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self-propagating high-temperature synthesis
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Published: 01 December 2008
Fig. 4 Schematic of self-propagating high-temperature synthesis plus centrifugal casting. (a) Radial centrifuge. (b) Axial centrifuge. 1, sample container; 2, reactant mixture; 3, ignitor; 4, axle; 5, reactor
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Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003063
EISBN: 978-1-62708-200-6
..., discontinuously reinforced composites and continuous-fiber-reinforced composites. Processing methods include cold pressing, sintering, hot pressing, reaction bonding, melt infiltration, directed metal oxidation, sol-gel and polymer pyrolysis, self-propagating high-temperature synthesis and joining. A table...
Abstract
Ceramic-matrix composites (CMCs) are being developed for a number of high-temperature and high-performance applications in industrial, aerospace, and energy conservation sectors. This article focuses on processing, fabrication, testing, and characterization methods of CMCs, namely, discontinuously reinforced composites and continuous-fiber-reinforced composites. Processing methods include cold pressing, sintering, hot pressing, reaction bonding, melt infiltration, directed metal oxidation, sol-gel and polymer pyrolysis, self-propagating high-temperature synthesis and joining. A table summarizes the properties of various ceramic reinforcements and industrial applications of these composites.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003421
EISBN: 978-1-62708-195-5
..., in situ chemical reaction techniques, sol-gel techniques, pyrolysis, polymer infiltration, self-propagating high-temperature synthesis, and electrophoretic deposition. The advantages and disadvantages of each technique are highlighted to provide a comprehensive understanding of the achievements...
Abstract
Ceramic-matrix composites (CMCs) have ability to withstand high temperatures and have superior damage tolerance over monolithic ceramics. This article describes important processing techniques for CMCs: cold pressing, sintering, hot pressing, reaction-bonding, directed oxidation, in situ chemical reaction techniques, sol-gel techniques, pyrolysis, polymer infiltration, self-propagating high-temperature synthesis, and electrophoretic deposition. The advantages and disadvantages of each technique are highlighted to provide a comprehensive understanding of the achievements and challenges that remain in this area.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003054
EISBN: 978-1-62708-200-6
... such as reaction sintering and self-propagating, high-temperature synthesis. It also describes several pressure densification methods, including hot isostatic pressing, gas pressure sintering, molten particle deposition, and sol-gel processing. The article concludes with a section on grain growth that discusses...
Abstract
Sintering provides the interparticle bonding that generates the attractive forces needed to hold together the otherwise loose ceramic powder mass. It also improves hardness, strength, transparency, toughness, electrical conductivity, thermal expansion, magnetic saturation, corrosion resistance, and other properties. This article discusses the fundamentals of sintering and its effects on pore structures and particle density. It addresses some of the more common sintering methods, including solid-state, liquid-phase, and gas pressure sintering, and presents alternative processes such as reaction sintering and self-propagating, high-temperature synthesis. It also describes several pressure densification methods, including hot isostatic pressing, gas pressure sintering, molten particle deposition, and sol-gel processing. The article concludes with a section on grain growth that discusses the underlying mechanisms and kinetics and the relationship between grain growth and densification.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005257
EISBN: 978-1-62708-187-0
... and backward movement, moving velocity, and spray on and off operations of the spray lance. It can also adjust height and tilt angle to align the lance with all customer mold sizes. Fig. 4 Schematic of self-propagating high-temperature synthesis plus centrifugal casting. (a) Radial centrifuge. (b) Axial...
Abstract
This article describes the applications, advantages, and disadvantages of three centrifugal casting processes as well as the equipment used. These processes are true centrifugal casting, semicentrifugal casting, and centrifuge mold casting. The article discusses the cooling, inoculation, fluxing, and extraction of castings. It reviews mold heating and coating techniques as well as the various molds used. The three most common defects observed in centrifugal castings are also discussed. The article concludes with information on the applications of centrifugal casting in investment casting and combustion synthesis as well as spin casting.
