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sodium silicates
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Book Chapter
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005354
EISBN: 978-1-62708-187-0
... in handling sand-resin mixtures for no-bake molds or cones and lists some advantages of no-bake air-set cores and molds. The article describes the process procedures, advantages, and disadvantages of gas curing and air-setting hardening of sodium silicates. It examines the members of the air-setting organic...
Abstract
No-bake sand molds are based on the curing of inorganic or organic binders with either gaseous catalysts or liquid catalysts. This article reviews the major aspects of no-bake sand bonding in terms of coremaking, molding methods, and sand processing. It discusses the points to be noted in handling sand-resin mixtures for no-bake molds or cones and lists some advantages of no-bake air-set cores and molds. The article describes the process procedures, advantages, and disadvantages of gas curing and air-setting hardening of sodium silicates. It examines the members of the air-setting organic binders, namely, furan no-bake resins, phenolic no-bake resins, and urethanes. The article provides an overview of gas-cured organic binders. It also illustrates the three commercial systems for sand reclamation: wet reclamation systems, dry reclamation systems, and thermal reclamation.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003172
EISBN: 978-1-62708-199-3
..., dry sand molds, resin-bonded sand molds, and sodium silicate bonded sand. The article describes the casting processes that use these molds, including the no-bake process, cold box process, hot box process, the CO2 process, lost foam casting process and vacuum molding process. The casting processes...
Abstract
This article discusses classification of foundry processes based on the molding medium, such as sand molds, ceramic molds, and metallic molds. Sand molds can be briefly classified into two types: bonded sand molds, and unbonded sand molds. Bonded sand molds include green sand molds, dry sand molds, resin-bonded sand molds, and sodium silicate bonded sand. The article describes the casting processes that use these molds, including the no-bake process, cold box process, hot box process, the CO2 process, lost foam casting process and vacuum molding process. The casting processes that use ceramic molds include investment casting, and plaster casting. Metallic molds are used in permanent mold casting, die casting, semisolid casting, and centrifugal casting.
Image
Published: 01 November 1995
Fig. 3 Effect of sodium-oxide concentration on the electrical conductivity of sodium-silicate glasses
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Image
Published: 01 December 2008
Fig. 2 Effect of various additives on hot strength and retained strength of sand bonded with sodium silicate
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Image
Published: 01 December 2008
Fig. 3 Effect of gassing time on the strength of cores. Data based on gassing cores made from sand mixed with 3.3% sodium silicate, 1.7% aluminum oxide, 1.7% kaolin clay, 2% invert sugar
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Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003693
EISBN: 978-1-62708-182-5
..., the curing solution may not be necessary. The earliest postcured zinc-rich coatings were based on a sodium silicate vehicle, and the most popular commercial products available have essentially the same chemistry. There are other inorganic zinc-rich coatings based on lithium or potassium silicates...
Abstract
This article describes the characteristics of zinc-rich coatings that can be subcategorized according to the type of binder material used. It discusses the formulations of zinc-rich coatings with organic binders. The three major groups of inorganic zinc-rich coatings categorized by the Society for Protective Coatings are also discussed. These include postcured water-based alkali metal silicates, self-cured water-based alkali metal silicates, and self-cured solvent-based alkyl silicates. The article concludes with information on comparisons of inorganic with organic zinc-rich coatings.
Image
Published: 31 August 2017
Fig. 8 Effect of surface condition and nodularity on fatigue properties of CG iron plates (8 mm, or 0.3 in.) cast in sodium silicate sand. AC, as-cast; M, machined. (a) S - N curves for 15% nodularity. (b) S - N curves for 40% nodularity. (c) Effect of nodularity on the skin factor. Source
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Image
Published: 01 December 2004
Fig. 16 Effect of sodium modification on microstructure of sand-cast aluminum-silicon hypoeutectic alloy 356-F. Both specimens were etched in 0.5% hydrofluoric acid and are shown at 100×. (a) As-cast structure in unmodified alloy consists of a network of silicon particles (sharp gray), which
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Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005242
EISBN: 978-1-62708-187-0
... be obtained with thermosetting silicates (warm box, Table 1 ) and self-setting (no-bake) inorganic compounds such as sodium-silicates, aluminates (cement), and phosphates ( Table 1 ). Comparison of mold and binder system characteristics Table 1 Comparison of mold and binder system characteristics...
