The steam turbine is the simplest and most efficient engine for converting large amounts of heat energy into mechanical work. This article discusses the primary corrosion mechanisms such as corrosion fatigue, stress-corrosion cracking (SCC), pitting, corrosion, and erosion-corrosion, in steam turbines. It illustrates the various causes of the corrosiveness of the steam turbine environments through a Mollier diagram. The article describes the four parts of design disciplines that affect turbine corrosion, namely, mechanical design, heat transfer, flow and thermodynamics, and physical shape. It lists the ways to control the steam and surface chemistry, and design and material improvements to minimize turbine corrosion.

This article illustrates typical wear and friction issues encountered in gas and steam turbines and their consequences as well as commonly adopted materials solutions. It contains tables that present the summary of wear and friction related issues encountered in steam turbines and gas turbines. The article outlines the differences in the operating conditions and the nature of the components involved in gas and steam turbines. It discusses the constraints and applicable coating solutions for wear and friction issues, and concludes with a broad set of challenges that need to be addressed to improve performance and operability of gas and steam turbines.

The corrosion issues in the compressor, combustor and turbine sections of industrial gas turbines used in steam production generally depend on the quality of the fuel, air, and water used in the engine than on the specific industrial application. This article focuses on the forms of corrosion and their preventive measures in the compressor, combustor and turbine sections of a steam turbine. The compressor section mainly suffers from aqueous corrosion; while in case of the combustor and turbine sections, which are made of nickel-base superalloys, high-temperature environmental attack in the form of high-temperature oxidation and hot corrosion are predominant. The effect of high-temperature oxidation and hot corrosion on the mechanical properties of superalloys is also discussed.

Liquid impingement erosion has been defined as progressive loss of original material from a solid surface due to continued exposure to impacts by liquid drops or jets. This article focuses on the core nature of erosion by liquid impingement, due to the greater appreciation of the distinctions between the different forms of erosion. It discusses steam turbine blade erosion, aircraft rain erosion, and rain erosion of wind turbine blades. The article describes the mechanisms of liquid impact erosion and time dependence of erosion rate. It reviews critical empirical observations regarding both impingement variables (velocity, impact angle, droplet size, and physical properties of liquids) and erosion resistance of materials, including the correlation between erosion resistance and mechanical properties and the effects of alloying elements and microstructure. The article also provides information on the ways to combat erosion.

This article focuses on common failures of the components associated with the flow path of industrial gas turbines. Examples of steam turbine blade failures are also discussed, because these components share some similarities with gas turbine blading. Some of the analytical methods used in the laboratory portion of the failure investigation are mentioned in the failure examples. The topics covered are creep, localized overheating, thermal-mechanical fatigue, high-cycle fatigue, fretting wear, erosive wear, high-temperature oxidation, hot corrosion, liquid metal embrittlement, and manufacturing and repair deficiencies.

This article discusses some elevated-temperature properties of carbon steels and low-alloy steels with ferrite-pearlite and ferrite-bainite microstructures for use in boiler tubes, pressure vessels, and steam turbines. The selection of steels to be used at elevated temperatures generally involves compromise between the higher efficiencies obtained at higher operating temperatures and the cost of equipment, including materials, fabrication, replacement, and downtime costs. The article considers the low-alloy steels which are the creep-resistant steels with 0.5 to 1.0% Mo combined with 0.5 to 9.0% Cr and perhaps other carbide formers. The factors affecting mechanical properties of steels include the nature of strengthening mechanisms, the microstructure, the heat treatment, and the alloy composition. The article describes these factors, with particular emphasis on chromium-molybdenum steels used for elevated-temperature service. Although the mechanical properties establish the allowable design-stress levels, corrosion effects at elevated temperatures often set the maximum allowable service temperature of an alloy. The article also discusses the effects of alloying elements in annealed, normalized and tempered, and quenched and tempered steels.

This article describes the control of water chemistry in the steam cycle of a power plant for achieving corrosion control, deposition prevention, and higher cycle efficiency. It discusses the materials requirements of the components exposed to supercritical water in supercritical (SC) and ultrasupercritical (USC) power plants. These components include high-pressure steam piping and headers, superheater and reheater tubing, water wall tubing in the boiler, high-and intermediate-pressure rotors, rotating blades, and bolts in the turbine section. The article reviews the boiler alloys, used in SC and USC boilers, such as ferritic steels, austenitic steels, and nickel-base alloys. It provides information on the materials used in turbine applications such as ferritic rotor steels, turbine blade alloys, and bolting materials. The article explains various factors influencing steamside corrosion in SC power plants. It also deals with the role of overall efficiency in the USC power generation.

Erosion of solid surfaces can be brought about solely by liquids in two ways: from damage induced by formation and subsequent collapse of voids or cavities within the liquid, and from high-velocity impacts between a solid surface and liquid droplets. The former process is called cavitation erosion and the latter is liquid-droplet erosion. This article emphasizes on manifestations of damage and ways to minimize or repair these types of liquid impact damage, with illustrations.

The primary fossil fuels are generally defined as coal, oil, natural gas, tar sands, and shale oil. This article discusses the characteristics and the types of fuels used in fossil and fuel industries. It describes the energy conversion in fuels and outlines the efficiency of a heat engine with the help of the Carnot equation.

Erosion occurs as the result of a number of different mechanisms, depending on the composition, size, and shape of the eroding particles; their velocity and angle of impact; and the composition of the surface being eroded. This article describes the erosion of ductile and brittle materials with the aid of models and equations. It presents three examples of erosive wear failures, namely, abrasive erosion, erosion-corrosion, and cavitation erosion.

