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rheological behavior
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Published: 01 December 2009
Image
Published: 01 January 1996
Fig. 16 Unloading and reloading behavior for two rheological models. The first strain history causes only elastic deformation during unloading, but the second one is sufficiently large to cause compressive yielding. The third history is completely reversed and causes a hysteresis loop
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Image
Published: 01 January 1996
Fig. 17 Behavior of a multistage spring-slider rheological model for an irregular strain history. A model having the monotonic stress-strain curve (a) is subjected to strain history (b), resulting in stress-strain response (c). Adapted from Ref 21
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Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005224
EISBN: 978-1-62708-187-0
... Abstract Semisolid metal (SSM) processing is a special die casting process, where partially solidified metal slurry is injected into a die cavity to form die cast components. This article discusses the flow behavior of an SSM slurry with emphasis on viscosity, rheological behavior, and yield...
Abstract
Semisolid metal (SSM) processing is a special die casting process, where partially solidified metal slurry is injected into a die cavity to form die cast components. This article discusses the flow behavior of an SSM slurry with emphasis on viscosity, rheological behavior, and yield stress. It illustrates the microstructural formation of semisolids under forced convection. The article concludes with an illustration that compares two SSM processes, namely, thixocasting and rheocasting.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006849
EISBN: 978-1-62708-395-9
... for Rheological Measurement of Polymer Melts Using Dynamic Mechanical Procedures ,” D 4440-15 Plastics (III), Vol 8.03 , Annual Book of ASTM Standards , ASTM International 23. “ Standard Practice for Measuring the Cure Behavior of Thermosetting Resins Using Dynamic Mechanical Procedures ,” D 4473-16...
Abstract
This article addresses some established protocols for characterizing thermoplastics and whether they are homogeneous resins, alloyed, or blended compositions or highly modified thermoplastic composites. It begins with a discussion on characterizing mechanical, rheological, and thermal properties of polymer. This is followed by a section describing molecular weight determination using viscosity measurements. Next, the article discusses the use of cone and plate and parallel plate geometries in melt rheology. It then reviews the processes involved in the analysis of thermoplastic resins by chromatography. Finally, the article covers three operations of thermoanalysis, namely differential scanning calorimetry, thermogravimetric analysis, and thermomechanical testing.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006930
EISBN: 978-1-62708-395-9
... begins with an examination of flow behavior. It describes the geometries and methods employed for rheological testing of polymers in their molten state. It also discusses materials that are predominantly in the solid state and the methods employed for solids testing. Examples of unidirectional...
Abstract
Rheology is defined as the study of the flow and deformation of matter. This article begins with an examination of flow behavior. It describes the geometries and methods employed for rheological testing of polymers in their molten state. It also discusses materials that are predominantly in the solid state and the methods employed for solids testing. Examples of unidirectional and dynamic oscillatory testing are provided for different mechanical behaviors.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003023
EISBN: 978-1-62708-200-6
... Abstract Thermal analysis provides a powerful tool for researchers and engineers in determining both unknown and reproducible behavioral properties of polymer molecules. This article covers the thermal analysis and thermal properties of engineering plastics with respect to chemical composition...
Abstract
Thermal analysis provides a powerful tool for researchers and engineers in determining both unknown and reproducible behavioral properties of polymer molecules. This article covers the thermal analysis and thermal properties of engineering plastics with respect to chemical composition, chain configuration, conformation of the base polymers, processing of the base polymers with or without additives; and the response to chemical, physical, and mechanical stresses of base polymers as unfilled, shaped articles or as components of composite structures. It also describes thermal analysis techniques, including differential scanning calorimetry, thermogravimetric analysis, thermomechanical analysis, and rheological analysis. This article also summarizes the basic thermal properties used in the application of engineering plastics, such as thermal conductivity, temperature resistance, thermal expansion, specific heat, and the determination of glass transition temperatures. It concludes with a discussion of the thermal and related properties of nine thermostat resin systems divided into three groups by low, medium, and high service temperature capabilities.
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006381
EISBN: 978-1-62708-192-4
... of the properties, such as pumpability. However, applicability for vibration-rich applications and the running speed require a more detailed analysis of the grease shear flow in order to understand the rheological behavior of the grease. Nevertheless, a first grease selection can already be made using...
Abstract
This article describes the main advantages of using grease as a lubricant rather than oil. It discusses the formulation, lubricating mechanism, degradation, and characterization of grease. The article describes the parameters that determine lifetime of grease, including low-temperature limit, low-temperature performance limit, high-temperature performance limit, and high-temperature limit. The article concludes with information on the practical use of grease as a lubricant reservoir.
Series: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006904
EISBN: 978-1-62708-392-8
... and negative impacts of high viscosity is mitigated by the shear-thinning behavior of many hydrogels. Changes in bioink concentration, polymer molecular weight, ion content, temperature, and encapsulated cell density directly influence bioink viscosity. In addition to shear-thinning, other rheological...
