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spectrophotometric detection
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Published: 01 January 1986
Fig. 6 Determination of transition metals using spectrophotometric detection. Wavelength of light used was 520 nm; chromatogram was obtained after a post-column reaction with PAR reagent.
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Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001778
EISBN: 978-1-62708-178-8
... conductivity detection, single-column ion chromatography with conductivity detection, ion chromatography with spectrophotometric detection, and amperometric electrochemical detection. It describes the modes of separation techniques in IC and reversed-phase IC. The article discusses the detection capabilities...
Abstract
Ion chromatography (IC) is an analytical technique that uses columns packed with ion exchange resins to separate ions in aqueous solutions and dynamically elute them to a detector. This article provides information on the different modes of detection, namely, eluent-suppressed conductivity detection, single-column ion chromatography with conductivity detection, ion chromatography with spectrophotometric detection, and amperometric electrochemical detection. It describes the modes of separation techniques in IC and reversed-phase IC. The article discusses the detection capabilities of IC, the procedures for preparing solid and liquid samples, as well as the applications of IC.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006630
EISBN: 978-1-62708-213-6
... detection, spectrophotometric detection, and electrochemical detection. Various separation modes in IC are then described. The article further provides information on various eluents species, analyte range, and sample preparation techniques in IC. It ends by providing information on the instrumentation...
Abstract
This article presents a detailed account of ion chromatography (IC). It begins by describing the principles of common separation modes in IC. This is followed by a section on the different modes of detection, namely suppressed conductivity detection, nonsuppressed conductivity detection, spectrophotometric detection, and electrochemical detection. Various separation modes in IC are then described. The article further provides information on various eluents species, analyte range, and sample preparation techniques in IC. It ends by providing information on the instrumentation and applications and future directions of IC.
Image
Published: 01 January 1986
Fig. 7 Indirect analysis of anions and cations using the same column and spectrophotometric detection. (a) Eluent: phthalate buffer; detector set at 280 nm. (b) Eluent: copper ion; detector set at 215 nm
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Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001731
EISBN: 978-1-62708-178-8
... approximately 185 nm is termed the vacuum ultraviolet; the optical paths for experiments in the vacuum ultraviolet are evacuated or purged with a nonabsorbing gas, such as helium. The long-wavelength low-energy end of the spectral region is defined by the fact that the eye can no longer detect light...
Abstract
Ultraviolet/visible (UV/VIS) absorption spectroscopy is a powerful yet cost-effective tool that is widely used to identify organic compounds and to measure the concentration of principal and trace constituents in liquid, gas, and solid test samples. This article emphasizes the quantitative analysis of elements in metals and metal-bearing ores. The instrumentation required for such applications consists of a light source, a filter or wavelength selector, and some type of visual or automated sensing mechanism. The article examines common sensing options and provides helpful information on how to set up and run a variety of UV/VIS absorption tests.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001777
EISBN: 978-1-62708-178-8
... spectrophotometric and photodiode array detectors, which monitor wavelength regions of interest so that qualitative identification by the spectrum is possible. Ultraviolet/visible detectors are nondestructive, and for a highly absorbing species, the lower limit of detection is about 10 −9 g of a component...
Abstract
This article introduces the fundamental concepts and the essential components of liquid chromatography (LC). It discusses the different modes of LC, such as liquid-solid chromatography, liquid-liquid chromatography, bonded-phase chromatograph, normal-phase chromatography, reversed-phase chromatography, ion-exchange chromatography, ion-pair chromatography, and size-exclusion chromatography. The article also includes a discussion on the qualitative and quantitative analyses and the applications of LC.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006647
EISBN: 978-1-62708-213-6
... or liquid form can be more challenging. The development and use of spectroscopic methods for elemental detection was first introduced by Bunsen and Kirchoff in 1860 with the discovery of cesium and rubidium by using a spectroscope invented in 1859 ( Ref 1 ). In 1934, the work of Lundergårdh demonstrated...
