This article describes some of the mechanical/ electrochemical phenomena related to the in vivo degradation of metals used for biomedical applications. It discusses the properties and failure of these materials as they relate to stress-corrosion cracking (SCC) and corrosion fatigue (CF). The article presents the factors related to the use of surgical implants and their deterioration in the body environment, including biomedical aspects, chemical environment, and electrochemical fundamentals needed for characterizing CF and SCC. It provides a discussion on the use of metallic biomaterials in surgical implant applications, such as orthopedic, cardiovascular surgery, and dentistry. It addresses the key issues related to simulation of the in vivo environment, service conditions, and data interpretation. Theses include frequency of dynamic loading, electrolyte chemistry, applicable loading modes, cracking mode superposition, and surface area effects. The article describes the fundamentals of CF and SCC, testing methodology, and test findings from laboratory, in vivo, and retrieval studies.

Stress-corrosion cracking (SCC) is a form of corrosion and produces wastage in that the stress-corrosion cracks penetrate the cross-sectional thickness of a component over time and deteriorate its mechanical strength. Although there are factors common among the different forms of environmentally induced cracking, this article deals only with SCC of metallic components. It begins by presenting terminology and background of SCC. Then, the general characteristics of SCC and the development of conditions for SCC as well as the stages of SCC are covered. The article provides a brief overview of proposed SCC propagation mechanisms. It discusses the processes involved in diagnosing SCC and the prevention and mitigation of SCC. Several engineering alloys are discussed with respect to their susceptibility to SCC. This includes a description of some of the environmental and metallurgical conditions commonly associated with the development of SCC, although not all, and numerous case studies.

This article discusses corrosion resistance of titanium and titanium alloys to different types of corrosion, including galvanic corrosion, crevice corrosion, stress-corrosion cracking (SCC), erosion-corrosion, cavitation, hot salt corrosion, accelerated crack propagation, and solid and liquid metal embrittlement. A short section discusses the addition of alloys that can improve the corrosion resistance of titanium.

This article discusses the corrosion resistance of aluminum and aluminum alloys in various environments, such as in natural atmospheres, fresh waters, seawater, and soils, and when exposed to chemicals and their solutions and foods. It describes the forms of corrosion of aluminum and aluminum alloys, including pitting corrosion, intergranular corrosion, exfoliation corrosion, galvanic corrosion, stray-current corrosion, deposition corrosion, crevice corrosion, filiform corrosion, stress-corrosion cracking, corrosion fatigue, and hydrogen embrittlement. The article also presents a short note on aluminum clad products and corrosion at joints.

This article discusses the effects of heavy metal impurities, environmental factors, the surface condition (such as as-cast, treated, and painted), and the assembly practice on the corrosion resistance of a magnesium or a magnesium alloy part. It provides information on stress-corrosion cracking and galvanic corrosion of magnesium alloys, as well as the surface protection of magnesium assemblies achieved by inorganic surface treatments.

This article describes the fundamental concepts of heat treatment simulation, including the physical events and their interactions, the heat treatment simulation software, and the commonly used simulation strategies. It summarizes material data needed for heat treatment simulations and discusses reliable data sources as well as experimental and computational methods for material data acquisition. The article provides information on the process data needed for accurate heat treatment simulation and the methods for their determination. Methods for validating heat treatment simulations are also discussed with an emphasis on the underlying philosophy for the selection and design of validation tests. The article also discusses the applications, capabilities, and limitations of heat treatment simulations via selected industrial case studies for a better understanding of the effect of microstructure, distortion, residual stress, and cracking in gears, shafts, and bearing rings.

The presence of macroscopic residual stresses in heat treatable aluminum alloys can give rise to machining distortion, dimensional instability, and increased susceptibility to in-service fatigue and stress-corrosion cracking. This article details the residual-stress magnitudes and distributions introduced into aluminum alloys by thermal operations associated with heat treatment. The available technologies by which residual stresses in aluminum alloys can be relieved are also described. The article shows why thermal stress relief is not a feasible stress-reduction technology for precipitation-hardened alloys. It examines the consequences of aging treatments on the residual stress, namely, annealing, precipitation heat treatment, and cryogenic treatment. The article provides information on uphill quenching, which attempts to reverse thermal gradients encountered during quenching. It examines how quench-induced residual stresses in heat treatable aluminum alloys are reduced when sufficient load is applied to cause plastic deformation. The article also shows how plastic deformation reduces residual stress.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of AISI/SAE alloy steels (4xxx steels) and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the brittle fracture, ductile fracture, impact fracture, fatigue fracture surface, reversed torsional fatigue fracture, transgranular cleavage fracture, rotating bending fatigue, tension-overload fracture, torsion-overload fracture, slip band crack, crack growth and crack initiation, crack nucleation, microstructure, hydrogen embrittlement, sulfide stress-corrosion failure, stress-corrosion cracking, and hitch post shaft failure of these steels. The components considered in the article include tail-rotor drive-pinion shafts, pinion gears, outboard-motor crankshafts, bull gears, diesel engine bearing cap bolts, splined shafts, aircraft horizontal tail-actuator shafts, bucket elevators, aircraft propellers, helicopter bolts, air flasks, tie rod ball studs, and spiral gears.

