This article presents a detailed account on the process flow, composition, alternative sources, and the advancement of ironmaking, steelmaking and secondary steelmaking practices. Some steels, such as bearing steels, heat-resistant steels, ultrahigh strength missile and aircraft steels, and rotor steels have higher quality requirements and tighter composition control than plain carbon or ordinary low-alloy steels. The production of special-quality steels requires vacuum-based induction or electric remelting and refining capabilities. The article explores the types and characteristics of various steel manufacturing processes, such as ingot casting, continuous casting, and hot rolling. It provides an outline of specialized processing routes of producing ultralow plain carbon steels, interstitial-free steels, high strength low-alloy steels, ultrahigh strength steels, stainless steels, and cold-rolled products, and briefly explains the analytical techniques for liquid steels.

This article focuses on the construction, operation of electric arc furnaces (EAF), and their auxiliary equipment in the steel foundry industry. It provides information on the power supply of EAF and discusses the components of the EAF, including the roof, furnace shell, spout and tap hole, water-cooling system, preheat and furnace scrap burners, and ladles. The article describes the acid and basic steelmaking practices. It discusses the raw materials used, oxidation process, methods of heat reduction, and deoxidation process in the practices. The article provides a discussion on the arc melting of iron and EAF steelmaking.

This article describes ironmaking and steelmaking practices (melt or liquid processing, including hot metal desulfurization) and discusses the evolution of these processes and their effects on steel properties. The physical chemistry of steelmaking may appear deceptively simple for integrated steel mill operations where ore from the ground is converted into steel. The various refining steps that occur in steelmaking are reviewed. The article also describes solid processing of steel, with emphasis on hot and cold rolling, thermomechanical processing, and annealing of flat steel products.

Notch toughness is an indication of the capacity of a steel to absorb energy when a stress concentrator or notch is present. The notch toughness of a steel product is the result of a number of interactive effects, including composition, deoxidation and steelmaking practices, solidification, and rolling practices, as well as the resulting microstructure. All carbon and high-strength low-alloy (HSLA) steels undergo a ductile-to-brittle transition as the temperature is lowered. The composition of a steel, as well as its microstructure and processing history, significantly affects both the ductile-to-brittle transition temperature range and the energy absorbed during fracture at any particular temperature.. Th article focuses on various aspects of notch toughness including the effects of composition and microstructure, general influence of manufacturing practices and the interactive effects that simultaneously influence notch toughness. With the exception of working direction, most of the same chemical, microstructural, and manufacturing factors that influence the notch toughness of wrought steels also apply to cast steels. The Charpy V-notch test is used worldwide to indicate the ductile-to-brittle transition of a steel. While Charpy results cannot be directly applied to structural design requirements, a number of correlations have been made between Charpy results and fracture toughness.

Steel sheet is widely used for industrial and consumer products, partly because it is relatively strong, easily joined, and readily available at moderate cost. This article discusses the mechanical properties and formability of steel sheet, the use of circle grid analysis to identify the properties of complicated shapes, and various simulative forming tests. The mechanical properties of steel sheet that influence its forming characteristics, either directly or indirectly, can be measured by uniaxial tension testing. The article covers the effects of steel composition, steelmaking practices, and metallic coatings, as well as the correlation between microstructure and formability. A guide to the selection of steel sheet is also included. The formability of steel sheet is related to various microstructural features of the sheet. The article describes some of the forming characteristics of the more commonly used formable grades. It also lists the typical mechanical properties for common grades of hot-rolled and cold-rolled steel sheets.

This article reviews the selection and formability characteristics of steels, with an emphasis on low-carbon steels and some coverage on the forming of high-carbon steels. It describes the key factors that affect the formability of steels in terms of steelmaking practices, surface finishes, metal thicknesses, and alloying. The article explains the bending and forming operations with some examples. It also describes the formation of various shells, including doubly contoured shells, deep recessed shells, and deep circular shells.

This article discusses the most common methods of melting steels, namely, electric arc and induction melting. It describes the classification of refractories by an index of the “basicity” of the slag formed on the steel surface. The article provides a discussion on the converter metallurgy, which includes melt refinement in argon oxygen decarburization (AOD) vessels and vacuum oxygen decarburization (VODC) in a converter vessel. It also discusses ladle metallurgy, which includes vacuum induction degassing, vacuum oxygen decarburization, and vacuum ladle degassing.

The properties of carbon and alloy steels are dependent on the relationships between chemical composition, processing, and microstructure. This article discusses the effects of alloying and residual elements on the mechanical properties of carbon and alloy steels. Tables listing values for the mechanical properties of selected carbon and alloy steels in the hot-rolled, normalized, annealed, and quenched-and tempered condition are provided.

Wire rod is a semifinished product rolled from billet on a rod mill and is used primarily for the manufacture of wire. Steel wire rod is usually cold drawn into wire suitable for further drawing; for cold rolling, cold heading, cold upsetting, cold extrusion, or cold forging; or for hot forging. The article explains these operations, along with the several recognized quality and commodity classifications applicable to steel wire rods. The heat treatments commonly applied to steel wire rod, either before or during processing into wire, include annealing, spheroidize annealing, patenting, and controlled cooling. When the end product must be heat treated, the heat treatment and mechanical properties should be clearly defined. Carbon steel rods are produced in various grades or compositions: low-carbon, medium-low-carbon, medium-high-carbon, and high-carbon steel wire rods. Rod for the manufacture of carbon steel wire is produced with manufacturing controls and inspection procedures intended to ensure the degree of soundness and freedom from injurious surface imperfections necessary for specific applications. This article also describes the various quality descriptors applicable to the rods as well as standard qualities and commodities available in alloy steel wire rod.

