This article discusses the methods of pulp production, pulp processing, pulp bleaching, and paper manufacturing. It describes various types of digesters, their construction materials, the corrosion problems encountered, and methods to protect these digesters from corrosion. The article examines the corrosion problems in high-yield mechanical pulping, sulfite process, neutral sulfite semichemical pulping, chemical recovery, tall oil plants, wastewater treatment, and recovery boilers. It explains the stages of chlorine-based and nonchlorine bleaching, process water reuse for elemental chlorine-free and nonchlorine bleaching stages, selection of material for bleaching equipment, developments in oxygen bleaching, and the use of highly corrosion-resistant materials for bleach plant equipment. The article reviews the materials used in the construction of paper machine components and specific corrosion problems that affect them. It discusses the composition and corrosive nature of white water. The article also addresses the corrosion and chemical recovery associated with kraft pulping liquors.

Gold electroplating was invented in 1840. During the first 100 years electrodeposited gold was used primarily for its aesthetic appeal as a decorative finish. This article provides a description of the gold plating process and the electrolytes used. It discusses the decorative and industrial applications of gold plating. The article reviews factors affecting the dragout of gold solution.

This article focuses on the electroless gold plating technique, describing the advantages and limitations, applications, and properties of plated deposits. It also reviews process variables of the technique, including gold concentration, reducing agent, agitation, and contaminants.

Thermal spray coatings, along with certain proprietary sealants, are widely used in the paper manufacturing industry for corrosion and wear resistance and to impart special surface characteristics. This article discusses the steps involved in the paper manufacturing process. Most modern papermaking machines are based on variations of the Fourdrinier machine. The article describes four operational sections of the machine: forming, press, drying, and calendar. It provides an overview of the machine components where thermal spray coatings are used, namely, digesters, blow tanks, suction roll, center press rolls, yankee dryer rolls, calendar rolls, doctor/scalping blades, and cutting equipment.

The inhibitors currently in use are generally complex mixtures of reaction products and have been formulated to meet the demands of a very competitive industry. This article discusses these demands on inhibitor formulation. The varying characteristics and number of organic inhibitors are explained by the varying characteristics of oil wells and gas wells. Water injection systems and pipelines are also discussed. The article describes the factors that influence the corrosivity of produced fluids and the various treatments applicable for oil, gas, and pumping wells. It examines the primary causes of corrosion inhibition in waterfloods: oxygen contamination and acid gases dissolved in the brine. A discussion on the bacteria-induced corrosion is provided. The article also explains various tests available for field corrosion monitoring. It details the methods used to monitor corrosion rates and inhibitor effectiveness. The article concludes information on the computerization of inhibitor treating programs.

The liquid nitriding process has several proprietary modifications and is applied to a wide variety of carbon steels, low-alloy steels, tool steels, stainless steels, and cast irons. This article discusses the applications, subclassifications, operating procedures, and maintenance procedures, as well as the equipment used (salt bath furnaces) and safety precautions to be undertaken during the liquid nitriding process. It describes the different types of liquid nitriding process, namely, liquid pressure nitriding, aerated bath nitriding, and liquid nitrocarburizing. Environmental considerations and the increased cost of detoxification of cyanide-containing effluents have led to the development of low-cyanide salt bath nitrocarburizing treatments. The article reviews the wear and antiscuffing characteristics of the compound zone produced in salt baths with the help of Falex scuff test.

This article focuses on the mechanisms of microbiologically influenced corrosion as a basis for discussion on the diagnosis, management, and prevention of biological corrosion failures in piping, tanks, heat exchangers, and cooling towers. It begins with an overview of the scope of microbial activity and the corrosion process. Then, various mechanisms that influence corrosion in microorganisms are discussed. The focus is on the incremental activities needed to assess the role played by microorganisms, if any, in the overall scenario. The article presents a case study that illustrates opportunities to improve operating processes and procedures related to the management of system integrity. Industry experience with corrosion-resistant alloys of steel, copper, and aluminum is reviewed. The article ends with a discussion on monitoring and preventing microbiologically influenced corrosion failures.