This article focuses on the various forms of corrosion occurred in the passive range of aluminum and its alloys, namely, pitting corrosion, galvanic corrosion, deposition corrosion, intergranular corrosion, stress-corrosion cracking, exfoliation corrosion, corrosion fatigue, erosion-corrosion, atmospheric corrosion, filiform corrosion, and corrosion in water and soils. It discusses the effects of composition, microstructure, stress-intensity factor, and nonmetallic building materials on the corrosion behavior of aluminum and its alloys. The article also describes the corrosion resistance of anodized aluminum in contact with foods, pharmaceuticals, and chemicals.

Corrosion of metals is defined as deterioration caused by chemical or electrochemical reaction of the metal with its environment. This article provides information on corrosion of iron and steel by aqueous and nonaqueous media. It discusses the corrosive environments of carbon and alloy steels, namely atmospheric corrosion, soil corrosion, corrosion in fresh water and seawater. The article describes the corrosion process in concrete, which tends to create conditions that increase the rate of attack. The focus is on the stress-corrosion cracking of steels; an environmentally induced crack propagation that results from the combined interaction of mechanical stress and corrosion reactions. The article tabulates a guide on corrosion prevention for carbon steels in various environments. It also discusses protection methods of steel from corrosion, including coatings, such as temporary protection, cleaning, hot dip coating, electroplating, thermal spray coatings, conversion coatings, thin organic coatings, and inhibitors.

This article reviews the corrosion behavior in various environments for seven important nickel alloy families: commercially pure nickel, Ni-Cu, Ni-Mo, Ni-Cr, Ni-Cr-Mo, Ni-Cr-Fe, and Ni-Fe-Cr. It examines the behavior of nickel alloys in corrosive media found in industrial settings. The corrosive media include: hydrochloric acid, sulfuric acid, phosphoric acid, hydrofluoric acid, hydrobromic acid, nitric acid, organic acids, salts, seawater, and alkalis. The modes of high-temperature corrosion include oxidation, carburization, metal dusting, sulfidation, nitridation, corrosion by halogens, and corrosion by molten salts. Applications where the corrosion properties of nickel alloys are important factors in materials selection include the petroleum, chemical, and electrical power industries. Most nickel alloys are much more resistant than the stainless steels to reducing acids, such as hydrochloric, and some are extremely resistant to the chloride-induced phenomena of pitting, crevice attack, and stress-corrosion cracking (to which the stainless steels are susceptible). Nickel alloys are also among the few metallic materials able to cope with hot hydrofluoric acid. The conditions where nickel alloys suffer environmentally assisted cracking are highly specific and therefore avoidable by proper design of the industrial components.

This article discusses the five basic matrix structures in cast irons: ferrite, pearlite, bainite, martensite, and austenite. The alloying elements, used to enhance the corrosion resistance of cast irons, including silicon, nickel, chromium, copper, molybdenum, vanadium, and titanium, are reviewed. The article provides information on classes of the cast irons based on corrosion resistance. It describes the various forms of corrosion in cast irons, including graphitic corrosion, fretting corrosion, pitting and crevice corrosion, intergranular attack, erosion-corrosion, microbiologically induced corrosion, and stress-corrosion cracking. The cast irons suitable for the common corrosive environments are also discussed. The article reviews the coatings used on cast irons to enhance corrosion resistance, such as metallic, organic, conversion, and enamel coatings. It explains the basic parameters to be considered before selecting the cast irons for corrosion services.

This article discusses the identifying characteristics of the forms or mechanisms of corrosion that commonly attack copper metals, as well as the most effective means of combating each. It tabulates corrosion ratings of wrought copper alloys in various corrosive media. The article describes the corrosion behavior of copper alloys in specific environments. It reviews the corrosion characteristics of copper and copper alloys in various acids, alkalis, salts, organic compounds, and gases. The article provides information on the behavior of copper alloys that is susceptible to stress-corrosion cracking in various industrial and chemical environments. It concludes with a discussion on various corrosion testing methods, including aqueous corrosion testing, dynamic corrosion tests, and stress-corrosion testing.