Abstract
This article provides a clear but nonexhaustive description of the general principle of atomic emission, with a particular focus on instrumentation, and summarizes the main characteristics of the inductively coupled plasma optical emission spectrometer technique. Basic atomic theory as well as the instrument characteristics and their influence on the instrument performances are presented. The advantages, drawbacks, and developments of this technique are discussed, and, finally, alternative techniques and examples of applications are provided.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006635
EISBN: 978-1-62708-213-6
... common presumptive tests for detecting anions and cations in aqueous solution. chemical spot testing quality testing presumptive tests Overview Introduction Chemical spot tests, also known as presumptive tests, provide a rapid, simple method for screening samples for the presence...
Abstract
This article presents a summary of the chemical fundamentals, general techniques, limitations, and applications of chemical spot testing as well as a brief overview of innovations and specialized applications. A list of selected reagents, including abbreviated instructions for preparing the reagent solution(s), for performing the spot test, and for interpreting the results, is also included. The article discusses two specialized applications of qualitative analysis, namely illicit drug identification and spacecraft drinking water quality testing. It also contains tables listing common presumptive tests for detecting anions and cations in aqueous solution.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001739
EISBN: 978-1-62708-178-8
..., and their detection limits may be extended to minute concentrations, a classical wet chemical “umpire” procedure still prevails in ultimate accuracy. Therefore, commercial agreements involving high-performance or critical commodities sometimes specify use of certain specific classical wet chemical procedures...
Abstract
This article provides information on basic chemical equilibria, wet analytical chemistry, and the appropriateness of classical wet methods. It focuses on nonoxidizing acids and oxidizing acids. The article includes information on the qualitative methods used to identify materials by wet chemical reaction. Gravimetry, in which a chemical species is weighed; titrimetry, which involves volume measurement of a liquid reactant; and a host of separation techniques, which require diverse forms of laboratory manipulation, are discussed. The article briefly describes the partitioning of oxidation states as well as those applications in surface studies and rapid material identification in which chemical techniques have proved useful.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.9781627081788
EISBN: 978-1-62708-178-8
Series: ASM Handbook
Volume: 17
Publisher: ASM International
Published: 01 August 2018
DOI: 10.31399/asm.hb.v17.a0006466
EISBN: 978-1-62708-190-0
... transducer located beneath the sample, as illustrated in Fig. 1 . Because this ultrasound cannot travel through air (making it an excellent tool for crack, void, and disbond detection), a fluid couplant is used to bring the ultrasound to the sample. Distilled water, spectrophotometric-grade alcohol...
Abstract
This article discusses the fundamentals and operating principles of the following acoustic microscopy methods: scanning laser acoustic microscopy, C-mode scanning acoustic microscopy, and scanning acoustic microscopy. It describes the applications of acoustic microscopy for detecting defects in metals, ceramics, glasses, polymers, and composites with examples.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.9781627082136
EISBN: 978-1-62708-213-6
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006679
EISBN: 978-1-62708-213-6
Abstract
This article describes various methods of electrochemical analysis, namely coulometry, electrogravimetry, voltammetry, electrometric titration, and nanometer electrochemistry. The discussion covers the general uses, sample requirements, application examples, advantages, and limitations of these methods. Some of the factors pertinent to electrochemical cells are also provided. In addition, the article provides information on various potentiometric membrane electrodes used to quantify numerous ionic and nonionic species.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001277
EISBN: 978-1-62708-170-2
Abstract
Painting is a generic term for the application of a thin organic coating to the surface of a material for decorative, protective, or functional purposes. This article provides a detailed account of the types and selection factors of paints and the various application methods, including conventional air atomized, airless, and electrostatic spray; roller coating; dip coating; flow coating; curtain coating; tumble coating; electrocoating; and powder coating. Surface preparation methods and prepaint treatments for coating systems are also discussed. The article includes information on quality control procedures, causes of paint film defects, cost calculation, and safety and environmental precautions. The composition and characteristics of organic coatings, coating system selection factors, the types of paints for structural steel, and the applications of paint on structural steel are also reviewed.