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Aging sequence in 7050. (a) Initial Guinier-Preston (GP) zone formation. (b...
Available to PurchasePublished: 01 June 2016
Fig. 32 Aging sequence in 7050. (a) Initial Guinier-Preston (GP) zone formation. (b) GP zone present and formation of semi-incoherent η′. (c) Semi-incoherent η′ and formation of coherent equilibrium precipitate η. (d) Precipitation of equilibrium precipitate η. Source: Ref 57
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Book Chapter
Metallurgy of Heat Treatable Aluminum Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006287
EISBN: 978-1-62708-169-6
... aluminum alloys include: Aluminum-copper systems, with strengthening from coherent and transition precipitates prior to the formation of the equilibrium intermetallic CuAl 2 (2 xxx and 2 xx.x alloy series) Al-Cu-Mg systems, in which magnesium intensifies precipitation hardening with CuAl 2...
Abstract
This article describes the general categories and metallurgy of heat treatable aluminum alloys. It briefly reviews the key impurities and each of the principal alloying elements in aluminum alloys, namely, copper, magnesium, manganese, silicon, zinc, iron, lithium, titanium, boron, zirconium, chromium, vanadium, scandium, nickel, tin, and bismuth. The article discusses the secondary phases in aluminum alloys, namely, nonmetallic inclusions, porosity, primary particles, constituent particles, dispersoids, precipitates, grain and dislocation structure, and crystallographic texture. It also discusses the mechanisms used for strengthening aluminum alloys, including solid-solution hardening, grain-size strengthening, work or strain hardening, and precipitation hardening. The process of precipitation hardening involves solution heat treatment, quenching, and subsequent aging of the as-quenched supersaturated solid solution. The article briefly discusses these processes of precipitation hardening. It also reviews precipitation in various alloy systems, including 2xxx, 6xxx, 7xxx, aluminum-lithium, and Al-Mg-Li systems.
Series: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006268
EISBN: 978-1-62708-169-6
... of reversion, duplex annealing, and retrogression and re-aging are included. age hardening aging alloying aluminum alloys coherent precipitates precipitate-free zones semi-coherent precipitates ternary phase diagrams AGE HARDENING (or just aging) is the final step of the entire hardening...
Abstract
This article describes the effects of alloying and heat treatment on the metastable transition precipitates that occur in age hardenable aluminum alloys. Early precipitation stages are less well understood than later ones. This article details the aging sequence and characteristics of precipitates that occur in the natural aging and artificial aging of Al-Mg-Si-(Cu) alloys, Al-Mg-Cu alloys, microalloyed Al-Mg-Cu-(Ag, Si) alloys, aluminum-lithium-base alloys, and Al-Zn-Mg-(Cu) alloys. Crystal structure, composition, dimensions, and aging conditions of precipitates are detailed. Effects of reversion, duplex annealing, and retrogression and re-aging are included.
Book Chapter
Heat Treatable Nonferrous Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006274
EISBN: 978-1-62708-169-6
.... If this step is done properly, the precipitates can result in significant hardening of the alloy. In some cases, the precipitates are even coherent with the crystal matrix of the parent metal (see also the article “Principles of Heat Treating of Nonferrous Alloys” in this Volume). Although the aging process...
Abstract
This article describes the different types of precipitation and transformation processes and their effects that can occur during heat treatment of various nonferrous alloys. The nonferrous alloys are aluminum alloys, copper alloys, magnesium alloys, nickel alloys, titanium alloys, cobalt alloys, zinc alloys, and heat treatable silver alloys, gold alloys, lead alloys, and tin alloys. It also provides a detailed discussion on the effects due to precipitation and transformation processes in these non-ferrous alloys.
Book Chapter
Heat Treating of Copper and Copper Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006276
EISBN: 978-1-62708-169-6
...% Co (or up to 2.2% Ni). They are solution heat treated in the range 760 to 955 °C (1400 to 1750 °F) and age hardened to produce the beryllium-rich coherent precipitates when aged in the range 260 to 565 °C (500 to 1050 °F), the specific temperature being chosen for the particular alloy and desired...
Abstract
This article provides information on the Unified Numbering System designations and temper designations of copper and copper alloys. It discusses the basic types of heat treating processes of copper and copper alloys, namely, homogenizing, annealing, and stress relieving, and hardening treatments such as precipitation hardening, spinodal hardening, order hardening, and quench hardening and tempering. The article presents tables that list the compositions and mechanical properties of copper alloys. It also discusses two strengthening mechanisms of copper alloys, solid-solution strengthening and work hardening. Finally, the article provides information on the equipment used for the heat treating of copper and copper alloys, including batch-type atmosphere furnaces, continuous atmosphere furnaces, and salt baths.
