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Book Chapter
Corrosion in Semiconductor Wafer Fabrication
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004171
EISBN: 978-1-62708-184-9
... that the factors outside the normal processing of wafers or tool-specific problems can contribute to metal-line corrosion. corrosion semiconductor wafer fabrication batch metal-etch systems single-wafer metal-etch systems metal-line corrosion THE MICROELECTRONICS INDUSTRY is one of the fastest...
Abstract
This article presents a detailed examination of corrosion at the various production stages of wafer fabrication. The corrosion issues related to batch metal-etch systems and single-wafer metal-etch systems are also discussed. The article provides a case study, which illustrates that the factors outside the normal processing of wafers or tool-specific problems can contribute to metal-line corrosion.
Book Chapter
Semiconductor Characterization
Available to PurchaseSeries: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006670
EISBN: 978-1-62708-213-6
..., fabrication methods, sample preparation, bulk/elemental characterization methods, microstructural characterization methods, surface characterization methods, and electronic characterization methods. semiconductor characterization Introduction This article introduces various techniques commonly...
Abstract
This article introduces various techniques commonly used in the characterization of semiconductors, namely single-crystal, polycrystalline, amorphous, oxide, organic, and low-dimensional semiconductors and semiconductor devices. The discussion covers material classification, fabrication methods, sample preparation, bulk/elemental characterization methods, microstructural characterization methods, surface characterization methods, and electronic characterization methods.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001091
EISBN: 978-1-62708-162-7
... silicon fabrication. It is much more difficult to grow a single-crystal ingot from two elements than it is from one, especially when the arsenic tends to diffuse out of the melt a temperatures lower than those required for GaAs crystal growth. Consequently, GaAs wafers have more imperfections...
Abstract
Gallium-base components can be found in a variety of products ranging from compact disk players to advanced military electronic warfare systems, owing to the factor that it can emit light, has a greater resistance to radiation and operates at faster speeds and higher temperatures. This article discusses the uses of gallium in optoelectronic devices and integrated circuits and applications of gallium. The article discusses the properties and grades of gallium arsenide and also provides information on resources of gallium. The article talks about the recovery techniques, including recovery from bauxite, zinc ore and secondary recovery process and purification. The article briefly describes the fabrication process of gallium arsenide crystals. Furthermore, the article gives a short note on world supply and demand of gallium and concludes with research and development on gallium arsenide integrated circuits.
Book Chapter
Plasma-Enhanced Chemical Vapor Deposition
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001285
EISBN: 978-1-62708-170-2
... fabrication, the surface needs to be planarized at some point before the next processing step. One method involves depositing the PECVD oxide film over the processed wafer, followed by deposition and flow of photoresist. The photoresist and the oxide films are then dry etched. The etch rate of the PECVD oxide...
Abstract
This article discusses the application of amorphous and crystalline films through plasma-enhanced chemical vapor deposition (PECVD) from the view point of microelectronic device fabrication. It describes the various types of PECVD reactors and deposition techniques. Plasma enhancement of the CVD process is discussed briefly. The article also describes the properties of amorphous and crystalline films deposited by the PECVD process for integrated circuit fabrication.
Book Chapter
Inductively Coupled Plasma Mass Spectrometry
Available to PurchaseSeries: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006641
EISBN: 978-1-62708-213-6
...-silicon or silicon-hydrogen bonds. Real-world silicon wafer surfaces are often covered with an oxide layer trapped with various particles (metallic and ionic) and contaminants, which must be removed through various surface-cleaning processes prior to semiconductor device fabrication. Cleaning...
Abstract
This article discusses the basic principles of inductively coupled plasma mass spectrometry (ICP-MS), covering different instruments used for performing ICP-MS analysis. The instruments covered include the sample-introduction system, ICP ion source, mass analyzer, and ion detector. Emphasis is placed on ICP-MS applications in the semiconductor, photovoltaic, materials science, and other electronics and high-technology areas.
Book Chapter
Chemical-Mechanical Planarization for Semiconductors
Available to PurchaseSeries: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003600
EISBN: 978-1-62708-182-5
... of CMP through a schematic illustration of CMP process equipment. The applications of CMP to tungsten and copper alloys are of prime interest in the semiconductor industry. The article discusses copper CMP and tungsten CMP in detail and analyzes polishing mechanism during CMP by application of direct...