This article discusses the particular corrosion problems encountered and the corrosion control methods used in petroleum production (i.e., upstream) and the storage and transportation of oil and gas (i.e., midstream) up to the refinery (i.e., downstream). These control methods include proper material selection, protective coatings, cathodic protection systems, use of inhibitors, use of nonmetallic materials, and control of the environment. The article reviews the aspects of corrosion that tend to be unique to corrosion as encountered in applications involving oil and gas exploration and production. It discusses corrosion problems that are specific to the various types of environments or equipment used in secondary recovery, including producing wells, producing flow lines, and injection wells. Corrosion mitigation methods and guidelines are also discussed for each type of environment.

Maintenance coating is an important part of any meaningful asset-preservation strategy in facilities producing pulp and paper and other chemicals. This article discusses maintenance coating for carbon steel structures and process equipment exposed to normal external pulp and paper mill atmospheric conditions. The important requirements and standards for surface preparation are emphasized and common issues encountered in maintenance coating projects are described.

This article provides an overview of the identification systems for various grades of wrought stainless steels, namely, the American Iron and Steel Institute numbering system, the Unified Numbering System, and proprietary designations. It elaborates on five major families of stainless steels, as defined by the crystallographic structure. These include ferritic stainless steels, austenitic stainless steels, martensitic stainless steels, and precipitation-hardening stainless steels. The mechanism of corrosion protection for stainless steels is reviewed. The article examines the effects of composition, processing, design, fabrication, and external treatments on the corrosion of stainless steels. Various forms of corrosion, namely, general, galvanic, pitting, crevice, intergranular, stress-corrosion cracking, erosion-corrosion, and oxidation, are reviewed. Corrosion testing for; corrosion in atmosphere, water, and chemical environments; and the applications of stainless steels in various industries are also discussed.

The corrosion processes of metals during burial are affected by environmental pollutants, other archaeological material, geography, microorganisms in the soil, vegetation, land use, soil chemistry, soil physical properties, and the presence or absence of water and air. This article discusses the key environmental variables that affect the corrosion of buried metal artifacts. These include water (including dissolved salts and gases), sulfate-reducing bacteria, pH (acidity), and potential (oxidizing or reducing capacity). The article contains tables that list some corrosion products identified on archaeological tin and pewter, lead, iron alloys, silver alloys, and copper alloys. It also discusses the corrosion problems after excavation and the techniques followed by archaeological department for conserving metal artifacts.

This article provides an overview of the degradation of metals and alloys in aqueous systems. The importance of the hydrogen ion lies in its ability to interact with an alloy surface. The article describes the effects of various conditions of pH on corrosion including strongly acid conditions, near-neutral conditions, and strongly basic conditions as well as the effects of temperature on corrosion. The influence of the fluid flow rate on corrosion depends on the alloy, fluid components, fluid physical properties, geometry in which the fluid is contained, and corrosion mechanism. The article discusses the influence of fluid flow rate through specific examples. It concludes with information on how the concentration of dissolved species works with other variables to influence corrosion behavior.

This article describes the methods for removing metallic contaminants, tarnish, and scale resulting from hot-working or heat-treating operations on nickel-, cobalt-, and iron-base heat-resistant alloys. It provides a brief description of applicable finishing and coating processes, including polishing, electroplating, ceramic coatings, diffusion coatings, and shot-peening. The article presents numerous examples that identify cleaning and finishing problems and the procedures used to solve them.

Controlled-potential coulometry is a highly precise and accurate method primarily used for major constituent analysis of analyte substances such as alloys, compounds, nonmetallic materials and organic compounds. This article illustrates the apparatus required for controlled-potential coulometry, and provides information on its techniques and applications. It contains a table that lists the metals for which accurate methods have been developed and the basic electrochemistry of the procedures. The article explains that gold and uranium are the elements that are determined frequently in various sample types.