Book Chapter
Heat Treating of Precipitation-Hardenable Stainless Steels and Iron-Base Superalloys
Available to PurchaseSeries: ASM Handbook
Volume: 4D
Publisher: ASM International
Published: 01 October 2014
DOI: 10.31399/asm.hb.v04d.a0005961
EISBN: 978-1-62708-168-9
... in each is similar and well understood. Hardening occurs from the precipitation of a coherent second phase that strains the crystal lattice, thus strengthening the alloy by impeding the motion of dislocations. The precipitates are produced by the step-process of a solution treatment (to create...
Abstract
Precipitation hardening is a hardening mechanism found in various steels and alloy systems, such as nickel-, cobalt-, titanium-, copper-, and iron-base alloys. This article provides a brief description of precipitation hardening process, furnace equipment, surface-related problems, and protective atmospheres used in heat treatment of iron-base precipitation-hardenable (PH) superalloys. It focuses on various factors to be considered in heat treating of PH stainless steels: cleaning prior to heat treatment, furnace atmospheres, time-temperature cycles, variations in cycles, and scale removal after heat treatment. The article describes the mechanical properties, solution treatment, and aging treatment for many martensitic PH alloys, including: Alloy 17-4 PH, Alloy 13-8 Mo, Alloy 15-5 PH, Custom 450, and Custom 455; as well as semiaustenitic PH stainless steels such as Alloy 17-7 PH, Alloy PH 15-7 Mo, AM-350, Pyromet 350, AM-355, and Pyromet 355; austenitic PH stainless steel, A-286; cast PH stainless steels; and iron-nickel PH superalloys.
Book Chapter
Fundamentals of Nitriding and Nitrocarburizing
Available to PurchaseSeries: ASM Handbook
Volume: 4A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v04a.a0005818
EISBN: 978-1-62708-165-8
... aging subsequent to quenching, the nitrogen dissolved at the nitriding temperature precipitates as iron nitrides in the diffusion zone, or, in the case of steel containing alloying elements with affinity for nitrogen, as aluminum and chromium, alloying element nitrides precipitate during nitriding...
Abstract
The nitriding process typically involves the introduction of nitrogen into the surface-adjacent zone of a component, usually at a temperature between 500 and 580 deg C. This article provides an overview of the essential aspects of the thermodynamics and kinetics of nitriding and nitrocarburizing of iron-base materials with gaseous processes. It describes nitriding potentials and the Lehrer diagram, carburizing potentials, controlled nitriding and nitrocarburizing, and the microstructural evolution of the compound layer and the diffusion zone.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006681
EISBN: 978-1-62708-213-6
... scattering is more probable in high-atomic-number materials at low beam energy. Elastic scattering is responsible for both electron diffraction (thin foils) and the generation of BEs (bulk samples in SEM and thin specimens in TEM). Coherent elastic scattering of electrons in the forward direction produces...
Abstract
Transmission electron microscopy (TEM) approach enables essentially simultaneous examination of microstructural features through imaging from lower magnifications to atomic resolution and the acquisition of chemical and crystallographic information from small regions of the thin specimen. This article discusses fundamentals of the technique, especially for solving materials problems. Background information is provided to help understand basic operations and principles, including instrumentation, the physics of signal generation and detection, image formation, electron diffraction, and spectrometry techniques with data analysis.
Book Chapter
X-Ray Imaging of Solidification Processes and Microstructure Evolution
Available to PurchaseBook: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005218
EISBN: 978-1-62708-187-0
.... Hence, for any phase contrast to be resolvable by the camera system, an extremely high degree of transversal coherence of the incident wave-field is required, corresponding to at least 10 5 λ. Since a high-photon flux also must be maintained at the sample to allow for real-time studies, conditions...
Abstract
Metal transparency and interaction with X-rays have been recognized as obvious candidate principles from which methods for in situ monitoring of solidification processes could be developed. This article describes the use of X-ray imaging-based techniques to investigate interface morphology evolution, solute transport, and various process phenomena at spatiotemporal resolutions. It discusses the three viable imaging techniques made available by synchrotron radiation for the real-time investigation of solidification microstructures in alloys. These include two-dimensional X-ray topography, two-dimensional X-ray radiography, and ultra-fast three-dimensional X-ray tomography.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006136
EISBN: 978-1-62708-175-7
... the opposing forces of a pair of rolling mill rolls to form a continuous green strip. The green strip is further densified and strengthened by sintering and rerolling. The critical step in the process is the formation of a coherent green strip having sufficiently high green strength and green density. A high...
Abstract
Direct powder rolling (DPR) is a process by which a suitable powder or mixture of powders is compacted under the opposing forces of a pair of rolling mill rolls to form a continuous green strip that is further densified and strengthened by sintering and rerolling. This article discusses the basic principle, process considerations, and advantages of DRP, and describes the application of this process in the manufacture of powder titanium and titanium alloy components. It further illustrates the complexity of the process and describes the benefits of using DRP in terms of economics and product quality.
