Submerged arc welding (SAW) is suited for applications involving long, continuous welds. This article describes the operating principle, application, advantages, limitations, power source, equipment, and fluxes in SAW. It reviews three different types of electrodes manufactured for SAW: solid, cored, and strip. The article highlights the factors to be considered for controlling the welding process, including fit-up of work, travel speed, and flux depth. It also evaluates the defects that occur in SAW: lack of fusion, slag entrapment, solidification cracking, and hydrogen cracking. Finally, the article provides information on the safety measures to be followed in this process.

Voltammetry is the study of the current voltage relationships observed when electroactive species in solution are subject to oxidation or reduction at electrodes under carefully controlled conditions. This article describes the basic principle of voltammetry performed using the dropping mercury electrode (polarography). It discusses the various methods of voltammetry, namely, linear sweep voltammetry, cyclic voltammetry, and stripping voltammetry that are carried out with different electrode material. The article also explores the modern instrumentation and developments achieved in voltammetry, and provides an outline of additional data, such as values of the formation, or stability, and constants of complexes formed by shifting the half-wave potential, which can be obtained by voltammetry. Additionally, the article provides a brief account of the applications of voltammetry.

Submerged arc welding (SAW) is an arc welding process in which the arc is concealed by a blanket of granular and fusible flux. This article provides a schematic illustration of a typical setup for automatic SAW and discusses the advantages and limitations and the process applications of SAW. The article discusses flux classification relative to production method, relative to effect on alloy content of weld deposit, and relative to basicity index. It describes the procedural variations and the effect of weld current, weld voltage, electrical stickout, travel speed, and flux layer depth on weld bead characteristics. The article concludes with information on weld defects, such as lack of fusion, slag entrapment, solidification cracking, hydrogen cracking, or porosity.

Molten salt baths are anhydrous, fused chemical baths used at elevated temperatures for a variety of industrial cleaning applications. This article discusses their applications in paint stripping, polymer removal, casting cleaning, glass removal, and plasma/flame spray removal. It provides an overview of the basic design and safety considerations of the salt bath equipment and describes the environmental impact of molten salt bath cleaning.

Electroslag welding (ESW) and electrogas welding (EGW) are two related procedures that are used to weld thick-section materials in the vertical or near-vertical position between retaining shoes. This article discusses the fundamentals of the electroslag process in terms of heat flow conditions and metal transfer and weld pool morphology. It presents constitutive equations for welding current, voltage, and travel rate for ESW. The article describes the metallurgical and chemical reactions in terms of fusion zone compositional effects, weld metal inclusions, solidification structure, and solid-state transformations. It describes the electroslag process development and the applications of electroslag and electrogas processes. The article concludes with a discussion on weld defects, such as temper embrittlement, hydrogen cracking, and weld distortion.

Electroslag welding (ESW) involves high energy input relative to other welding processes, resulting generally in inferior mechanical properties and specifically in lower toughness of the heat-affected zone. Electrogas welding (EGW) is a method of gas metal or flux cored arc welding, wherein an external gas is supplied to shield the arc, and molding shoes are used to confine the molten weld metal for vertical-position welding. This article describes the fundamentals, temperature relations, consumables, metallurgical and chemical reactions, and process development of ESW. The problems, quality control, and process applications of ESW and EGW are also discussed.

This article discusses the operating principles, types, and applications of shearing and slitting of different forms of steel, including plates, flat sheets, bars, coiled sheet and strips. In addition, it provides a detailed account of the cutting methods such as oxyfuel gas cutting, plasma arc cutting, oxygen arc cutting, laser beam cutting, and air carbon arc cutting and gouging, describing their process capabilities, equipment used, operating principles and parameters, and factors affecting their efficiency.

This article focuses on the various techniques for removing contaminants in the surface preparation of steel for hot-dip coatings: wet cleaning methods, including alkaline cleaning, electrolytic cleaning, chemical pickling, and electrolytic pickling; flame cleaning and furnace-atmosphere techniques, such as Sendzimir oxidation/reduction method; other specialized methods, namely, fluxes, mechanical cleaning, and ultrasonic methods; or a combination of these.

