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Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001252
EISBN: 978-1-62708-170-2
... Abstract Electroplated silver is used in both decorative and functional applications, such as engineering and electrical/electronic applications. This article explains the solution formulations and specifications of electrolytes used in silver plating. decorative applications...
Abstract
Electroplated silver is used in both decorative and functional applications, such as engineering and electrical/electronic applications. This article explains the solution formulations and specifications of electrolytes used in silver plating.
Book Chapter
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001261
EISBN: 978-1-62708-170-2
... an absorbent wrapping for applying the solution to the workpiece (cathode). This article focuses on the selective plating systems that include a power pack, plating tools, anode covers, specially formulated plating solutions, and any auxiliary equipment required for the particular application. It provides...
Abstract
Selective plating, also known as brush plating, differs from traditional tank or bath plating in that the workpiece is not immersed in a plating solution (electrolyte). Instead, the electrolyte is brought to the part and applied by a handheld anode or stylus, which incorporates an absorbent wrapping for applying the solution to the workpiece (cathode). This article focuses on the selective plating systems that include a power pack, plating tools, anode covers, specially formulated plating solutions, and any auxiliary equipment required for the particular application. It provides a detailed account of the applications of selective plating, with examples. The article describes the advantages, limitations, key process elements, and health and safety considerations of selective plating. It also includes the most important industrial, government, and military specifications.
Series: ASM Handbook
Volume: 4C
Publisher: ASM International
Published: 09 June 2014
DOI: 10.31399/asm.hb.v04c.a0005892
EISBN: 978-1-62708-167-2
... trade-off curve. The sets Ξ and Φ characterize the solution of a multiobjective problem in the X and Y spaces, respectively; in particular, Φ is the image of Ξ through F . According to the previous definitions, it is possible to give a general formulation for a problem with any number...
Abstract
Optimization plays a key role in the design of any structure or system, and electromagnetic devices are no exception. This article provides a description of the formulation of a design problem, and provides a review of the Paretian optimality. It focuses on nondominating sorting algorithms and multiobjective evolutionary strategy algorithms associated with evolutionary computing. The article provides information on field-based optimization problems. It also discusses the design of the pancake inductor that implies the solution of coupled electromagnetic and thermal fields, along with the use of optimal design procedures, to identify the best possible device or process.
Series: ASM Handbook
Volume: 4C
Publisher: ASM International
Published: 09 June 2014
DOI: 10.31399/asm.hb.v04c.a0005879
EISBN: 978-1-62708-167-2
...- quasi-, or hard coupled formulation. tages. The electrical conductivity of metals perature calculations (see Eq 96 in the article and their alloys heated by induction can vary Electromagnetic Problem Solution and Eq 1 Weak Coupled Formulation greatly with temperature. For induction heating...
Abstract
Induction heating computations deal with a multiphysics problem containing analysis of several coupled physical fields such as electromagnetic, temperature, mechanical, and metallurgical. In order to solve coupled electromagnetic-temperature field problems, it is necessary to develop suitable algorithms and numerical procedures, which make it possible to deal with these nonlinear coupled problems. This article focuses on the most common approaches to coupled electromagnetic and heat transfer problems, namely, weak-, quasi-, and hard-coupled formulations.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001253
EISBN: 978-1-62708-170-2
... took place, the semiconductor industry developed a need for high-purity golds at increased thicknesses. This led to a series of formulations by Ehrheart that plated gold from mild acid solutions. Raising the pH resulted in better covering power and higher current efficiency. At first the hardness...
Abstract
Gold electroplating was invented in 1840. During the first 100 years electrodeposited gold was used primarily for its aesthetic appeal as a decorative finish. This article provides a description of the gold plating process and the electrolytes used. It discusses the decorative and industrial applications of gold plating. The article reviews factors affecting the dragout of gold solution.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006041
EISBN: 978-1-62708-172-6
.... The molecular weight varied significantly, from as low as 2,000 to upward of 80,000 (number average M w = 4000–150,000). The solution-grade resin was studied extensively. It was used in two-component (i.e., 2K) formulations with melamine-formaldehyde resins in bake systems and polyisocyanates in ambient cure...
Abstract
This article provides background information on the chemistry, coating properties, resin types, applications techniques, and performance characteristics of fluoroethylene vinyl ether (FEVE) resins. It describes the formulation methods of FEVE resins, namely, solvent-based coating formulations, water-based coating formulations, and powder coating formulations. The basic concerns to be addressed when formulating and using FEVE coatings are also discussed. The article concludes with a section on health and related safety regulations.
Series: ASM Handbook
Volume: 14B
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v14b.a0005159
EISBN: 978-1-62708-186-3
... at room temperature, but water insoluble at elevated temperatures. This property can be very useful in formulating solutions that are clear in the circulating system but will separate polyglycol and the additive package from solution at the hot tool-workpiece interface. Polyisobutylenes can be made...
