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James R. Ciulik, John A. Shields, Jr., Prabhat Kumar, Todd Leonhardt, John L. Johnson
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John A. Shields, Jr., Kurt D. Moser, R. William Buckman, Jr., Todd Leonhardt, C. Craig Wojcik
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Published: 30 September 2015
Fig. 6 Particle shape of tantalum powder produced by sodium reduction of potassium tantalum fluoride. Courtesy of Prabhat Kumar
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Image
Published: 30 September 2015
Fig. 7 Particle shape of tantalum powder produced by electron beam melting, hydriding, crushing, and degassing. Courtesy of Prabhat Kumar
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Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006121
EISBN: 978-1-62708-175-7
.... The effects of processing conditions on the physical and chemical properties of tungsten, molybdenum, tantalum, niobium, and rhenium powders are reviewed. chemical properties molybdenum powders niobium powders physical properties powder production refractory metal powders rhenium powders tantalum...
Abstract
Refractory metals are extracted from ore concentrates or scrap, processed into intermediate chemicals, and then reduced to metal, usually in powder form. This article discusses the raw materials needed and the processing steps for producing pure and alloyed refractory metal powders. The effects of processing conditions on the physical and chemical properties of tungsten, molybdenum, tantalum, niobium, and rhenium powders are reviewed.
Image
Published: 30 September 2015
Fig. 4 Capacitance of sodium-reduced and electron beam melted, degassed-hydride tantalum powder. Thirty min anode sintering temperature at anode green densities commonly used for each powder
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Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006124
EISBN: 978-1-62708-175-7
... Abstract This article discusses the pressing and sintering of various refractory metal powders for the production of intermediate products as well as special cases of finished products. The metal powders considered include tungsten, molybdenum, tantalum, niobium and their alloys, as well...
Abstract
This article discusses the pressing and sintering of various refractory metal powders for the production of intermediate products as well as special cases of finished products. The metal powders considered include tungsten, molybdenum, tantalum, niobium and their alloys, as well as rhenium.
Book Chapter
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006123
EISBN: 978-1-62708-175-7
... Abstract This article focuses on the selection, properties, and applications of powder metallurgy refractory metals and their alloys, including tungsten, molybdenum, tantalum, niobium, and rhenium. molybdenum niobium powder metallurgy refractory metals rhenium tantalum tungsten...
Abstract
This article focuses on the selection, properties, and applications of powder metallurgy refractory metals and their alloys, including tungsten, molybdenum, tantalum, niobium, and rhenium.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001079
EISBN: 978-1-62708-162-7
... for tantalum is as powder and anodes for electronic capacitors, representing about 50% of total consumption. Mill products—sheet and plate, rod and bar, and tubing—constitute nearly 25% of tantalum consumption. The major end use for tungsten is in cemented carbides, which are used for cutting tools and wear...
Abstract
All refractory metals, except osmium and iridium, have the highest melting temperatures and lowest vapor pressures of all metals. This article discusses the commercial applications, and production procedures of refractory metals and alloys. These procedures include fabrication, machining, forming, cleaning, joining, and coatings. The article also presents information on, and specifications for, the following metals and their alloys: niobium, tantalum, molybdenum, tungsten, rhenium, and refractory metal fiber-reinforced composites. It discusses the processes involved in their production, their mechanical properties, physical properties, thermal properties, electrical properties, chemical properties, applications, and corrosion resistance.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001426
EISBN: 978-1-62708-173-3
..., including tantalum, niobium, rhenium, molybdenum, and tungsten. Refractory metal alloys are discussed in the order of decreasing weldability: tantalum, niobium, rhenium, molybdenum, and tungsten. microstructure molybdenum niobium refractory metals rhenium tantalum tungsten weldability welding...
Abstract
This article discusses special metallurgical considerations during the fusion welding of refractory metal alloys. These considerations are: microstructure, interstitial impurities, and welding conditions that are considered during the fusion welding of refractory metal alloys, including tantalum, niobium, rhenium, molybdenum, and tungsten. Refractory metal alloys are discussed in the order of decreasing weldability: tantalum, niobium, rhenium, molybdenum, and tungsten.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003777
EISBN: 978-1-62708-177-1
... , Volume 2 of ASM Handbook . Powder production and powder metallurgy of refractory metals are described in Powder Metal Technologies and Applications , Volume 7 of ASM Handbook . This article focuses on the refractory metals of niobium, tantalum, molybdenum, tungsten, and rhenium. Other metals...
