This article illustrates the polymer matrices used for composite materials. It describes the use of prepeg materials in manufacturing high-performance composites. The article discusses the various infusion processes for the development of fiber-reinforced composites, namely, resin transfer molding, vacuum-assisted resin transfer molding, and resin film infusion. It explains the composite- and matrix-toughening methods for fiber-reinforced composites, such as dispersed-phase toughening and interlayer toughening. The article concludes with information on optical microscopy, which provides an insight into the micro- and macrostructure of fiber-reinforced composites.

Resin transfer molding and structural reaction injection molding belong to a family, sometimes denoted as liquid composite molding. This article provides information on the characteristics and automotive and aerospace applications of liquid composite molding. It reviews techniques that use hard tooling and positive (superatmospheric) pressures to produce structures. The techniques include vacuum-assisted resin injection, vacuum infusion, resin-film infusion, and injection-compression molding. The article provides an overview of the materials that are commonly used together with some of processing characteristics that are important to processing speed and part quality. It concludes with a discussion on design guidelines for the liquid composite molding.

This article presents the basic guidelines considered in designing a composite structure, and the basic definitions of terms that apply to composites. It describes the analysis of a composite laminate based on stress-strain relationships, stress-strain load relationships, general load displacement case, and general load case solution. Factors affecting the composite materials properties and allowables of fiber-reinforced polymers are reviewed. The article discusses the process considerations for mold design, such as master model, metal tooling, composite tooling, and tool care. It describes the resin selection in designing the composite for use in a particular application. The article illustrates the various methods that are used to process a composite component, namely, wet lay-up, autoclave, resin transfer molding, and vacuum-assisted resin transfer molding. It provides a discussion on electromagnetic interference shielding, electrostatic discharge protection, metal plating, fire resistance, and corrosion resistance on composite materials.

Resin transfer molding (RTM) and structural reaction injection molding (SRIM) are two similar processes that are well suited to the manufacture of large, complex, and high-performance structures. This article discusses the similarities and differences of RTM and SRIM processes and the unique design considerations with respect to the physical properties, geometry, surface quality, process economics, equipment, and tooling of a component that should be considered in choosing RTM or SRIM over other competing processes for fabricating reinforced components.

This article discusses bismaleimide (BMI) chemistry and the use of BMI in composites. An analysis of the applications illustrates how the advantages of BMIs have been exploited and perhaps suggests how these advantages might be extended to other applications. The article describes the mechanical properties of BMI composites. BMIs suitable for resin transfer molding processing are provided. The article concludes with information on the elevated-temperature applications of 5250-4 BMI system.

Vacuum infusion is a resin injection technique derived from resin transfer molding. This article discusses the characteristics of the technique and its applications. It presents the theory and background of the technique and provides an illustration of how parts are made. The article provides information on equipment and material used for vacuum infusion. It describes the mechanical properties of components and summarizes the influence of production on the properties. The article concludes with a discussion on design guidelines.

Continuous fiber composite materials offer dramatic opportunities for producing lightweight laminates with tremendous performance capabilities. This article describes the kinematics of fabric deformation and explains the algorithms used in draping simulation. It discusses the basic components, such as laminate and ply, of continuous fiber composite. The article provides information on core sample and ply analysis. It describes producibility, flat-pattern evaluations, and laminate surface offset. The article provides a discussion on various interfaces, such as structural analysis interface, resin transfer molding interface, fiber placement and tape-laying interface, and laser projection interface.

Molding compounds are plastic materials in varying stages of pellets or granulation that consist of resin, filler, pigments, reinforcement, plasticizers, and other ingredients ready for use in a molding operation. This article describes the material components and physical properties of sheet molding compounds (SMC). The three types of resin paste mixing techniques, such as batch, batch/ continuous, and continuous, for an SMC operation are reviewed. The article discusses the design features and functional operations of the two types of SMC machines, namely, continuous-belt and beltless machines. It explains the formulation and processing of bulk molding compounds and reviews molding methods for bulk molding compounds, including compression, transfer, and injection molding. The article discusses the effects of fiber type and length and matrix type on thermoset bulk molding compounds. It describes the four injection molding processes of injection molding compounds such as feeding, transporting, injecting, and flowing.

Shell molding is used for making production quantities of castings that range in weight from a few ounces to approximately 180 kg (400 lb), in both ferrous and nonferrous metals. This article lists the limitations or disadvantages of shell mold casting. It describes the two methods for preparation of resin-sand mixture for shell molding, namely, mixing resin and sand according to conventional dry mixing techniques, and coating the sand with resin. Shaping of shell molds and cores from resin sand mixtures is accomplished in machines. The article discusses the major steps in producing a mold or core and describes the problems most frequently encountered in shell-mold casting. The problems include mold cracking, soft molds, low hot tensile strength of molds, peelback, and mold shift. The article concludes with information on examples that provide some relative cost comparisons between shell molding and green sand molding.