Abstract
This article provides an overview of the interfacial interactions with a lubricant film between a die and a metal, lubricant mechanisms, chemistry, qualification testing, application methods, and property test methods. It focuses on sheet metal-forming operations, although the discussions are relevant to metal-forming operations in general. The article also deals with lubricant selection as influenced by the metal to be formed and particular sheet-metal forming operations. The article also discusses some aspects of microbiology and toxicity in lubricants.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001251
EISBN: 978-1-62708-170-2
... … … 2 54 7.25 5.6 0.75 … … 50 6.75 Because the acid and the salt used in the solutions in Table 3 are highly soluble in water, sulfamate baths can be prepared either by adding constituents singly or as formulated salts to water. Solutions are usually formulated to concentrations...
Abstract
Lead has been deposited from a variety of electrolytes, including fluoborates, fluosilicates, sulfamates, and methane sulfonic acid baths. This article provides a discussion on these electrolytic baths and includes information on the process sequence, equipment requirements, and applications of lead plating.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006028
EISBN: 978-1-62708-172-6
... coating integrity and adhesion (e.g., aminopropyltriethoxy silane, Fig. 3 ). Whether applying the alkoxy silanes directly onto a substrate, or formulating a silane-enriched coating, reaction of alkoxy silanes involves four chemical steps ( Fig. 4 ). Initially, hydrolysis of the alkoxy ( X ) groups...
Abstract
This article focuses on those areas of coatings technology where silicon-based technology (SBT) is the primary enabling technology and where SBT is used as an additive to provide unique properties to the coating film. It describes the chemistry and the uses of alkoxy silanes. The uses of silicates, siliconates, silicone fluids, and silicone resins in coatings are reviewed. The article discusses the various applications of SBT, namely, primers, heat-resistant coatings, industrial maintenance coatings, hygienic coatings, and abrasion-resistant coatings, and for marine biofouling control. It also provides information on the benefits of silicon-base additives.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001265
EISBN: 978-1-62708-170-2
... of alkalinity, and the chelate, other important components are present in commercial electroless copper solutions. These components are generally considered the proprietary portion of the formulation, and they control such parameters as initiation and plating rate, stability (versus dragged-in catalyst; versus...
Abstract
Electroless, or autocatalytic, metal plating is a nonelectrolytic method of deposition from solution that can be plated uniformly over all surfaces, regardless of size and shape. The plating's ability to plate onto nonconductors is an advantage that contributes to the choice of electroless copper in various applications. This article provides information on the bath chemistry and deposit properties of electroless copper and discusses the applications of electroless copper plating, such as printed wiring boards, decorative plating-on-plastic, electromagnetic interference shielding, and hybrid and other advanced applications. It describes two commercial processes, pretreatment and post-treatment. The article reviews the solutions used, controls and control equipment, and performance criteria of electroless copper plating. It concludes with information on the environmental and safety issues associated with electroless copper plating.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006652
EISBN: 978-1-62708-213-6
... simple, consisting of just a solvent or chemical reagent, for instance. Alternatively, they can be very complex, consisting of a number of solvents and organic and inorganic materials present in the formulation to meet certain performance requirements. In some solutions, the species and concentrations...
Abstract
This article introduces various analytical techniques commonly used in the characterization of organic solids and liquids and discusses the challenges in performing the analysis, with examples. Some general advice in approaching a material analysis is also provided.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003693
EISBN: 978-1-62708-182-5
... Abstract This article describes the characteristics of zinc-rich coatings that can be subcategorized according to the type of binder material used. It discusses the formulations of zinc-rich coatings with organic binders. The three major groups of inorganic zinc-rich coatings categorized...
Abstract
This article describes the characteristics of zinc-rich coatings that can be subcategorized according to the type of binder material used. It discusses the formulations of zinc-rich coatings with organic binders. The three major groups of inorganic zinc-rich coatings categorized by the Society for Protective Coatings are also discussed. These include postcured water-based alkali metal silicates, self-cured water-based alkali metal silicates, and self-cured solvent-based alkyl silicates. The article concludes with information on comparisons of inorganic with organic zinc-rich coatings.
Series: ASM Handbook
Volume: 22A
Publisher: ASM International
Published: 01 December 2009
DOI: 10.31399/asm.hb.v22a.a0005456
EISBN: 978-1-62708-196-2
... upper bound method metal forming THE GOVERNING RELATIONS OF PLASTICITY used in metal forming are highly nonlinear, with complex boundary conditions. They can only be solved for a limited number of idealized processes with known boundary conditions. Several examples of the ideal solutions...
Abstract
This article focuses on approximate closed-form analytical methods, such as slab and upper bound methods, used for forward and inverse design of metal forming problems. Selected examples of application of these methods to metal forming processes are also discussed.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003699
EISBN: 978-1-62708-182-5
... Abstract The inhibitors currently in use are generally complex mixtures of reaction products and have been formulated to meet the demands of a very competitive industry. This article discusses these demands on inhibitor formulation. The varying characteristics and number of organic inhibitors...