Low-carbon steel sheet and strip are used primarily in consumer goods. This article discusses quality descriptors and mechanical properties of low-carbon steel sheet and strip and carbon and low-alloy steel plate. Alloy steel sheet and strip are used primarily for those special applications that require the mechanical properties normally obtained by heat treatment. Steel sheet is coated in coil form before fabrication either by the steel mills or by specialists called coil coaters. Porcelain enamels are glass coatings applied primarily to products or parts made of sheet steel, cast iron, or aluminum to improve appearance and to protect the metal surface.

Cr-Mo steels are preferred in the construction of high-temperature components because they possess excellent strength, toughness, and corrosion resistance relative to carbon steels and most low-alloy steels. This article discusses the composition and metallurgy of the heat-resistant Cr-Mo steels. It details the Charpy V-notch (CVN) toughness properties of Cr-Mo steels relevant to fatigue and fracture resistance. The fracture mechanics of Cr-Mo steels are reviewed. The article analyzes the characterization of low-cycle fatigue based on fatigue damage calculations. It concludes with information on fatigue crack growth and fatigue behavior of weldments.

Hot-rolled steel bars and other hot rolled steel shapes are produced from ingots, blooms, or billets converted from ingots, or from strand cast blooms and billets, and comprise a variety of sizes and cross sections. This article provides a brief discussion on mechanical properties, quality descriptors and chemical compositions of hot-rolled steel bars, cold-finished steel bars, steel wire rod and steel wire. It contains tables that provide size tolerances for cold-finished carbon steel bar and cold-finished alloy steel bar.

This article provides an overview of the corrosion theory relating to refractories on the basis of acid/base reactions, thermodynamics, and kinetic considerations. The tests to evaluate refractory corrosive wear are reviewed. The article describes the specific refractories used in steel, glass, aluminum, and chemical-resistant applications. Specific material issues that should be considered or evaluated when choosing or using refractory materials are discussed.

Ores, which consist of the primary valuable mineral, predominant gangue content, valuable by-products, and detrimental impurities, are extracted and directed to mineral processing. This article describes the mineral processing facilities, such as crushers, grinders, concentrators, separators, and flotation devices that are used for particle size reduction, separation of particles according to their settling rates in fluids and dewatering of concentrate particles. It explains the basic principles, flow diagrams, ore concentrate preparation methods, and equipment of major types of metallurgical processes, including pyrometallurgical, hydrometallurgical, and electrometallurgical processes.

A significant amount of the worldwide demand for metals is met with recycled materials acquired by metal producers in the form of purchased scrap. This article focuses primarily on the methods and technology used to process and repurpose the vast amounts of purchased scrap that recirculate in the industrial supply chain. It describes the U.S. market for iron and steel scrap, providing information on scrap use by industry, factors influencing demand, and the purchased scrap supply. Iron and steel recycling is discussed separately from stainless steel and superalloy recycling in this article, as the scrap industry treats them differently. The scrap processing of iron involves collection, separation and sorting, size reduction and compaction, detinning, blending, and incineration. The recycling of stainless steels and superalloys follows the same process, but requires several additional steps, including secondary nickel refining, degreasing, and separation of metallurgical wastes.

This article provides a discussion on the structural ceramics used in gas turbine components, the automotive and aerospace industries, or as heat exchangers in various segments of the chemical and power generation industries. It covers the fundamental aspects of chemical corrosion and describes the corrosion resistance characteristics of specific classes of refractories and structural ceramics. The article also examines the prevention strategies that minimize corrosion failures of both classes of materials.

The mechanism of contact fatigue can be understood in terms of several sources of stress concentration, or stress raisers, within the macroscopic Hertzian stress field. This article focuses primarily on rolling contact fatigue of hardened bearing steels. It discusses Hertzian shear stresses at and below the contact surfaces and briefly summarizes bearings and gear characteristics. The article provides an overview of the key types of gear and bearing steels. It analyzes two types of macropitting that result from the subsurface growth of fatigue cracks, namely, subsurface-origin macropitting and surface-origin macropitting. The article describes the factors influencing contact fatigue life of hardened steel bearings and gears, including hardness, inclusions, carbides, and residual stresses.

This article addresses classifications and designations for carbon and low-alloy steel sheet and strip product forms based on composition, quality descriptors, mechanical properties, and other factors. Carbon steel sheet and strip are available as hot-rolled and as cold-rolled products. Low-alloy steel sheet and strip are used primarily for applications that require the mechanical properties normally obtained by heat treatment. The descriptors of quality used for hot-rolled plain carbon steel sheet and strip and cold-rolled plain carbon steel sheet include structural quality, commercial quality, drawing quality, and drawing quality, special killed. The surface texture of low-carbon cold-rolled steel sheet and strip can be varied between rather wide limits. The modified low-carbon steel grades discussed in the article are designed to provide sheet and strip products having increased strength, formability, and/or corrosion resistance. The article also summarizes the key operations involved in the three alternative direct casting processes: thin slab, thin strip, and spray casting.

This article provides a discussion on the corrosion of industrial refractory materials and technical ceramics. These materials, which are used to minimize heat losses and provide a barrier between the vessel and its contents, are utilized in the metallurgical, chemical process, power generation, automotive, and aerospace industries. The article covers the fundamental principles of chemical corrosion of refractories and ceramics, and the use of thermodynamic calculations and kinetic models to evaluate the probability of the occurrence of corrosion-causing chemical reactions. It describes the corrosion resistance characteristics of specific classes of refractories and structural ceramics. The article also examines the prevention strategies that minimize corrosion failures of both classes of materials.