Thermal analysis provides a powerful tool for researchers and engineers in determining both unknown and reproducible behavioral properties of polymer molecules. This article covers the thermal analysis and thermal properties of engineering plastics with respect to chemical composition, chain configuration, conformation of the base polymers, processing of the base polymers with or without additives; and the response to chemical, physical, and mechanical stresses of base polymers as unfilled, shaped articles or as components of composite structures. It also describes thermal analysis techniques, including differential scanning calorimetry, thermogravimetric analysis, thermomechanical analysis, and rheological analysis. This article also summarizes the basic thermal properties used in the application of engineering plastics, such as thermal conductivity, temperature resistance, thermal expansion, specific heat, and the determination of glass transition temperatures. It concludes with a discussion of the thermal and related properties of nine thermostat resin systems divided into three groups by low, medium, and high service temperature capabilities.

This article discusses slurry molding that encompasses two distinct processes: plaster molding and ceramic molding. Plaster mold casting is a specialized casting process used to produce nonferrous castings that have greater dimensional accuracy, smoother surfaces, and more finely reproduced detail. The article describes three generally recognized plaster mold processes, namely, conventional plaster mold casting, the Antioch process, foamed plaster process. Ceramic molding techniques are based on processes that employ permanent patterns and fine-grained zircon and calcined, high-alumina mullite slurries for molding. The Shaw process and the proprietary Unicast processes are also discussed.

This article provides an overview of the fundamentals of tribology. It describes the advantages, disadvantages, and applications of pin-on-disk method, which is the most commonly used configuration for testing biomaterials and for the reproducible measurement of friction and wear. The article illustrates practical tribocorrosion setup that allows the user to perform wear tests in corrosive environments under well-defined electrochemical conditions and at controlled temperature. It describes the effect of changes in electrical contact resistance on tribological mode. The article discusses various in vivo environmental conditions in tribological tests. Some typical examples of biomaterials testing are also provided.

Electroforming is the process by which articles or shapes can be exactly reproduced by electrodeposition on a mandrel or form that is later removed, leaving a precise duplicate of the original. This article discusses electroforming applications, and explains electroforming of nickel, cobalt, iron, and copper, providing information on mandrel design and selection, electroforming solutions and operating variables. It discusses the significant aspects of electroforming that demand special considerations, such as metal distribution, internal deposit stress, roughness, and treeing. The article concludes with an overview of alloy electroforming.

Hardenability is usually the single most important factor in the selection of steel for heat-treated parts. The hardenability of steel is best assessed by studying the hardening response of the steel to cooling in a standardized configuration in which a variety of cooling rates can be easily and consistently reproduced from one test to another. These include the Jominy end-quench test, the carburized hardenability test, and the surface-area-center hardenability test. This article discusses the effects of varying carbon content as well as the influence of different alloying elements on hardenability of steels. The basic information needed before a steel with adequate hardenability can be specified as the as-quenched hardness required prior to tempering to final hardness that will produce the best stress-resisting microstructure; the depth below the surface to which this hardness must extend; and the quenching medium that should be used in hardening.

Self-consistent models are a particular class of models in continuum micromechanics, that is, the field concerned with making predictions of the properties and evolution of aggregates whose single-crystal deformation behavior is known. This article provides information on the measurement and representation of textures as well as prediction of texture evolution in single-phase materials and two-phase aggregates.

Pultrusion is an automated process for manufacturing composite materials into continuous, constant cross-sectional profiles. The article provides an overview of the pultrusion process and the wide range of materials that can be used to provide a broad spectrum of composite properties. It discusses the mechanical, physical and material properties of pultruded products, and the orientation options available to utilize the properties advantageously. The article also provides guidelines for designing pultruded products.

Sheet molding compound (SMC) is a composite material - consisting of glass-fiber-reinforced polyester in a resin matrix - that’s available in sheet form for the production of compression-molded parts. This article discusses the components incorporated into the resin paste, including catalysts, fillers, thickeners, pigments, thermoplastic polymers, flame retardants, and ultraviolet absorbers, and how to optimize them to achieve the desired processing and molding characteristics and the necessary properties in the resulting parts. The article also presents several mixing techniques, including batch, batch/continuous, and continuous mixing, and describes the operations of continuous-belt and beltless machine type SMCs.

Homogenization, in a broad sense, refers to processes designed to achieve uniform distribution of solutes or phases in a given matrix. This article addresses the root cause for inhomogeneities in cast components. It is nearly standard industrial practice to homogenize alloys before thermomechanical processing. The article lists objectives of homogenization and benefits of homogenization treatments. The benefits include increased resistance to pitting corrosion, increased resistance to stress-corrosion cracking, improved ductility, and uniform precipitate distribution during subsequent aging. The article provides a schematic illustration of energy-dispersive x-ray spectroscope (EDS) scattered data of solute distributions across a dendrite due to microsegregation of chromium and molybdenum. It concludes with a section on computational modeling for simulation of microsegregation of chromium and molybdenum.

