This article explores the use of the electrochemical and nonelectrochemical techniques for measuring the corrosion behavior of buried metals and the types of probes used. The electrical resistance technique is the main nonelectrochemical technique used for measuring corrosion rate. Electrochemical techniques discussed include linear polarization resistance, electrochemical noise, harmonic distortion analysis, electrochemical impedance spectroscopy, and hydrogen permeation. The principles of operation for the corrosion measuring techniques are described along with examples of their use in soils.

This article discusses the environmental factors and kinetics of atmospheric corrosion, aqueous corrosion, and soil corrosion of carbon steels. It also provides information on corrosion in concrete and steel boilers.

Corrosion of metals is defined as deterioration caused by chemical or electrochemical reaction of the metal with its environment. This article provides information on corrosion of iron and steel by aqueous and nonaqueous media. It discusses the corrosive environments of carbon and alloy steels, namely atmospheric corrosion, soil corrosion, corrosion in fresh water and seawater. The article describes the corrosion process in concrete, which tends to create conditions that increase the rate of attack. The focus is on the stress-corrosion cracking of steels; an environmentally induced crack propagation that results from the combined interaction of mechanical stress and corrosion reactions. The article tabulates a guide on corrosion prevention for carbon steels in various environments. It also discusses protection methods of steel from corrosion, including coatings, such as temporary protection, cleaning, hot dip coating, electroplating, thermal spray coatings, conversion coatings, thin organic coatings, and inhibitors.

This article describes the test methods for evaluating the durability of a metal in soil. It provides useful information on soil characteristics such as soil electrical resistivity, pH value, and soil texture. Specimen design, preparation, burial, and retrieval techniques are discussed. The type of information sought during soil-induced corrosion evaluation controls the design configuration and the nature of the corrosion measurements. Consideration of these factors during the planning stage helps the corrosion engineer to obtain the maximum amount of information with the minimum number of problems.

Steel storage tanks are the primary means for storing large volumes of liquids and gaseous products. The stored fluid could be water, but it could also be volatile, corrosive, and flammable fluid requiring special precautions for storage as well. Corrosion is generally worst where the tank is in contact with the soil. This article describes the soil characteristics and addresses cathodic protection (CP) criteria for submerged metallic piping systems. It provides information on the data required for designing a CP system, alone or in conjunction with a protective coating system. These data are collected from predesign site assessments, tank electrical characteristics, and soil-resistivity measurements. The article addresses NACE Standard RP0169, which gives requirements and desired characteristics for coating in conjunction with CP. It also explains the methods of protecting aboveground storage tanks and underground storage tanks.

This article provides a summary of the concepts discussed in the article under the section "Corrosion Testing and Evaluation" in ASM Handbook, Volume 13A: Corrosion: Fundamentals, Testing, and Protection. This section presents fundamental information on step-by-step instructions for techniques, examples of actual test data, and hints to help in interpretation. The topics covered include planning corrosion tests and evaluating results, laboratory corrosion testing, simulated service corrosion testing, in-service techniques for damage detection and monitoring, and evaluating forms of corrosion.

Alkaline cleaning is a commonly used method for removing a wide variety of soils from the surface of metals. This article focuses on the composition, operating conditions, and test and control of alkaline cleaners, as well as equipment used and their application methods. It describes the mechanisms of alkaline cleaning, such as saponification, displacement, emulsification and dispersion, and metal oxide dissolution. The article concludes with information of the safety and environmental considerations in the usage of alkaline cleaners.

This article provides information on predesign surveys and the various testing procedures associated with wastewater treatment plants. These include soil testing, atmospheric testing, and hydrogen sulfide testing. The primary parameters that influence the production of sulfides within the piping system that transports the wastewater to the treatment facility are discussed. The article describes the corrosion performance of various materials in the soil, fluid, and atmospheric exposures. These include concrete, steel, ductile iron, aluminum, copper, brass, stainless steel, and coatings used for wastewater facilities.

This article describes the mechanisms of differential corrosion cells corrosion, microbiologically influenced corrosion, and stray direct current corrosion. It discusses the most common causes and contributing factors for corrosion and stress-corrosion cracking, as well as prevention, mitigation, detection, and repair processes.