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Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003834
EISBN: 978-1-62708-183-2
...: noble metal clad systems, corrosion barrier systems, sacrificial metal systems, transition metal systems, complex multilayer systems, and clad diffusion alloys. cladding corrosion control sacrificial metal systems clad metals noble metal clad systems corrosion barrier systems transition...
Abstract
This article describes the principal cladding processes and methods for calculating properties of clad metals. It reviews the designing processes of clad metals to achieve specific requirements. The article discusses six categories of clad metal systems designed for corrosion control: noble metal clad systems, corrosion barrier systems, sacrificial metal systems, transition metal systems, complex multilayer systems, and clad diffusion alloys.
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Schematics of typical coating systems. These include (a) the “as-deposited”...
Available to PurchasePublished: 01 January 2006
Fig. 10 Schematics of typical coating systems. These include (a) the “as-deposited” pure aluminum or zinc sacrificial metallic coating, without the addition of any organics, applied to SAE 1018 steel; (b) the pure sacrificial coating applied to SAE 1018 steel plus a sealer or conversion coat
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Book Chapter
Marine Cathodic Protection
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004109
EISBN: 978-1-62708-184-9
... Abstract Cathodic protection (CP) is an electrochemical means of corrosion control widely used in the marine environment. This article discusses two types of CP systems: impressed current systems and sacrificial anode (passive) systems. It describes the anode materials used in these systems...
Abstract
Cathodic protection (CP) is an electrochemical means of corrosion control widely used in the marine environment. This article discusses two types of CP systems: impressed current systems and sacrificial anode (passive) systems. It describes the anode materials used in these systems and the CP criteria. The article examines the design considerations and procedures involved in the CP of marine pipelines, offshore structures, and ship hulls. An illustration of sacrificial anode calculation is also provided.
Book Chapter
Corrosion Control for Marine- and Land-Based Infrastructure Applications
Available to PurchaseBook: Thermal Spray Technology
Series: ASM Handbook
Volume: 5A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v05a.a0005709
EISBN: 978-1-62708-171-9
... of the environment Electrical methods of control Selection of corrosion-resistant materials Use of coatings Of the aforementioned, coatings often are chosen by the industry due to the versatility they offer. Historically, coating systems used to protect metallic infrastructure, be it marine- or land...
Abstract
Corrosion of marine- and land-based infrastructure is of major concern and its control forms an important objective. Thermal spray coatings (TSCs) are widely used for corrosion protection. This article focuses on two types of TSCs: cathodic or noble coatings and anodic or sacrificial coatings. It describes the factors affecting the performance of sacrificial TSCs in atmospheric and immersion environments. The article provides information on the applications of sacrificial TSCs, non-sacrificial coatings, and sealants/top coats, and exemplifies the use of sacrificial TSCs on structures for corrosion protection.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003697
EISBN: 978-1-62708-182-5
... the oxidation reaction in a galvanic cell is concentrated at the anode, which suppresses corrosion of the cathode in the same cell. Figure 1 shows a simple cathodic protection system. The steel pipeline is cathodically protected by its connection to a sacrificial magnesium anode buried in the same soil...
Abstract
Cathodic protection is an electrochemical means of corrosion control in which the oxidation reaction in a galvanic cell is concentrated at the anode, which suppresses corrosion of the cathode in the same cell. This article provides a detailed discussion on the fundamentals and types of cathodic protection as well as their power sources and design considerations. The criteria for the cathodic protection and types of materials used in sacrificial anodes and impressed-current anodes are also discussed. The article provides examples selected for familiarizing the design engineer with the steps for selecting a specific corrosion control method.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003607
EISBN: 978-1-62708-182-5
... films, such as mill scale (magnetite, or Fe 3 O 4 ) or iron sulfides on steel, or of lead sulfate on lead. Such films can be cathodic to the base metal exposed at breaks or pores in the scale ( Fig. 1 ) or even to such extraneous items as valves or pumps in a piping system. Fig. 1 Schematic...
Abstract
This article describes the various factors that affect the extent of corrosion resulting from galvanic coupling. The factors include galvanic series, polarization behavior, and geometric relationship of metals and alloys. The article briefly discusses the various modes of attack that lead to galvanic corrosion of anodic members. It also explains the three electrochemical techniques of screening tests for predicting galvanic corrosion. The electrochemical techniques comprise of potential measurements, current measurements, and polarization measurements. The article provides a detailed discussion on the performance of alloy groupings. It concludes with information on various control methods that reduce or eliminate galvanic-corrosion effects.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004113
EISBN: 978-1-62708-184-9
... the tank is in contact with the soil. This article describes the soil characteristics and addresses cathodic protection (CP) criteria for submerged metallic piping systems. It provides information on the data required for designing a CP system, alone or in conjunction with a protective coating system...