Erosion of a solid surface can be brought about by liquid droplet impingement (LDI), which is defined as "progressive loss of original material from a solid surface due to continued exposure to erosion by liquid droplets." In this article, the emphasis is placed on the damage mechanism of LDI erosion under the influence of a liquid film and surface roughness and on the prediction of LDI erosion. The fundamentals of LDI and processes involved in initiation of erosion are also discussed.

Stress-corrosion cracking (SCC) is a form of corrosion and produces wastage in that the stress-corrosion cracks penetrate the cross-sectional thickness of a component over time and deteriorate its mechanical strength. Although there are factors common among the different forms of environmentally induced cracking, this article deals only with SCC of metallic components. It begins by presenting terminology and background of SCC. Then, the general characteristics of SCC and the development of conditions for SCC as well as the stages of SCC are covered. The article provides a brief overview of proposed SCC propagation mechanisms. It discusses the processes involved in diagnosing SCC and the prevention and mitigation of SCC. Several engineering alloys are discussed with respect to their susceptibility to SCC. This includes a description of some of the environmental and metallurgical conditions commonly associated with the development of SCC, although not all, and numerous case studies.

This article provides an overview of key abradable thermal spray coating systems based on predominant function and key design criteria. It describes two families of coatings which have evolved for use at higher temperature: flame (combustion)-sprayed abradable powders and atmospheric plasma-sprayed abradable powders. Three classic examples of flame spray abradables are nickel-graphite powders, NiCrAl-bentonite powders, and NiCrFeAl-boron nitride powders. The article provides information on various abradable coating testing procedures, namely, abradable incursion testing; aging, corrosion, thermal cycle and thermal shock testing; hardness testing; and erosion resistance testing.

Erosion is the progressive loss of original material from a solid surface due to mechanical interaction between that surface and a fluid, a multicomponent fluid, an impinging liquid, or impinging solid particles. The detrimental effects of erosion have caused problems in a number of industries. This article describes the processes involved in erosion of ductile materials, brittle materials, and elastomers. Some examples of erosive wear failures are given on abrasive erosion, liquid impingement erosion, cavitation, and erosion-corrosion. In addition, the article provides information on the selection of materials for applications in which erosive wear failures can occur.

Stainless steels are widely used at elevated temperatures when carbon and low-alloy steels do not provide adequate corrosion resistance and/or sufficient strength at these temperatures. This article deals with the wrought stainless steels used for high temperature applications. It gives some typical compositions of wrought heat-resistant stainless steels, which are grouped into ferritic, martensitic, austenitic, and precipitation-hardening (PH) grades. Quenched and tempered martensitic stainless steels are essentially martensitic and harden when air cooled from the austenitizing temperature. These alloys offer good combinations of mechanical properties. The article focuses on mechanical property considerations and corrosion resistance considerations of stainless steels. The corrosion and oxidation resistance of wrought stainless steels is similar to that of cast stainless steels with comparable compositions.

This article commences with a discussion on the characteristics of stress-corrosion cracking (SCC) and describes crack initiation and propagation during SCC. It reviews the various mechanisms of SCC and addresses electrochemical and stress-sorption theories. The article explains the SCC, which occurs due to welding, metalworking process, and stress concentration, including options for investigation and corrective measures. It describes the sources of stresses in service and the effect of composition and metal structure on the susceptibility of SCC. The article provides information on specific ions and substances, service environments, and preservice environments responsible for SCC. It details the analysis of SCC failures, which include on-site examination, sampling, observation of fracture surface characteristics, macroscopic examination, microscopic examination, chemical analysis, metallographic analysis, and simulated-service tests. It provides case studies for the analysis of SCC service failures and their occurrence in steels, stainless steels, and commercial alloys of aluminum, copper, magnesium, and titanium.

Thermal spray is a generic term for a group of coating processes used to apply metallic, ceramic, cermet, and some polymeric coatings for a broad range of applications. This article provides a brief description of commercially important thermal spray processes, namely, powder-fed flame spray, wire- or rod-fed flame spray, electric arc spray, plasma arc spray, vacuum plasma spray, high-velocity oxyfuel spray, detonation gun deposition, and cold spray, and their advantages. It provides details on the microstructural characteristics of thermal spray coatings. The article also presents information on a wide variety of materials that can be thermal sprayed, such as metals, ceramics, intermetallics, composites, cermets, polymers, and functionally gradient materials. Tables are included, which list the thermal spray processes and coating properties of importance for various industrial applications.

This article addresses the major heat-transfer components of the water-steam loop of a power plant. It describes the various types of condensers, including water-cooled condensers and air-cooled condensers. The article explains the corrosion mechanisms encountered in the condensers, including erosion-corrosion, galvanic corrosion, and pitting corrosion. It discusses the types of deaerators and deals with their corrosion problems. The article provides a discussion on two types of feedwater heaters: channel feedwater heaters and header feedwater heaters. It summarizes the corrosion problems associated with common feedwater heater tube materials.

This article briefly describes water and steam chemistry, which influence the effect of corrosion in boilers. The appropriate control measures to prevent corrosion in boilers are also presented. The article provides a discussion on the common causes of fluid-side corrosion such as flow-accelerated corrosion, oxygen pitting, chelant corrosion, caustic corrosion, acid corrosion, organic corrosion, phosphate corrosion, hydrogen damage, and corrosion-assisted cracking.

This article describes the two critical goals in a failure investigation: damage mechanisms and damage modes. It explains the determination of primary and secondary damage mechanisms and discusses the methodology used to classify the damage mechanisms.