, nonclassical creep behavior. The determination of creep-rupture behavior under the conditions of intended service requires extrapolation and/or interpolation of raw data. The article describes the various techniques employed for data handling of most materials and applications of engineering interest. These techniques include graphical methods, methods using time-temperature parameters, and methods used for estimations when data are sparse or hard to obtain. The article reviews the estimation of required creep-rupture properties based on insufficient data. Methods for evaluation of remaining creep-rupture life, including parametric modeling, isostress testing, accelerated creep testing, evaluation by the Monkman-Grant coordinates, and the Materials Properties Council (MPC) Omega method, are also reviewed.
Series: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006862
EISBN: 978-1-62708-392-8
... the different critical material aspects of additively manufactured medical devices, beginning with the preprinting phase (material consistency and recycling), the printing phase (build orientation), and the postprinting phase (part evaluation, biocompatibility, and sterilization) with supporting materials...
Abstract
The article presents an in-depth discussion on the various additive manufacturing techniques such as binder jetting, directed-energy deposition, material extrusion, material jetting, powder-bed fusion, sheet lamination, and vat polymerization processes. This article then discusses the different critical material aspects of additively manufactured medical devices, beginning with the preprinting phase (material consistency and recycling), the printing phase (build orientation), and the postprinting phase (part evaluation, biocompatibility, and sterilization) with supporting materials.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003362
EISBN: 978-1-62708-195-5
... with primary, secondary and tertiary amines are illustrated in Fig. 6 . Primary and secondary amines proceed as addition reactions where one nitrogen-hydrogen group reacts with one epoxy group. Reaction with tertiary amines results from the unshared electron pair on the nitrogen. Since there are no secondary...
Abstract
This article discusses the three basic elements of an epoxy resin formulation that must be understood when selecting a thermoset system. These include base resins, epoxy resin curatives, and modifiers. The article provides examples of epoxy resin formulations that illustrate how raw materials are combined to tailor a formulation to a specific application. It concludes with a discussion on general guidelines for the safe handling of epoxy resins and their associated products.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006007
EISBN: 978-1-62708-172-6
... anhydrides, organic acids, and phenolics. Basic curing agents include materials such as aromatic amines, aliphatic amines, amides, and dihydrazides. Catalytic hardeners cause the homopolymerization of the epoxy resin and include such materials as Lewis acids and tertiary amines. Each curing system...
Abstract
Functional fusion-bonded epoxy (FBE) coatings are used as external pipe coatings, base layer for three-layer pipe-coating systems, internal pipe linings, and corrosion coatings for concrete reinforcing steel (rebar). This article provides information on the chemistries of FBE, and discusses the application procedures for internal and external FBE pipe coating. The procedures involve pipe inspection, surface preparation, heating, powder application, curing, cooling, coating inspection, and repairing. It describes the problems and solutions for FBE external pipe coatings, girth weld FBE application, FBE custom coatings, internal FBE pipe linings, and FBE rebar coatings.
Book: Fractography
Series: ASM Handbook
Volume: 12
Publisher: ASM International
Published: 01 June 2024
DOI: 10.31399/asm.hb.v12.a0006947
EISBN: 978-1-62708-387-4
...) as this secondary crack coalesces with the primary crack. Original magnification: 1000×. Creep Rupture Creep is the response of a material to a continuously applied load; it is often described as occurring in three phases (primary, secondary, and tertiary), with failure occurring during the tertiary phase...
Abstract
This article provides an overview of polymer fractography, with examples of various fracture surfaces created under diverse loading conditions. The focus is on the interpretation of polymer fracture-surface features in light of the unique viscoelastic nature of polymers. The article presents fractographic examples of three time-dependent cracking mechanisms: fatigue fracture, creep rupture, and environmental stress cracking. It details characteristic fractographic features that can be observed in optical microscopy (OM) and scanning electron microscopy (SEM).
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003169
EISBN: 978-1-62708-199-3
...—as an alloy, intermetallic, or surface-modified product—its usefulness depends on the continued usefulness of the entire system, which is generally cut short at some point, often by corrosion. In the present industrial environment, valuable metals cannot be discarded. Regeneration or recycling of metals back...