Abstract
This article describes various procedures used in the metallographic preparation of niobium, tantalum, molybdenum, and tungsten alloys. It provides information on sectioning, grinding, mounting, polishing, and electrolytic etching as well as alternate procedures that have been used on refractory metals. The article presents and analyzes several micrographs, provides etchant formulas for various materials, and discusses the unique characteristics of rhenium and its alloys.
Book Chapter
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003825
EISBN: 978-1-62708-183-2
... tantalum, and Ta-10W has superior high-temperature strength (service up to 2480 °C, or 4500 °F). Tantalum is processed as a powder that can be sintered or remelted using an electron beam or vacuum arc. Ta-40Nb (UNS R05240) provides higher tensile and yield strength than pure tantalum, while retaining much...
Abstract
Tantalum is one of the most versatile corrosion-resistant metals known. The outstanding corrosion resistance and inertness of tantalum are attributed to a very thin, impervious, protective oxide film that forms on exposure of the metal to slightly anodic or oxidizing conditions. This article provides a discussion on the mechanism of corrosion resistance and on the behavior of tantalum in different corrosive environments, namely, acids; salts; organic compounds; reagents, foods, and pharmaceuticals; body fluids and tissues; and gases. It contains several tables that summarize the effects of acids, salts, and miscellaneous corrosive reagents on tantalum and applications for tantalum equipment in chemical, pharmaceutical, and other industries. Finally, the article presents a discussion on hydrogen embrittlement, the galvanic effects, and cathodic protection of tantalum and describes the corrosion resistance of different types of tantalum-base alloys.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006133
EISBN: 978-1-62708-175-7
... niobium quality control refractory metal powders rhenium secondary operations tantalum tungsten tungsten heavy alloys welding REFRACTORY METALS are typically processed from powders into ingots that are subsequently swaged into round bars or rolled into plates. Additional rolling, drawing...
Abstract
Refractory metals are typically processed from powders into ingots that are subsequently swaged into round bars or rolled into plates. Secondary operations are required to fabricate more complex refractory metal components. This article discusses two such secondary operations, namely, machining and joining processes for tungsten, tungsten heavy alloys, molybdenum, tantalum, niobium, and rhenium components. It describes the various types of metal joining processes, including mechanical fastening, brazing, and welding.
Book Chapter
Series: ASM Handbook
Volume: 14A
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v14a.a0003994
EISBN: 978-1-62708-185-6
... Abstract This article focuses on the forging characteristics of different types of refractory metals and alloys, namely, niobium and niobium alloys, molybdenum and molybdenum alloys, tantalum and tantalum alloys, and tungsten and tungsten alloys. forging molybdenum molybdenum alloys...
Abstract
This article focuses on the forging characteristics of different types of refractory metals and alloys, namely, niobium and niobium alloys, molybdenum and molybdenum alloys, tantalum and tantalum alloys, and tungsten and tungsten alloys.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003151
EISBN: 978-1-62708-199-3
... high solid solubility for other refractory and reactive metals. The single largest use for tantalum is as powder and anodes for electronic capacitors, representing about 50% of total consumption. Tantalum is used as an alloying element in superalloys, and tantalum carbide is an important...
Abstract
The refractory metals include niobium, tantalum, molybdenum, tungsten, and rhenium. They are readily degraded by oxidizing environments at moderately low temperatures. Protective coating systems have been developed, mostly for niobium alloys, to permit their use in high-temperature oxidizing aerospace applications. This article discusses the properties, processing, applications, and classes of refractory metals and its alloys, namely molybdenum, tungsten, niobium, tantalum and rhenium. It also provides an outline of the coating processes used to improve their oxidation resistance.
Book: Thermal Spray Technology
Series: ASM Handbook
Volume: 5A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v05a.a0005735
EISBN: 978-1-62708-171-9
... if chromium- or nickel-bearing alloys are placed into the vessel with some form of electrical connection to the tantalum. Under low-pH conditions, tantalum will become sacrificial to those elements; however, a very small addition of platinum, mechanically blended with the tantalum powder during spraying...
Abstract
This article focuses on noble and neutral coatings and the requirements necessary to achieve successful industrial applications. These include corrosion and wear control and repair applications in processing and chemical industries, and valve and downhole drilling applications in the petrochemical industry. The article also discusses substrate chemistry and preparation; coating selection process and microstructure; sealing by chemical, post-heat treatments, and laser processing; and thermal spray process alternatives.
