This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of a type of resin-matrix composites, carbon-epoxy composites. The fractographs illustrate the fracture modes found in composite prepregs, composite panels, solid rocket motor nozzles, and tension, flexural, compressive, and shear loadings.

This article describes the resin and fabrication requirements associated with fiberglass-reinforced plastic equipment. It provides a discussion on various resins and their resistance to various environments. These include polyester, epoxy, epoxy vinyl-ester, and furan and phenolic thermosetting resins. The article concludes with a discussion on the curing system of thermosetting resins.

This article discusses the materials and properties of polymer-matrix composites to characterize each generic material according to its composition and method of manufacture. It contains a table that lists the key physical, mechanical, thermal, and electrical properties, and in-service conditions of concern for resin-matrix composites. Axes definitions, symbols, and special property calculations for composite material property tests are reviewed. The article provides an overview of the performance capabilities of selected polymer-matrix composite materials such as thermoplastic-matrix composites and thermoset-matrix composites. The thermoplastic-matrix composites include thermoplastic polyester resins and fiber resin composites; thermoplastic polyamide resins and fiber-resin composites; and thermoplastic polysulfone resins and fiber-resin composites.

This article discusses the composition of the major components of dental composite resins: organic resin matrix, filler, coupling agents, and initiator-accelerator systems. It describes the properties of composite resins that are related to the amount and type of filler and resin-matrix compositions. The article also discusses the compositions, properties, and clinical applications of polyacid-modified composite resins and resin-modified glass-ionomer cements. It concludes with information on biodegradation and biocompatibility of resin-based restorative materials.

This article provides an overview of the environmental performance of the most commonly used nonmetallic materials, including elastomers, plastics, thermosetting resins, resin-matrix composites, organic coatings, concrete, refractories, and ceramics. It also discusses the applications and uses of these materials.

This article discusses the material combinations, design details, and fabrication processes considered in the adhesive bonding or melt-fuse interface (amorphous bond) bonding method of joining resin-matrix composites to metals.

The design and analysis of aerospace and industrial composite components and assemblies requires a detailed knowledge of materials properties, which, in turn, depend on the manufacturing, machining, and assembly methods used. This article, through several tables and graphs, provides the mechanical properties, physical properties, and service characteristics of representative composite fiber-resin combinations, including thermoplastic matrix composites such as thermoplastic polyester resins, thermoplastic polyamide resins, and thermoplastic polysulfone resins, and thermoset matrix composites such as thermoset polyester resins, thermoset phenolic resins, thermoset epoxy resins, thermoset polyimide resins, and thermoset bismaleimide resins.

This article describes the interaction of composition, manufacturing process, and composite properties of composites. The manufacturing process includes resin-matrix, metal-matrix, and carbon/carbon matrix processing. The article discusses various mechanical properties of composites. It explores how variations in the composition, manufacturing, shop process instructions, and loading/environmental conditions can affect the use of a composite product in a performance/service life operation.

This article begins with a discussion on fiber-reinforced composite materials and describes the generic behavior and structure/property relationships of composites. The article summarizes lamina properties and presents equations that help in the calculation of lamina properties. Composite laminates are constructed from lamina with uniaxial fiber orientation and frequently from textile fabrics as well. The article explains the characteristics of symmetric in-plane and through-thickness laminates; asymmetric in-plane and symmetric through-thickness laminates; asymmetric laminates; and curved laminates. It provides information on controlled thermal expansion composites, metal-matrix composites, and ceramic-matrix composites. The article illustrates the types of bonded joints and concludes with a discussion on design for manufacturing.

This article discusses the types, properties, and uses of continuous-fiber-reinforced composites, including glass, carbon, aramid, boron, continuous silicon carbide, and aluminum oxide fiber composites. While polyester and vinyl ester resins are the most used matrix materials for commercial applications, epoxy resins, bismaleimide resins, polyimide resins, and thermoplastic resins are used for aerospace applications. The article addresses design considerations as well as product forms and fabrication processes.