Abstract
The field of bioprinting is a subset of additive manufacturing (AM) that is rapidly expanding to meet the needs of regenerative medicine and tissue engineering. Bioprinting encompasses a broad spectrum of issues, from cell expansion and novel bioink development to cell/stem cell printing, from organoid-based tissue organization to bioprinting of human-scale tissue structures, and from building cell/tissue/organ-on-a-chip to biomanufacturing of multicellular engineered living systems. This article focuses on two challenges regarding bioprinting: bioinks and crosslinking. It describes the methods for characterizing the performance of bioink formulations and the effectiveness of crosslinking strategies. The topics covered include modalities of bioprinting, characteristics of bioink, rheological properties of bioink sols, rheological measurements, mathematical models of bioink rheology, postfabrication polymer network mechanics, mechanical properties of crosslinked bioinks, and printability of bioinks. Finally, specific strategies used for crosslinking bioinks, as well as some emerging strategies to further improve bioinks and their crosslinking, are summarized.
Series: ASM Handbook
Volume: 22B
Publisher: ASM International
Published: 01 November 2010
DOI: 10.31399/asm.hb.v22b.a0005509
EISBN: 978-1-62708-197-9
... (shape change) Statistical dispersion of geometrical and quality parameters of HIPed parts as a result of a normal scatter in the process parameters and the starting properties of the processed materials Influence of the rheological properties of the materials involved during HIP of a capsule...
Abstract
This article discusses the two major applications of hot isostatic pressing (HIP), such as healing of inherent internal defects in castings and welds, and consolidation of powder materials. It describes the design principles of the HIP tooling, as well as the problems associated with mathematical modeling of HIP. The article presents an example for the modeling process of the HIP. It reviews the numerical modeling and tooling design of a casing component demonstration.
Series: ASM Handbook
Volume: 24
Publisher: ASM International
Published: 15 June 2020
DOI: 10.31399/asm.hb.v24.a0006571
EISBN: 978-1-62708-290-7
... ceramic processes. For traditional powder metallurgy processes, binder functions include binding of particles, prevention of particle agglomeration, tailoring of rheological behavior, complete burnout, ensuring postsintering part retention, and minimization of debinding defects ( Ref 1 ). Because few...
Abstract
The highly irregular morphologies of ceramic powder particles due to their process history present a challenge to binder jetting additive manufacturing (BJ-AM) ceramic powder feedstock processability, but knowledge of powder metallurgy of ceramics benefits the development and analysis of the BJ-AM ceramic processes. Understanding BJ-AM process principles and ceramics processing challenges requires reviewing a number of fundamental principles, which this article delineates. The discussion covers the processability considerations, a brief summary of some fundamental aspects of modeling of liquid permeation in the powder bed, and process capabilities and advantages of BJ-AM technology.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006924
EISBN: 978-1-62708-395-9
... amine Fig. 3 Fast-reacting two-part polyurethane thermoset. Approximately 5 mg, heated at 10 °C/min (18 °F/min) from 10 to 250 °C (50 to 480 °F). DSC, differential scanning calorimetry. Source: Ref 10 Fig. 5 Thermoset rheological measurements. Schematics adapted from Ref 2...
Abstract
This article discusses the most common thermal analysis methods for thermosetting resins. These include differential scanning calorimetry, thermomechanical analysis, thermogravimetric analysis, and dynamic mechanical analysis. The article also discusses the characterization of uncured thermosetting resins as well as the curing process. Then, the techniques to characterize the physical properties of cured thermosets and composites are presented. Several examples of stress-strain curves are shown for thermosets and thermoplastic polymers.
Series: ASM Handbook
Volume: 4B
Publisher: ASM International
Published: 30 September 2014
DOI: 10.31399/asm.hb.v04b.a0005933
EISBN: 978-1-62708-166-5
... on CNT nanofluid by Ding et al. ( Ref 41 ) found shear-thinning behavior at low shear rates but slight shear thickening at shear rates greater than 200 s −1 . Kulkarni et al. investigated the rheological behavior of copper oxide (CuO) nanoparticles of 29 nm average diameter dispersed in deionized water...
Abstract
Nanofluids offer a completely different behavior of wetting kinetics and heat-removal characteristics, which are exploited in industrial heat treatment for quenching. This article provides information on the important thermophysical properties of nanofluids, namely, thermal conductivity, viscosity, specific heat, density, and surface tension. It reviews wetting and boiling heat-transfer characteristics of nanofluids as quenchants and highlights the importance of using nanofluids as effective quench media for the hardening process during heat treatment. The article describes the effect of nanoparticle addition on the microstructure, mechanical properties of components, wetting kinetics, and kinematics.
Series: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006855
EISBN: 978-1-62708-392-8
... for the 3D bioprinting process ( Ref 13 ). Further, biological cues, such as growth factors or ECM molecules, can be added to the hydrogel to improve or guide cell behavior toward specialized applications ( Ref 3 ); however, such biomolecule-based approaches are not considered in this article...