Abstract
This article reviews the basic types of mold aggregates and bonding methods for expendable molds and coremaking. It provides an overview of mold media and the basic types of sands and their properties. The most significant clays used in green sand operations, such as bentonites, are discussed. The article describes the methods of sand bonding with inorganic compounds. It provides a description of resin-bonded sand systems: no-bake binder systems, heat-cured binder systems, and cold box binder systems. The article concludes with a discussion on the media used for expendable molds, namely, ceramic shells and rammed graphite, for casting reactive metals such as titanium or zirconium.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006049
EISBN: 978-1-62708-172-6
... Charles John Nightingall of Victoria, Australia, began to develop a zinc-rich product based on a sodium silicate binder. His developments led to an Australian patent, dated March 20, 1937 ( Ref 3 ), and British patent 505,710 in May 1939. He applied for another patent on September 26, 1940, which...
Abstract
The use of zinc in corrosion-protective coatings is due to its higher galvanic activity relative to that of steel. Pure zinc dust provides the best sacrificial protection to steel in a galvanic couple. Zinc-rich coatings can be subcategorized according to the type of binder material used, namely, inorganic and organic zinc-rich coatings. Common inorganic binders such as post-cured water-based alkali metal silicates, self-cured water-based alkali metal silicates, and self-cured solvent-based alkyl silicates, are reviewed. The article also compares inorganic and organic zinc-rich coatings, and discusses the concerns regarding zinc-rich coatings.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006297
EISBN: 978-1-62708-179-5
... hardness. In Europe, where calcium bentonite is available only naturally, soda ash also is used to convert it to sodium bentonite ( Ref 1 , 17 ). Special additives, such as iron oxide or fly ash, chemically react with silica sand at high temperatures, forming viscous semiliquid silicates...
Abstract
Aggregate molding, or sand casting, is the gravity pouring of liquid metal into a mold that is made of a mixture molded against a permanent pattern. This article summarizes the most important materials in the process of sand casting of cast iron, including different types of molding aggregates, clays, water, and additives in green sand, chemically bonded organic resins, and inorganic binders in self-setting, thermosetting, and gas-triggered systems. It discusses three main types of reclamation systems: wet, dry, and thermal. The article concludes with a description of both nonpermanent and permanent mold processes.
Image
Published: 01 January 1994
1.5 (15) (e) 2.5 (25) (f) Terminating voltage, V For normal thickness 320 320 For heavy coatings 350–380 350–380 Treatment time, min 12–15 12–15 Sealing post-treatment (g) Solution, vol% sodium silicate (42° Bé) 10 Temperature, °C (°F) 85–100 (185–212
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Book Chapter
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003684
EISBN: 978-1-62708-182-5
... the years with growing technology to meet industry needs. The first silicate cements were composed of a sodium silicate (Na 2 SiO 3 ) liquid and a combination of fillers, such as silica flour, clay, silica aggregates, and barytes, and were formulated as chemical-resistant mortars for use in ambient or high...
Abstract
Inorganic chemical-setting ceramic linings are one of the most widely used construction materials in designing the protective linings for industrial installations. Monolithic linings can be applied by cast or gunite (shotcreting) methods over steel or concrete as well as brick and mortar masonry. This article provides a discussion on the function of monolithic linings, the advantages of these materials, the types of applications in which these materials can be successfully used, and the limitations of these linings. It describes the application procedures that should be followed to ensure proper installation of a dual-lining system. The industrial applications that illustrate the corrosion resistance and some uses of monolithic linings, as well as other applications in wastewater treatment systems and the chemical industry, are discussed.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003066
EISBN: 978-1-62708-200-6
... with the atomic mass of the added ion. Although sodium-silicate glasses are significantly more dense than the corresponding lithium-silicate glasses, potassium-silicate glasses have densities that are almost identical to those of the corresponding sodium-silicate glasses. The densities of the alkali-borate...
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006313
EISBN: 978-1-62708-179-5
... Effect of surface condition and nodularity on fatigue properties of CG iron plates (8 mm, or 0.3 in.) cast in sodium silicate sand. AC, as-cast; M, machined. (a) S - N curves for 15% nodularity. (b) S - N curves for 40% nodularity. (c) Effect of nodularity on the skin factor. Source: Ref 12...