The corrosion process that occurs in industrial systems is often difficult to discern until extensive deterioration has occurred. For boilers to function properly, the incoming water must be processed to meet the water quality required for the boiler. This article discusses pretreatment methods of the incoming water and preboiler corrosion protection methods. It analyzes internal treatment and condensate treatment of boilers. The article discusses three types of cooling systems: once-through systems, open recirculating systems, and closed recirculating systems. The corrosion processes which occur in water-recirculating systems and the effect of dissolved gases, temperature, pH, suspended solids, dissolved salts, and scale deposition on corrosivity of water, are also reviewed. The article also considers anodic and cathodic inhibitors and the control of corrosion in municipal water systems.

The electroplating of platinum-group metals (PGMs) from aqueous electrolytes for engineering applications is limited principally to palladium and, to a lesser extent, to platinum, rhodium, and thin layers of ruthenium. This article provides a discussion on the plating operations of these PGMs along with the types of anodes used in the process.

This article discusses the fundamentals of electroplating processes, including pre-electroplating and surface-preparation processes. It illustrates the four layers of a plating system, namely, top or finish coat, undercoat, strike or flash, and base material layers. The article describes various plating methods, such as pulse electroplating, electroless plating, brush plating, and jet plating. It reviews the types of electrodeposited coatings, including hard coatings and soft coatings. The article also details the materials available for electroplating, including electroplated chromium, electroplated nickel, electroless (autocatalytic) nickel, electroless nickel composite coatings, electroplated gold, and platinum group coatings. These are specifically tailored toward plated coatings for friction, lubrication, and wear technology. The article concludes with a discussion on the common issues encountered with electroplating.

Hard chromium plating is produced by electrodeposition from a solution containing chromic acid and a catalytic anion in proper proportion. This article presents the major uses of hard chromium plating, and focuses on the selection factors, plating solutions, solution and process control, equipment, surface preparation, and crack patterns and other characteristics of hard chromium plating. It offers recommendations for the design and use of plating racks, describes the problems encountered in hard chromium plating, and their corrective procedures. The article provides information on the removal of chromium plate from coated metals, recovery and disposal of wastes, and stopoff media for selective plating.

Phosphoric acid is less corrosive than sulfuric and hydrochloric acids. This article discusses the corrosion rates of metal alloys in phosphoric acid, including aluminum, carbon steel and cast irons, stainless steels, nickel-rich G-type alloys, copper and copper alloys, nickel alloys, lead, titanium alloys, and zirconium alloys. Nonmetallic materials may be chemically attacked in some corrosive environments, which can result in swelling, hardening, or softening phenomena; extraction of ingredients; chemical conversion of the nonmetallic constituents; cross-linking oxidation; and/or substitution reactions. The article also describes the corrosion resistance of nonmetallic materials such as rubber and elastomeric materials, plastics, carbon and graphite, and ceramic materials.

True alkaline chemicals include caustic soda or sodium hydroxide (NaOH), caustic potash or potassium hydroxide (KOH), and soda ash or sodium carbonate (Na2CO3). This article reviews alkaline chemicals and provides a basis for a general discussion on various alkaline exposures. It describes the corrosion effects of caustic soda on aluminum and aluminum alloys, iron and steel, carbon and low-alloy steels, stainless steels, high-performance austenitic alloys, nickel and nickel alloys, copper and copper alloys, titanium and titanium alloys, and zirconium and zirconium alloys. The article discusses the corrosion effects of caustic soda on nonmetallic materials: plastics, thermoplastics, thermosetting resin materials, carbon and graphite, and ceramics. It concludes with information on the effects of contamination of and by caustic and of admixtures of caustic with other chemicals, including chlorates, chlorides, chlorine/hypochlorite, mercury, sulfur, and iron.