Open molding is the method used in the polymer-matrix composites industry to make thermoset composite products. This article discusses the advantages, disadvantages, and applications of the open molding. It describes the various process of the open molding, such as hand lay-up process and spray-up process. Workmanship for hand lay-up and spray-up processes is reviewed. The article provides information on the matrix-resin materials used for open molding, including unsaturated polyester resins, epoxy vinyl ester resins, and reinforcements. It explains the component design and short- and long-term properties of a fiber reinforced composite laminate depending on material selection and workmanship. The article also presents the basic design guidelines for open molding.

Characterization of nonmechanical properties is performed in the testing and certification of composite materials. This article focuses on the properties of composites that are commonly investigated. The properties include: per ply thickness; constituent content; density; coefficient of thermal expansion and coefficient of moisture expansion; glass transition temperature; thermal conductivity, diffusivity, and specific heat.

This article provides an overview of how fractographs in this Atlas are organized and presented. It contains a table that lists the distribution content of illustrations for various materials discussed in the Atlas. The causes of fractures for various ferrous and nonferrous alloys and engineered materials are also illustrated.

This article illustrates the polymer matrices used for composite materials. It describes the use of prepeg materials in manufacturing high-performance composites. The article discusses the various infusion processes for the development of fiber-reinforced composites, namely, resin transfer molding, vacuum-assisted resin transfer molding, and resin film infusion. It explains the composite- and matrix-toughening methods for fiber-reinforced composites, such as dispersed-phase toughening and interlayer toughening. The article concludes with information on optical microscopy, which provides an insight into the micro- and macrostructure of fiber-reinforced composites.

Hygrothermal behavior of cured composite materials relates to the combined and commonly synergistic effects of moisture absorption and temperature on various physical, chemical and mechanical properties. This article focuses on the influence of resins or matrices, reinforcements, processing, and diffusion on hygrothermal behavior of polymer-matrix composites and provides an outline on general considerations in assessing them. It discusses the hygrothermal testing and conditioning of polymer-matrix composites to assess fundamental hygrothermal behavior. The article provides information on the accelerated aging process for understanding the degradation mechanisms and failure modes in composites. It also describes the effect of moisture absorption on mechanical properties of polymer-matrix composites.

This article addresses the types, properties, forms, and applications of fibers that are available for use in fiber-reinforced polymeric matrix composites, including glass, graphite, carbon, aramid, boron, silicon carbide, ceramic, continuous oxide and discontinuous oxide fibers. It describes the functions, types, and chemical composition of fiber sizing agents. The article discusses the styles, properties, applications, and weaving methods of unidirectional, two-directional and multidirectionally reinforced fabrics. The article also reviews the use of prepreg resins in aerospace and lower performance applications.

This article provides information on the thermoplastic resins used as matrix materials for continuous fiber reinforced composites. It focuses on the materials that are suitable for fabrication of structural laminates and used for aerospace applications. The article provides a discussion on the background, categories, characteristics, product forms, properties, cost benefits, and processing techniques of thermoplastic resins. Strategies that have been advanced to deal with impregnation difficulties are also discussed.

The goal of design is to improve the overall performance of the metal or ceramic matrix rather than to create a material with different response than the base matrix. This article focuses on the design for manufacturing polymeric composites. Specially developed methods including contact molding, compression-type molding, resin-injection molding, and pultrusion are described. The article also discusses the various factors to be considered in designing for composite manufacturing.

This article describes the use of conventional machining techniques, laser cutting and water-jet cutting for producing finished composite parts. It explains two representative polymer-matrix composites--graphite and aramid composites--and discusses the machining and drilling problems such as delamination and fiber or resin pullout. The article describes machining and drilling techniques and the necessary tools and cutting parameters. It presents a description of laser cutting. The article also provides information on the advantages, disadvantages, cutting characteristics, and applications of water-jet cutting and abrasive water-jet cutting.

This article provides a summary of the concepts discussed in the articles under the Section “Constituent Materials” in ASM Handbook, Volume 21: Composites. The Section describes the major matrix resins and reinforcing fibers used in composite materials, as well as some of the intermediate material forms available for composite fabrication.