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Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003821
EISBN: 978-1-62708-183-2
... corrosive media include: hydrochloric acid, sulfuric acid, phosphoric acid, hydrofluoric acid, hydrobromic acid, nitric acid, organic acids, salts, seawater, and alkalis. The modes of high-temperature corrosion include oxidation, carburization, metal dusting, sulfidation, nitridation, corrosion by halogens...
Abstract
This article reviews the corrosion behavior in various environments for seven important nickel alloy families: commercially pure nickel, Ni-Cu, Ni-Mo, Ni-Cr, Ni-Cr-Mo, Ni-Cr-Fe, and Ni-Fe-Cr. It examines the behavior of nickel alloys in corrosive media found in industrial settings. The corrosive media include: hydrochloric acid, sulfuric acid, phosphoric acid, hydrofluoric acid, hydrobromic acid, nitric acid, organic acids, salts, seawater, and alkalis. The modes of high-temperature corrosion include oxidation, carburization, metal dusting, sulfidation, nitridation, corrosion by halogens, and corrosion by molten salts. Applications where the corrosion properties of nickel alloys are important factors in materials selection include the petroleum, chemical, and electrical power industries. Most nickel alloys are much more resistant than the stainless steels to reducing acids, such as hydrochloric, and some are extremely resistant to the chloride-induced phenomena of pitting, crevice attack, and stress-corrosion cracking (to which the stainless steels are susceptible). Nickel alloys are also among the few metallic materials able to cope with hot hydrofluoric acid. The conditions where nickel alloys suffer environmentally assisted cracking are highly specific and therefore avoidable by proper design of the industrial components.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003826
EISBN: 978-1-62708-183-2
... hafnium in specific media, namely, water, steam, hydrochloric acid, nitric acid, sulfuric acid, alkalis, organics, molten metals, and gases. Forms of corrosion, namely, galvanic corrosion, crevice corrosion, and pitting corrosion are included. The article explains the corrosion of hafnium alloys such as...
Abstract
This article describes the processes involved in the production of hafnium and its alloys. It discusses the physical, mechanical and chemical properties of hafnium. The aqueous corrosion testing of hafnium and its alloys is detailed. The article reviews the corrosion resistance of hafnium in specific media, namely, water, steam, hydrochloric acid, nitric acid, sulfuric acid, alkalis, organics, molten metals, and gases. Forms of corrosion, namely, galvanic corrosion, crevice corrosion, and pitting corrosion are included. The article explains the corrosion of hafnium alloys such as hafnium-zirconium alloys and hafnium-tantalum alloys. It also deals with the applications of hafnium and its alloys in the nuclear and chemical industries.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001281
EISBN: 978-1-62708-170-2
... Abstract Anodizing refers to conversion coating of the surface of aluminum and its alloys to porous aluminum oxide. This article provides the reasons for performing anodizing and discusses the three principal types of anodizing processes, namely, chromic acid process, sulfuric acid process, and...
Abstract
Anodizing refers to conversion coating of the surface of aluminum and its alloys to porous aluminum oxide. This article provides the reasons for performing anodizing and discusses the three principal types of anodizing processes, namely, chromic acid process, sulfuric acid process, and hard anodic process. It describes the limitations imposed by variables, such as alloy composition, surface finish, prior processing, temper or heat treatment, and the use of inserts, on the anodizing processes. The article explains the causes and means adopted for correcting several specific problems in anodizing aluminum. It also discusses the process control techniques and equipment used for anodizing. The article reviews the sealing processes for anodic coatings and the method for coloring the coatings. It concludes with a discussion on the effects of anodic coatings on the surface and mechanical properties of aluminum and its alloys.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001227
EISBN: 978-1-62708-170-2
... acid, citric acid, ethylenediamine tetraacetic acid (EDTA), formic acid, gluconic acid, and hydroxyacetic acid. Depending on the application, acids may be used alone, but often are formulated with bases and other additives. Organic acids often replace mineral acids, such as hydrochloric and sulfuric...
