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Image
Published: 01 June 2016
Fig. 17 Schematics of thermal shape memory effect and superelasticity. Thermal shape memory (left) occurs when austenite is cooled to form twinned martensite. Then an applied stress rearranges the twins to produce a new shape, and subsequent heating reverts the martensite to austenite, thus
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Image
Published: 01 June 2012
Fig. 6 Schematics of shape memory effect and superelasticity. Thermal shape memory (left) occurs when austenite is cooled to form twinned martensite. Then an applied stress rearranges the twins to produce a new shape, and subsequent heating reverts the martensite to austenite, thus reproducing
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Image
Published: 01 June 2012
Fig. 12 Superelastic alloy extended beyond the point at which it is able to completely recover. The springback strain is partitioned into elastic recovery of recovery of the transformational strain as martensite reverts to austenite, and the elasticity of austenite.
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Published: 01 June 2012
Fig. 14 The superelastic window is shown to be strongly dependent on deformation strain, using data obtained from the same Ti-50.8Ni alloy as described in Fig. 13 .
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Published: 01 June 2012
Fig. 25 The nickel release rate is compared for two superelastic wire devices, one with a passivated surface and the other oxidized. Both tests are static immersion tests performed in phosphate-buffered saline solution at 37 °C (99 °F). The nickel concentration was measured using inductively
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Image
Published: 01 June 2024
Fig. 1 Representative stress-strain curve of a superelastic Nitinol tube specimen. The test was conducted at 37 °C (100 °F) according to ASTM F2516 using a video extensometer to track the true strain on the specimen. The inset shows a closeup of the 6% load-unload portion of the stress-strain
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Series: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005658
EISBN: 978-1-62708-198-6
... Abstract This article focuses on the specific aspects of nitinol that are of interest to medical device designers. It describes the physical metallurgy, physical properties, and tensile properties of the nitinol. The article discusses the factors influencing superelastic shape memory effects...
Abstract
This article focuses on the specific aspects of nitinol that are of interest to medical device designers. It describes the physical metallurgy, physical properties, and tensile properties of the nitinol. The article discusses the factors influencing superelastic shape memory effects, fatigue, and corrosion in medical device design. It reviews the biocompatibility of nitinol based on corrosion behavior. The article explains the general principles, potential pitfalls, and key properties for manufacturing, heat treatment, and processing of nitinol.
Book: Fractography
Series: ASM Handbook
Volume: 12
Publisher: ASM International
Published: 01 June 2024
DOI: 10.31399/asm.hb.v12.a0007028
EISBN: 978-1-62708-387-4
... Abstract This article focuses on the fractography of Nitinol, a shape memory alloy of nickel and titanium, in superelastic biomedical applications, which primarily comprise drawn and/or laser-cut wire and tube components. Overload fracture, hydrogen embrittlement fracture, and fatigue fracture...
Abstract
This article focuses on the fractography of Nitinol, a shape memory alloy of nickel and titanium, in superelastic biomedical applications, which primarily comprise drawn and/or laser-cut wire and tube components. Overload fracture, hydrogen embrittlement fracture, and fatigue fracture are discussed in detail.
Image
Published: 01 June 2012
band at the bottom of the figure indicates the range at which some vestiges of superelasticity may be detected; the black band indicates the ideal superelastic range.
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Series: ASM Handbook
Volume: 14B
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v14b.a0005147
EISBN: 978-1-62708-186-3
... drawing, superplastic forming/diffusion bonding, forging, extrusion, and dieless drawing. It provides information on superelastic forming equipment and tooling. The article explains the thinning characteristics and quick plastic forming and its technological elements. It describes the manufacturing...
Abstract
This article discusses many of the processes and related considerations involved in the forming of superplastic sheet metal parts. It reviews the requirements for superplasticity and describes the characteristics of superplastic metals. The characterization of superplastic behavior includes the characterization of plastic flow, internal cavitation, and fracture behavior. Processing variables needed for the overall characterization of superplastic behavior are summarized. The article discusses the superplastic forming methods, namely, blow forming, vacuum forming, thermoforming, deep drawing, superplastic forming/diffusion bonding, forging, extrusion, and dieless drawing. It provides information on superelastic forming equipment and tooling. The article explains the thinning characteristics and quick plastic forming and its technological elements. It describes the manufacturing practice of the process. The article concludes with a discussion on the superplastic behavior in iron-base alloys.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003160
EISBN: 978-1-62708-199-3
... need to be restrained in the desired memory shape during the heat treatment; otherwise, it may not remain there. Applications Applications for NiTi alloys can be grouped into four broad categories: actuation devices, constrained recovery devices, superelastic devices, and martensitic devices...