Book Chapter
Book: Thermal Spray Technology
Series: ASM Handbook
Volume: 5A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v05a.a0005749
EISBN: 978-1-62708-171-9
... microscope/microscopy sfm surface feet per minute SG spheroidal graphite SHS self-propagating high-temperature synthesis sin sine of an angle sLm standard liters per minute slpm standard liters per minute SME Society of Manufacturing Engineers SNECMA Societe...
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006012
EISBN: 978-1-62708-172-6
... micelles ( Ref 25 ). The solvothermal method includes heating of precursor salts in organic solvents at high temperatures, even at supercritical conditions ( Ref 20 ). The sol-gel method allows in situ formation of some quantum dots and other nanoparticles into coatings so they are strongly coupled...
Abstract
Nanotechnology and smart-coating technologies have been reported to show great promise for improved performance in critical areas such as corrosion resistance, durability, and conductivity. This article exemplifies nanofilms and nanomaterials used in coatings applications, including carbon nanotubes, silica, metals/metal oxides, ceramics, clays, buckyballs, graphene, polymers, titanium dioxide, and waxes. These can be produced by a variety of methods, including chemical vapor deposition, plasma arcing, electrodeposition, sol-gel synthesis, and ball milling. The application of nanotechnology and the development of smart coatings have been dependent largely on the availability of analytical and imaging techniques such as Raman spectroscopy, scanning and transmission electron microscopy, atomic force microscopy, and scanning tunneling microscopy.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006869
EISBN: 978-1-62708-395-9
... to the increment in friction and high temperature of the contact zone. These are attributed to fiber breakage and the thermal failure of the polymeric matrix ( Ref 21 ). In general, when SFRPs undergo the wear process, the higher portion of the load is sustained by the fibers. Therefore, the polymeric matrix...
Abstract
Reinforced polymers (RPs) are widely used in structural, industrial, automotive, and engineering applications due to their ecofriendly nature and the potential to manipulate their properties. This article addresses the technical synthesis of RPs, referring to their tribological behavior, to provide insights into the contribution and interaction of influential parameters on the wear behavior of polymers. It provides a brief discussion on the effects of significant parameters on RP tribology. The article describes abrasive and adhesive wear and provides a theoretical synthesis of the literature regarding the wear mechanisms of RPs. It also describes the synthesis of abrasive wear failure of different types of RPs and highlights the contribution of these influential parameters. The article addresses the synthesis of adhesive wear failure of different types of RPs.
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006405
EISBN: 978-1-62708-192-4
.... The SAE International viscosity grades and API service classifications are the usual means used to define the performance of automotive engine lubricants ( Ref 6 , 7 ). The viscosity classification assures easy starting and lubrication at low temperatures, and adequate protective lubrication at high...
Abstract
This article focuses on lubricants classified as either internal combustion engine or nonengine lubricants, and the lubricant additives. The functional groups of chemically active and inert additives, as well as friction modifiers and other additives, are described in detail. The chemically active additives include dispersants, detergents, antiwear, and extreme-pressure agents, oxidation inhibitors, and rust and corrosion inhibitors. The chemically inert additives include emulsifiers, demulsifiers, pour-point depressants, foam inhibitors, and viscosity improvers. The article also discusses the multifunctional nature of additives and concludes with information on lubricant formulation.
Series: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005552
EISBN: 978-1-62708-174-0
...) of ceramics to one another or to metals. These are collectively known as combustion synthesis reactions but are also referred to as self-propagating high-temperature synthesis reactions. The generic process has potential both for joining and for applying surfacing layers. Electric Arc Fusion Welding...
Abstract
This article overviews the classification of welding processes and the key process embodiments for joining by various fusion welding processes: fusion welding with chemical sources for heating; fusion welding with electrical energy sources, such as arc welding or resistance welding; and fusion welding with directed energy sources, such as laser welding, electron beam welding. The article reviews the different types of nonfusion welding processes, regardless of the particular energy source, which is usually mechanical but can be chemical, and related subprocesses of brazing and soldering.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0006515
EISBN: 978-1-62708-200-6
... surface feet per minute TPI thermoplastic polyimide; turns per inch Z atomic number; impedance SG standard grade TPUR thermoplastic polyurethane SHS self-propagating high-temperature TPX polymethylpentene ZTA zirconia-toughened alumina synthesis TS thermoset ZTS zirconium titanium stannate SI silicone...
