This article focuses on the modes of operation, physical basis, sample requirements, properties characterized, advantages, and limitations of common characterization methods that are used to evaluate the physical morphology and chemical properties of component surfaces for medical devices. The methods include light microscopy, scanning electron microscopy, atomic force microscopy, energy-dispersive x-ray spectroscopy, Auger electron spectroscopy, secondary ion mass spectrometry, x-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and Raman spectroscopy.

The classes of tool materials for machining operations are high-speed tool steels, carbides, cermets, ceramics, polycrystalline cubic boron nitrides, and polycrystalline diamonds. This article discusses the expanding role of surface engineering in increasing the manufacturing productivity of carbide, cermet, and ceramic cutting tool materials used in machining operations. The useful life of cutting tools may be limited by a variety of wear processes, such as crater wear, flank wear or abrasive wear, builtup edge, depth-of-cut notching, and thermal cracks. The article provides information on the applicable methods for surface engineering of cutting tools, namely, chemical vapor deposited (CVD) coatings, physical vapor deposited coatings, plasma-assisted CVD coatings, diamond coatings, and ion implantation.

A catalyst must be designed to have high activity and selectivity. The chemical process being catalyzed should have high productivity within a specified reactor volume with high reaction rates for the desired reactions and low rates for undesired reaction pathways. This article reviews the most general catalyst preparation procedures: impregnation, ion exchange, and precipitation. It explains the various categorizations of carrier materials: active carriers such as alumina, silica-alumina, zeolites, titanium oxide, and carbon in powder or particulate form; inert carriers such as silica, in powder or particulate form; and structural supports such as the monoliths upon which catalyzed carders are deposited. The article also describes catalyst powder processing techniques for tableting, beading, extrusion, spray drying and honeycombing.

This article introduces thermal spray coatings and describes the various types of coating processes and coating devices, including the flame spray, electric-arc spray, plasma spray, transferred plasma arc, high-velocity oxyfuel, and detonation gun. It provides information on the surface preparation methods and finishing treatments of coated parts. The article also explains the tests to evaluate the coating quality and the effects of coating structures and mechanical properties on coated parts. It concludes with a discussion on the uses of thermal spray coatings.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of sulfur concrete and asphalt and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the crystal morphology, noninterconnecting voids, and microvoids of these surfaces.