Abstract
Ores, which consist of the primary valuable mineral, predominant gangue content, valuable by-products, and detrimental impurities, are extracted and directed to mineral processing. This article describes the mineral processing facilities, such as crushers, grinders, concentrators, separators, and flotation devices that are used for particle size reduction, separation of particles according to their settling rates in fluids and dewatering of concentrate particles. It explains the basic principles, flow diagrams, ore concentrate preparation methods, and equipment of major types of metallurgical processes, including pyrometallurgical, hydrometallurgical, and electrometallurgical processes.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005295
EISBN: 978-1-62708-187-0
... extended over gray iron molds. These irons have not been as successfully used in stool applications but have had limited success in specialty applications. Ingot molds are recycled for use, and the cycle time between uses is a critical factor in the casting process. The cycle time must be appropriate...
Abstract
When a heat of steel is melted and refined, it is necessary to solidify it into useful forms for further processing or final use. Ingot casting remains the preferred method for certain specialty, tool, forging, and remelted steels. This article discusses the methods, equipment, and theory for pouring, solidifying, and stripping steel ingots. It describes two basic types of pouring methods, top pouring and bottom pouring, and provides information on equipment such as hot tops, ingot molds, and stools. The design of the ingot is dictated by the application and type of steel involved. The article concludes with information on the applications of solidification simulation.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001278
EISBN: 978-1-62708-170-2
... not received much attention is vapor permeation curing, which offers the advantage of much lower baking temperatures, even as low as room temperature. Its disadvantage is the requirement of vaporous tertiary amine catalyst, which may be difficult to control in a production situation. Nevertheless, this coating...
Abstract
This article describes elastomeric coatings that are suitable for painting flexible plastic substrates. It focuses on coatings systems that find utility in automotive exterior applications, where the requirements of appearance and durability are most severe. The article discusses acrylic polyols, condensation polymers, vapor curing systems, water-based coatings, and coatings for thermoplastic olefins.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006059
EISBN: 978-1-62708-172-6
... treatment. These are essentially aerobic processes that cause the formation of high microorganism concentrations or biomasses via the recycling of biological solids. The microorganisms grown and suspended in the wastewater convert biodegradable, organic wastewater constituents into different cell masses...
Abstract
This article provides information on the municipal wastewater system components such as piping, pump stations, headworks, clarifiers, aeration structures, digesters, biosolids dewatering equipment, and sludge stabilization. It explains the major corrosion damage mechanisms to which those component parts of the system are exposed. It presents useful guidelines for selecting and using protective coatings in municipal sewerage collection systems and water reclamation facilities in wastewater treatment plants. The article includes annotated flow diagrams of a wastewater collection system, wastewater treatment plants, and spreadsheets listing the most widely used generic coating systems by structure and substrate material. It concludes with a section on quality watchouts when selecting or using protective coatings in municipal wastewater systems.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003699
EISBN: 978-1-62708-182-5
... been abandoned because of the high cost of corrosion. Inhibitors also allowed the injection and production of high volumes of corrosive water resulting from the secondary-recovery concept of waterflooding. Tertiary recovery floods, such as CO 2 , steam, polymer, and in situ combustion floods, would...
Abstract
The inhibitors currently in use are generally complex mixtures of reaction products and have been formulated to meet the demands of a very competitive industry. This article discusses these demands on inhibitor formulation. The varying characteristics and number of organic inhibitors are explained by the varying characteristics of oil wells and gas wells. Water injection systems and pipelines are also discussed. The article describes the factors that influence the corrosivity of produced fluids and the various treatments applicable for oil, gas, and pumping wells. It examines the primary causes of corrosion inhibition in waterfloods: oxygen contamination and acid gases dissolved in the brine. A discussion on the bacteria-induced corrosion is provided. The article also explains various tests available for field corrosion monitoring. It details the methods used to monitor corrosion rates and inhibitor effectiveness. The article concludes information on the computerization of inhibitor treating programs.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003356
EISBN: 978-1-62708-195-5
... resistance soy resin composites biodegradable composites ADVANCES in genetic engineering, natural fiber development, and composite science offer significant opportunities for new, improved materials from renewable resources, which can be biodegradable and/or recyclable with enhanced support for global...