Book Chapter
Selection of Wrought Precipitation-Hardening Stainless Steels
Available to PurchaseSeries: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001412
EISBN: 978-1-62708-173-3
... steels. heat treatment martensitic precipitation hardening stainless steels material selection microstructure semi-austenitic precipitation-hardening steels solidification PRECIPITATION-HARDENING (PH) STAINLESS STEELS are iron-chromium-nickel alloys with corrosion resistance superior...
Abstract
This article commences with a brief description of the solidification characteristics and microstructures of martensitic precipitation hardening (PH) stainless steels. It reviews the welding parameters for types 17-4PH, 15-5PH, PH13-8 Mo, Custom 450, and Custom 455. The article describes the microstructural evolution and weld parameters associated with semiaustenitic PH steels. It discusses the weldability and welding recommendations for A-286 and JBK-75 austenitic PH stainless steels. The article also presents tables that list properties and heat treatments for the PH stainless steels.
Book Chapter
Metallographic Techniques for Aluminum and Its Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003769
EISBN: 978-1-62708-177-1
.... The newer 7 xxx alloys contain zirconium, which forms coherent Al 3 Zr dispersoids, while most of the older 7 xxx alloys contain Al 12 Mg 2 Cr dispersoids, which exhibit incoherent interfaces. The incoherent interfaces serve to nucleate MgZn 2 precipitates during the quench, so alloys containing...
Abstract
This article focuses on the metallography and microstructures of wrought and cast aluminum and aluminum alloys. It describes the role of major alloying elements and their effect on phase formation and the morphologies of constituents formed by liquid-solid and/or solid-state transformations. The article also describes specimen preparation procedures and examines the microstructure of several alloy samples.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005331
EISBN: 978-1-62708-187-0
... with adverse effects on castability and eutectic structure. Antimony will chemically combine with and precipitate the common modifiers sodium and strontium; therefore, antimony has the potential to act as a modification poisoner if it enters the scrap recycling stream. Chemical analysis of antimony content...
Abstract
This article begins with a discussion on the effects of alloying and impurity elements on the properties of aluminum cast alloys and their chemical compositions. It describes the various means of structural control, namely, chemistry control, control of element ratios based on the stoichiometry of intermetallic phases, and control of solidification conditions. The article discusses the modification and grain refinement of aluminum-silicon alloys by the use of modifiers and refiners to influence eutectic and hypereutectic structures in aluminum-silicon alloys. It provides information on foundry alloys for specific casting applications. The article concludes with a discussion on the heat treatment practices and properties of aluminum casting alloys.
Book Chapter
Quenching of Aluminum Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006260
EISBN: 978-1-62708-169-6
... of homogeneous (coherent or semi coherent) precipitation for strengthening by age hardening at room temperature or moderately elevated temperatures. In addition, another purpose of quenching is to maintain a certain minimum number of vacant lattice sites to assist in promoting the low-temperature diffusion...
Abstract
Quenching refers to the rapid cooling of metal from the solution treating temperature, typically between 465 and 565 deg C (870 and 1050 deg F) for aluminum alloys. This article provides an overview on the appropriate quenching process and factors used to determine suitable cooling rate. It describes the quench sensitivity and severity of alloys, quench mechanisms and the different types of quenchants used in immersion, spray, and fog quenching. The article provides a detailed description of the quench-factor analysis that mainly includes residual stress and distortion, which can be controlled by proper racking. It concludes with information on agitation and the quench tank system used in the quenching of aluminum alloys.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001305
EISBN: 978-1-62708-170-2
... amounts result in a microstructure that is not fully martensitic. Precipitation-Hardenable (PH) Stainless Steels Precipitation-hardenable (PH) stainless steels are chromium-nickel grades that can be hardened by an aging treatment. These grades are classified as austenitic (such as S66286), semi...
Abstract
Passivation; pickling, that is, acid descaling; electropolishing; and mechanical cleaning are important surface treatments for the successful performance of stainless steel used for piping, pressure vessels, tanks, and machined parts in a wide variety of applications. This article provides an overview of the various types of stainless steels and describes the commonly used cleaning methods, namely, alkaline cleaning, emulsion cleaning, solvent cleaning, vapor degreasing, ultrasonic cleaning, and acid cleaning. Finishing operations of stainless steels, such as grinding, polishing, and buffing, are reviewed. The article also explains the procedures of electrocleaning, electropolishing, electroplating, painting, surface blackening, coloring, terne coatings, and thermal spraying. It includes useful information on the surface modification of stainless steels, namely, ion implantation and laser surface processing. Surface hardening techniques, namely, nitriding, carburizing, boriding, and flame hardening, performed to improve the resistance of stainless steel alloys are also reviewed.