Abstract
This article focuses on the mineral and organic acid cleaning of iron and steel. It begins with a discussion on the application methods, process selection criteria, solution composition, equipment used, and control of process variables in mineral acid cleaning. The article then describes the advantages and disadvantages of organic acid cleaning. Applications, including boiler cleaning, stainless steel cleaning, and removal of iron- and copper-bearing deposits, are discussed. The article concludes with an overview of acid cleaning of nonferrous alloys.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001229
EISBN: 978-1-62708-170-2
... Abstract Pickling is the most common of several processes used to remove scale from steel surfaces. This article provides a discussion on pickling solutions, such as sulfuric and hydrochloric acid, and describes the role of inhibitors in acid pickling. It discusses the equipment and processes...
Abstract
Pickling is the most common of several processes used to remove scale from steel surfaces. This article provides a discussion on pickling solutions, such as sulfuric and hydrochloric acid, and describes the role of inhibitors in acid pickling. It discusses the equipment and processes involved in the batch, continuous, and electrolytic pickling of carbon steel components. The article describes the effects of process variables on scale removal in sulfuric and hydrochloric acid. It concludes with a description of pickling defects, spent pickle liquor disposal, and safety practices.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003824
EISBN: 978-1-62708-183-2
... complex fluoride plating baths where it is preferred over tantalum ( Ref 12 ). The performance of niobium-tantalum alloys in boiling 70% sulfuric acid is reported in Ref 13 . The tantalum-rich alloys showed a decrease in corrosion rate with increasing exposure time, as was found for pure tantalum and...
Abstract
For chemical processing, niobium resists a wide variety of corrosive environments. These environments include mineral acids, many organic acids, liquid metals, and most salt solutions. This article focuses on the mechanisms of corrosion resistance of niobium alloys in these environments. The niobium alloys include Nb-1Zr, Nb-55Ti, Nb-50Ta, and Nb-40Ta. The article describes the use of these corrosion resistant niobium alloys. It provides information on applications of niobium in various industries.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001242
EISBN: 978-1-62708-170-2
... Constituent or condition Copper sulfate bath Copper fluoborate bath General Printed circuit through-hole Low copper High copper Bath composition, g/L (oz/gal) Copper sulfate, CuSO 4 · 5H 2 O 200–240 (27–32) 60–110 (8–15) … … Sulfuric acid, H 2 SO 4 45–75 (6–10) 180–260 (24–35...
Abstract
This article provides a detailed account of the various alkaline and acid plating baths used for electrolytic copper plating. Dilute cyanide and Rochelle cyanide baths, high-efficiency sodium and potassium cyanide baths, alkaline noncyanide copper plating baths, and alkaline copper pyrophosphate baths, are discussed. The article reviews acid plating baths such as copper sulfate bath and copper fluoborate bath. It also presents information on the surface preparation considerations, bath composition, and operating variables of copper plating as well as the equipment used.
Book Chapter
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003825
EISBN: 978-1-62708-183-2
... Chemical Condensers, bromide plants … Ethylene dichloride Chlorination Chemical Condensers … Ethylene glycol Reactor, sulfuric acid concentrator Chemical Bayonet heaters, multiple … Ferric chloride Dissolving concentration Chemical Bayonet heaters, single and multiple … Sewage...