Abstract
Steel storage tanks are the primary means for storing large volumes of liquids and gaseous products. The stored fluid could be water, but it could also be volatile, corrosive, and flammable fluid requiring special precautions for storage as well. Corrosion is generally worst where the tank is in contact with the soil. This article describes the soil characteristics and addresses cathodic protection (CP) criteria for submerged metallic piping systems. It provides information on the data required for designing a CP system, alone or in conjunction with a protective coating system. These data are collected from predesign site assessments, tank electrical characteristics, and soil-resistivity measurements. The article addresses NACE Standard RP0169, which gives requirements and desired characteristics for coating in conjunction with CP. It also explains the methods of protecting aboveground storage tanks and underground storage tanks.
Book Chapter
Corrosion of Metallic Coatings
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004107
EISBN: 978-1-62708-184-9
... grit. (c) Void extending to substrate Sealing and Topcoat A standard practice is to seal the thermal spray coating with low-viscosity sealers because the metal coating is inherently porous. Once the thermal spray sacrificial coatings are applied, the sealer is applied. The sealer is used...
Abstract
A sacrificial coating applied to a steel substrate can add 20 years or more of life to the substrate, depending on its thickness and composition. Different techniques to apply sacrificial coatings offer various characteristics that contribute to corrosion resistance. This article discusses thermal spray, hotdipping, and electroplating processes used to apply coatings in steel structures. It describes the corrosion attributes of the resulting coatings and discusses the methods of protecting steel from corrosion using aluminum and zinc coatings.
Book Chapter
Conventions and Definitions in Corrosion and Oxidation
Available to PurchaseSeries: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003709
EISBN: 978-1-62708-182-5
... Simplified layouts for cathodic protection systems. (a) Impressed current cathodic protection system (b) Galvanic or sacrificial cathodic protection system Sacrificial CP (SACP)—also known as galvanic CP—protects the structure by coupling the structure to a consumable anode of a more active material...
Abstract
This article presents common conventions and definitions in corrosion, electrochemical cells, cathodic protection (CP), electricity, and oxidation. Evans diagrams for impressed current CP in neutral or basic environment and galvanic or sacrificial CP, in both neutral or basic environment and acidic environment, are illustrated.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003672
EISBN: 978-1-62708-182-5
... hand, the metal with the higher corrosion potential undergoes a negative shift in potential, causing it to support additional cathodic reaction and thus to corrode less. The principles of galvanic corrosion can be and often are used as means of corrosion protection. In this case, a sacrificial metal...
Abstract
This article discusses the factors affecting corrosion behavior. It describes galvanic corrosion and its protection methods. The article also provides information on coatings and inhibitors, which are used in corrosion protection.
Book Chapter
Compatibility Guide
Available to PurchaseBook: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0006541
EISBN: 978-1-62708-183-2
...+paint or resin seal C Cadmium, beryllium Chromate conversion coating+paint or resin seal D Aluminum, Al-Mg, Al-Zn Anodic coating+paint or resin seal E Aluminum-copper Anodic coating+paint or resin seal F Steel, carbon and low alloy Metallic coating, sacrificial (Zn) or nonsacrificial...
Abstract
This guide rates the compatibility of dissimilar structural materials joined together for service in seawater, marine atmosphere, or industrial atmosphere. It contains a table that indicates the material code and most generally effective surface treatment typically used to reduce corrosion of bare metals.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003808
EISBN: 978-1-62708-183-2
... Abstract From the standpoint of corrosion protection of iron and steel, metallic coatings can be classified into two types: noble coatings and sacrificial coatings. This article focuses on hotdipped zinc, aluminum, zinc-aluminum alloy and aluminum-zinc alloy coatings. It discusses the Sendzimir...
Abstract
From the standpoint of corrosion protection of iron and steel, metallic coatings can be classified into two types: noble coatings and sacrificial coatings. This article focuses on hotdipped zinc, aluminum, zinc-aluminum alloy and aluminum-zinc alloy coatings. It discusses the Sendzimir process and the Cook-Norteman process, which are the two commercial processes that are used for almost all hot-dip galvanized sheet steel in the United States. The article provides a discussion on the aqueous corrosion and atmospheric corrosion of galvanized steel and aluminized steel, as well as the intergranular corrosion of galvanized steel.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001322
EISBN: 978-1-62708-170-2
... of the replacement coatings sacrificially corrode to protect the substrate, so coating thickness exerts a significant influence on coating service life. In general, thicker sacrificial coatings contain more metal (i.e., greater coating weight) and will sacrificially corrode to protect the substrate steel...
Abstract
Environmental and worker health regulations have increased the costs associated with cadmium coating application and cadmium-beating waste disposal, thus creating economic incentives for industrial users to seek cadmium plating replacements. This article presents a cadmium replacement identification matrix that includes information on the specifications, corrosion control performance, environment-assisted cracking, coating lubricity, environmental and worker health regulations, and cost and performance factors for various replacement processes.
Book Chapter
Laser-Induced Forward Transfer Processes in Additive Manufacturing
Available to PurchaseSeries: ASM Handbook
Volume: 24
Publisher: ASM International
Published: 15 June 2020
DOI: 10.31399/asm.hb.v24.a0006565
EISBN: 978-1-62708-290-7
... Abstract This article discusses the basic operating principles, industrial applications, and advantages as well as the parameters influencing the process of laser-induced forward transfer (LIFT) of solid materials, liquid materials, laser-absorbing layers, intact structures, and metallic 3D...