Image
in Metallography and Microstructures of Refractory Metals and Alloys
> Metallography and Microstructures
Published: 01 December 2004
Fig. 18 Differential interference contrast light micrograph of powder metallurgy tantalum (hot isostatically pressed) showing equiaxed grains with substructure and fine porosity. Chemically polished (solution A, Table 2 ), swabbed for ∼90 s, and swab etched (solution B, Table 2 ) for ∼20 s
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Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001456
EISBN: 978-1-62708-173-3
... and molybdenum, as well as all of the recommendations made for niobium, can be considered for use with tantalum. The diffusion-sink titanium powder and a Ti-30V brazing filler alloy (braze temperature of 1760 °C, or 3200 °F) produced a remelt temperature of 2100 °C (3810 °F). A similar approach with a 33Zr...
Abstract
This article provides a discussion on filler metal selection, brazing procedures, and brazing equipment for brazing refractory metals. These include molybdenum, tungsten, niobium, and tantalum, and reactive metals. Commercially pure and alpha titanium alloys, alpha-beta alloys, zirconium alloys, and beryllium alloys are some reactive metals discussed in the article.
Series: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006255
EISBN: 978-1-62708-169-6
... molybdenum alloys niobium niobium alloys refractory metals rhenium tantalum tantalum alloys tungsten tungsten alloys THE REFRACTORY METALS include tungsten, molybdenum, niobium, tantalum, and rhenium. Tungsten, molybdenum, and rhenium are typically processed by pressing and sintering powders...
Abstract
This article briefly discusses the annealing practices for refractory metals such as tungsten, molybdenum, niobium, tantalum, and rhenium and their alloys. It also presents the applications and properties of these metals and their alloys.
Series: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005656
EISBN: 978-1-62708-198-6
..., were the first to describe manufacturing of a porous metal as an implantable material ( Ref 12 ). They discussed the fabrication of a porous femoral stem made from water-atomized cobalt alloys in which porosity was induced via powder metallurgy techniques. They believed this porous material to possess...
Abstract
Porous coatings are used in the field of joint replacement, particularly in cementless total hip/knee arthroplasty. This article reviews the offerings and biomaterial properties in orthopedic surgery for the contemporary class of highly porous metals. It describes the traditional porous metals/coatings having an open-cell structure, high porosity, and a microstructure resembling that of the cancellous bone. The traditional porous metal/coating includes fiber-metal mesh, cobalt-chromium (CoCr) beads, cancellous-structured titanium, and plasma spray. The article discusses other porous metals/coatings that have been developed due to the limitations of traditional porous metals for numerous open-cell-structured metals, such as titanium-base foams and trabecular metals.
Series: ASM Handbook
Volume: 14B
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v14b.a0005167
EISBN: 978-1-62708-186-3
... by suspending powdered copper in acrylic resin. Ordinary oils and greases are commonly used in the forming of niobium and tantalum, because these metals are generally formed at room temperature. Petrolatum is frequently used for severe forming operations. Solid lubricants and suspensions of suitable...
Abstract
This article describes the formability and surface contamination of the refractory metals such as niobium, tantalum, molybdenum, tungsten, and titanium-zirconium-molybdenum alloys. It reviews the factors that affect mechanical properties and formability during rolling and heat treatment. The effect of temperature on the formability of refractory metals is discussed. The article provides a description of the forming methods of sheet and preformed blanks using refractory metals. It also discusses the types of lubricants, including oils, soaps, waxes, silicones, graphite, and molybdenum disulphide, used in the forming of refractory metals.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006052
EISBN: 978-1-62708-175-7
..., tantalum, niobium, zirconium, molybdenum, vanadium, and chromium carbide powders are produced by carbothermal reduction of the respective oxide powders at temperatures in the range of 1300 to 2000 °C (2370 to 3630 °F). Titanium carbide powder can also be produced by direct carburization of metallic powder...
Abstract
This article discusses the methods and procedures used to extract, purify, and synthesize tungsten carbide powder, metal, and other refractory carbide/nitride powders used in hard metal production. Selection of powders, additives, equipment, and processes for making ready-to-press hard metal powders is also discussed. The article also provides information on the emerging technologies for tungsten carbide synthesis and binders in hard metal production, such as cobalt, iron, and nickel.
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