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006421
EISBN: 978-1-62708-192-4
..., heat treatment, and laser-assisted coatings technologies (laser-assisted synthesis of in-situ interstitial, metallic alloy coatings, ceramic coatings, and thin films). Coverage also includes novel coatings such as high entropy alloy coatings and amorphous metallic coatings, as well as laser-based...
Abstract
Lasers evolved as a versatile materials processing tool due to their advantages such as rapid, reproducible processing, chemical cleanliness, ability to handle variety of materials, and suitability for automation. This article focuses on state-of-the-art laser applications to improve tribological performance of structural materials in lubricated and nonlubricated environments. It discusses the fundamentals of various laser materials interactions and reviews laser-based surface-modification strategies, including laser surface heating and melting, laser-synthesized coatings, and laser-based design approaches such as laser patterning and dimpling. Laser-surface modification of novel materials, such as high-entropy alloys and metallic glasses, is explored. The article provides an overview of hybrid techniques involving laser as a secondary tool, as well as a discussion on the improved capabilities of laser surface engineering for tribological applications by means of integrated computational process modeling.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006018
EISBN: 978-1-62708-175-7
..., manganese Soldering Lead, tin, solder alloys Thermit welding Aluminum Lubricants Anti-galling pipe joint compound Copper, lead, zinc, graphite Copper lubricants Copper Greases Lead, graphite High-temperature lubricants Aluminum, graphite Plastic-filled metals Iron...
Abstract
Metal powders are used as fuels in solid propellants, fillers in various materials, such as polymers or other binder systems, and for material substitution. They are also used in food enrichment, environmental remediation market, and magnetic, electrical, and medical application areas. This article reviews some of the diverse and emerging applications of ferrous and nonferrous powders. It also discusses the functions of copier powders and the processes used frequently for copier powder coating.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006093
EISBN: 978-1-62708-175-7
... assemblies ( Ref 16 ) ( Fig. 1 ) Self-propagating high-temperature synthesis ( Ref 17 ) Additive manufacturing methods such as selective laser melting or electron beam melting ( Ref 18 , 19 , 20 ) Screen printing ( Ref 21 ) Roll compaction ( Ref 22 ) Sintering of open-pore foams using space...
Abstract
Cellular or foam structures can be described by means of two broader cases: foams in which the pores are all connected to each other and with the environment (open-pore foams) and foams in which every single pore is completely enclosed by the matrix (closed-pore foams). This article describes the four process groups for the production of open- and closed-pore metal foams. It discusses the principles of the foaminal process with the description of various foaming agents, solidified metal foam, and geometries and derived structures of metal foams. The use of syntactic metal foam in various fields is included. The article reviews the mechanical properties of closed-pore metal foams, details the machining and joining procedures of the metal foams, and presents the applications of the metal foam.
Book: Thermal Spray Technology
Series: ASM Handbook
Volume: 5A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v05a.a0005706
EISBN: 978-1-62708-171-9
... the mixture and produces a controlled explosion that propagates down the length of the barrel. The process is cyclic, with the barrel being swept with nitrogen between detonations. The high temperatures and pressures that are generated heat the coating materials to their melting point and accelerate them...
Abstract
Thermal spray is a generic term for a group of coating processes used to apply metallic, ceramic, cermet, and some polymeric coatings for a broad range of applications. This article provides a brief description of commercially important thermal spray processes, namely, powder-fed flame spray, wire- or rod-fed flame spray, electric arc spray, plasma arc spray, vacuum plasma spray, high-velocity oxyfuel spray, detonation gun deposition, and cold spray, and their advantages. It provides details on the microstructural characteristics of thermal spray coatings. The article also presents information on a wide variety of materials that can be thermal sprayed, such as metals, ceramics, intermetallics, composites, cermets, polymers, and functionally gradient materials. Tables are included, which list the thermal spray processes and coating properties of importance for various industrial applications.
