This article reviews the corrosion interactions between biomedical alloys, in particular iron-base, titanium-base, and cobalt-base alloys, in complex geometries and in applications where there are significant cyclic stresses and potential for wear and fretting motion. It discusses the nature of these metal surfaces and their propensity for corrosion reactions when combined with similar or different alloys in complex restrictive environments within the human body, and under loading conditions. The article describes factors that influence mechanically assisted crevice corrosion. It reviews tests, such as scratch test and in vitro fretting corrosion test, developed to investigate the aspects of mechanically assisted corrosion of metallic biomaterials.

Optical testing of plastics includes characterization of materials and analysis of optical components. This article focuses on procedures for testing various characteristics of optical components, including transmission and haze, yellowness, refractive index, birefringence, as well as surface irregularity, contamination, gloss, and color. It provides a short note on ad hoc testing, which is beneficial for practical applications in which lenses, prisms, and light pipes are being used and tested, as other test instruments are often not available.

This article reviews nondestructive testing (NDT) and inspection techniques, namely liquid penetrant, magnetic particle, ultrasonics, X-ray, eddy current, visual and radiography that are commonly used to detect and evaluate flaws or leaks in an engineering system. This article compares the merits and limitations of these techniques and describes the various uses of NDT, including leak detection, metrology, structure or microstructure characterization, stress-strain response determination, and rapid identification of metals and alloys.

This article focuses on the testing and typical corrosion behavior of coating-substrate systems in aqueous solutions and humid aggressive atmospheres. It includes a short review of the fundamentals of corrosion, followed by a discussion of specific system behavior, electrochemical and laboratory accelerated tests, and simulated service tests. The article also contains examples of different types of corrosion damage and presents guidelines for improving corrosion resistance.

This article describes testing and characterization methods of ceramics for chemical analysis, phase analysis, microstructural analysis, macroscopic property characterization, strength and proof testing, thermophysical property testing, and nondestructive evaluation techniques. Chemical analysis is carried out by X-ray fluorescence spectrometry, atomic absorption spectrophotometry, and plasma-emission spectrophotometry. Phase analysis is done by X-ray diffraction, spectroscopic methods, thermal analysis, and quantitative analysis. Techniques used for microstructural analysis include reflected light microscopy using polarized light, scanning electron microscopy, transmission electron microscopy, energy dispersive analysis of X-rays, and wavelength dispersive analysis of X-rays. Macroscopic property characterization involves measurement of porosity, density, and surface area. The article describes testing methods such as room and high-temperature strength test methods, proof testing, fracture toughness measurement, and hardness and wear testing. It also explains methods for determining thermal expansion, thermal conductivity, heat capacity, and emissivity of ceramics and glass and measurement of these properties as a function of temperature.

Tribology is the science and technology of interacting surfaces in relative motion or, the study of friction, wear, and lubrication. This article focuses on friction and wear processes that aid in the evaluation and selection of materials, for polymers and some composites used in friction and wear applications. It provides information on friction, types of wear, and lubrication. The article includes a brief description of the friction and wear test methods, laboratory-scale friction, and wear testing, usually performed either to rank the performance of candidate materials for an application or to investigate a particular wear process. It describes the wear tests conducted with/without abrasives and explains the concept of PV limit (where P is contact pressure and V is velocity). The article concludes with references and tables of friction and wear test data for polymeric materials.

Wear is mechanically-induced surface damage that results in the progressive removal of material. Because different types of wear occur in machinery, many different types of wear tests have been developed to evaluate its effects on materials and surface treatments. This article provides an explanation on mechanisms, forms (sliding, impact, and rolling) and the causes of wear. It describes the wear measuring methods, including the mass loss method, wear width method, and scar depth method. The units used to report wear vary with type of wear and with the purpose for which the data are to be used. Listing the considerations of tribosystem analysis, the article provides information on selection of ASTM wear test methods grouped by wear type. The article concludes by tabulating the testing geometries and parameters that are commonly controlled and reported when conducting wear tests.

Stress-corrosion cracking (SCC) occurs under service conditions, which can result, often without any prior warning, in catastrophic failure. Hydrogen embrittlement is distinguished from stress-corrosion cracking generally by the interactions of the specimens with applied currents. To determine the susceptibility of alloys to SCC and hydrogen embrittlement, several types of testing are available. This article describes the constant extension testing, constant load testing, constant strain-rate testing for smooth specimens and precracked or notched specimens of SCC. It provides information on the cantilever beam test, wedge-opening load test, contoured double-cantilever beam test, three-point and four-point bend tests, rising step-load test, disk-pressure test, slow strain-rate tensile test, and potentiostatic slow strain-rate tensile test for hydrogen embrittlement.

The interaction of an implant with the human body environment may result in degradation of the implant, called corrosion. This article discusses the corrosion testing of metallic implants and implant materials. The corrosion environments for medical implants are the extracellular human body fluids, very complex solutions containing electrolytes and nonelectrolytes, inorganic and organic constituents, and gases. The article describes the fundamentals of electrochemical corrosion testing and provides a brief discussion on various types of corrosion tests. It illustrates corrosion current density determination by Tafel extrapolation, potentiodynamic measurement of the polarization resistance, electrochemical impedance measurement, and potentiostatic deaeration. Tests combining corrosion and mechanical forces, such as fretting corrosion tests, environment-assisted cracking tests, and ion-leaching tests are also discussed.

This article reviews the various types of mechanical testing methods, including hardness testing; tension testing; compression testing; dynamic fracture testing; fracture toughness testing; fatigue life testing; fatigue crack growth testing; and creep, stress-rupture, and stress-relaxation testing. Shear testing, torsion testing, and formability testing are also discussed. The discussion of tension testing includes information about stress-strain curves and the properties described by them.