Abstract
Tantalum is one of the most versatile corrosion-resistant metals known. The outstanding corrosion resistance and inertness of tantalum are attributed to a very thin, impervious, protective oxide film that forms on exposure of the metal to slightly anodic or oxidizing conditions. This article provides a discussion on the mechanism of corrosion resistance and on the behavior of tantalum in different corrosive environments, namely, acids; salts; organic compounds; reagents, foods, and pharmaceuticals; body fluids and tissues; and gases. It contains several tables that summarize the effects of acids, salts, and miscellaneous corrosive reagents on tantalum and applications for tantalum equipment in chemical, pharmaceutical, and other industries. Finally, the article presents a discussion on hydrogen embrittlement, the galvanic effects, and cathodic protection of tantalum and describes the corrosion resistance of different types of tantalum-base alloys.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006629
EISBN: 978-1-62708-213-6
... thiocyanate/acetone Blue color Cu Dithizone Purple color Fe Potassium ferricyanide Blue precipitate Pb Sulfuric acid White precipitate Mo Potassium thiocyanate/stannous chloride Pink color Ni Dimethylglyoxime Red precipitate In its simplest terms, gravimetry is a...
Abstract
This article focuses on wet chemical methods that have stood the test of time in laboratories around the world. It begins with a description of the appropriateness of classical wet methods. This is followed by sections on sampling procedures, basic chemical equilibria, and wet analytical chemistry. Mechanical methods and nonoxidizing acids and/or acid mixtures for dissolving solid samples for wet chemical analysis are then reviewed. Qualitative methods that are used to identify materials by wet chemical reaction are also included. The article provides information on various methods for the separation of chemical mixtures and on the types of gravimetry and titrimetry. Strategies for removing inclusions are also included to aid in their compositional understanding. The article also briefly describes the processes involved in chemical surface studies and partitioning of oxidation states. It ends by presenting some examples of the applications of classical wet methods.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001305
EISBN: 978-1-62708-170-2
... is transferred to a water bath, and the violent reaction that results on immersion blasts much of the scale from the steel. The surface is essentially free of scale, but quite dull and dirty. To remove the last remnants of oxide, the rack is transferred to a 10 to 15% sulfuric acid (H 2 SO 4...
Abstract
Passivation; pickling, that is, acid descaling; electropolishing; and mechanical cleaning are important surface treatments for the successful performance of stainless steel used for piping, pressure vessels, tanks, and machined parts in a wide variety of applications. This article provides an overview of the various types of stainless steels and describes the commonly used cleaning methods, namely, alkaline cleaning, emulsion cleaning, solvent cleaning, vapor degreasing, ultrasonic cleaning, and acid cleaning. Finishing operations of stainless steels, such as grinding, polishing, and buffing, are reviewed. The article also explains the procedures of electrocleaning, electropolishing, electroplating, painting, surface blackening, coloring, terne coatings, and thermal spraying. It includes useful information on the surface modification of stainless steels, namely, ion implantation and laser surface processing. Surface hardening techniques, namely, nitriding, carburizing, boriding, and flame hardening, performed to improve the resistance of stainless steel alloys are also reviewed.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0004050
EISBN: 978-1-62708-183-2
... additions for oxidation resistance is preferred at this temperature and above for key equipment components such as those used in gas turbines ( Ref 8 ). However, for temperatures between 600 and 750 °C (1110 and 1380 °F), where acid fluxing can occur, chromia-forming coatings are preferred ( Ref 9 ). A...
Abstract
This article describes the specific features and mechanisms of oxidation in thermal spray coatings. It discusses the two forms of hot corrosion in sulfur-containing combustion, namely high-temperature hot corrosion and low-temperature hot corrosion. The article reviews the behavior of corrosion-resistant coatings in boilers. The effects of high-temperature corrosion in waste incinerators are detailed. The article also examines the effects of erosion-corrosion in fluidized bed combustion boilers.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003147
EISBN: 978-1-62708-199-3
..., making the alloy weakly ferromagnetic at room temperature. Nickel-copper alloys are strong and tough, offering corrosion resistance in various environments, including brine and sulfuric and other acids, and showing immunity to chloride-ion stress corrosion. They are used in chemical processing and...