Abstract
Chemical-mechanical planarization (CMP) of metals is described as mechanically accelerated corrosion, erosion corrosion, or metallic corrosion enhanced by wear. This article reviews the history, process, chemistry, electrochemistry, and defect issues for CMP. It provides an overview of CMP through a schematic illustration of CMP process equipment. The applications of CMP to tungsten and copper alloys are of prime interest in the semiconductor industry. The article discusses copper CMP and tungsten CMP in detail and analyzes polishing mechanism during CMP by application of direct current potentiodynamic polarization and alternating current impedance measurements. It concludes with information on chemically induced defects such as pitting corrosion, galvanic corrosion, and chemical etching.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006644
EISBN: 978-1-62708-213-6
.../precipitates, stacking faults, growth-sector boundaries, twins, and low-angle grain boundaries, as well as other lattice distortions in crystalline materials of a wide range of chemical compositions and physical properties, such as semiconductors, oxides, metals, and organic materials. The complete name x-ray...
Abstract
X-ray topography is the general term for a family of x-ray diffraction imaging techniques capable of providing information on the nature and distribution of imperfections. This article provides a detailed account of x-ray topography techniques, providing information on the historical background and development trends in x-ray diffraction topography. The discussion covers the general principles, components of systems, and applications of x-ray topography techniques, namely conventional X-ray topographic techniques and synchrotron x-ray topographic techniques.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006658
EISBN: 978-1-62708-213-6
.... However, there are many special situations in which larger samples must be investigated. These include stages for the following applications: Semiconductor wafers: There are several applications in the semiconductor industry that require AFM scanning on structures located on a semiconductor wafer...
Abstract
This article focuses on laboratory atomic force microscopes (AFMs) used in ambient air and liquid environments. It begins with a discussion on the origin of AFM and development trends occurring in AFM. This is followed by a section on the general principles of AFM and a comprehensive list of AFM scanning modes. There is a brief description of how each mode works and what types of applications can be made with each mode. Some of the processes involved in preparation of samples (bulk materials and those placed on a substrate) scanned in an AFM are then presented. The article provides information on the factors applicable to the accuracy and precision of AFM measurements. It ends by discussing the applications for AFMs in the fields of science, technology, and engineering.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004170
EISBN: 978-1-62708-184-9
... susceptible to fine airborne particles with aerodynamic diameters of 0.05∼2 μm (0.002∼0.08 mil) ( Ref 34 , 35 , 36 ). These fine particles are rich in ammonium acid sulfate and are difficult to remove by filtration. See the article “Corrosion in Semiconductor Wafer Fabrication” in this Volume. Storage...
Abstract
This article discusses the influence of the materials, design, package type, and environment on corrosion in microelectronics. It describes the common sources and mechanisms of corrosion in microelectronics, including anodic, cathodic, and electrolytic reactions resulting in uniform corrosion, galvanic corrosion, pitting corrosion, creep corrosion, dendrite growth, fretting, stress-corrosion cracking, and whisker growth. The article presents effective measures for minimizing the moisture retention in hermetic packages and/or moisture ingress in plastic packages. It concludes with information corrosion tests.
Book Chapter
Thermal Spray Coatings for Electrical and Electronic Applications
Available to PurchaseBook: Thermal Spray Technology
Series: ASM Handbook
Volume: 5A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v05a.a0005736
EISBN: 978-1-62708-171-9
... and their cost advantage also have attracted the attention of the thin-film (PVD and CVD) community toward thermal spray technology. In recent years, thermal spray processing increasingly has been used to support thin-film processes involved in the fabrication of semiconductor electronics and other related...
Abstract
Thermal spray processes involve complete or partial melting of a feedstock material in a high-temperature flame, and propelling and depositing the material as a coating on a substrate. This article describes the properties of sprayed electronic materials, including dielectrics, conductors, and resistors, and discusses their implications and associated limitations for device applications and potential remedial measures. The article presents specific examples of electrical/electronic device applications, including electromagnetic interference/radio-frequency interference shielding, planar microwave devices, waveguide devices, sensing devices, solid oxide fuel cells, heating elements, electrodes for capacitors and other electrochemical devices.