Abstract
The term shape memory alloys (SMAs) refers to the group of metallic materials that demonstrate the ability to return to some previously defined shape or size when subjected to the appropriate thermal procedure. Materials that exhibit shape memory only upon heating are referred to as having a one-way shape memory. Some materials also undergo a change in shape upon recooling. These materials have a two-way shape memory. This article discusses the general characteristics of SMAs by using typical transformation versus temperature curve. It describes the processing, applications and properties (mechanical and physical) of commercial SMA alloys, namely nickel-titanium alloys and copper-base alloys.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001100
EISBN: 978-1-62708-162-7
... a valve controls the rate of fluid flow by carefully heating a shape0-memory-alloy component just enough to close the valve the desired amount. Repeatable positioning within 0.25 μm (10 −5 in.) is possible with this technique. Superelastic Applications A number of products have been brought...
Abstract
This article discusses the history of shape memory alloys (SMAs) along with their properties, capabilities, and crystallography, including phase transformations that occur during thermal treatment. It describes the thermomechanical behaviors of SMAs and explains how to characterize them using differential scanning calorimeter (DSC) techniques as well as other methods. The article examines the most common shape memory alloys, namely, nickel-titanium and copper-base SMAs, and provides information on their respective properties.
Series: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005657
EISBN: 978-1-62708-198-6
... to the number of slip systems available in the fcc crystal structure. This fatigue-induced cleavagelike morphology is attributed to the very low stacking-fault energies found in cobalt alloys. Fig. 31 SEM image of fatigue surface morphology in ASTM F75 cobalt-chromium alloy Nitinol Superelastic...
Abstract
This article focuses on the analysis of materials and mechanical- (or biomechanical-) based medical device failures. It reviews the failure analysis practices, including evidence receipt, cleaning, nondestructive examination, destructive examination, exemplars analysis, and device redesign. The article examines the common failure modes, such as overload, fatigue, corrosion, hydrogen embrittlement, and fretting, of medical devices. The failure analysis of orthopedic implants, such as permanent prostheses and internal fixation devices, is described. The article reviews the failure mechanisms in some of the more common medical device materials, namely, stainless steels, titanium alloys, cobalt-base alloys, and nitinol. It presents case histories with examples for failure analysis.
Series: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006261
EISBN: 978-1-62708-169-6
Abstract
This article provides information on nickel alloying elements, and the heat treatment processes of various nickel alloys for applications requiring corrosion resistance and/or high-temperature strength. These processes are homogenization, annealing, solution annealing, solution treating, stabilization treatment, age hardening, stress relieving, and stress equalizing. Discussion of furnaces, fixtures, and atmospheres is included. Nickel alloys used for the heat treatment processes include corrosion-resistant nickel alloys, heat-resistant nickel alloys, nickel-beryllium alloys, special-purpose alloys such as nitinol shape memory alloys, low-expansion alloys, electrical-resistance alloys and soft magnetic alloys. Finally, the article focuses on heat treatment modeling for selecting the appropriate heat treatment process.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006811
EISBN: 978-1-62708-329-4
... be biocompatible, corrosion resistant, and able to endure the expected in vivo loading on the device. This results in relatively few options for materials selection, with most devices being manufactured from stainless steel, titanium, cobalt-chrome, or superelastic nitinol. Nitinol, a near-equiatomic alloy...
Abstract
Bearing in mind the three-legged stool approach of device design/manufacturing, patient factors, and surgical technique, this article aims to inform the failure analyst of the metallurgical and materials engineering aspects of a medical device failure investigation. It focuses on the device "failures" that include fracture, wear, and corrosion. The article first discusses failure modes of long-term orthopedic and cardiovascular implants. The article then focuses on short-term implants, typically bone screws and plates. Lastly, failure modes of surgical tools are discussed. The conclusion of this article presents several case studies illustrating the various failure modes discussed throughout.