Abstract
Nickel and nickel-base alloys are vitally important to modern industry because of their ability to withstand a wide variety of severe operating conditions involving corrosive environments, high temperatures, high stresses, and combinations of these factors. This article discusses the mining and extraction of nickel and describes the uses of nickel. It discusses the categories of nickel-base alloys, including wrought corrosion-resistant alloys, cast corrosion-resistant alloys, heat-resistant alloys (superalloys), and special-purpose alloys. The article covers the corrosion resistance of nickel with the inclusion of varying alloying elements. It provides useful information on the behavior of nickel and nickel alloys in specific environments describes its corrosion resistance in certain acids, alkalis, and salts.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001313
EISBN: 978-1-62708-170-2
... severe and permanent injury to bone, and even death if burns are not treated properly. Tungsten normally receives no other acid cleaning treatments, but molybdenum is occasionally further acid cleaned in a nitric-sulfuric acid bath. Acid concentrations are normally 750 to 900 g/L (100 to 120 oz/gal...
Abstract
This article addresses surface cleaning, finishing, and coating operations that have proven to be effective for molybdenum, tungsten, tantalum, and niobium. It describes standard procedures for abrasive blasting, molten caustic processing, acid cleaning, pickling, and solvent and electrolytic cleaning as well as mechanical grinding and finishing. The article also provides information on common plating and coating methods, including electroplating, anodizing, and oxidation-resistant coatings.
Book Chapter
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001308
EISBN: 978-1-62708-170-2
... concentrated or dilute acid solutions that contain oxidizing agents. The acids commonly used are sulfuric, nitric, phosphoric, acetic, and, to a lesser extent, chromic and hydrofluoric. Ammonium bifluoride is used when it is desirable to avoid the hazards that attend the use of hydrofluoric acid. Fluoboric and...
Abstract
Aluminum or aluminum alloy products have various types of finishes applied to their surfaces to enhance appearance or improve functional properties. This article discusses the procedures, considerations, and applications of various methods employed in the cleaning, finishing, and coating of aluminum. These include abrasive blast cleaning, barrel finishing, polishing, buffing, satin finishing, chemical cleaning, chemical brightening, electrolytic brightening, chemical etching, alkaline etching, acid etching, chemical conversion coating, electroplating, immersion plating, electroless plating, porcelain enameling, and shot peening.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001243
EISBN: 978-1-62708-170-2
... solutions that can be used for other determinations; this may be the deciding factor as to which procedure to use. The following procedure is simple and quite rapid: Reagents Acid mixture: Mix 1 part sulfuric acid, 1 part phosphoric acid, and 1 part water. Ferrous ammonium sulfate (FAS) 0.1 N...
Abstract
Hard chromium plating is produced by electrodeposition from a solution containing chromic acid and a catalytic anion in proper proportion. This article presents the major uses of hard chromium plating, and focuses on the selection factors, plating solutions, solution and process control, equipment, surface preparation, and crack patterns and other characteristics of hard chromium plating. It offers recommendations for the design and use of plating racks, describes the problems encountered in hard chromium plating, and their corrective procedures. The article provides information on the removal of chromium plate from coated metals, recovery and disposal of wastes, and stopoff media for selective plating.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003137
EISBN: 978-1-62708-199-3
... saline solutions, alkaline solutions, and organic chemicals. However, copper is susceptible to more rapid attack in oxidizing acids, oxidizing heavy-metal salts, sulfur, ammonia (NH 3 ), and some sulfur and NH 3 compounds. Resistance to acid solution depends mainly on the severity of oxidizing...
