The electronic microcircuit industry has placed severe demands on metal suppliers to provide metals of the highest reproducible purity attainable as a result of the constant quest for the true values of physical and chemical properties of metals. This article describes the commonly used methods for ultrapurification of metals produced by electrolytic processes, including fractional crystallization, zone refining, vacuum melting, distillation, chemical vapor deposition, and solid state refining techniques. In addition, it describes the trace element analysis and resistance-ratio test methods used to characterize purity. Tables list the values for resistance ratios of zone-refined metals and their corresponding chemical compositions, and provide an example of the detection of impurities to concentrations in the parts per billion range, utilizing a combination of the glow discharge mass spectroscopy method and Leco combustion methods.

This article discusses selected highlights of thermodynamic relationships during solidification and nucleation kinetics behavior in connection with the basis of nucleation treatments, such as grain refinement and inoculation, to provide a summary of nucleation phenomena during casting. The article describes nucleation phenomenon such as homogeneous nucleation and heterogeneous nucleation. It examines various grain refinement models, such as the carbide-boride model, the free growth model, and the constitutional undercooling model. The article concludes with information on the thermal analysis techniques for assessing grain-refining characteristics during master alloy processing.

Semisolid metal (SSM) processing, also known as semisolid metal casting, semisolid forming, or semisolid metal forging, is a special die casting process. This article discusses the origin and advantages of the SSM processing. It describes three major semisolid processing routes: thixocasting, rheocasting, and thixomolding.

The majority of currently used additive manufacturing (AM) processes are solidification based (SAM). Another class of AM processes consists of those that rely on deformation (DAM) to place material instead of solidification. Although SAM processes are much more widely used, as research and development continues in DAM processes, they are becoming increasingly attractive, especially for the AM of metals. This article discusses some of the more widely used DAM processes, namely ultrasonic additive manufacturing, cold spray process, and friction stir welding, focusing on their applications, advantages, and limitations.