Book Chapter
Corrosion in the Assembly of Semiconductor Integrated Circuits
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004172
EISBN: 978-1-62708-184-9
... Abstract In a typical semiconductor integrated circuits (SICs) component, corrosion may be observed at the chip level and at the termination area of the lead frames that are plated with a solderable metal or alloy, such as tin and tin-lead alloys that are susceptible to corrosion. This article...
Abstract
In a typical semiconductor integrated circuits (SICs) component, corrosion may be observed at the chip level and at the termination area of the lead frames that are plated with a solderable metal or alloy, such as tin and tin-lead alloys that are susceptible to corrosion. This article focuses on the key factors contributing to corrosion of electronic components, namely, chemicals (salts containing halides, sulfides, acids, and alkalis), temperature, air (polluted air), moisture, contact between dissimilar metals in a wet condition, applied potential differences, and stress. It discusses the chip corrosion and oxidation of tin and tin-lead alloys (solders) in SIC. The article also addresses the corrosion of the device terminations resulting in lead (termination) tarnishing that are caused by various factors, including galvanic corrosion, chemical residues, base metal migration and plating additives.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001292
EISBN: 978-1-62708-170-2
... the 1970s to introduce dopant atoms reproducibly into silicon wafers to modify electrical performance, and it is used routinely in several stages of integrated circuit production. It allows fabrication of electronic devices not producible by any other process, largely due to the highly reproducible control...
Abstract
Ion implantation involves the bombardment of a solid material with medium-to-high-energy ionized atoms and offers the ability to alloy virtually any elemental species into the near-surface region of any substrate. This article describes the fundamentals of the ion implantation process and discusses the advantages, limitations, and applications of ion implantation. It also reviews a typical medium current semiconductor implanter adapted for implantation of metals with the aid of illustrations.
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006394
EISBN: 978-1-62708-192-4
... in the past 30 years as an essential technology for planar and defect-free surfaces of microelectrical semiconductor devices such as the submicron integrated circuit ( Ref 51 , 52 , 53 ). Present challenges in the field include the CMP of patterned copper wafers ( Ref 54 ), multifilm layers ( Ref 55...
Abstract
Current understanding of polishing wear involves a combination of abrasive, plastic flow, and tribochemical wear. This article explains these mechanisms and the correlation between them. Some explanations about practical polishing wear control, applications, and future prospects are also given. This article discusses the influence of size and number of wear particles on polishing at three abrasive wear modes. These include cutting, wedge forming, and plowing. The article concludes with information on applications and prospects of polishing wear control.
Book Chapter
Ultrasonic and Thermal Metal Embedding for Polymer Additive Manufacturing
Available to PurchaseSeries: ASM Handbook
Volume: 24
Publisher: ASM International
Published: 15 June 2020
DOI: 10.31399/asm.hb.v24.a0006558
EISBN: 978-1-62708-290-7
... by the width to determine the squares, and multiply the result by the sheet resistance. Sheet resistance is well suited for semiconductor electronics because the resistance depth profiles in silicon wafers can be simplified to a single sheet resistance reported in ohms per square. However, conductive inks...
Abstract
This article provides an overview of the implementation of wire embedding with ultrasonic energy and thermal embedding for polymer additive manufacturing, discussing the applications and advantages of the technique. The mechanical and electrical performance of the embedded wires is compared with that of other conductive ink processes in terms of electrical conductivity and mechanical strength.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001090
EISBN: 978-1-62708-162-7
... 1960s. The use of germanium as a semiconductor substrate deserves special mention. In this application, single-crystal wafers of germanium are used as substrates for the epitaxial deposition of gallium arsenide (GaAs) or gallium arsenide phosphide (GaAsP) for use as light-emitting diodes or solar...