The basic quality analysis tools are cause-and-effect diagrams, check sheets, control charts, histograms, Pareto charts, scatter diagrams, and run charts. This article reviews how the basic quality analysis tools are built upon to become a more advanced set of quality tools. It describes the advanced quality tools: advanced product quality planning, failure mode and effects analysis, control planning, measurement systems analysis, lean tools, statistical process control, production viability and tryout, and Six Sigma.

This article examines how cellular automaton (CA) can be applied to the simulation of static and dynamic recrystallization. It describes the steps involved in the CA simulation of recrystallization. These include defining the CA framework, generating the initial microstructure, distributing nuclei of recrystallized grains, growing the recrystallized grains, and updating the dislocation density. The article concludes with information on the developments in CA simulations.

Electrical resistance alloys used to control or regulate electrical properties are called resistance alloys, and those used to generate heat are referred to as heating alloys. This article covers both alloy types, describing the construction and use of resistors as well as heating elements. It also discusses soldering and joining methods, sensitivity and stability factors, and various design coefficients. In addition, it provides a detailed account of the properties and applications of thermostat metals and discusses the design of resistance heaters and their operating ranges.

Ion implantation involves the bombardment of a solid material with medium-to-high-energy ionized atoms and offers the ability to alloy virtually any elemental species into the near-surface region of any substrate. This article describes the fundamentals of the ion implantation process and discusses the advantages, limitations, and applications of ion implantation. It also reviews a typical medium current semiconductor implanter adapted for implantation of metals with the aid of illustrations.

This article focuses on the testing and typical corrosion behavior of coating-substrate systems in aqueous solutions and humid aggressive atmospheres. It includes a short review of the fundamentals of corrosion, followed by a discussion of specific system behavior, electrochemical and laboratory accelerated tests, and simulated service tests. The article also contains examples of different types of corrosion damage and presents guidelines for improving corrosion resistance.

This article summarizes the types of hot working simulation tests such as hot tension, compression, and torsion testing used in the assessment of workability. It illustrates the use of hot torsion testing for the optimization of hot working processes. The article concludes with information on some hot torsion application examples.

This article provides a brief account of glow discharge mass spectrometry (GDMS) for direct determination of trace elements in solid samples and for fast depth profiling in a great variety of innovative materials. It begins by describing the general principles of GDMS. This is followed by a discussion on the various components of a GDMS system as well as commercial GDMS instruments. A description of processes involved in specimen preparation and cleaning in GDMS is then presented. Various problems pertinent to multielemental calibrations in GDMS are discussed along with measures to overcome them. The article further provides information on the processes involved in the analytical setup of parameters in GDMS, covering the steps involved in the analysis of GDMS data. It ends with a section on the application and interpretation of GDMS in the metals industry.

Casting can be done with either expendable molds for one-time use or permanent molds for reuse many times. This article lists various methods used to fabricate expendable molds from permanent patterns. The methods include molding of sand with clay, inorganic binders, or organic resins; shell molding of sand with a thin resin-bonded shell; no-bond vacuum molding of sand; plaster-mold casting; ceramic-mold casting; rammed graphite molding; and magnetic (no-bond) molding of ferrous shot. The article tabulates a general comparison of casting methods and discusses the basic requirements of foundry molds.

The Replicast process is developed to overcome the formation of lustrous carbon defects and carbon pickup observed in conventional evaporative pattern casting processes. This article provides a discussion on the pattern production, process capabilities, advantages, and limitations of Replicast process.

This article begins with a list of the factors that influence the properties of physical vapor deposited films. It describes the steps involved in ion plating, namely, surface preparation, nucleation, interface formation, and film growth. The article discusses the factors influencing the properties of ion-plated films. The sources of potential applied on substrate surface, bombarding species, and depositing species are addressed. The article also provides information on the parameters that influence bombardment. It concludes with a discussion on the advantages, limitations, and applications of ion plating.

X-ray diffraction (XRD) residual-stress analysis is an essential tool for failure analysis. This article focuses primarily on what the analyst should know about applying XRD residual-stress measurement techniques to failure analysis. Discussions are extended to the description of ways in which XRD can be applied to the characterization of residual stresses in a component or assembly and to the subsequent evaluation of corrective actions that alter the residual-stress state of a component for the purposes of preventing, minimizing, or eradicating the contribution of residual stress to premature failures. The article presents a practical approach to sample selection and specimen preparation, measurement location selection, and measurement depth selection; measurement validation is outlined as well. A number of case studies and examples are cited. The article also briefly summarizes the theory of XRD analysis and describes advances in equipment capability.