Series: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005680
EISBN: 978-1-62708-198-6
...-Bending Fatigue of a Laser-Welded Superelastic NiTi Alloy Wire , Mater. Charact. , Vol 57 , 2006 , p 58 – 63 10.1016/j.matchar.2005.12.009 ...
Abstract
Microjoining methods are commonly used to fabricate medical components and devices. This article describes key challenges involved during microjoining of medical device components. The primary mechanisms used in microjoining for medical device applications include microresistance spot welding (MRSW) and laser welding. The article illustrates the fundamental principles involved in MRSW and laser welding. The article presents examples of various microjoining methods used in medical device applications, including pacemaker and nitinol microscopic forceps.
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006418
EISBN: 978-1-62708-192-4
... and subsequent implosion of bubbles in liquids. Cavitation erosion rates are often influenced by surface topography, yield properties (such as hardness and rate of strain hardening), elastic properties (elastic modulus, resilience, and superelasticity), and toughness. For thermal spray coatings, there is good...
Abstract
Cemented carbides, best known for their superior wear resistance, have a range of industrial uses more diverse than that of any other powder metallurgy product including metalworking and mining tools and wear-resistant components. This article discusses raw materials and manufacturing methods used in the production of cemented carbides, the physical and mechanical properties of carbides, and wear mechanisms encountered in service. Emphasis is placed on tungsten carbide-cobalt (WC-Co) or tungsten carbide-nickel (WC-Ni) materials as used in nonmachining applications. Nominal composition and properties of representative cemented carbide grades and their applications are listed in a table.
Series: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005660
EISBN: 978-1-62708-198-6
... alloy (50/50 by atomic percent weight), more popularly known as Nitinol. A significant feature of Nitinol is its so-called superelasticity. As shown in Fig. 5 , an impressive mechanical property of this alloy is a (recoverable) strain that is approximately 8 to 11% (depending on how slightly nickel...
Abstract
The biocompatibility of a material relates to its immunological response, toxicity profile, and ability to integrate with surrounding tissue without undesirable local or systemic effects on a patient. This article underscores the transformation of the medical device design ecosystem engaged as an integral part of the device ecosystem. It discusses the applications of biomaterials, including orthopedic, cardiovascular, ophthalmic, and dental applications. The article describes four major categories of biomaterials such as metals, polymers, glass and ceramics, and composites. A discussion on natural materials, nanomaterials, and stem cells is also provided. The article concludes with examples of biomaterials applications, such as endovascular devices, knee implants, and neurostimulation.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004207
EISBN: 978-1-62708-184-9
..., and zirconium are alpha stabilizers. Alloying with these elements can improve the strength and fatigue resistance. Another titanium alloy that is seeing increased use is nickel-titanium (NiTi) alloy ( Ref 17 ). This near equiatomic alloy has superelastic and shape memory characteristics and is used...
Abstract
This article tabulates the chemical composition of iron-base, titanium-base, and cobalt-base alloys and illustrates the microstructures of these materials. It discusses the surface morphology and chemistry of oxide-film-covered alloys and provides insights into the interaction. The article illustrates the interfacial structure of a biomaterial surface contacting with the biological environment. It describes the corrosion behavior of stainless steel, cobalt-base alloy, and titanium alloys. The electrochemical methods used for studying metallic biomaterials corrosion are also discussed. The article concludes with information on the biological consequences of in vivo corrosion and biocompatibility.
Series: ASM Handbook
Volume: 22A
Publisher: ASM International
Published: 01 December 2009
DOI: 10.31399/asm.hb.v22a.a0005435
EISBN: 978-1-62708-196-2
Abstract
This article assesses the evolution of martensite modeling in the changing materials engineering environment. It describes the physics of displacive transformations using Ginzburg-Landau theory, microstructure representation, dynamics and simulations, density functional theory, and shuffle transitions. The article reviews the application of the Ginzburg-Landau approach to rigorous solutions for issues in the structure of a martensitic nucleus based on the martensitic nucleation theory. The three basic behavior modes of martensitic growth, such as elastic, elastic/plastic, and fully plastic are discussed. The article also reviews the overall kinetics of martensitic transformations.
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