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006434
EISBN: 978-1-62708-192-4
... and dramatic changes in liquid-lubricant properties during service. Operating conditions where solid lubricants are used include extremely high and low temperatures, high sliding speeds, vacuum, locations difficult or impossible to service during operation, applications that cannot tolerate contamination due...
Abstract
Solid lubricants consist of materials placed at the interface between moving bodies to mitigate friction and wear. This article begins with a historical overview of solid lubricants and discuses the characteristics and fundamental aspects of solid lubricants. It describes the material categories of solid lubricant coatings, including graphite, graphite fluoride, transition metal dichalcogenides, diamond-like-carbon, polymeric materials, and metallic films. The article presents a description of deposition methods from the simplest processes involving burnishing and impingement in open air to modern vacuum-based methods for solid lubricants. It concludes with a discussion on metrics that can be used to qualify solid lubricants in high-consequence applications.
Book Chapter
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006939
EISBN: 978-1-62708-395-9
.... They also have a strong tendency to agglomerate to form even larger structures of silica aggregates. Fumed silica, also often referred to as colloidal, pyrogenic, or anhydrous silicas, is produced by a high-temperature gaseous process. Like precipitated silicas, fumed silicas also form aggregates...
Abstract
Polymer materials are key building blocks of the modern world, commonly used in packaging, automobiles, building materials, electronics, telecommunications, and many other industries. These commercial applications of polymeric materials would not be possible without the use of additives. This article is divided into five sections: mechanical property modifiers, physical property modifiers, biological function modifiers, processing aids, and colorants. It describes three classes of additives that are used to inhibit biological activity, six classes of mechanical property modifiers, three classes of physical property modifiers, and two classes of both colorants and processing aids.
Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006495
EISBN: 978-1-62708-207-5
... ) Self-propagating high-temperature synthesis ( Ref 23 ) Additive manufacturing methods such as laser beam melting or electron beam melting ( Ref 24 – 26 ) Screen printing ( Ref 27 ) Roll compaction ( Ref 28 ) Sintering of open-porous foams using spaceholders ( Ref 11 ) Most...
Abstract
This article describes manufacturing procedures that produce aluminum foams and have since become industrially important and successful. It discusses the foaming of melts by blowing agents and foaming of melts by gas injection. The article focuses on aluminum foams based on the Foaminal technology, because those foams dominate the technical applications of aluminum foams. It also discusses the mechanical properties of metal foams, such as general compression behavior, elastic behavior, strain-rate sensitivity, tensile behavior, ductility, fatigue, and mechanical damping. The article concludes with information on the applications of highly porous metal structures.
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006367
EISBN: 978-1-62708-192-4
... composites is reduced very little or even increased in some cases ( Ref 36 ). Another important use of graphene is as a lubricant for metals and ceramics. Considering their high melting point, low density, and good oxidation resistance, ceramics are expected to operate at very high temperatures...
Abstract
This article discusses the importance of friction and wear and the role of lubricants in composites. It highlights the progress and developments in using different forms of carbon allotropes in composites for improved friction and wear performance of materials. The article focuses on the widely used form known as carbon black (CB) and shows how to deal with friction and wear of polymers and composites when gamma irradiation is involved. It also discusses the role of graphite in composite materials, which is widely used as a dry lubricant. The article examines the tribology of carbon nanotubes (CNTs) as components in composite materials. It also highlights some of the most pronounced examples of graphene use as a reinforcement agent for improving tribological performance in composite matrices. The article concludes with a discussion on the progress of research in diamond-containing composites.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003059
EISBN: 978-1-62708-200-6
... phases: quartz, tridymite, and cristobalite, all three of which exist in high- and low-temperature modifications. The ideal cristobalite structure can be described in terms of the zinc blende lattice. The A atoms of cristobalite occupy both the A and X sites of the zinc blende structure...
Abstract
This article provides crystallographic and engineering data for single oxide ceramics, zirconia, silicates, mullite, spinels, perovskites, borides, carbides, silicon carbide, boron carbide, tungsten carbide, silicon-nitride ceramics, diamond, and graphite. It includes data on crystal structure, density, mechanical properties, physical properties, electrical properties, thermal properties, and magnetic properties.
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