Ceramics are used widely in a number of different clinical applications in the human body. This article provides a brief history of the bioceramics field and information on the classification of the different types of bioceramics. These include bioinert ceramics, bioactive ceramics, and bioresorbable ceramics. The article describes the third-generation bioceramics, classified by Hench and Polak, such as silicate-substituted hydroxyapatite and bone morphogenic protein-carrying calcium phosphate coatings. It reviews several examination methods that are used to test the biocompatibility of ceramics, namely, biosafety testing, biofunctionality testing, bioactivity testing, and bioresorbability testing.

This article describes the allotropic modification and atmospheric corrosion of pure tin. Corrosion of pure tin due to oxidation reaction, and reaction with the other gases, water, acids, bases, and other liquid media, is discussed. The article provides information on corrosion behavior on soft solders, pewter, bearing alloys, tin-copper alloys, and tin-silver alloys. It reviews the influence of corrosion on immersion tin coating, tin-cadmium alloy coatings, tin-cobalt coatings, tin-copper coatings, tin-lead coatings, tin-nickel coatings, and tin-zinc coatings. The general properties and corrosion resistance of tinplate are summarized. The article also describes the methods of corrosion testing of coatings; these include an analysis of coating thickness measurements, porosity and rust resistance testing, solderability test, and specific special tests.

The characterization, testing, and nondestructive evaluation of ceramics and glasses are vital to manufacturing control, property improvement, failure prevention, and quality assurance. This article provides a broad overview of characterization methods and their relationship to property control, both in the production and use of ceramics and glasses. Important aspects covered include the means for characterizing ceramics and glasses, the corresponding rationale behind them, and relationship of chemistry, phases, and microconstituents to engineering properties. The article also describes the effects that the structure of raw ceramic materials and green products and processing parameters have on the ultimate structure and properties of the processed piece. The effects that trace chemistry and processing parameters have on glass properties are discussed. The article describes mechanical tests and failure analysis techniques used for ceramics.

This article describes some of the mechanical/ electrochemical phenomena related to the in vivo degradation of metals used for biomedical applications. It discusses the properties and failure of these materials as they relate to stress-corrosion cracking (SCC) and corrosion fatigue (CF). The article presents the factors related to the use of surgical implants and their deterioration in the body environment, including biomedical aspects, chemical environment, and electrochemical fundamentals needed for characterizing CF and SCC. It provides a discussion on the use of metallic biomaterials in surgical implant applications, such as orthopedic, cardiovascular surgery, and dentistry. It addresses the key issues related to simulation of the in vivo environment, service conditions, and data interpretation. Theses include frequency of dynamic loading, electrolyte chemistry, applicable loading modes, cracking mode superposition, and surface area effects. The article describes the fundamentals of CF and SCC, testing methodology, and test findings from laboratory, in vivo, and retrieval studies.

This article describes the methods and equipments involved in the preparation of specimens for examination by light optical microscopy, scanning electron microscopy, electron microprobe analysis for microindentation hardness testing, and for quantification of microstructural parameters, either manually or by the use of image analyzers. Preparation of metallographic specimens generally requires five major operations: sectioning, mounting, grinding, chemical polishing, and etching. The article provides information on the principles of technique selection in mechanical polishing, and describes the procedures, advantages, and disadvantages of electrolytic and chemical polishing. It also provides a detailed account of procedures, precautions, and composition for preparation and handling of etchants.

Visual inspection (VI) is the oldest inspection technique man has used as a quality-control tool to evaluate products, assess their final form in terms of fabrication accuracy and external features based on experience, and decide on their acceptance or rejection. This article discusses the basic principles of visual inspection in terms of direct visual examination and indirect visual examination as well as advantages and limitations of visual inspection. It reviews the factors affecting the effectiveness of VI as a nondestructive testing (NDT): lighting conditions of observation, condition of surface under inspection, physical state/condition of inspector, proper training of personnel and level of expertise, and knowledge of applicable standards. The article provides schematic illustrations of rigid borescopes, fiberscopes, and videoscopes. It concludes with a discussion on automated optical inspection systems.

Wear of metals occurs by plastic displacement of surface and near-surface material, and by detachment of particles that form wear debris. This article presents a table that contains the classification of wear. It describes the testing and evaluation of wear and talks about the abrasive wear, lubrication and lubricated wear, and selection of steels for wear resistance. The article discusses the effect of alloying elements, composition, and mechanical properties of carbon and low-alloy steels at elevated temperatures. It talks about the fatigue resistance characteristics of steels, and describes the forms of embrittlement associated with carbon and low-alloy steels. The article provides information on the effect of composition, manufacturing practices, and microstructure on notch toughness of steels. Finally, it explains the effects of alloy elements, inclusion content, microstructure and heat treatment on fracture toughness of steels.

Visual inspection is a nondestructive testing technique that provides a means to detect and examine a variety of surface flaws, such as corrosion, contamination, surface finish, and surface discontinuities. This article discusses the equipment used to aid visual inspection, including borescopes (rigid and flexible), optical sensors, and magnifying systems. The article discusses the special features of borescopes, the factors that influence the choice of a flexible or rigid borescope for use in a specific application, and some of the image sensors used in visual inspection.

This article provides information on the application of nondestructive examination (NDE) technologies to tube and pipe products. These include modeling and simulation methods, eddy-current methods, magnetic methods, acoustic methods, and physical methods. A summary of nondestructive examination methods based on flaw type and product stage is presented in a table. The article also discusses in-service inspection of tubular products and presents an example that illustrates the importance of nondestructive testing (NDT) for welds in austenitic stainless steel tubing.