Copper and copper alloys are widely used in many environments and applications because of their excellent corrosion resistance, which is coupled with combinations of other desirable properties. This article lists the identifying characteristics of the forms of corrosion that commonly attack copper metals as well as the most effective means of combating each. General corrosion, galvanic corrosion, pitting, impingement, fretting, intergranular corrosion, dealloying, corrosion fatigue, and stress-corrosion cracking (SCC) are some forms of corrosion. The article also lists a galvanic series of metals and alloys valid for dilute aqueous solutions, such as seawater and weak acids. It provides useful information on the effects of alloy compositions, selection for specific environments, and atmospheric corrosion of selected copper alloys. The article also tabulates the corrosion ratings of wrought copper alloys in various corrosive media.

Titanium alloys are often used in highly corrosive environments because they are better suited than most other materials. The excellent corrosion resistance is the result of naturally occurring surface oxide films that are stable, uniform, and adherent. This article offers explanations and insights on the most common forms of corrosion observed with titanium alloys, including general corrosion, crevice corrosion, anodic pitting, hydrogen damage, stress-corrosion cracking, galvanic corrosion, corrosion fatigue, and erosion-corrosion. It also provides practical strategies for expanding the useful application range for titanium and includes a comprehensive overview of available corrosion data.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of austenitic stainless steels and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the following: fatigue-crack fracture, rock candy fracture, cleavage fracture, brittle fracture, high-cycle fatigue fracture, fatigue striations, hydrogen-embrittlement failure, creep crack propagation, fatigue crack nucleation, intergranular creep fracture, torsional overload fracture, stress-corrosion cracking, and grain-boundary damage of these steels. The austenitic stainless steel components include spring wires, preheater-reactor slurry transfer lines and gas lines of coal-liquefaction pilot plants, oil feed tubes and suction couch rolls of paper machines, cortical screws and compression hip screws of orthopedic implants, and Jewett nails.

Stress-corrosion cracking (SCC) occurs under service conditions, which can result, often without any prior warning, in catastrophic failure. Hydrogen embrittlement is distinguished from stress-corrosion cracking generally by the interactions of the specimens with applied currents. To determine the susceptibility of alloys to SCC and hydrogen embrittlement, several types of testing are available. This article describes the constant extension testing, constant load testing, constant strain-rate testing for smooth specimens and precracked or notched specimens of SCC. It provides information on the cantilever beam test, wedge-opening load test, contoured double-cantilever beam test, three-point and four-point bend tests, rising step-load test, disk-pressure test, slow strain-rate tensile test, and potentiostatic slow strain-rate tensile test for hydrogen embrittlement.

This article begins with a discussion of the basic fracture modes, including dimple ruptures, cleavages, fatigue fractures, and decohesive ruptures, and of the important mechanisms involved in the fracture process. It then describes the principal effects of the external environment that significantly affect the fracture propagation rate and fracture appearance. The external environment includes hydrogen, corrosive media, low-melting metals, state of stress, strain rate, and temperature. The mechanism of stress-corrosion cracking in metals such as steels, aluminum, brass, and titanium alloys, when exposed to a corrosive environment under stress, is also reviewed. The final section of the article describes and shows fractographs that illustrate the influence of metallurgical discontinuities such as laps, seams, cold shuts, porosity, inclusions, segregation, and unfavorable grain flow in forgings and how these discontinuities affect fracture initiation, propagation, and the features of fracture surfaces.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of wrought aluminum alloys and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the corrosion-fatigue fracture, fatigue striations, tension-overload fracture surface, ductile fracture, cone-shaped fracture surface, intergranular crack propagation, transgranular crack propagation, stress-corrosion cracking, hydrogen damage, and grain-boundary separation of these alloys. Fractographs are also provided for a forged aircraft main-landing gear wheel and actuator beam, an aircraft wing spar, a fractured aircraft propeller blade, shot peened fillet, an aircraft lower-bulkhead cap, and clevis-attachment lugs.

This article reviews the corrosion behavior of intermetallics for the modeling of the corrosion processes and for devising a strategy to create corrosion protective systems through alloy and coating design. It discusses the high-temperature corrosion properties of intermetallics and aqueous corrosion properties. Thermodynamic principles in the context of high-temperature corrosion and information on oxidation; sulfidation; hot corrosion of NiAl-, FeAl-, and TiAl-based intermetallics; and silicides are included. The article explores the thermodynamic consideration, ordering influencing kinetics, stress-cracking corrosion, and hydrogen embrittlement of aqueous corrosion. It also explains the practical issues dealing with the corrosion problems.