The formation of defects within additive-manufactured (AM) components is a major concern for critical structural and cyclic load applications. Thus, understanding the mechanisms of defect formation in fusion-based processes is important for prescribing the appropriate process parameters specific to the alloy system and selected processing technique. This article discusses the formation of defects within metal additive manufacturing, namely fusion-based processes and solid-state/sintering processes. Defects observed in fusion-based processes include lack of fusion, keyhole collapse, gas porosity, solidification cracking, solid-state cracking, and surface-connected porosity. The types of defects in solid-state/sintering processes are sintering porosity and improper binder burnout. The article also discusses defect-mitigation strategies, such as postprocess machining, surface treatment, and postprocessing HIP to eliminate defects detrimental to properties from the as-built condition. The use of noncontact thermal, optical, and ultrasound techniques for inspecting AM components are also considered. The final section summarizes the knowledge gap in our understanding of the defects observed within AM components.

Sintering is a thermal treatment process in which a powder or a porous material, already formed into the required shape, is converted into a useful article with the requisite microstructure. Sintering can be classified as solid-state, viscous, liquid-phase, and pressure-assisted (or pressure) sintering. This article provides information on the mechanisms and theoretical analysis of sintering and focuses on the types, mechanisms, process and microstructural variables, computer simulation, stages, and fundamentals of densification and grain growth of solid-state sintering and liquid-phase sintering. It describes the models for viscous sintering and the methods used in pressure-assisted sintering, namely, uniaxial hot pressing, hot isostatic pressing, sinter forging, and spark plasma sintering.

Sintering provides the interparticle bonding that generates the attractive forces needed to hold together the otherwise loose ceramic powder mass. It also improves hardness, strength, transparency, toughness, electrical conductivity, thermal expansion, magnetic saturation, corrosion resistance, and other properties. This article discusses the fundamentals of sintering and its effects on pore structures and particle density. It addresses some of the more common sintering methods, including solid-state, liquid-phase, and gas pressure sintering, and presents alternative processes such as reaction sintering and self-propagating, high-temperature synthesis. It also describes several pressure densification methods, including hot isostatic pressing, gas pressure sintering, molten particle deposition, and sol-gel processing. The article concludes with a section on grain growth that discusses the underlying mechanisms and kinetics and the relationship between grain growth and densification.

The residual porosity in sintered refractory metal ingots is usually eliminated by different densification processes, such as thermomechanical processes. This article focuses on thermomechanical processing of tungsten, molybdenum, and tantalum. It provides an overview of liquid-phase sintering of tungsten heavy alloys and describes the infiltration of tungsten and molybdenum for attaining full density. The article concludes by providing information on hot isostatic pressing of refractory metal alloys to full density.

This article describes part selection, feedstock (powders and binders) characteristics and properties, tool design, and material and tooling for fabrication of metal powder injection molding (MIM) machines. It discusses the process parameters, operation sequence, molding machines, debinding techniques, consolidation (sintering) techniques, advantages, and limitations of MIM.

Power metallurgy (PM) is a process of shaping metal powders into near-net or net shape parts combined with densification or consolidation processes for the development of final material and design properties. This article introduces the general considerations, models, and applications in the modeling of PM processes. It describes the PM process in terms of powder compaction and sintering. The article schematically illustrates powder injection molding for the production of plastic parts and describes PM process models such as discrete-element model (DEM), linear continuum model, and nonlinear continuum model. It concludes with information on the application of press and sinter modeling to practical problems in PM.

This article focuses on four industrial additive manufacturing approaches that are used to create polymer parts. The first section focuses on material extrusion, providing information on lumped-parameter material flow models and higher-fidelity models developed to estimate temperature distribution. The second section covers polymer powder-bed sintering/ fusion, discussing the different levels of scale used to address modeling and the impact of process settings: thermodynamics at the powder-bed surface, consolidation of adjacent particles in the fusion process, and fusion and molecular-level behavior within particles. The third section on vat photopolymerization (VPP) discusses two primary approaches to modeling VPP processes, namely a lumped-parameter approach to estimate cured regions in the vat, known as the Jacobs model, and a high-fidelity, continuum approach that uses finite-element methods. The final section is devoted to material jetting, focusing on simulations used to study droplet generation at the nozzle and droplet impact.