Abstract
This article discusses the basic operating principles, industrial applications, and advantages as well as the parameters influencing the process of laser-induced forward transfer (LIFT) of solid materials, liquid materials, laser-absorbing layers, intact structures, and metallic 3D microstructures in additive manufacturing.
Book Chapter
Introduction to Corrosion in Specific Environments
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004100
EISBN: 978-1-62708-184-9
..., particularly chlorides, by the availability of moisture in fogs, dew, and precipitation, and by the distance from the sea. Nickel alloys and stainless steels have good corrosion resistance in marine atmospheres. Sacrificial metallic coatings applied by thermal spray, hot dipping, or electroplating can...
Abstract
This article describes the various environments affecting corrosion performance, corrosion protection, and corrosion control. These include freshwater environments, marine environments, and underground environments. The article provides information on corrosion in military environments and specialized environments, representing less-well-known environments with more limited applications.
Book Chapter
Design for Corrosion Resistance
Available to PurchaseSeries: ASM Handbook
Volume: 20
Publisher: ASM International
Published: 01 January 1997
DOI: 10.31399/asm.hb.v20.a0002471
EISBN: 978-1-62708-194-8
... paint system may comprise three or more coatings, with the first (primer) coat applied to the clean, grease-free surface. The primer coat provides corrosion suppression due to the presence of, for instance, sacrificial zinc or aluminum metallic particles, or zinc chromate or phosphate inhibitors...
Abstract
This article discusses the principles of corrosion and the basis of the various prevention measures that can be taken for different corrosion modes. It describes aqueous corrosion phenomena in terms of the electrochemical reactions that occur at the metal-environment interface. The article explains the specific forms of corrosion, including general corrosion, localized attack, and environmentally assisted cracking. It provides a discussion on the engineering aspects of design that can, without due care and attention, precipitate unexpected premature failure. The article reviews ways to improve corrosion awareness and prevent corrosion/degradation. It describes a life prediction method with an example of environmental degradation in light-water nuclear reactors. The article concludes with a discussion on the validation of life-prediction algorithms and their applications.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004162
EISBN: 978-1-62708-184-9
...-resistant sheet metals, such as electrogalvanized steel, hot dip galvanized steel, and hot dip galvannealed steel, are reviewed. The article provides information on the paint and sealant systems for corrosion control in automotive body applications. automotive body applications corrosion control...
Abstract
This article discusses the commonly encountered forms of automotive body corrosion. The corrosion forms include general or uniform corrosion, cosmetic or under-film corrosion, galvanic corrosion, crevice corrosion, poultice or under-deposit corrosion, and pitting corrosion. Corrosion-resistant sheet metals, such as electrogalvanized steel, hot dip galvanized steel, and hot dip galvannealed steel, are reviewed. The article provides information on the paint and sealant systems for corrosion control in automotive body applications.
Book Chapter
Introduction to Corrosion of Nonferrous Metals and Specialty Products
Available to PurchaseBook: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003814
EISBN: 978-1-62708-183-2
... (the coatings become sacrificial anodes). In such cases, coating porosity is acceptable, and low-cost/rapid-deposition spray processes can be used. Second, dense coatings of metals and alloys with much higher corrosion resistance than steel (notably titanium and nickel-base) can be used, provided they are dense...
Abstract
Nonferrous metals and alloys are widely used to resist corrosion. This article describes the corrosion behavior of the most widely used nonferrous metals, such as aluminum, copper, nickel, and titanium. It also provides information on several specialty nonferrous products that cannot easily be categorized by elemental base.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001250
EISBN: 978-1-62708-170-2
... Abstract A tin deposit provides sacrificial protection to copper, nickel, and many other nonferrous metals and alloys. Tin also provides good protection to steel. Tin can be deposited from either alkaline or acid electrolytes. This article explains the compositions and operating conditions...
Abstract
A tin deposit provides sacrificial protection to copper, nickel, and many other nonferrous metals and alloys. Tin also provides good protection to steel. Tin can be deposited from either alkaline or acid electrolytes. This article explains the compositions and operating conditions of these electrolytes.
Book Chapter
Thermal Spray Coatings for Corrosion Protection in Atmospheric and Aqueous Environments
Available to PurchaseBook: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003832
EISBN: 978-1-62708-183-2
... and aluminum-magnesium that have a corrosion potential less noble than that of steel. When the steel surface is covered with such metals, it does not corrode, even if pores exist in the coating. The coating is acting as a sacrificial anode, and the steel is cathodically protected. The term metallizing...
Abstract
This article provides a general technical description of thermal spray coatings used for corrosion protection in atmospheric and aqueous environments. It further discusses two basic coating approaches of corrosion protection, namely, the sacrificial coating of thermal spray aluminum (TSA) and thermal spray zinc (TSZ), and the barrier-type coating of corrosion-resistant materials. The emphasis is on sacrificial coatings. The article describes the steps involved in the application of TSA and TSZ: surface preparation, coating deposition, and postspray treatment. It discusses their field exposure tests and application history. The article also contains helpful information on the dense barrier coatings by high-velocity spraying processes along with their corrosion performance.
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