Hardfacing is a form of surfacing that is applied for the purpose of reducing wear, abrasion, impact, erosion, galling, or cavitation. This article describes the deposition of hardfacing alloys by oxyfuel welding, various arc welding methods, laser welding, and thermal spray processes. It discusses the categories of hardfacing alloy, such as build-up alloys, metal-to-metal wear alloys, metal-to-earth abrasion alloys, tungsten carbides, and nonferrous alloys. A summary of the selection guide for hardfacing alloys is presented in a table. The article describes the procedures for stainless steel weld cladding and the factors influencing joint integrity in dissimilar metal joining. It concludes with a discussion on joining carbon and low-alloy steels to various dissimilar materials (both ferrous and nonferrous) by arc welding.

The gas-tungsten arc welding (GTAW) process is performed using a welding arc between a nonconsumable tungsten-base electrode and the workpieces to be joined. The arc discharge requires a flow of electrons from the cathode through the arc column to the anode. This article discusses two cases of electron discharge at the cathode: thermionic emission and nonthermionic emission, also called cold cathode, or field emission. It schematically illustrates relative heat transfer contributions to workpiece in the GTAW process. The article provides information on the effects of cathode tip shape and shielding gas composition in the GTAW process.

Direct powder rolling (DPR) is a process by which a suitable powder or mixture of powders is compacted under the opposing forces of a pair of rolling mill rolls to form a continuous green strip that is further densified and strengthened by sintering and rerolling. This article discusses the basic principle, process considerations, and advantages of DRP, and describes the application of this process in the manufacture of powder titanium and titanium alloy components. It further illustrates the complexity of the process and describes the benefits of using DRP in terms of economics and product quality.

Upset welding (UW) is a resistance welding process utilizing both heat and deformation to form a weld. A wide variety of shapes and materials can be joined using upset welding in either a single-pulse or continuous mode. This article discusses the advantages and disadvantages of upset welding, as well as the types of welds. The advantages include speed, ease of control, fewer defects, enhanced weld properties, simplicity of equipment, less-strict composition requirements, and ability to join difficult-to-weld materials. The article reviews the role of a homopolar generator as an alternative method for supplying the electrical current for upset welding.

Resistance welding (RW) encompasses a group of processes in which the heat for welding is generated by the resistance to the flow of electrical current through the parts being joined. The three major resistance welding processes are resistance spot welding (RSW), resistance seam welding (RSEW), and projection welding (PW). This article addresses the considerations for using these processes to join specific types of materials. It discusses the process variations, applicability, advantages, and limitations of these resistance welding processes. The article provides information on flash welding, high-frequency resistance welding, and capacitor discharge stud welding. It concludes with a discussion on resistance welding of stainless steels, aluminum alloys, and copper and copper alloys.

This article provides information about the selection of brazing processes and filler metals and describes the brazing (heating) methods, including manual torch brazing, furnace brazing, induction brazing, dip brazing, resistance brazing and specialized brazing processes such as diffusion and exothermic brazing. The article explains joint design, filler materials, fuel gases, equipment, and fluxes in the brazing methods. The article also describes the brazing of steels, stainless steels, cast irons, heat-resistant alloys, aluminum alloys, copper and copper alloys, and titanium and titanium alloys.

This article reviews the fundamentals of electrochemical corrosion test methods. The features and requirements of the instrumentation needed for an electrochemical test are briefly discussed. The article provides a discussion on the various electrochemical techniques and tests available for laboratory studies of corrosion phenomena. The techniques and tests include no-applied-signal tests, small-signal polarization tests, large-signal polarization tests, scanning electrode techniques, and miscellaneous techniques.

The electrode potential is one of the most important parameters in the thermodynamics and kinetics of corrosion. This article discusses the fundamentals of electrode potentials and illustrates the thermodynamics of chemical equilibria by using the hydrogen potential scale and the Nernst equation. It describes galvanic cell reactions and corrosion reactions in an aqueous solution in an electrochemical cell. The article explores the most common cathodic reactions encountered in metallic corrosion in aqueous systems. The reactions included are proton reduction, water reduction, reduction of dissolved oxygen, metal ion reduction, and metal deposition. The article also presents the standard equilibrium potentials measured at 25 deg C relative to a standard hydrogen electrode for various metal-ion electrodes in a tabular form.