Abstract
Copper and copper alloys are widely used in many environments and applications because of their excellent corrosion resistance, which is coupled with combinations of other desirable properties. This article lists the identifying characteristics of the forms of corrosion that commonly attack copper metals as well as the most effective means of combating each. General corrosion, galvanic corrosion, pitting, impingement, fretting, intergranular corrosion, dealloying, corrosion fatigue, and stress-corrosion cracking (SCC) are some forms of corrosion. The article also lists a galvanic series of metals and alloys valid for dilute aqueous solutions, such as seawater and weak acids. It provides useful information on the effects of alloy compositions, selection for specific environments, and atmospheric corrosion of selected copper alloys. The article also tabulates the corrosion ratings of wrought copper alloys in various corrosive media.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003213
EISBN: 978-1-62708-199-3
... Electrolytic Phosphoric acid 70 … 70 … … 15–25 … Sodium acid pyrophosphate … 16.5 … 16.5 16.5 … … Sodium bisulfate … 80 … 80 80 … … Sulfuric acid … … … … … … 55–70 Nonionic wetting agent (a) 5 … 5 … … 7–20 … Anionic wetting agent … 3 … 3 3...
Abstract
Metal surfaces must often be cleaned before subsequent operations to remove unwanted substances such as pigmented drawing compounds, unpigmented oil and grease, chips and cutting fluids, polishing and buffing compounds, rust and scale, and miscellaneous contaminants. The article describes common cleaning processes, including alkaline, electrolytic, solvent, emulsion, molten salt bath, ultrasonic and acid cleaning as well as pickling and abrasive blasting. It also explains how to select the appropriate process for a given soil type and surface composition.
Series: ASM Handbook
Volume: 4A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v04a.a0005777
EISBN: 978-1-62708-165-8
... complex-shaped parts with deep recesses and other irregularities Pickling Done in hot, strong solutions of sulfamic, phosphoric, sulfuric, or hydrochloric acid Scale Complete removal of scale from mill products and fabricated parts Electrolytic pickling removes scale twice as...
Abstract
This article provides an overview of surface contaminants that may affect the heat treatment processes and end-product quality. It presents information on the chemicals used to clean different surface contaminants of steels. The article discusses three types of cleaning methods, namely, mechanical, chemical, and electrochemical and their effectiveness and applicability. The mechanical cleaning methods include grinding, brushing, steam or flame jet cleaning, abrasive blasting, and tumbling. Solvent cleaning, emulsion cleaning, alkaline cleaning, acid cleaning, pickling, and descaling are chemical cleaning methods. The electrochemical cleaning methods include electropolishing, electrolytic alkaline cleaning, and electrolytic pickling. The article provides information on cleanliness measurement methods such as qualitative tests and quantitative tests to ensure product quality. Health hazards that may be associated with each cleaning method and the general control measures to be used for each hazard are tabulated.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001221
EISBN: 978-1-62708-170-2
... cleaning steps should be separated with a thorough rinse. Plating is initiated on an active surface. A wide variety of activators is available, and most are acidic in nature. Hydrochloric, sulfuric, or fluoboric acids are commonly used. Water rinse after activation is critical to avoid contaminating...
Abstract
This article describes the basic attributes of the most widely used metal surface cleaning processes to remove pigmented drawing compounds, unpigmented oil and grease, chips, cutting fluids, polishing and buffing compounds, rust and scale from steel parts, and residues and lapping compounds from magnetic particle and fluorescent penetrant inspection. The cleaning processes include emulsion cleaning, electrolytic alkaline cleaning, acid cleaning, solvent cleaning, vapor degreasing, alkaline cleaning, ultrasonic cleaning, and glass bead cleaning. The article provides guidelines for choosing an appropriate process for particular applications and discusses eight well-known methods for determining the degree of cleanliness of the work surface.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001251
EISBN: 978-1-62708-170-2
... hot dipping. Electrodeposited lead has been used for the protection of metals from corrosive liquids such as dilute sulfuric acid; the lining of brine refrigerating tanks, chemical apparatus, and metal gas shells; and barrel plating of nuts and bolts, storage battery parts, and equipment used in the...
Abstract
Lead has been deposited from a variety of electrolytes, including fluoborates, fluosilicates, sulfamates, and methane sulfonic acid baths. This article provides a discussion on these electrolytic baths and includes information on the process sequence, equipment requirements, and applications of lead plating.