Book Chapter
Surface Engineering of Titanium and Titanium Alloys
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001311
EISBN: 978-1-62708-170-2
... with an “impurity” atom increases the load required to permit dislocation movement. Precipitation hardening is effected by dislocations being pinned by coherent or incoherent precipitates. For the maximum precipitation hardening effect, a fine distribution of coherent precipitates is required. For very low ion...
Abstract
This article reviews cleaning and finishing operations that have proven to be effective on titanium, its alloys, and semi-fabricated titanium products. It explains how to remove scale, tarnish films, grease, and other soils and how to achieve required finishes and/or improve wear and oxidation resistance through the use of polishing, buffing, and wire brushing operations. The article also covers a wide range of surface modification and coating processes, including ion implantation, diffusion, chemical and physical vapor deposition, plating, anodizing, and chemical conversion coatings as well as sprayed and sol-gel coatings and laser and electron-beam treatments.
Book Chapter
Modeling of Hot Tearing and Other Defects in Casting Processes
Available to PurchaseSeries: ASM Handbook
Volume: 22A
Publisher: ASM International
Published: 01 December 2009
DOI: 10.31399/asm.hb.v22a.a0005420
EISBN: 978-1-62708-196-2
... formation, transport, collisions, and removal or entrapment in the molten metal during upstream refining processes is the next crucial step. Thermodynamic reactions to quantify the precipitates that form in these multicomponent alloy systems can be predicted by simultaneous solution of chemical equilibrium...
Abstract
This article focuses on the concepts involved in heat-transfer modeling, thermomechanical modeling, and microsegregation modeling of hot tearing. It discusses the modeling of solidification defects, namely, inclusion entrapment, segregation, shrinkage cavities, gas porosity, mold-wall erosion, and hot-tear cracks.
Book: Fatigue and Fracture
Series: ASM Handbook
Volume: 19
Publisher: ASM International
Published: 01 January 1996
DOI: 10.31399/asm.hb.v19.a0002355
EISBN: 978-1-62708-193-1
... stress concentration at the surface. Second-phase particles, such as inclusions and precipitates, have elastic properties different from those of the matrix and generally also serve as stress concentrators. Argon ( Ref 2 ) showed very instructively that the effect of second-phase particles at the free...
Abstract
This article presents an overview of fatigue crack nucleation from the point of view of the material microstructure and its evolution during cycling. It describes the sites of microcrack nucleation at the free surfaces. The article discusses the relation of dislocation structures and surface relief and reviews the mechanisms of crack nucleation. The damage of material due to crack nucleation, the extent (in terms of the number of cycles) of the nucleation stage, and the factors influencing crack nucleation are discussed.
Book Chapter
Modeling of Microstructure Evolution during the Thermomechanical Processing of Titanium Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 22A
Publisher: ASM International
Published: 01 December 2009
DOI: 10.31399/asm.hb.v22a.a0005409
EISBN: 978-1-62708-196-2
..., equiaxed alpha and secondary (lamellar) alpha in alpha/beta titanium alloys during cooling following heat treatment in the alpha+beta phase field Precipitation of acicular/lamellar alpha in alpha/beta and near-beta alloys following beta solution treatment The following discussion focuses...
Abstract
This article focuses on the modeling of microstructure evolution during thermomechanical processing in the two-phase field for alpha/beta and beta titanium alloys. It also discusses the mechanisms of spheroidization, the coarsening, particle growth, and phase decomposition in titanium alloys, with their corresponding equations.
Series: ASM Handbook
Volume: 1
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v01.a0001046
EISBN: 978-1-62708-161-0
... Abstract This article discusses the composition, characteristics, and properties of the five groups of wrought stainless steels: martensitic stainless steels, ferritic stainless steels, austenitic stainless steels, duplex stainless steels, and precipitation-hardening stainless steels...
Abstract
This article discusses the composition, characteristics, and properties of the five groups of wrought stainless steels: martensitic stainless steels, ferritic stainless steels, austenitic stainless steels, duplex stainless steels, and precipitation-hardening stainless steels. The selection of stainless steels may be based on corrosion resistance, fabrication characteristics, availability, mechanical properties in specific temperature ranges and product cost. The fabrication characteristics of stainless steels include formability, forgeability, machinability, and weldability. The product forms of wrought stainless steels are plate, sheet, strip, foil, bar, wire, semifinished products, pipes, tubes, and tubing. The article describes tensile properties, elevated-temperature properties, subzero-temperature properties, physical properties, corrosion properties, and fatigue strength of stainless steels. It characterizes the experience of a few industrial sectors according to the corrosion problems most frequently encountered and suggests appropriate grade selections. Corrosion testing, surface finishing, mill finishes, and interim surface protection of stainless steels are also discussed.
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