Abstract
The appearance, morphology, and extent of the casting skin are the consequence of mold-metal interface interaction. This article discusses the classification of the mold-metal interaction based on severity: mild mold-metal interaction and severe mold-metal interaction. The casting surface exhibits some roughness, which depends on the molding materials used in the casting process. The article describes the effects of the casting skin in spheroidal graphite (SG) and compact graphite (CG) irons, as well as the mechanism of casting skin formation. It discusses the physics of liquid metal penetration in sand molds and concludes with information on the effect of sand additives and mold coatings.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001339
EISBN: 978-1-62708-173-3
.... These low-hydrogen binders include sodium silicate and potassium silicate. The second type of binding agent does function as a hydrogen source. The binders used for high-hydrogen electrodes can be organic in nature and include gum arabic, sugar, dextrine, and other specialized synthetic organic binders...
Abstract
Fluxes are added to the welding environment to improve arc stability, to provide a slag, to add alloying elements, and to refine the weld pool. This article describes the effect of oxygen that directly reacts with alloying elements to alter their effective role by reducing hardenability, promoting porosity, and producing inclusions. It proposes basicity index for welding as a measure of expected weld metal cleanliness and mechanical properties. The article discusses alloy modification in terms of slipping and binding agents, slag formation, and slag detachability. It reviews the types of fluxes for different arc welding processes, such as shielded metal arc welding (SMAW), flux-cored arc welding (FCAW), and submerged arc welding (SAW).
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005255
EISBN: 978-1-62708-187-0
... Yttria is now being used in forecoats for casting titanium and certain nickel-base superalloys that contain yttrium. Binders The commonly used binders are also siliceous and include colloidal silica, hydrolyzed ethyl silicate, and sodium silicate. Hybrid binders have also been developed...
Abstract
This article reviews the pattern materials used in investment casting, which can be loosely grouped into waxes and plastics. The patternmaking process, pattern tooling, and pattern and cluster assembly are described. The article also describes the manufacture of ceramic shell molds and cores, detailing the binders and other materials used, as well as the formulation and control of slurries. Methods for pattern removal, mold firing, melting, casting, postcasting treatment, and inspection are explained. After presenting design recommendations for investment castings, the article concludes with information on applications and special versions of the investment casting process.
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Published: 15 January 2021
Fig. 32 Effect of sea salt (SS) and sodium sulfate mixture on calcium-magnesium-alumino-silicate (CMAS) melting temperature in tests conducted in ambient air. Courtesy of U.S. Navy
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Book Chapter
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001308
EISBN: 978-1-62708-170-2
... or greases, but not mineral oils or greases. Therefore, they can sometimes remove fresh buffing compounds and the lard oils used in spinning operations. Nonetching cleaners can be classified as either silicated or nonsilicated. The silicated cleaners are based on aqueous solutions of sodium carbonate...
Abstract
Aluminum or aluminum alloy products have various types of finishes applied to their surfaces to enhance appearance or improve functional properties. This article discusses the procedures, considerations, and applications of various methods employed in the cleaning, finishing, and coating of aluminum. These include abrasive blast cleaning, barrel finishing, polishing, buffing, satin finishing, chemical cleaning, chemical brightening, electrolytic brightening, chemical etching, alkaline etching, acid etching, chemical conversion coating, electroplating, immersion plating, electroless plating, porcelain enameling, and shot peening.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005249
EISBN: 978-1-62708-187-0
... Ingredient Weight kg lb Washed silica sand (AFS 50 is typical) 20.0 45 White molding plaster 18.6 41 Ceramic talc 3.6 8.0 Portland cement 0.2 0.4 Sodium silicate 0.4 0.8 Western benonite 1.1 2.5 Terra alba 1.5 3.4 Note: Slurry is made by mixing 45 kg (100 lb...
Abstract
This article discusses slurry molding that encompasses two distinct processes: plaster molding and ceramic molding. Plaster mold casting is a specialized casting process used to produce nonferrous castings that have greater dimensional accuracy, smoother surfaces, and more finely reproduced detail. The article describes three generally recognized plaster mold processes, namely, conventional plaster mold casting, the Antioch process, and the foamed plaster process. Ceramic molding techniques are based on processes that employ permanent patterns and fine-grained zircon and calcined, high-alumina mullite slurries for molding. The Shaw process and the proprietary Unicast processes are also discussed.
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