Abstract
This article describes the synthesis, manufacturing, and properties of both the neat soy-based resins and the glass, flax, and hemp composites. A tabulation of the fatty-acid distribution in various plant oils is provided. The article discusses synthetic pathways for triglyceride-based monomers and provides a discussion on acrylated epoxidized soybean oils (AESO), maleinized soyoil monoglyceride (SOMG/MA), and maleinized hydroxylated oil (HO/MA). The polymer properties of the AESO, SOMG/MA, and HO/MA are also discussed. The article explains the ballistic impact resistance of soy resin composites and concludes with a discussion on biodegradable composites.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005242
EISBN: 978-1-62708-187-0
... is primarily made up of recycled, reclaimed, and reused sand. New or reclaimed sand additions are of critical importance. Their most important function is to reduce the concentration of contaminants in the system sand, such as dead clay, excessive fines, ash, oolitic material, metallics, or contamination from...
Abstract
This article reviews the basic types of mold aggregates and bonding methods for expendable molds and coremaking. It provides an overview of mold media and the basic types of sands and their properties. The most significant clays used in green sand operations, such as bentonites, are discussed. The article describes the methods of sand bonding with inorganic compounds. It provides a description of resin-bonded sand systems: no-bake binder systems, heat-cured binder systems, and cold box binder systems. The article concludes with a discussion on the media used for expendable molds, namely, ceramic shells and rammed graphite, for casting reactive metals such as titanium or zirconium.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006058
EISBN: 978-1-62708-175-7
... due to adiabatic gas cooling activates secondary and tertiary (nonbasal) cleavage systems. Powder particle morphology is improved compared with the flake shape, resulting in a blocky shape ( Fig. 5 ). Substantially less correlation between crystallographic basal planes and flat particles reduces...
Abstract
This article briefly describes the production of beryllium powder and beryllium/beryllium oxide metal-matrix powder. It discusses fully dense consolidation methods: vacuum hot pressing, hot isostatic pressing, and cold isostatic pressing. Secondary fabrication operations of beryllium and aluminum-beryllium alloys such as extrusion, rolling, welding, joining, and machining are discussed. The article discusses quality control and provides information on the structural, optical, and high-purity grades of beryllium.
Book Chapter
Series: ASM Handbook
Volume: 24A
Publisher: ASM International
Published: 30 June 2023
DOI: 10.31399/asm.hb.v24A.a0006983
EISBN: 978-1-62708-439-0
...., stress relief, hot isostatic pressing, solution, aging), support removal, build plate removal, machining, inspections, cleaning, polishing, and joining operations. The purpose of the secondary or tertiary manufacturing steps is often to refine a material or mechanical property (e.g., anisotropy, porosity...
Abstract
This article presents the use of additive manufacturing (AM) in the space industry. It discusses metal AM processes and summarizes metal AM materials, including their relevant process categories and references. It also presents the design for AM for spacecraft. The article also provides an overview of in-space manufacturing and on-orbit servicing, assembly, and manufacturing. It presents some of the specific areas that must be understood for the qualification of AM. The article also discusses future trends, challenges, and opportunities for aerospace.
Book Chapter
Series: ASM Handbook
Volume: 20
Publisher: ASM International
Published: 01 January 1997
DOI: 10.31399/asm.hb.v20.a0005751
EISBN: 978-1-62708-194-8
... between alternatives. dary cre.ep; and that occurring at an accelerat- application having to translate or transfer the A sketch of the part and preliminary decisions ing rate, tertiary creep. data. Associativity also requires that applica- on material selection and manufacturing meth- tions can recognize...
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004190
EISBN: 978-1-62708-184-9
..., recovery boilers, and causticizers to eventually produce white liquor that is recycled back to the digester. See the sections “Corrosion Control in Chemical Recovery” and “Corrosion in Recovery Boilers” for details. A by-product of the kraft black liquor process is tall oil, which is refined and used...
Abstract
This article discusses the methods of pulp production, pulp processing, pulp bleaching, and paper manufacturing. It describes various types of digesters, their construction materials, the corrosion problems encountered, and methods to protect these digesters from corrosion. The article examines the corrosion problems in high-yield mechanical pulping, sulfite process, neutral sulfite semichemical pulping, chemical recovery, tall oil plants, wastewater treatment, and recovery boilers. It explains the stages of chlorine-based and nonchlorine bleaching, process water reuse for elemental chlorine-free and nonchlorine bleaching stages, selection of material for bleaching equipment, developments in oxygen bleaching, and the use of highly corrosion-resistant materials for bleach plant equipment. The article reviews the materials used in the construction of paper machine components and specific corrosion problems that affect them. It discusses the composition and corrosive nature of white water. The article also addresses the corrosion and chemical recovery associated with kraft pulping liquors.
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