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Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0009071
EISBN: 978-1-62708-177-1
... transfer molding, vacuum-assisted resin transfer molding, and resin film infusion. It explains the composite- and matrix-toughening methods for fiber-reinforced composites, such as dispersed-phase toughening and interlayer toughening. The article concludes with information on optical microscopy, which...
Abstract
This article illustrates the polymer matrices used for composite materials. It describes the use of prepeg materials in manufacturing high-performance composites. The article discusses the various infusion processes for the development of fiber-reinforced composites, namely, resin transfer molding, vacuum-assisted resin transfer molding, and resin film infusion. It explains the composite- and matrix-toughening methods for fiber-reinforced composites, such as dispersed-phase toughening and interlayer toughening. The article concludes with information on optical microscopy, which provides an insight into the micro- and macrostructure of fiber-reinforced composites.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003413
EISBN: 978-1-62708-195-5
... that use hard tooling and positive (superatmospheric) pressures to produce structures. The techniques include vacuum-assisted resin injection, vacuum infusion, resin-film infusion, and injection-compression molding. The article provides an overview of the materials that are commonly used together with some...
Abstract
Resin transfer molding and structural reaction injection molding belong to a family, sometimes denoted as liquid composite molding. This article provides information on the characteristics and automotive and aerospace applications of liquid composite molding. It reviews techniques that use hard tooling and positive (superatmospheric) pressures to produce structures. The techniques include vacuum-assisted resin injection, vacuum infusion, resin-film infusion, and injection-compression molding. The article provides an overview of the materials that are commonly used together with some of processing characteristics that are important to processing speed and part quality. It concludes with a discussion on design guidelines for the liquid composite molding.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003432
EISBN: 978-1-62708-195-5
... functionality, which is useful in differentiating epoxies with similar EEWs. A thin film of resin is placed on a crystal, and IR light is passed through the crystal and film at varying frequencies. Functional groups absorb at certain defined frequencies. The test is usually qualitative, but because absorption...
Abstract
This article focuses on epoxy because this resin category has widespread use and because it is tested using quality control measures typical of most resin systems. It explains that a typical resin system will consist of one or more epoxy resins, a curing agent, and a catalyst to control the rate of reaction. The article describes the component material tests, mixed resin system tests, and prepreg tests for the resin system. These tests include high-performance liquid chromatography, infrared spectroscopy, and gel permeation chromatography. The article contains a table that lists typical resin and prepreg property tests.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006046
EISBN: 978-1-62708-172-6
.... , The Chemistry of Phenolic Resins , J ohn Wiley & Sons , New York , 1956 • Morrison R.T. and Boyd R.N. , Organic Chemistry , 3rd ed. , Allyn and Bacon , Boston, MA , 1973 • Myers R.R. and Long J.S. , Film Forming Compositions , Marcel Dekker Inc. , New York...
Abstract
Phenols are a class of aromatic organic compounds in which one or more hydroxyl groups are attached directly to the aromatic benzene ring, C6H6. This article describes the development of phenolic resin and the formation of novolac resin and resol resin. Phenolic resol resins are used in interior can coatings and tank linings as well as for heat exchanger tube coatings because of their high chemical and thermal resistance. The article concludes with a description of the concerns that a specifier, user, or applicator should be aware of regarding the use of phenolic coatings.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003435
EISBN: 978-1-62708-195-5
... Research Laboratories Often requires ionic doping to decrease resistivity. Can be combined with SMARTweave resin flow monitoring. Dosimetry Adherent For EB processing, film coatings or coated optical fiber versions indicate exposure levels by color changes in the film layer. See text for more...
Abstract
This article discusses the attempts made by the industry to create sensing approaches for modeling a process, part, and chemistry and kinetics. It reviews microwave curing of thick-section composites and the resin cure sensors that are used for resin cure monitoring. These include dielectric cure sensors, fiberoptics-based resin cure sensors, ultrasonics-based resin cure sensors, and dosimetry-based resin cure sensors. The article provides information on the resin cure control flow sensing, flow modeling, flow mapping, and resin flow. It addresses some practical issues in sensing resin cure and flow.
Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006530
EISBN: 978-1-62708-207-5
... adhesives modified with nitrile rubber. Thermosetting Resins Thermosetting resins are high-molecular-weight polymers that react further to form a rigid, cross-linked molecular structure. After this setting, or curing, of the resin, the permanently hard, virtually infusible solid that results cannot...
Abstract
Adhesive bonding is a proven technology in the manufacture of automotive assemblies, helping carmakers achieve weight reduction goals without compromising body stiffness, crash performance, and noise-vibration-handling characteristics. This article discusses the advantages and limitations of adhesive-bonded aluminum joints and the procedures used to produce them. It addresses surface preparation, the addition of interfacial coatings and primers, and the application of thermoplastic and thermosetting resins. The article examines the nature and role of the various layers that constitute the joint and explains how each contributes to performance. It also discusses adhesive selection factors, joint design, and testing procedures.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0009072
EISBN: 978-1-62708-177-1
.... Although this increases the cure speed, it also leads to greater cure shrinkage of the mounting resin. To ensure complete impregnation of the specimens, the mold can be placed in a vacuum chamber while infusing the resin ( Fig. 9 ). This is essentially a bell jar with a vacuum and resin port and a pinch...
