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Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001289
EISBN: 978-1-62708-170-2
... the properties of ion-plated films. The sources of potential applied on substrate surface, bombarding species, and depositing species are addressed. The article also provides information on the parameters that influence bombardment. It concludes with a discussion on the advantages, limitations, and applications...
Abstract
This article begins with a list of the factors that influence the properties of physical vapor deposited films. It describes the steps involved in ion plating, namely, surface preparation, nucleation, interface formation, and film growth. The article discusses the factors influencing the properties of ion-plated films. The sources of potential applied on substrate surface, bombarding species, and depositing species are addressed. The article also provides information on the parameters that influence bombardment. It concludes with a discussion on the advantages, limitations, and applications of ion plating.
Book Chapter
Corrosion Testing of Coatings
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001296
EISBN: 978-1-62708-170-2
... or in coating-substrate systems, the different electrochemical reactions take place simultaneously, resulting in a mixed or galvanic couple potential. The corrosion behavior of a specific system is determined by the relation of the respective metals in contact. Furthermore, environmental conditions such as pH...
Abstract
This article focuses on the testing and typical corrosion behavior of coating-substrate systems in aqueous solutions and humid aggressive atmospheres. It includes a short review of the fundamentals of corrosion, followed by a discussion of specific system behavior, electrochemical and laboratory accelerated tests, and simulated service tests. The article also contains examples of different types of corrosion damage and presents guidelines for improving corrosion resistance.
Book Chapter
Metallurgy Basics for Aluminum Surface Treatment
Available to PurchaseSeries: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006522
EISBN: 978-1-62708-207-5
... of the substrate in general as well as the local chemical potential from point to point across the substrate surface. Different alloys therefore exhibit different responses and sensitivities to corrosion and chemical processing such as etching, cleaning, even rinsing with water—steps critical to anodizing...
Abstract
This article discusses the properties of aluminum surface and the applications of aluminum alloys. It explains the effects of trace elements on aluminum alloys. The article considers microstructural development of aluminum in terms of the surface and explains how it will impact corrosion resistance and surface treatment. It describes the thermodynamics of equilibrium oxidation processes and non-equilibrium corrosion processes. The article provides a discussion on aluminum oxidation under atmospheric and dynamic conditions. It presents the potential/pH (Pourbaix) diagram for aluminum under atmospheric and dynamic conditions. The article also explains the polarization effects during the formation of stable aluminum oxide under dynamic conditions. It concludes with information on the designation system for aluminum finishes.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003672
EISBN: 978-1-62708-182-5
.... The metal in the galvanic couple with the lower corrosion (electrochemical) potential has its potential pulled in the positive direction by the metal that has the higher corrosion potential. This generally causes the metal or alloy with the lower potential to experience accelerated corrosion. On the other...
Abstract
This article discusses the factors affecting corrosion behavior. It describes galvanic corrosion and its protection methods. The article also provides information on coatings and inhibitors, which are used in corrosion protection.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003681
EISBN: 978-1-62708-182-5
... to megavolt ion accelerating potentials. The second method, laser processing, is high-power laser melting with or without mixing of materials precoated on the substrate, followed by rapid melt quenching. The article also describes the advantages and disadvantages of the surface modification approach...
Abstract
Surface modification is the alteration of the surface composition or structure using energy or particle beams. This article discusses two different surface modification methods. The first, ion implantation, is the introduction of ionized species into the substrate using kilovolt to megavolt ion accelerating potentials. The second method, laser processing, is high-power laser melting with or without mixing of materials precoated on the substrate, followed by rapid melt quenching. The article also describes the advantages and disadvantages of the surface modification approach to promote corrosion resistance.
Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006523
EISBN: 978-1-62708-207-5
..., such as an electrodeposited metal, or an applied layer, such as paint or lacquer. It is also not a chemical conversion coating such as a phosphate or chromate conversion coating. All conversion coatings are equilibrium processes, with only the chemical potential difference between the electrolyte and substrate driving...
Abstract
Anodizing produces a uniform, continuous, highly ordered network of individual cells comprising a layer whose thickness and cell dimensions, and ultimately engineering properties, depend on the electrochemical parameters of the anodizing process. This article discusses the nucleation and growth of anodic aluminum oxide and the important characteristics of the finished porous anodic aluminum oxide. In industry, anodic oxides and the anodizing processes have been categorized into types that exhibit specific properties to suit specific applications. The article reviews the two most basic types of oxides, namely, barrier-layer anodic oxides and porous anodic oxides. It concludes with a description of postanodizing processes, such as dyeing and sealing.
Image
Individual oxide particles or nodes, represented by the hemisphere originat...
