This article is a compilation of binary alloy phase diagrams for which rhenium (Re) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

This article is a compilation of binary alloy phase diagrams for which vanadium (V) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

This article is a compilation of binary alloy phase diagrams for which uranium (U) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

This article is a compilation of binary alloy phase diagrams for which tellurium (Te) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

This article is a compilation of binary alloy phase diagrams for which silicon (Si) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

This article is a compilation of binary alloy phase diagrams for which niobium (Nb) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

This article is a compilation of binary alloy phase diagrams for which molybdenum (Mo) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

This article is a compilation of binary alloy phase diagrams for which boron (B) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

This article is a compilation of binary alloy phase diagrams for which nickel (Ni) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

This article is a compilation of binary alloy phase diagrams for which chromium (Cr) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

This article is a compilation of more than 35 binary alloy phase diagrams for which cobalt (Co) is the first named element in the binary pair. The diagrams plot alloy composition in terms of weight percent, while indicating atomic percent along a secondary scale. Each diagram is accompanied by a table of crystallographic data that includes composition ranges as well as the Pearson symbol, space group, and prototype for each phase.

This article describes various procedures used in the metallographic preparation of niobium, tantalum, molybdenum, and tungsten alloys. It provides information on sectioning, grinding, mounting, polishing, and electrolytic etching as well as alternate procedures that have been used on refractory metals. The article presents and analyzes several micrographs, provides etchant formulas for various materials, and discusses the unique characteristics of rhenium and its alloys.

This article discusses special metallurgical considerations during the fusion welding of refractory metal alloys. These considerations are: microstructure, interstitial impurities, and welding conditions that are considered during the fusion welding of refractory metal alloys, including tantalum, niobium, rhenium, molybdenum, and tungsten. Refractory metal alloys are discussed in the order of decreasing weldability: tantalum, niobium, rhenium, molybdenum, and tungsten.

This article focuses on the industrial applications of phase diagrams. It presents examples to illustrate how a multicomponent phase diagram calculation can be readily useful for industrial applications. The article demonstrates how the integration of a phase diagram calculation with kinetic and microstructural evolution models greatly enhances the power of the CALPHAD approach in materials design and processing development. It also discusses the limitations of the CALPHAD approach.

The application of phase diagrams is instrumental in solid-state transformations for the processing and heat treatment of alloys. A unary phase diagram plots the phase changes of one element as a function of temperature and pressure. This article discusses the unary system that can exist as a solid, liquid, and/or gas, depending on the specific combination of temperature and pressure. It describes the accomplishment of conversion between weight percentage and atomic percentage in a binary system by the use of formulas. The article analyzes the effects of alloying on melting/solidification and on solid-state transformations. It explains the construction of phase diagrams by the Gibbs phase rule and the Lever rule. The article also reviews the various types of alloy systems that involve solid-state transformations. It concludes with information on the sources of phase diagram.

This article discusses the adhesion behavior of materials in low-pressure and vacuum environments and provides a schematic illustration of an apparatus for measuring adhesion and friction in ultrahigh vacuum. It describes the effects of low-oxygen pressures and vacuum environments on adhesion and friction, as well as the effects of defined exposure to oxygen on friction. The article discusses the wear of various metals in contact with ceramics, and alloying element effects on friction, wear, and transfer of materials. It also describes studies that characterize the contributions of surface contamination and chemical changes to tribology in low-pressure and vacuum environments.

Directionally solidified (DS) and single-crystal (SX) superalloys and process technology are contributing to significant advances in turbine engine efficiency and durability. These gains are expected to arise from the development of higher creep strength and improved oxidation-resistant SX alloy compositions as well as from the development of SX casting and fabrication technology to utilize advanced transpiration-cooling schemes. This article provides a detailed discussion on the chemistry and castability of first- and second-generation DS and SX superalloys. It summarizes the chemistry modifications applied to MAR-M 247 to develop CMSX-2 with respect to function and objectives. The article also lists the nominal compositions of first- and second-generation DS and SX superalloys.

This article examines the characteristics and behavior of scale produced by various types of oxidation. The basic models, concepts, processes, and open questions for high-temperature gaseous corrosion are presented. The article describes the development of geometrically induced growth stresses, transformation stresses, and thermal stresses in oxide scales. It discusses the ways in which stresses can be relieved. The article provides information on catastrophic oxidation, internal oxidation, sulfidation, alloy oxidation, selective oxidation, and concurrent oxidation. It illustrates the relationships between scale morphologies on binary alloys and concludes with a discussion on metal dusting and chlorine corrosion.

Chemical vapor deposition (CVD) involves the formation of a coating by the reaction of the coating substance with the substrate. Serving as an introduction to CVD, the article provides information on metals, ceramics, and diamond films formed by the CVD process. It further discusses the characteristics of different pack cementation processes, including aluminizing, siliconizing, chromizing, boronizing, and multicomponent coating.

This article explains how to prepare precious metal test samples for metallographic examination. It discusses cutting, mounting, grinding, polishing, and etching and addresses some of the challenges of working with small, relatively soft specimens. It includes dozens of example micrographs, comparing and contrasting the microstructural features of gold, platinum, iridium, palladium, and ruthenium-base alloys. It examines pure gold, intermetallic gold compounds, gold and platinum jewelry alloys, platinum-containing shape memory alloys, and alloys consisting of platinum, aluminum, and copper.