Abstract
This article describes how composite specimens are sectioned, documented, and labeled during sample preparation. The mounting procedures for the specimen are summarized. The article explains sample clamping, which involves not mounting the specimens using an adhesive or casting resin and corresponds to clamped samples used in automated polishing heads. It details that cavity molds involve mounting the composite specimens using a casting resin in a preset mold. The article also discusses the mounting of composite materials for hand polishing.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003481
EISBN: 978-1-62708-195-5
... chloride foam or Kevlar honeycomb. Advanced fabrication processes, such as resin transfer molding, resin film infusion, or autoclaving, are used in the construction of the hull and decks to produce composites that are defect-free, excellent dimensional tolerance, and a high fiber content for maximum...
Abstract
This article provides information on the potential applications of fiber-reinforced polymer (FRP) composites for maritime craft and offshore drilling platforms. The key benefits gained from using FRP materials together with an examination of the drawbacks and major issues impeding the more widespread use of composites in marine structures are presented.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003407
EISBN: 978-1-62708-195-5
... tapes. There are few, truly low-temperature cure systems, and hence the selection of core materials is limited to those suitable for elevated cure. Resin infusion has its own constraints. Open cellular cores are not readily adapted to this system, and depending upon the resin system used, some...
Abstract
This article focuses on the design process, materials, and manufacturing techniques for one-off and low-volume production sailing craft. These include racing yachts of typically 10-20 m length for short coastal events, 20-25 m ocean racers, 24 m America's Cup racing craft, multihull racers of 35 m or more, and large luxury cruising craft. The article discusses the tooling, laminating practice, curing, mold removal, and quality control, for manufacturing hulls, decks, masts, and appendages using composites.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003366
EISBN: 978-1-62708-195-5
... Abstract This article describes the chemistry of phenolic resins and reviews their characteristics and properties for various composites fabrication processes. The fabrication processes include solution/hot-melt process, pultrusion, vacuum infusion, filament winding, sheet molding, and hand lay...
Abstract
This article describes the chemistry of phenolic resins and reviews their characteristics and properties for various composites fabrication processes. The fabrication processes include solution/hot-melt process, pultrusion, vacuum infusion, filament winding, sheet molding, and hand lay-up. The article illustrates the manufacturing process of phenolic honeycomb and provides information on the applications of phenolic composites.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003395
EISBN: 978-1-62708-195-5
... “Resin Transfer Molding and Structural Reaction Injection Molding,” , “Vacuum Infusion,” and “Compression Molding” in this Volume. Preimpregnated Tapes and Fabrics Laminated preimpregnated materials often offer the greatest mechanical properties. High specific strength and stiffness...
Abstract
Designing composites for structural performance initially involves meeting a set of desired performance specifications at a minimum cost. This article discusses the factors that are considered in designing the manufacturing of polymeric composites. It describes the various aspects of manufacturing, forming process, and post-processing and fabrication for designing the composites.
Book: Fatigue and Fracture
Series: ASM Handbook
Volume: 19
Publisher: ASM International
Published: 01 January 1996
DOI: 10.31399/asm.hb.v19.a0002416
EISBN: 978-1-62708-193-1
...-weight impact tests ( Ref 9 ). The [45/0/−45/90] ns AS4/3501-6 uniweave laminates were made using a resin-film-infusion (RFI) process. The average thickness per ply was 0.14 mm. The falling-weight impact tests were conducted with a 5.31 kg weight and a 12.7 mm diam hemispherical tup. The plates were...
Abstract
This article presents the damage tolerance criteria for military composite aircraft structures to safely operate the structures with initial defects or in-service damage. It describes the effects of defects, such as wrinkles in aircraft structures, and the reduction in compressive strength and tensile strength. The article reviews low velocity impacts in aircraft structures in terms of resin toughness, laminate thickness, specimen size and impactor mass, and post-impact fatigue. It explains the tension strength analysis, such as linear elastic fracture mechanics and R-curve methods, to predict the residual strength of the structures.
Book: Fractography
Series: ASM Handbook
Volume: 12
Publisher: ASM International
Published: 01 June 2024
DOI: 10.31399/asm.hb.v12.a0006878
EISBN: 978-1-62708-387-4
... is a reduction in the fiber/matrix interface strength. This can occur due to an increase in the moisture content of the resin, high temperatures, or incorrect processing ( Ref 24 , 30 ). Fig. 4 Compression microbuckling in carbon-fiber-reinforced plastic. Original magnification: 2500×. Source: Ref 5...