This article focuses on binder-jetting technologies in additive manufacturing (AM) that produce metal artifacts either directly or indirectly. The intent is to focus on the most strategic and widespread uses of the binder jetting technology and review some of the challenges and opportunities for that technology. The discussion includes a historical overview and covers the major steps involved and the advantages of using the binder jetting process. The major steps of the process covered include printing, curing, de-powdering, and sintering.

Additive manufacturing (AM) technologies print three-dimensional (3D) parts through layer-by-layer deposition based on the digital input provided by a computer-aided design file. This article focuses on the binder jet printing process, common biomaterials used in this AM technique, and the clinical applications relevant to these systems. It reviews the challenges and future directions of binder-jetting-based 3D printing.

This article focuses on powder bed fusion (PBF) of ceramics, which has the potential to fabricate functional ceramic parts directly without any binders or post-sintering steps. It presents the results of three oxide ceramic materials, namely silica, zirconia, and alumina, processed using PBF techniques. The article discusses the challenges encountered during PBF of ceramics, including nonuniform ceramic powder layer deposition, laser and powder particle interactions, melting and consolidation mechanisms, optimization of process parameters, and presence of residual stresses in ceramics after processing. The applications of PBF ceramics are also discussed.

This article focuses on various vacuum heat treating processes for additively manufactured parts, namely annealing and stress relieving, solid-solution annealing, and solution treating and aging. It addresses several practical concerns involved in using vacuum heat treatment, including temperature measurement, unvented cavities, loose powder, and direct contact of metals in the high-temperature vacuum. The article provides a short discussion on sintering and evaporation of metals in vacuum furnaces.

Powder metallurgy (PM) has been called a lost art. Long before furnaces were developed that could approach the melting point of metal, PM principles were used. This article provides an overview of the major historical developments of various methods of platinum powder production. The development of production methods took place in various phases starting from prehistoric time, post-war period, to recent and commercial period. The article discusses the powder metallurgy of platinum, as well as the commercial and post-war developments of PM. Literature and trade associations are also discussed.

Sintering atmosphere protects metal parts from the effects of contact with air and provides sufficient conduction and convection for uniform heat transfer to ensure even heating or cooling within various furnace sections, such as preparation, sintering, initial cooling, and final cooling sections. This article provides information on the different zones of these furnace sections. It describes the types of atmospheres used in sintering, namely, endothermic gas, exothermic gas, dissociated ammonia, hydrogen, and vacuum. The article concludes with a discussion on the furnace zoning concept and the problems that arise when these atmospheres are not controlled.

This article characterizes the physical differences between powder metallurgy (PM) and wrought or cast materials, as they apply to joining. It discusses acceptable joining procedures and techniques, including welding and brazing and solid-state methods. Information on the weldability of various PM materials is presented. The article also describes the effects of porosity on several important properties that affect the welding characteristics.

Consolidation and shaping of grade powders is carried out using several methods, depending on the size, complexity, shape, and quantity of parts required. This article details the powder consolidation methods of carbide powders: uniaxial pressing, cold isostatic pressing, extrusion, green machining, and injection molding.

This article discusses metal powder processing via hot isostatic pressing (HIP) and HIP cladding when metal powders are being employed in the cladding process. It traces the history of the process and details the equipment, pressing cycle, and densification mechanisms for HIP. The article describes the available process routes for fabricating products using HIP and the steps involved in the production of a part via direct HIP of encapsulated gas-atomized spherical powder. It concludes with information on the microstructures of 316L stainless steel HIP powder metallurgy valve body and a list of the mechanical properties of several powder metallurgy alloys.

This article is a detailed account of additive manufacturing (AM) processes for copper and copper alloys such as copper-chromium alloys, GRCop, oxide-dispersion-strengthened copper, copper-nickel alloys, copper-tin alloys, copper-zinc alloys, and copper-base shape memory alloys. The AM processes include binder jetting, ultrasonic additive manufacturing, directed-energy deposition, laser powder-bed fusion, and electron beam powder-bed fusion. The article presents a review of the literature and state of the art for copper alloy AM and features data on AM processes and industrial practices, copper alloys used, selected applications, material properties, and where applicable, compares these data and properties to traditionally processed materials. The data presented and the surrounding discussion focus on bulk metallurgical processing of copper components. The discussion covers the composition and performance criteria for copper alloys that have been reported for AM and discusses key differences in process-structure-property relationships compared to conventionally processed material. The article also provides information on feedstock considerations for copper powder handling.