Abstract
The inhibitors currently in use are generally complex mixtures of reaction products and have been formulated to meet the demands of a very competitive industry. This article discusses these demands on inhibitor formulation. The varying characteristics and number of organic inhibitors are explained by the varying characteristics of oil wells and gas wells. Water injection systems and pipelines are also discussed. The article describes the factors that influence the corrosivity of produced fluids and the various treatments applicable for oil, gas, and pumping wells. It examines the primary causes of corrosion inhibition in waterfloods: oxygen contamination and acid gases dissolved in the brine. A discussion on the bacteria-induced corrosion is provided. The article also explains various tests available for field corrosion monitoring. It details the methods used to monitor corrosion rates and inhibitor effectiveness. The article concludes information on the computerization of inhibitor treating programs.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006031
EISBN: 978-1-62708-172-6
..., PVDF-TFE copolymers have been designed for use in solution- and dispersion-based coatings. They have increased flexibility and impact resistance, especially at subzero temperatures. Coatings based on PVDF-TFE copolymers are easily custom formulated and can be applied to a broad range of substrates...
Abstract
Polyvinylidene fluoride (PVDF)-based coatings are typically used in outdoor applications that require exceptionally high performance and excellent long-term exterior durability with little maintenance. This article provides a background of three fluoropolymers most commonly used for coatings, namely, PVDF, polyvinyl fluoride, and polytetrafluoroethylene. It focuses on general properties, polymerization, resin types, coating formulation, technology of organic coatings, coating properties, and health and related safety considerations of PVDF. The article describes the application and typical end uses of PVDF-based coatings and the opportunities for improvement in PVDF-based coatings as with all organic coatings.
Image
in Chromate and Chromate-Free Conversion Coatings
> Corrosion: Fundamentals, Testing, and Protection
Published: 01 January 2003
Fig. 2 Nodular morphologies associated with the nucleation stage of CCC growth. Left, AFM image of a CCC formed on freshly polished 2024-T3 exposed for 1 s to a commercial bath formulation chilled to <5 °C (<40 °F) illustrating nodular CCC morphology. Rapid CCC nucleation on Al-Cu-Fe-Mn
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Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003216
EISBN: 978-1-62708-199-3
... those reduced with boron compounds or hydrazine include lower cost, greater ease of control, and better corrosion resistance of the deposit. Early electroless nickel formulations were ammoniacal and operated at high pH. Later acid solutions were found to have several advantages over alkaline solutions...
Abstract
This article describes the steps, bath composition and characteristics, equipment, plating rate, deposit thickness, and applications for different types of nonelectrolytic deposition processes, including electroless nickel plating, electroless copper plating and mechanical plating.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003692
EISBN: 978-1-62708-182-5
... thermoplastic vinyl solution coatings contain solvents (generally oxygenated solvents such as ketones and glycol ethers) ranging from 75 to 90% of the total volume of the formulated paint. Figure 2 shows an example of a PVC-PVA vinyl. Vinyl solution coatings are noted for their outstanding toughness and water...
Abstract
This article discusses the coating systems categorized by the generic type of binder or resin and grouped according to the curing or hardening mechanism inherent within that generic type. It focuses on the properties, advantages, and limitations of various autooxidative cross-linked resins, thermoplastic resins, and cross-linked thermosetting resins. The autooxidative cross-linked resins include alkyd resins and epoxy esters. The article examines the two types of coatings based on thermoplastic resins: those deposited by evaporation of a solvent, commonly called lacquers, and those deposited by evaporation of water, a class of coatings called water-borne coatings. The coatings that chemically cross link by copolymerization, including epoxies, unsaturated polyesters, urethanes, high-temperature curing silicones, and phenolic linings, are also described.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001245
EISBN: 978-1-62708-170-2
... (45 g/L, or 6 oz/gal). Wetting agents or surfactants , formulated specifically for nickel plating solutions, are almost always added to control pitting. Their function is to lower the surface tension of the plating solution so that air and hydrogen bubbles do not cling to the parts being plated...
Abstract
This article discusses the process considerations and deposit properties of nickel plating. It describes the Watts solution and the anode materials used. The article focuses on the nickel plating processes used for decorative, engineering, and electroforming purposes. It provides information on the quality control of nickel plating. It concludes with a review of the environmental, health, and safety considerations associated with nickel plating.
Series: ASM Handbook
Volume: 4C
Publisher: ASM International
Published: 09 June 2014
DOI: 10.31399/asm.hb.v04c.a0005876
EISBN: 978-1-62708-167-2
... is an example of an integral formulation; another class of integral procedures are the so-called boundary element methods based on applications of Green's integral theorems. While these methods often are difficult to apply, they can produce accurate economic solutions. Static, Time-Dependent, Frequency Domain...
Abstract
Designing of induction heating, or, generally electro technological installations, requires mathematical modeling for solving problems related to various physical phenomena, including electromagnetic (EM), thermal, mechanical, fluidic, and metallurgical fields. This article focuses on the solution of Maxwell's equations (MEs) and provides some basic information regarding the heat transfer and fluid equations, because these physical phenomena usually are strongly coupled to magnetic and electric fields. The solutions are usually obtained by using specific numerical methods such as finite-element method, finite difference method, boundary-element method or volume-integral method, and direct-solution method. The article also discusses the typical structure of commercial codes (preprocessor, solver, and postprocessor) to solve field problems mainly in finite-element method.
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