The term cast iron designates a group of materials that contain more than one constituent in their microstructure due to excess carbon that result in unique characteristics such as the fracture appearance and graphite morphology. This article discusses the classification of cast iron and the various metallurgical aspects, such as composition, alloying element, solidification, and graphite morphologies, of different types of cast iron. It describes the physical properties for various cast irons and the influence of microstructure and chemical composition on each property. The article provides a detailed account on thermal properties, conductive properties, magnetic properties, and acoustic properties of cast iron. It also discusses heat treatment, namely, stress relieving, annealing, normalizing, through hardening, and surface hardening. The article presents a discussion on the welding, machining and grinding, and coating of the types of cast iron.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of low-carbon steels and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the following: the intergranular fracture, bending impact fracture, brittle fracture, tensile-test fracture, transgranular fracture, cleavage fracture, delayed fracture, corrosion fatigue, inclusion morphology, fatigue crack propagation, and in-service fatigue fracture of various automotive components. These components include tie rod adjusting sleeves, automotive bolts, hydraulic jack shafts, crank handle collars, boiler tubes, drive shafts, bicycle pedal axles, lift-truck hydraulic-piston rods, and steel springs.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of wrought aluminum alloys and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the corrosion-fatigue fracture, fatigue striations, tension-overload fracture surface, ductile fracture, cone-shaped fracture surface, intergranular crack propagation, transgranular crack propagation, stress-corrosion cracking, hydrogen damage, and grain-boundary separation of these alloys. Fractographs are also provided for a forged aircraft main-landing gear wheel and actuator beam, an aircraft wing spar, a fractured aircraft propeller blade, shot peened fillet, an aircraft lower-bulkhead cap, and clevis-attachment lugs.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of precipitation-hardening stainless steels and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the cup-and-cone tension-overload fracture, low-cycle and high-cycle fatigue fracture, fracture surface, brittle intergranular fracture, hydrogen embrittlement, and intergranular stress-corrosion cracking of stainless steel components of these steels. The components include high-pressure compressor parts, springs, deflector yokes of aircraft main landing gears, and aircraft engine mount beams.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of pure irons and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the grain-boundary cavitation; slip lines; intergranular fracture; cleavage fracture; notch-impact fracture; oxide inclusions and blowholes; ductile rupture; impact fracture and tensile-test fracture surfaces; fatigue striations; and crack initiation and propagation of pure irons.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of polymers, including polycarbonate, polyethylene, and polyimide, and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the quasi-brittle fatigue crack propagation, brittle and ductile fracture, crack-growth mechanisms, tearing, fibrillation, and fatigue striations of these surfaces.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of cobalt alloys (cast Vitallium and cast ASTM F75 alloys) and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the fatigue fracture, microcrack, and stair-step fracture surface of these alloys.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of maraging steels and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the tensile-test fracture, low-cycle fatigue fracture, fibrous fracture, crack-initiation zone, microvoid coalescence, fatigue-crack surface, hydrogen embrittlement, and fatigue striations of these steels.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of P/M aluminum alloys (aluminum-lithium alloys) and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the fracture surface, and corrosion-fatigue crack initiation and propagation of these alloys.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of titanium alloys and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the fracture surface, fatigue crack growth, intergranular fracture, crack propagation, ductile overload fracture, dimpled rupture, microvoid coalescence, and quasi-cleavage fracture of these alloys.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of AISI/SAE alloy steels (4xxx steels) and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the brittle fracture, ductile fracture, impact fracture, fatigue fracture surface, reversed torsional fatigue fracture, transgranular cleavage fracture, rotating bending fatigue, tension-overload fracture, torsion-overload fracture, slip band crack, crack growth and crack initiation, crack nucleation, microstructure, hydrogen embrittlement, sulfide stress-corrosion failure, stress-corrosion cracking, and hitch post shaft failure of these steels. The components considered in the article include tail-rotor drive-pinion shafts, pinion gears, outboard-motor crankshafts, bull gears, diesel engine bearing cap bolts, splined shafts, aircraft horizontal tail-actuator shafts, bucket elevators, aircraft propellers, helicopter bolts, air flasks, tie rod ball studs, and spiral gears.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of martensitic stainless steels and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the fracture surface, high-cycle fatigue fracture, tensile-shear fracture, intergranular crack, fatigue striations, and microvoid coalescence of conveyor-chain links, hub socket of aircraft propellers, and automotive intake valves of these steels.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of high-carbon steels and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the following: torsional fatigue fracture, hydrogen-embrittlement fracture, fatigue crack propagation, and corrosion fatigue of components made from high-carbon steels. The high-carbon steel components include bull gear, drive shaft, power boiler stoker grate, steel wheel, spring wire, suspension spring, automotive engine valve spring, power spring, cantilever-type spring, railroad rail, and seamless drill pipe.

This article reviews general corrosion of uranium and its alloys under atmospheric and aqueous exposure as well as with gaseous environments. It describes the dependence of uranium and uranium alloy corrosion on microstructure, alloying, solution chemistry, and temperature as well as galvanic interactions between uranium, its alloys, and other metals. The article provides information on the atmospheric corrosion of uranium based on oxidation in dry air or oxygen, water vapor, and oxygen-water vapor mixtures depending upon particular storage conditions. The mechanism and morphology of hydride corrosion of uranium are discussed. The article provides information on environmentally assisted cracking, protective coatings, and surface modification of uranium and its alloys. It also summarizes the environmental, safety, and health considerations for their use.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of pearlitic malleable and ferritic malleable white irons, and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the fracture sequence, localized plastic deformation, and microcrack initiation and propagation of these irons.