Sheet molding compound (SMC) is a composite material - consisting of glass-fiber-reinforced polyester in a resin matrix - that’s available in sheet form for the production of compression-molded parts. This article discusses the components incorporated into the resin paste, including catalysts, fillers, thickeners, pigments, thermoplastic polymers, flame retardants, and ultraviolet absorbers, and how to optimize them to achieve the desired processing and molding characteristics and the necessary properties in the resulting parts. The article also presents several mixing techniques, including batch, batch/continuous, and continuous mixing, and describes the operations of continuous-belt and beltless machine type SMCs.

This article discusses various molten-metal treatments, namely fluxing, degassing, and molten-metal filtration. It focuses on various molten-metal handling systems for transporting, holding, or delivering molten metal to the mold/die system. These include launders, tundishes, holding furnaces or transport crucibles, molten-metal transfer pumps, teeming ladles, and dosing and pouring furnaces.

Rotational molding is a simple but unique process that has the capability of producing small to large hollow items with very uniform wall thicknesses. Providing an overview of the operating principles of rotational molding, this article discusses the key selection factors, including function and property requirements for resins and additives; size, shape, design, and cost of molded parts; equipment type and size; and the type of mold to be used. Commonly used molds include cast aluminum, fabricated sheet metal, nickel deposit, machined aluminum, silicone, fiberglass, and prototype molds.

This article discusses classification of foundry processes based on the molding medium, such as sand molds, ceramic molds, and metallic molds. Sand molds can be briefly classified into two types: bonded sand molds, and unbonded sand molds. Bonded sand molds include green sand molds, dry sand molds, resin-bonded sand molds, and sodium silicate bonded sand. The article describes the casting processes that use these molds, including the no-bake process, cold box process, hot box process, the CO2 process, lost foam casting process and vacuum molding process. The casting processes that use ceramic molds include investment casting, and plaster casting. Metallic molds are used in permanent mold casting, die casting, semisolid casting, and centrifugal casting.

This article focuses on epoxy because this resin category has widespread use and because it is tested using quality control measures typical of most resin systems. A typical resin system will consist of one or more epoxy resins, a curing agent, and a catalyst to control the rate of reaction. The article describes the component material tests, mixed resin system tests, and prepreg tests for the resin system. The tests include high-performance liquid chromatography, infrared spectroscopy, and gel permeation chromatography. The article contains a table that lists typical resin and prepreg property tests.

This article describes the resin and fabrication requirements associated with fiberglass-reinforced plastic equipment. It provides a discussion on various resins and their resistance to various environments. These include polyester, epoxy, epoxy vinyl-ester, and furan and phenolic thermosetting resins. The article concludes with a discussion on the curing system of the thermosetting resins with a wide variety of hardener types.

This article discusses the materials and properties of polymer-matrix composites to characterize each generic material according to its composition and method of manufacture. It contains a table that lists key physical, mechanical, thermal, and electrical properties, and in-service conditions of concern for resin-matrix composites. Axes definitions, symbols, and special property calculations for composite material property tests are reviewed. The article provides an overview of the performance capabilities of selected polymer-matrix composite materials such as thermoplastic-matrix composites and thermoset-matrix composites. The thermoplastic-matrix composites include thermoplastic polyester resins and fiber resin composites; thermoplastic polyamide resins and fiber-resin composites; and thermoplastic polysulfone resins and fiber-resin composites. The thermoset-matrix composites include thermoset polyester resins and fiber resin composites; thermoset phenolic resins and fiber resin composites; thermoset epoxy resins and fiber-resin composites; thermoset polyimide resins and fiber resin composites; and thermoset bismaleimide resins and fiber resin composites.

Injection molding is a process of forcing or injecting a fluid plastic material into a closed mold. The process generally has the advantages of being more readily automated and of permitting finer part details. Injection-molding compounds are thermoplastic or thermosetting materials and their composites that are specifically formulated for the injection-molding process. This article discusses the injection molding process, which includes the two basic categories of thermoplastic and thermoset injection molding, and lists the common thermoplastic and thermoset molding compounds and applications. It also describes the operation of the different types of injection molding machines as well as mold design and process controls. The article also describes the selection of injection-moldable thermosets, and provides an overview of part performance, properties, blowing agents, and aesthetic concerns related to thermoplastic structural-foam injection molding.

Bulk molding compounds can be molded into a variety of complex shapes by methods that can be readily automated for high volume production. This article describes the formulation and processing (compound formation, and molding methods) of bulk molding compounds. It discusses the effects of fiber type, fiber length, and matrix type on thermoset bulk molding compounds. The markets for long-fiber-reinforced bulk molding compounds are electrical, ordnance, aerospace, industrial, sporting goods, and automotive.

The compression molding process is most commonly called the sheet molding compound (SMC) process in reference to the precursor sheet molding compound material it uses. This article discusses the types of materials used for sheet manufacture, and describes the manufacturing and processing parameters of SMC components, providing details on tooling and process advantages and limitations. The article provides a general overview of the types of compression molding processes, including structural compression molding and thermoplastic compression molding.

Compression molding is the single largest primary manufacturing process used for automotive composite applications. This article provides a general overview of the compression molding process. It describes the basic design, materials, and processing equipment of three main groups of composite materials, namely, glass-fiber-mat-reinforced thermoplastics, long-fiber-reinforced thermoplastics, and sheet molding compounds. It presents information on the application examples and market volume of compression molding.