Abstract
This article presents the failure of polymer-matrix composites and the methodology for fractography. It provides a detailed discussion on the types of translaminar, interlaminar, and intralaminar failures. The article also presents a discussion on the types of fatigue failures, and the influence of composite architecture. It provides details of the fractography associated with defects and damage.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006864
EISBN: 978-1-62708-395-9
... parts can be categorized as: Stheets with a flat extruded cross section greater than 0.4 mm (0.016 in.) thick ( Fig. 1a ) Film with a flat extruded cross section less than 0.4 mm (0.016 in.) thick ( Fig. 1a ) Annular extrudates with a hollow circular (tubular) cross section ( Fig. 1b ) Fiber...
Abstract
This article discusses technologies focused on processing plastic materials or producing direct tools used in plastics processing. The article focuses on extrusion and injection molding, covering applications, materials and their properties, equipment, processing details, part design guidelines, and special processes. It also covers the functions of the extruder, webline handling, mixing and compounding operations, and process troubleshooting. Thermoforming and mold design are covered. Various other technologies for polymer processing covered in this article are blow molding, rotational molding, compression molding, transfer molding, hand lay-up process, casting, and additive manufacturing.
Series: ASM Handbook
Volume: 20
Publisher: ASM International
Published: 01 January 1997
DOI: 10.31399/asm.hb.v20.a0002492
EISBN: 978-1-62708-194-8
... with the skin. Film adhesive that has a similar cure cycle as the resin can be used to increase the integrity of the bond line. In Fig. 8(b) , the stiffener may or may not be precured. A second variation has the stiffener now integrated with the skin. In Fig. 8(c) , the macroscale of the design has increased...
Abstract
The goal of design is to improve the overall performance of the metal or ceramic matrix rather than to create a material with different response than the base matrix. This article focuses on the design for manufacturing polymeric composites. Specially developed methods including contact molding, compression-type molding, resin-injection molding, and pultrusion are described. The article also discusses the various factors to be considered in designing for composite manufacturing.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003010
EISBN: 978-1-62708-200-6
... Abstract A thermosetting resin, or thermoset, is a synthetic organic polymer that cures to a solid, infusible mass by forming a three-dimensional network of covalent chemical bonds. Significant applications include construction and thermoset engineering plastics. This article discusses...
Abstract
A thermosetting resin, or thermoset, is a synthetic organic polymer that cures to a solid, infusible mass by forming a three-dimensional network of covalent chemical bonds. Significant applications include construction and thermoset engineering plastics. This article discusses the general and family characteristics of thermosetting resin families, including allyls, aminos (urea formaldehyde and melamine formaldehyde), cyanates, epoxies, polybenzimidazoles, unsaturated polyesters, thermoset polyimides, phenolics, and vinyl esters. It also explains processing methods, including curing and curing agents. The article provides descriptions of commercial product forms and the wide array of applications of thermosetting resins. It also tabulates the performance properties (mechanical, thermal, electrical and chemical resistance) of some families of unfilled or unreinforced thermosetting resins and reinforced or filled grades.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003464
EISBN: 978-1-62708-195-5
... in a vacuum impregnation chamber while infusing the resin. The use of moderate vacuum to remove entrapped air, followed by applying pressure during cure, is highly effective for sample preparation and creating good adhesion. The following steps are recommended to achieve a good mounted specimen without...
Abstract
Microscopy is a valuable tool in materials investigations related to problem solving, failure analysis, advanced materials development, and quality control. This article describes the sample preparation techniques of composite materials. These techniques include mounting, rough grinding, and polishing. The preparation techniques of ultrathin sections are also summarized. The article explains the illumination methods used by reflected light microscopy to view a specimen. These consist of epi-bright-field illumination, epi-dark-field illumination, epi-polarized light, and epi-fluorescence. The article also provides information on transmitted light microscopy.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006916
EISBN: 978-1-62708-395-9
.... The next step involves impregnating (or infusing) the resin into the fiber matrix, which may include woven fibers (glass cloth or woven carbon fiber) or unidirectional fiber tows. To achieve good fiber wetting, the impregnation process needs to be carefully controlled. Some prepregs are made using a hot...
Abstract
This article focuses on manufacturing-related failures of injection-molded plastic parts, although the concepts apply to all plastic manufacturing processes It provides detailed examples of failures due to improper material handling, drying, mixing of additives, and molecular packing and orientation. It also presents examples of failures stemming from material degradation improper use of metal inserts, weak weld lines, insufficient curing of thermosets, and inadequate mixing and impregnation in the case of thermoset composites.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.9781627082006
EISBN: 978-1-62708-200-6
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003068
EISBN: 978-1-62708-200-6
... pressure in a medium to the rate of alternating flow of between the catalyst and the resin (usually in the polym- the medium through a specified surface due to the abbesive. A material that resists adhesion. A film or erizing of resins or vulcanization of rubbers). Also sound wave. coating applied...
Abstract
This article is a compilation of definitions for terms related to engineering materials, including plastics, elastomers, polymer-matrix composites, adhesives and sealants, ceramics, ceramic-matrix composites, glasses, and carbon-carbon composites.
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