Available to PurchasePublished: 30 November 2018
Fig. 3 Individual oxide particles or nodes, represented by the hemisphere originating at point c at the center of the schematic, initially form by way of diffusion and reaction of atmospheric oxygen with the base metal. The nodes grow laterally (x direction), outward from the substrate (y, z
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Book Chapter
Thermal Spray Coatings for Electrical and Electronic Applications
Available to PurchaseBook: Thermal Spray Technology
Series: ASM Handbook
Volume: 5A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v05a.a0005736
EISBN: 978-1-62708-171-9
... Abstract Thermal spray processes involve complete or partial melting of a feedstock material in a high-temperature flame, and propelling and depositing the material as a coating on a substrate. This article describes the properties of sprayed electronic materials, including dielectrics...
Abstract
Thermal spray processes involve complete or partial melting of a feedstock material in a high-temperature flame, and propelling and depositing the material as a coating on a substrate. This article describes the properties of sprayed electronic materials, including dielectrics, conductors, and resistors, and discusses their implications and associated limitations for device applications and potential remedial measures. The article presents specific examples of electrical/electronic device applications, including electromagnetic interference/radio-frequency interference shielding, planar microwave devices, waveguide devices, sensing devices, solid oxide fuel cells, heating elements, electrodes for capacitors and other electrochemical devices.
Book Chapter
Friction Surfacing
Available to PurchaseSeries: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005560
EISBN: 978-1-62708-174-0
... of metallizing ceramics has potential uses in heat sinking applications on temperature-sensitive substrates and as tracks for providing electrical conductivity. Fig. 1 Friction surfacing of an aluminum layer on an alumina substrate. Courtesy of The Welding Institute Friction surfacing can deposit...
Abstract
The friction surfacing process enables deposition of a wide variety of high-specification materials with an ideal metallurgical bond onto a range of metal substrates. This article provides a process description and discusses the equipment used for, and the applications of, friction surfacing.
Book Chapter
Fundamentals of Nitriding and Nitrocarburizing
Available to PurchaseSeries: ASM Handbook
Volume: 4A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v04a.a0005818
EISBN: 978-1-62708-165-8
... = μ N, s where μ N 2 , g and µ N,s represent the chemical potentials of nitrogen in the gas atmosphere and the solid substrate, respectively. Assuming ideal gases or, at least, adopting a constant fugacity coefficient, [1] it follows from Eq 3 : (Eq 4) 1 2 μ...
Abstract
The nitriding process typically involves the introduction of nitrogen into the surface-adjacent zone of a component, usually at a temperature between 500 and 580 deg C. This article provides an overview of the essential aspects of the thermodynamics and kinetics of nitriding and nitrocarburizing of iron-base materials with gaseous processes. It describes nitriding potentials and the Lehrer diagram, carburizing potentials, controlled nitriding and nitrocarburizing, and the microstructural evolution of the compound layer and the diffusion zone.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003687
EISBN: 978-1-62708-182-5
... as possible in potential to the substrate in moist environments, because few coatings are completely free of pores, cracks, and other defects. Even if a coating does start out defect free, scratching, normal wear, or gouging can change this condition. Accordingly, in a corrosive environment, plated components...
Abstract
This article discusses the various factors that affect the corrosion performance of electroplated coatings. It describes the effects of environment and the deposition process on substrate coatings. The article provides a discussion on the electrochemical techniques capable of predicting the corrosion performance of a plated part. It reviews the designs of coating systems for optimal protection of the substrate. The article also discusses controlled weathering tests and accelerated tests used to predict and determine the relative durability of the coating.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001383
EISBN: 978-1-62708-173-3
... that suit bearings and seal-contact areas on shafts, and the cladding of the exposed regions of shafts that are used in pernicious environments. Various substrate geometries that have interesting potential for friction cladding are shown in Fig. 4 . Shell banding may be another application, where...
Abstract
In the friction surfacing process, a rotating consumable is brought into contact with a moving substrate, which results in a deposited layer on the substrate. This article describes the process as well as the equipment used. It also provides information on the applications of the friction surface process.
Image
Electrochemical equilibrium diagrams for copper and tin comparing equilibri...
Available to PurchasePublished: 01 January 2005
Fig. 21 Electrochemical equilibrium diagrams for copper and tin comparing equilibria for pure elemental form to that in various intermetallic compounds. Lines are drawn for the chemical potentials for equilibrium between two phases. The equilibria between ions and insoluble oxides
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Image
Foot pressure measurement using piezoelectric self-powered sensor. (a) Wavy...
Available to Purchase
in Additively Manufactured Biomedical Energy Harvesters
> Additive Manufacturing in Biomedical Applications
Published: 12 September 2022
Fig. 11 Foot pressure measurement using piezoelectric self-powered sensor. (a) Wavy substrate sensor with an active area (4.5 × 3 cm, or 1.8 × 1.2 in.) on matrix-formatted electrode. (b–d) Two-dimensional contour plots of different positions of foot mapping pressure potential. Source: Ref 139
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Series: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005668
EISBN: 978-1-62708-198-6
... to control independently the mechanical and chemical parameters. For example, by imposing a given potential to the rubbing metal, one can simulate the oxidation potential of the environment, and, in addition, under certain conditions, the current flow is a measure of the instantaneous corrosion rate...