Abstract
Germanium is a semiconducting metalloid element found in Group IV A. Germanium is used in the field of electronics, infrared optics, and in the fields of gamma ray spectroscopy, catalysis, and fiber optics. This article discusses the sources, manufacturing, and processing of germanium, and focuses on the chemical properties of various germanium compounds, including germanium halides, germanates, germanides, germanes, inorganic, and organogermanium compounds. It also tabulates the physical, thermal, electronic, and optical properties of germanium, and explains the economical aspects and specifications of germanium. The article describes the analytical and test methods of germanium, including gravimetric method, titrimetric method, and spectral method. It provides a short note on toxicology, and concludes with the uses of germanium in different fields.
Book Chapter
Film Thickness Measurements Using Optical Techniques
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001295
EISBN: 978-1-62708-170-2
... of the photomultiplier, the laser, and the desktop computer have greatly enhanced the use of this technique to the point that it is now routinely used as a metrology tool in semiconductor wafer manufacturing. Instrumentation Figure 4 shows the basic requirements for SWE. The figure shows the arrangement...
Abstract
Measuring the thickness of thin films can be accomplished in many ways. This article focuses on the optical method of single-wavelength ellipsometry, two multiple-wavelength methods of reflectometry and spectroscopic ellipsometry for measuring the thickness of thin films. The general capabilities, principles and applications of ellipsometry and reflectometry are discussed in terms of nondestructive methods.
Book Chapter
Properties and Selection of Powder Metallurgy Refractory Metals
Available to PurchaseBook: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006123
EISBN: 978-1-62708-175-7
... layers between silicon semiconductor wafers and copper conductors in integrated circuits. Diffusion barriers are typically 2 to 3 nm thick and are deposited by magnetron sputtering using either PM or ingot metallurgical (IM) tantalum targets. Some 80 to 90% of tantalum powders for capacitor...
Abstract
This article focuses on the selection, properties, and applications of powder metallurgy refractory metals and their alloys, including tungsten, molybdenum, tantalum, niobium, and rhenium.
Book Chapter
Electrical/Electronic Applications for Advanced Ceramics
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003062
EISBN: 978-1-62708-200-6
.... Tubular SOFCs, the design most intensively studied, offer the potential for less complex gas manifolding but with more complex cell fabrication. The SOFC relies on transport of oxygen ions through a dense ceramic electrolyte. In operation, oxygen (in air) is fed to the cathode (porous perovskite...
Abstract
Ceramic materials serve important insulative, capacitive, conductive, resistive, sensor, electrooptic, and magnetic functions in a wide variety of electrical and electronic circuitry. This article focuses on various applications of advanced ceramics in both electric power and electronics industry, namely, dielectric, piezoelectric, ferroelectric, sensing, magnetic and superconducting devices.
Book Chapter
Chemical Vapor Deposition of Semiconductor Materials
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001284
EISBN: 978-1-62708-170-2
..., such as scrubbing systems, particle filters, and burn boxes. Effluent Scrubbing Systems The semiconductor wafer fabrication industry uses a variety of corrosive, toxic, pyrophoric, and flammable chemicals. In order to control pollution by toxic materials, different types of scrubbers are used. In the past...
Abstract
This article describes the vapor-phase growth techniques applied to the epitaxial deposition of semiconductor films and discusses the fundamental processes involved in metal-organic chemical vapor deposition (MOCVD). It reviews the thermodynamics that determine the driving force behind the overall growth process and the kinetics that define the rates at which the various processes occur. The article provides information on the reactor systems and hardware, MOCVD starting materials, engineering considerations that optimize growth, and the growth parameters for a variety of Group III-V, II-VI, and IV semiconductors.
Book Chapter
Thermal Management and Electronic Packaging Applications
Available to PurchaseBook: Composites
Series: ASM Handbook Archive
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003480
EISBN: 978-1-62708-195-5
... strength and stiffness Reduced thermal stresses Increased reliability Simplified thermal design Potential elimination of heat pipes Low cost, net-shape fabrication processes Potential cost reductions Composites are in a state of continual development that undoubtedly will result...
Abstract
This article presents an overview of advanced composites, namely, polymer matrix composites, metal-matrix composites, ceramic-matrix composites, and carbon-matrix composites. It also provides information on the properties and applications of the composites in thermal management and electronic packaging.
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