Abstract
This article discusses alginate/gelatin-based bioinks in 3D bioprinting applications, providing a summary of the most relevant previous work in the field. It presents advanced compositions to enhance functionality and/or optimize hydrogels for 3D bioprinting. The article discusses advanced printing techniques for alginate/gelatin-based bioinks.
Series: ASM Handbook
Volume: 22B
Publisher: ASM International
Published: 01 November 2010
DOI: 10.31399/asm.hb.v22b.a0005503
EISBN: 978-1-62708-197-9
.... However, the rheological behavior of a powder-binder feedstock mixture is significantly different from that of a thermoplastic. Hence, the direct application of methods developed for thermoplastics to PIM requires caution ( Ref 4 , 10 ). Commercial software packages, including Moldflow (Moldflow Corp...
Abstract
This article focuses on the axisymmetric 2.5-dimensional approach used in metal powder injection molding (PIM) simulations. It describes three stages of PIM simulations: filling, packing, and cooling. The article discusses the process features of numerical simulation of PIM, such as filling and packing analysis, cooling analysis, and coupled analysis between filling, packing, and cooling stages. It explains the experimental material properties and verification for filling, packing, and cooling stages in the PIM simulations. The article presents simulation results from some of the 2.5-dimensional examples to demonstrate the usefulness of the computer-aided engineering analysis and optimization capability of the PIM process.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.9781627083959
EISBN: 978-1-62708-395-9
Book: Fatigue and Fracture
Series: ASM Handbook
Volume: 19
Publisher: ASM International
Published: 01 January 1996
DOI: 10.31399/asm.hb.v19.a0002365
EISBN: 978-1-62708-193-1
... at a yield stress σ o . Unloading and reloading may cause only elastic deformation, or the frictional slider may move if the strain excursion is sufficiently large. Fig. 16 Unloading and reloading behavior for two rheological models. The first strain history causes only elastic deformation during...
Abstract
This article discusses two major approaches in estimating fatigue life from the viewpoint of their use as engineering methods. These include the stress-based (S-N curve) approach and strain-based approach. The stress-based and strain-based approaches are compared, with some comments on their manner of use and limitations. The use of the Palmgren-Miner rule for life prediction for variable amplitude loading is also discussed.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005273
EISBN: 978-1-62708-187-0
... be reheated to achieve the structures necessary for casting. The second casting process combines billet sawing, reheating, and the actual injecting of material into the mold. The article focuses on these processes and provides information on rheological tests. It discusses some key design concepts used...
Abstract
This article provides an overview of the thixocasting process and discusses the concepts that are important to the practical application of this technology. The thixocasting process involves two casting processes. The first casting process is required to make the feedstock that must be reheated to achieve the structures necessary for casting. The second casting process combines billet sawing, reheating, and the actual injecting of material into the mold. The article focuses on these processes and provides information on rheological tests. It discusses some key design concepts used in thixocasting. The article illustrates the differences between a conventional high-pressure die-casting injection profile and the thixocasting injection profile used to produce the same part.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006941
EISBN: 978-1-62708-395-9
... related, in the sense that both terms describe the combined elastic solid and viscous fluid mechanical behavior of plastic materials. However, viscoelasticity is primarily the term used for solid polymers, while rheologic terminology would be used to describe the flow of liquid polymers. One...
Abstract
This article describes the viscoelastic behavior of plastics in their solid state only, from the standpoint of the material deforming without fracturing. The consequences of viscoelasticity on the mechanical properties of plastics are described, especially in terms of time-dependencies, as well as the dependence of the viscoelastic character of a plastic on chemical, physical, and compositional variables. By examining the viscoelastic behavior of plastics, the information obtained are then applied in situations in which it may be important to anticipate the long-term properties of a material. This includes assessing the extent of stress decay in materials that are pre-stressed, the noise and vibration transmission characteristics of a material, the amount of heat build-up in a material subjected to cyclic deformation, and the extent a material can recover from any prior deformation. Several qualitative graphs are presented, which highlights the possible differences in the viscoelastic behavior that can exist among plastics.
Series: ASM Handbook
Volume: 20
Publisher: ASM International
Published: 01 January 1997
DOI: 10.31399/asm.hb.v20.a0002490
EISBN: 978-1-62708-194-8
... forming, and injection molding are similar in principle to processes used in the metals, plastics, and food industries. Experience in these areas can be used insofar as rheological behavior is similar. The abrasiveness of ceramics requires that production equipment otherwise similar to other industries...
Abstract
This article provides an overview of the steps that are used in ceramics processing and related mechanical design considerations. It discusses various design approaches, such as the empirical design, the deterministic design, and the probabilistic design. The article presents a general process design flowchart for ceramic processing. Information on traditional ceramics and advanced ceramics is also provided. The article describes various ceramic forming processes, such as wet processing, plastic forming, dry processing, and machining. The factors for evaluating different ceramic forming processes are summarized in a table. The article discusses vitrification and sintering that generally pertain to ceramic firing and concludes with a discussion on firing process factors.
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