Abstract
This article provides an overview of the fundamentals of tribology. It describes the advantages, disadvantages, and applications of the pin-on-disk method, which is the most commonly used configuration for testing biomaterials and for the reproducible measurement of friction and wear. The article illustrates a practical tribocorrosion setup that allows a user to perform wear tests in corrosive environments under well-defined electrochemical conditions and at controlled temperature. It explains the effect of changes in electrical contact resistance on tribological mode. The article discusses various in vivo environmental conditions in tribological tests. Some typical examples of biomaterials testing are also provided.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001326
EISBN: 978-1-62708-170-2
... with candidate cleaner. Perform mechanical property test simulating subsequent operations. Compatibility Expose substrates to candidate cleaners. Observe for deterioration of substrates. Corrosion potential Immersion corrosion, ASTM F 483; sandwich corrosion, ASTM F 1110; hydrogen embrittlement, ASTM F...
Abstract
Wipe solvents are used to remove contaminants from a workpiece before it undergoes manufacturing operations that require clean surfaces, such as bonding, sealing, painting, welding, plating, specialized surface treatment procedures, and others. This article describes the evaluation parameters for wipe solvent cleaners, including methyl ethyl ketone, methyl isobutyl ketone, trichloroethene, tetrachloroethylene, acetone, toluene, dichloromethane, benzene, xylene, and other alternate wipe solvent cleaners. It contains a table that lists the compositions and properties of wipe solvent cleaners.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001288
EISBN: 978-1-62708-170-2
... pressure and substrate temperature Microstructural changes similar to those induced by temperature and pressure can be reproduced to some degree by applying a negative bias potential to the substrate during deposition. Under the influence of this negative potential, positively charged ions impact...
Abstract
Sputtering is a nonthermal vaporization process in which the surface atoms are physically ejected from a surface by momentum transfer from an energetic bombarding species of atomic/molecular size. It uses a glow discharge or an ion beam to generate a flux of ions incident on the target surface. This article provides an overview of the advantages and limitations of sputter deposition. It focuses on the most common sputtering techniques, namely, diode sputtering, radio-frequency sputtering, triode sputtering, magnetron sputtering, and unbalanced magnetron sputtering. The article discusses the fundamentals of plasma formation and the interactions on the target surface. A comparison of reactive and nonreactive sputtering is also provided. The article concludes with a discussion on the several methods of process control and the applications of sputtered films.
Book Chapter
Thermal Spray Coatings for Corrosion Protection in Atmospheric and Aqueous Environments
Available to PurchaseBook: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003832
EISBN: 978-1-62708-183-2
... to alloy 625 can provide significantly better corrosion resistance and, consequently, better protection to a steel substrate than similar high-quality HVOF coatings of stainless steel. All the HVOF-sprayed coatings of stainless steel 316L exhibit a significantly lower rest potential and show a much more...
Abstract
This article provides a general technical description of thermal spray coatings used for corrosion protection in atmospheric and aqueous environments. It further discusses two basic coating approaches of corrosion protection, namely, the sacrificial coating of thermal spray aluminum (TSA) and thermal spray zinc (TSZ), and the barrier-type coating of corrosion-resistant materials. The emphasis is on sacrificial coatings. The article describes the steps involved in the application of TSA and TSZ: surface preparation, coating deposition, and postspray treatment. It discusses their field exposure tests and application history. The article also contains helpful information on the dense barrier coatings by high-velocity spraying processes along with their corrosion performance.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006628
EISBN: 978-1-62708-213-6
... For the calculation of the classical trajectory between projectile and target atoms, the modified universal potential is needed. In the energy region under 10 keV, the screening effect produced by the electron clouds, which partially mask the Coulomb potential, has to be taken into account. There are two...
Abstract
This article is a brief account of low-energy ion-scattering spectroscopy (LEIS) for determining the atomic structure of solid surfaces. It begins with a description of the general principles of LEIS. This is followed by a section providing information on the equipment used for LEIS. Various steps involved in the sample preparation, calibration, and data analysis are then discussed. The article concludes with a section on the applications and interpretation of LEIS in material analysis, including discussion on surface structural analysis, layer-by-layer (Frank-van der Merwe) growth, and low-energy atom-scattering spectroscopy.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001260
EISBN: 978-1-62708-170-2
... to species with widely separated deposition potentials, nor is it necessary to modify well-established bath chemistries. However, plating a multiple layers using two baths requires the substrate cathode to be periodically moved between the baths. If transferring the cathode between baths takes substantial...
Abstract
Multiple-layer alloy electrodeposition involves the formation of an inhomogeneous alloy consisting of lamellae of different composition. This article reviews the process description, engineering parameters, characterization, and applications of multiple-layer alloys. Pulsed-current plating and pulsed-potential plating are also discussed.
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